A carbon fiber mat is a sheet composed of intercrossing short carbon fibers,which has more stable and lower electrical resistivity compared with dispersed short carbon fiber mixed in cement.Thereby carbon fiber mat ce...A carbon fiber mat is a sheet composed of intercrossing short carbon fibers,which has more stable and lower electrical resistivity compared with dispersed short carbon fiber mixed in cement.Thereby carbon fiber mat cement could exhibit obvious electro-thermal effect.When electrified,the temperature of composite structures made up of cement mortar and carbon fiber mat will rise rapidly.If the temperature field is not uniform,temperature difference will cause structures to deform,which can be used to adjust the deformation of structures.The temperature field and deformation response driven by the electro-thermal effects of a type of carbon fiber mat cement beams are studied.Firstly,the temperature and deformation responses are studied using theories of thermal conduction and elasticity.Secondly,experimental results are given to verify the theoretical solution.These two parts lay the foundation for temperature and deformation adjustment.展开更多
A type of crank beam electro-thermal micro actuator was prescribed. Mechanical model of the actuator was established, and the static characteristic was analyzed.Comparing the theoretical analysis with experimental dat...A type of crank beam electro-thermal micro actuator was prescribed. Mechanical model of the actuator was established, and the static characteristic was analyzed.Comparing the theoretical analysis with experimental data, it is found that the thermodynamic character of material in micro actuator has a different variable regularity contrasted to that used in macro scale machines. It is the micro scale effect that results in the deviation between the simulating result and experimental results. The thermodynamic expression of polysilicon, which was fitted by means of the experimental data concerned, was used to modify the mechanical model. The modified model, in which the micro scale thermodynamic characteristic was considered, was more reasonable and could make the optimal design and control strategies analyzing the straight-line micro actuator more feasible.展开更多
Electro-thermal explosion directional spraying was used to prepare the stellite coating on substrate of the AISI 1045 steel. The morphologies of cross-section and worn scar, porosity, distribution of elements, micro- ...Electro-thermal explosion directional spraying was used to prepare the stellite coating on substrate of the AISI 1045 steel. The morphologies of cross-section and worn scar, porosity, distribution of elements, micro- hardness and wear resistance of the coating were determined by means of SEM, EDAX, micro-hardness tester and sliding wear tester. Because of the compact construction, good bonding and high hardness, the coating is characterized by good wear resistance. The results show that the mainly failure mode of the stellite coating is micro- plowing.展开更多
In the present paper,444 patients with vulvar leukoplasia were treated by selectingacupoints in the local area and along the meridian plus Qugu(CV 2)and Huiyin(CV 1)and usingelectro-thermal needling.The total effe...In the present paper,444 patients with vulvar leukoplasia were treated by selectingacupoints in the local area and along the meridian plus Qugu(CV 2)and Huiyin(CV 1)and usingelectro-thermal needling.The total effective rate was up to 100.0%and the cure rate 87.3%.Theelectro-thermal effect directly acted on the affected area but strengthened the immunologic function ofthe whole body and raised the content of serum copper.展开更多
98 patients with sciatica are treated.by stimubting acupoints using a self-made electro-thermal moxibustion instrument.Results show that 82 cases arecured,8 improved and 5 effective,with the total effective rate of 9...98 patients with sciatica are treated.by stimubting acupoints using a self-made electro-thermal moxibustion instrument.Results show that 82 cases arecured,8 improved and 5 effective,with the total effective rate of 96.9%.The temperature relesed from this instrument is adjustable.The electro-thermal moxibustion therapy is short in treatment duration and rapid in taking effect.Ithas no needling-induced pain and no side-effects,and is accepted preferably by patients.展开更多
As a new spraying technology used in the remanufacturing engineering, electro-thermal explosion spraying holds a lot of advantages. Electro-thermal explosion spraying coating aliquation phenomena are reduced and non-c...As a new spraying technology used in the remanufacturing engineering, electro-thermal explosion spraying holds a lot of advantages. Electro-thermal explosion spraying coating aliquation phenomena are reduced and non-crystal, micro-crystal and millimicron-crystal and other microstructure are formed. The corrosion-resistance ability of electro-thermal explosion spraying coating in high temperature environment was surveyed respectively. SEM equipped with EDS was employed to analyze the microstructure of spraying coating before and after corrosion. The corrosion-resistance mechanism of the spraying coating was discussed.展开更多
With surface- and bulk-micromachining, an 8 × 8 mirrors array is designed, fabricated and tested, which is based on electro-thermal actuators and can be addressed individually. The micromirror is square shaped, 4...With surface- and bulk-micromachining, an 8 × 8 mirrors array is designed, fabricated and tested, which is based on electro-thermal actuators and can be addressed individually. The micromirror is square shaped, 4-corner-actuated. Its dimension is 200 μm × 200 μm. The substrate below it is caved away to ensure a tilt at an angle as large as possible. To protect the etch-sensitive features on the front side of the wafer undamaged during wet deep silicon etch on the backside, the wax protective coating process is used. Mirror actuated by powering an alternative pair of heaters will tilt in 2-DOF. If its 4 cantilevers/heaters are powered synchronously, it will move in a piston mode. The effective arrays are more than 80% out of the three finished wafers. When the ramp voltage frequency applied to a pair of neighboring cantilevers is 5 Hz at 10 V, the average tilting angle can be ± 8°.展开更多
Carbon fiber-reinforced silicon carbonitride ceramic matrix composites (C/SiCN) were prepared by rapid electro-thermal pyrolysis CVD using liquid polymer hexamethyldisilazane (HMDS, (CH3)3SiNHSi(CH3)3) as prec...Carbon fiber-reinforced silicon carbonitride ceramic matrix composites (C/SiCN) were prepared by rapid electro-thermal pyrolysis CVD using liquid polymer hexamethyldisilazane (HMDS, (CH3)3SiNHSi(CH3)3) as precursor. Microstructure morphology and production technique of C/SiCN composites were investigated. Scanning electron microscopy and transmission electron microscopy were respectively employed to characterize microstructures of the as-received C/SiCN composites samples. The high temperature pyrolysis of HMDS results in destruction of molecular chain, fracture of bonds, as well as liquid-gas-solid conversion from polymer to ceramic. Microstructures observation indicates that there is a high degree of coalescence between SiCN matrix and C fiber. The deposition model of liquid precursor electro-thermal pyrolysis CVD is different from that of gas precursor isothermal chemical vapor infiltration. Rapid liquid flow and slow gas diffusion are key factors for the difference of two methods. Preparation of rapid electro-thermal pyrolysis CVD consists of four steps including liquid polymer infiltration, polymer pyrolysis, rapid deposition of pyrolyzed substances and rapid densification, respectively.展开更多
The fuzzy numerical value analysis method is adopted for the first time, which solves the problem of nanometer electro-thermal in filming process, The key technique is embodied by controlling the time distribution, te...The fuzzy numerical value analysis method is adopted for the first time, which solves the problem of nanometer electro-thermal in filming process, The key technique is embodied by controlling the time distribution, temperature and press in the filming process. The concrete technique of filming is showed by establishing the fuzzy mumbership function of above three indexes, which improves the precision of the materials of nanometer electro-thermal in hot-working. At the same time, the principles of the fuzzy relationship mapping inversion (FRMI) is put forward, Therefore, the standardization and continuity can be met.展开更多
A static security assessment approach considering electro-thermal coupling of transmission lines is proposed in this paper. Combined with the dynamic thermal rating technology and energy forecasting, the approach can ...A static security assessment approach considering electro-thermal coupling of transmission lines is proposed in this paper. Combined with the dynamic thermal rating technology and energy forecasting, the approach can track both the electrical variables and transmission lines’ temperature varying trajectory under anticipated contingencies. Accordingly, it identifies the serious contingencies by transmission lines’ temperature violation rather than its power flow, in this case the time margin of temperature rising under each serious contingency can be provided to operators as warning information and some unnecessary security control can also be avoided. Finally, numerical simulations are carried out to testify the validity of the proposed approach.展开更多
In recent years, Combined electro-thermal system has developed rapidly. In order to provide the initial data for the analysis of the combined electro-thermal system, a practical energy flow calculation method for the ...In recent years, Combined electro-thermal system has developed rapidly. In order to provide the initial data for the analysis of the combined electro-thermal system, a practical energy flow calculation method for the combined electro-thermal system is proposed in this paper. Based on the detailed analysis of the topology structure of the heating network and its hydraulic and thermodynamic model, the forward-backward sweep method for the heat flow of the heating network is established, which is more suitable for the actual radial heating network. The electric and thermal coupling model for heating source, such as thermoelectric unit and electric boiler is established, and the heat flow of heating network and the power flow of power grid are calculated orderly, thus a fast calculation method for the combined electro-thermal system is formed. What’s more, a combined electro-thermal system with two-stage peak-shaving electric boiler is used as the example system. This paper validates the effectiveness and rapidity of this method through the example system, and analyzes the influence for the energy flow of combined electro-thermal system caused by the operating parameters such as the installation location of electric boiler, the outlet water temperature of heat source and the outlet flow rate, etc.展开更多
A polycrystalline dense Ti3SiC2 based ceramic material has been produced by several techniques. The effect of addition of TiC and SiC is also studied. The Ti3SiC2 material shows extraordinary electrical, thermal and m...A polycrystalline dense Ti3SiC2 based ceramic material has been produced by several techniques. The effect of addition of TiC and SiC is also studied. The Ti3SiC2 material shows extraordinary electrical, thermal and mechanical properties. Furthermore, it shows a damage tolerance capability and oxidation resistance. In this work, we have synthesized Ti3SiC2 by electro-thermal explosion chemical reaction (ETE) with high current density (900 Amperes/a.u) followed by uniaxial pressure. The structural properties of the as-prepared materials are studied by x-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive x-ray spectroscopy (EDX) techniques. The chemical cartography, imaging and electronic properties are investigated using Ultra-STEM and electron high energy loss resolution spectroscopy (EELS) techniques, respectively. The surface of Ti3SiC2 is characterized by means of X-ray photoelectron spectroscopy (XPS). High resolution C 1s, Si 2p, Ti 2p, Ti 3s core level spectra are explained in terms of crystallographic and electronic structure. Valence band spectrum is performed to confirm the validity of the theoretical calculations.展开更多
Molasses can serve as a natural adhesive for plywood and particleboard.However,several disadvantages remain,including lower dimensional stability and low bonding strength compared to other adhesives.Therefore,modifica...Molasses can serve as a natural adhesive for plywood and particleboard.However,several disadvantages remain,including lower dimensional stability and low bonding strength compared to other adhesives.Therefore,modifications are needed to use molasses as an adhesive for plywood.This research aims to improve bio-based molasses(MO)adhesive for plywood using citric acid(CA)adhesive.In addition,this research aims to analyze the effect of adding citric acid and to investigate the optimum hot-pressing temperature to produce the best quality plywood.In the first stage,the molasses and citric acid were combined in a ratio of 100:0,75:25,50:50,25:75,0:100 w/w%.Then,the second stage focuses on analyzing the influences of pressing temperature based on an optimum first stage.The research demonstrated that the addition of CA altered the gelation time,solid content,viscosity,and pH of the molasses adhesives.In addition,the thermal properties of molasses adhesives were changed after mixing with citric acid.These phenomena indicate changes in characteristics,such as the curing of adhesive.Overall,the characteristics of plywood showed a steady improvement as the CA ratio increased but revealed a significant decline for the 25:75 MO-CA ratio.By raising the pressing temperature from 180℃ to 200℃,the quality of plywood was effectively improved.The plywood that was bonded using adhesives with a 50:50 MO-CA ratio exhibited superior mechanical properties and improved dimensional stability compared to the plywood bonded solely with MO.Furthermore,the optimal mechanical and physical properties resulted in plywood bonded with a 50:50 MO-CA ratio when subjected to a pressing temperature of 200℃.The Thermal and FTIR measurements revealed that CA established ester bonds with both the MO and wood veneers.In conclusion,the mechanical characteristics of plywood were improved,while maintaining its excellent dimensional stability.展开更多
In our study, we replaced traditional adhesives with compounds made with recycled plastic shopping bags in order to make hot-melt plywood using various amounts of plastic film, different hot-pressing temperatures and ...In our study, we replaced traditional adhesives with compounds made with recycled plastic shopping bags in order to make hot-melt plywood using various amounts of plastic film, different hot-pressing temperatures and hot-pressing times. All three variables have an effect on the intensity and water-resistance of plywood. The results show that the bonding strength of plywood does not increase with increasing amounts of plastic film. When the hot-pressing temperature is increased to 150℃, the bonding strength does not necessarily increase any further. At a hot-pressing time of 6 min, the bonding strength reaches a maximum, after which it will decrease. The optimum hot-pressing parameters are as follows: 100 g·m^-2 of recycled plastic, a hot-pressing temperature of 150℃ and a hot-pressing time of 6 min. This study puts forward a new idea of making use of plastic waste, which, ultimately, may solve the problem of formaldehyde emission without damaging the environment. It has enormous potential market applications.展开更多
Hem-fir plywood were exposed to two brown rot fungi, Gloeophyllum trabeum and Postia placenta, and one white rot fungus, Trametes versicolor, to investigate the effect of fungal decay on mechanical properties of plywo...Hem-fir plywood were exposed to two brown rot fungi, Gloeophyllum trabeum and Postia placenta, and one white rot fungus, Trametes versicolor, to investigate the effect of fungal decay on mechanical properties of plywood. Results showed that modulus of rupture (MOR) and modulus of elasticity (MOE) of hem-fir plywood declined significantly by inoculating fungi, and weight loss of sample had a modest decrease. The fungi also made a greater effect on MOR than on MOE. Of three fungi, Postia placenta caused a most significant weight loss, and Gloeophyllum trabeum resulted in a largest flexural properties loss. Substantial declines in MOR and MOE of hem-fir plywood were also observed when the plywood samples were stored under wet conditions over 15 weeks, even in the absence of fungal attack.展开更多
Adhesive for bamboo plywood prepared directly using lignin existing in the black liquor as a kind of material replacing phenol was proposed on the basis of the same structural properties of lignin and phenol. The resu...Adhesive for bamboo plywood prepared directly using lignin existing in the black liquor as a kind of material replacing phenol was proposed on the basis of the same structural properties of lignin and phenol. The results indicate that the reaction time of black liquor methylating is 30min, when the ratio of alkali to formaldehyde is controlled at approximately 0.20, decomposition rate of formaldehyde is the lowest and the effect of black liquor methylating is the best, the optimal molar ratio of phenol: formaldehyde to NaOH to H2O of preparing phenolic resin is 1.00 : 1.50 : 0.50 : 9.00, and the suitable viscosity is 27 - 30 Pa· s. At different mass ratios of methylated black liquor to phenolic resin, all terms of performance of black liquor phenolic resin are excellent and satisfy the requirement. All terms of performance of bamboo plywood prepared using this technique are hetter than that of excellent bamboo plywood of national criteria. Using this technique, the cost is depressed by 28.69% without altering the traditional adhesive producing technique flow, and without using additional equipment.展开更多
In order to improve the fire resistance,water resistance and wear resistance of ordinary plywood products in the wood processing industry,three composite structures of plywood products S1,S2 and S3 were designed in th...In order to improve the fire resistance,water resistance and wear resistance of ordinary plywood products in the wood processing industry,three composite structures of plywood products S1,S2 and S3 were designed in this paper,and a reasonable production process was proposed.Through the physical and mechanical properties and fire resistance testing and technical and economic analysis,the applicability of composite plywood was evaluated.The results of the study showed that the physical mechanics of the three kinds of composite structure plywood met the standard requirements,and their fire resistance was far better than that of ordinary plywood.Among them,the S1 structural board had the best overall physical and mechanical properties.The S3 structural board showed the best fire resistance,which was about 1.9 times more than that of ordinary plywood,and the added cost was the lowest.The thin cork board added to the S2 structural board had poor fire performance since the air in the cork board cavities had a certain combustion-supporting effect,which inhibited the fire resistance of high-pressure laminate(HPL)layer.Moreover,the additional cost of the S2 board was the highest,and its comprehensive performance was the worst.The S3 structural plywood product composed of HPL fireproof board with a thickness of about 1 mm in the surface layer and ordinary plywood with a thickness of about 12 mm in the core layer was the most cost-effective product,which could meet the needs of various fields such as construction,home furnishing,decoration and transportation.展开更多
The curing behavior of lignin-based phenol-formaldehyde (LPF) resin with different contents of nano-crystalline cellulose (NCC) was studied by differential scanning calorimetry (DSC) at different heating rates (5, 10 ...The curing behavior of lignin-based phenol-formaldehyde (LPF) resin with different contents of nano-crystalline cellulose (NCC) was studied by differential scanning calorimetry (DSC) at different heating rates (5, 10 and 20°C/min) and the bonding property was evaluated by the wet shear strength and wood failure of two-ply plywood panels after soaking in water (48 hours at room temperature and followed by 1-hour boiling). The test results indicated that the NCC content had little influence on the peak temperature, activation energy and the total heat of reaction of LPF resin at 5 and 10°C/min. But at 20°C/min, LPF0.00% (LPF resin without NCC) showed the highest total heat of reaction, while LPF0.25% (LPF resin containing 0.25% NCC content) and LPF0.50% (LPF resin containing 0.50% NCC content) gave the lowest value. The wet shear strength was affected by the NCC content to a certain extent. With regard to the results of one-way analysis of variance, the bonding quality could be improved by NCC and the optimum NCC content ranged from 0.25% to 0.50%. The wood failure was also affected by the NCC content, but the trend with respect to NCC content was not clear.展开更多
Larix tannin-phenol-formaldehyde (TPF) adhesive, having 60% by weight of phenol bcing replaced, was evaluated for its utilization in plywood. The kinetic characteristic of the TPF resin was investigated through differ...Larix tannin-phenol-formaldehyde (TPF) adhesive, having 60% by weight of phenol bcing replaced, was evaluated for its utilization in plywood. The kinetic characteristic of the TPF resin was investigated through differential scanning calorimetry (DSC) and the results obtained from the DSC scans show that the resin has a little bit different thermochemical behavior from that of phenol-formaldehyde (PF) resin. Two kinds of plywood panels wcre produced using the TPF adhesive in laboratory. The desired test results met the Chinese GB 9846-88 and ZB B70006-88, respectively, and the long assembly time of TPF resin in preparing plywood can be improved by mixing with the filler.All the properties of plywoods bonded with the TPF adhesive were compared with those obtaincd with synthetic PF adhesive.展开更多
A flame retardant composition was prepared by using phosphoguanidine,guanidine sulfamate,disodium octaborate tetrahydrate and dodecyl dimethyl benzyl ammonium chloride.Veneers were immersed in such flame retardant mix...A flame retardant composition was prepared by using phosphoguanidine,guanidine sulfamate,disodium octaborate tetrahydrate and dodecyl dimethyl benzyl ammonium chloride.Veneers were immersed in such flame retardant mixture to prepare plywood.The combustion characteristics and thermal stability of plywood were assessed using a cone calorimeter and TG.Results showed that:(1)High concentration and loading of flame retardant were beneficial for the fire resistance of the plywood.(2)The limiting oxygen index(LOI)and residual mass of plywood processed using the flame retardant was increased by 87.52%and 58.66%compared to those of the untreated plywood,while the average heat release rate(av-HRR),total heat release(THR),effective heat of combustion(EHC),total smoke release(TSR),CO yield(COY),CO_(2) yield(CO_(2)Y)and oxygen consumption were decreased by 44.3%,82.9%,47.0%,86.0%,89.9%,50.1%and 83.1%,respectively.(3)Treated plywood which had a low fire growth index(FGI)displayed a later combustion heat release rate peak and slower flame spread than observed for the untreated material.Combustion of treated plywood displayed a higher fire performance index(FPI),indicating a longer time to ignition.This suggests that burning structures from this material would be subject to a longer time for escape from the structure and would present lower fire risk than similar structures containing treated plywood.(4)TG results demonstrated that the presence of the flame retardant can decrease the pyrolysis temperature for hemicellulose and cellulose,change the decomposition and reaction progress for plywood degradation and promote dehydration carbonization and accelerated charformation.Moreover,the formed char was more stable than that combustion of untreated plywood.(5)The flame retardant contains nitrogen(N),phosphorus(P),boron(B),chlorine(Cl)and guanidine(Gu)compounds.The adhesive also contains N and P compounds.These substances display flame resistance and supplement each other to generate flame retardance than any one used alone.By changing the thermolysis and thermal decomposition processes,the heat release and smoke release from plywood,undergoing combustion was reduced.This controlled generation of combustible substances and promoted dehydration and carbonization to form char.As a result,the flame resistance of plywood was improved significantly.The probability of smoke asphyxia or poisoning death of those trapped in structures containing treated plywood during fire accidents can be decreased dramatically.展开更多
基金Project supported by National Natural Science Foundation of China(No.50238040).
文摘A carbon fiber mat is a sheet composed of intercrossing short carbon fibers,which has more stable and lower electrical resistivity compared with dispersed short carbon fiber mixed in cement.Thereby carbon fiber mat cement could exhibit obvious electro-thermal effect.When electrified,the temperature of composite structures made up of cement mortar and carbon fiber mat will rise rapidly.If the temperature field is not uniform,temperature difference will cause structures to deform,which can be used to adjust the deformation of structures.The temperature field and deformation response driven by the electro-thermal effects of a type of carbon fiber mat cement beams are studied.Firstly,the temperature and deformation responses are studied using theories of thermal conduction and elasticity.Secondly,experimental results are given to verify the theoretical solution.These two parts lay the foundation for temperature and deformation adjustment.
文摘A type of crank beam electro-thermal micro actuator was prescribed. Mechanical model of the actuator was established, and the static characteristic was analyzed.Comparing the theoretical analysis with experimental data, it is found that the thermodynamic character of material in micro actuator has a different variable regularity contrasted to that used in macro scale machines. It is the micro scale effect that results in the deviation between the simulating result and experimental results. The thermodynamic expression of polysilicon, which was fitted by means of the experimental data concerned, was used to modify the mechanical model. The modified model, in which the micro scale thermodynamic characteristic was considered, was more reasonable and could make the optimal design and control strategies analyzing the straight-line micro actuator more feasible.
文摘Electro-thermal explosion directional spraying was used to prepare the stellite coating on substrate of the AISI 1045 steel. The morphologies of cross-section and worn scar, porosity, distribution of elements, micro- hardness and wear resistance of the coating were determined by means of SEM, EDAX, micro-hardness tester and sliding wear tester. Because of the compact construction, good bonding and high hardness, the coating is characterized by good wear resistance. The results show that the mainly failure mode of the stellite coating is micro- plowing.
文摘In the present paper,444 patients with vulvar leukoplasia were treated by selectingacupoints in the local area and along the meridian plus Qugu(CV 2)and Huiyin(CV 1)and usingelectro-thermal needling.The total effective rate was up to 100.0%and the cure rate 87.3%.Theelectro-thermal effect directly acted on the affected area but strengthened the immunologic function ofthe whole body and raised the content of serum copper.
文摘98 patients with sciatica are treated.by stimubting acupoints using a self-made electro-thermal moxibustion instrument.Results show that 82 cases arecured,8 improved and 5 effective,with the total effective rate of 96.9%.The temperature relesed from this instrument is adjustable.The electro-thermal moxibustion therapy is short in treatment duration and rapid in taking effect.Ithas no needling-induced pain and no side-effects,and is accepted preferably by patients.
文摘As a new spraying technology used in the remanufacturing engineering, electro-thermal explosion spraying holds a lot of advantages. Electro-thermal explosion spraying coating aliquation phenomena are reduced and non-crystal, micro-crystal and millimicron-crystal and other microstructure are formed. The corrosion-resistance ability of electro-thermal explosion spraying coating in high temperature environment was surveyed respectively. SEM equipped with EDS was employed to analyze the microstructure of spraying coating before and after corrosion. The corrosion-resistance mechanism of the spraying coating was discussed.
文摘With surface- and bulk-micromachining, an 8 × 8 mirrors array is designed, fabricated and tested, which is based on electro-thermal actuators and can be addressed individually. The micromirror is square shaped, 4-corner-actuated. Its dimension is 200 μm × 200 μm. The substrate below it is caved away to ensure a tilt at an angle as large as possible. To protect the etch-sensitive features on the front side of the wafer undamaged during wet deep silicon etch on the backside, the wax protective coating process is used. Mirror actuated by powering an alternative pair of heaters will tilt in 2-DOF. If its 4 cantilevers/heaters are powered synchronously, it will move in a piston mode. The effective arrays are more than 80% out of the three finished wafers. When the ramp voltage frequency applied to a pair of neighboring cantilevers is 5 Hz at 10 V, the average tilting angle can be ± 8°.
基金Funded by the National Natural Science Foundation of China(No.50772089)the Program of Introducing Talents of Discipline in the Project of Advanced Materials and their Forming Technology(B08040)
文摘Carbon fiber-reinforced silicon carbonitride ceramic matrix composites (C/SiCN) were prepared by rapid electro-thermal pyrolysis CVD using liquid polymer hexamethyldisilazane (HMDS, (CH3)3SiNHSi(CH3)3) as precursor. Microstructure morphology and production technique of C/SiCN composites were investigated. Scanning electron microscopy and transmission electron microscopy were respectively employed to characterize microstructures of the as-received C/SiCN composites samples. The high temperature pyrolysis of HMDS results in destruction of molecular chain, fracture of bonds, as well as liquid-gas-solid conversion from polymer to ceramic. Microstructures observation indicates that there is a high degree of coalescence between SiCN matrix and C fiber. The deposition model of liquid precursor electro-thermal pyrolysis CVD is different from that of gas precursor isothermal chemical vapor infiltration. Rapid liquid flow and slow gas diffusion are key factors for the difference of two methods. Preparation of rapid electro-thermal pyrolysis CVD consists of four steps including liquid polymer infiltration, polymer pyrolysis, rapid deposition of pyrolyzed substances and rapid densification, respectively.
文摘The fuzzy numerical value analysis method is adopted for the first time, which solves the problem of nanometer electro-thermal in filming process, The key technique is embodied by controlling the time distribution, temperature and press in the filming process. The concrete technique of filming is showed by establishing the fuzzy mumbership function of above three indexes, which improves the precision of the materials of nanometer electro-thermal in hot-working. At the same time, the principles of the fuzzy relationship mapping inversion (FRMI) is put forward, Therefore, the standardization and continuity can be met.
文摘A static security assessment approach considering electro-thermal coupling of transmission lines is proposed in this paper. Combined with the dynamic thermal rating technology and energy forecasting, the approach can track both the electrical variables and transmission lines’ temperature varying trajectory under anticipated contingencies. Accordingly, it identifies the serious contingencies by transmission lines’ temperature violation rather than its power flow, in this case the time margin of temperature rising under each serious contingency can be provided to operators as warning information and some unnecessary security control can also be avoided. Finally, numerical simulations are carried out to testify the validity of the proposed approach.
文摘In recent years, Combined electro-thermal system has developed rapidly. In order to provide the initial data for the analysis of the combined electro-thermal system, a practical energy flow calculation method for the combined electro-thermal system is proposed in this paper. Based on the detailed analysis of the topology structure of the heating network and its hydraulic and thermodynamic model, the forward-backward sweep method for the heat flow of the heating network is established, which is more suitable for the actual radial heating network. The electric and thermal coupling model for heating source, such as thermoelectric unit and electric boiler is established, and the heat flow of heating network and the power flow of power grid are calculated orderly, thus a fast calculation method for the combined electro-thermal system is formed. What’s more, a combined electro-thermal system with two-stage peak-shaving electric boiler is used as the example system. This paper validates the effectiveness and rapidity of this method through the example system, and analyzes the influence for the energy flow of combined electro-thermal system caused by the operating parameters such as the installation location of electric boiler, the outlet water temperature of heat source and the outlet flow rate, etc.
文摘A polycrystalline dense Ti3SiC2 based ceramic material has been produced by several techniques. The effect of addition of TiC and SiC is also studied. The Ti3SiC2 material shows extraordinary electrical, thermal and mechanical properties. Furthermore, it shows a damage tolerance capability and oxidation resistance. In this work, we have synthesized Ti3SiC2 by electro-thermal explosion chemical reaction (ETE) with high current density (900 Amperes/a.u) followed by uniaxial pressure. The structural properties of the as-prepared materials are studied by x-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive x-ray spectroscopy (EDX) techniques. The chemical cartography, imaging and electronic properties are investigated using Ultra-STEM and electron high energy loss resolution spectroscopy (EELS) techniques, respectively. The surface of Ti3SiC2 is characterized by means of X-ray photoelectron spectroscopy (XPS). High resolution C 1s, Si 2p, Ti 2p, Ti 3s core level spectra are explained in terms of crystallographic and electronic structure. Valence band spectrum is performed to confirm the validity of the theoretical calculations.
基金funded by Riset dan Inovasi untuk Indonesia Maju(RIIM)National Riset and Innovation Agency(Grant Numbers:4/IV/KS/05/2023 and 13955/IT3/PT.01.03/P/B/2023)Research Program by Research Organization of Nanotechnology and Materials,National Research and Innovation Agency(Grant Number 20/III.10/HK/2024).
文摘Molasses can serve as a natural adhesive for plywood and particleboard.However,several disadvantages remain,including lower dimensional stability and low bonding strength compared to other adhesives.Therefore,modifications are needed to use molasses as an adhesive for plywood.This research aims to improve bio-based molasses(MO)adhesive for plywood using citric acid(CA)adhesive.In addition,this research aims to analyze the effect of adding citric acid and to investigate the optimum hot-pressing temperature to produce the best quality plywood.In the first stage,the molasses and citric acid were combined in a ratio of 100:0,75:25,50:50,25:75,0:100 w/w%.Then,the second stage focuses on analyzing the influences of pressing temperature based on an optimum first stage.The research demonstrated that the addition of CA altered the gelation time,solid content,viscosity,and pH of the molasses adhesives.In addition,the thermal properties of molasses adhesives were changed after mixing with citric acid.These phenomena indicate changes in characteristics,such as the curing of adhesive.Overall,the characteristics of plywood showed a steady improvement as the CA ratio increased but revealed a significant decline for the 25:75 MO-CA ratio.By raising the pressing temperature from 180℃ to 200℃,the quality of plywood was effectively improved.The plywood that was bonded using adhesives with a 50:50 MO-CA ratio exhibited superior mechanical properties and improved dimensional stability compared to the plywood bonded solely with MO.Furthermore,the optimal mechanical and physical properties resulted in plywood bonded with a 50:50 MO-CA ratio when subjected to a pressing temperature of 200℃.The Thermal and FTIR measurements revealed that CA established ester bonds with both the MO and wood veneers.In conclusion,the mechanical characteristics of plywood were improved,while maintaining its excellent dimensional stability.
基金supported by the National Natural Science Foundation of China (Grant No.31070501)Beijing Scientific Research and Base Construction Project in 2010 and the College Student Research Training Plan in Beijing Forestry University (No.200705005)
文摘In our study, we replaced traditional adhesives with compounds made with recycled plastic shopping bags in order to make hot-melt plywood using various amounts of plastic film, different hot-pressing temperatures and hot-pressing times. All three variables have an effect on the intensity and water-resistance of plywood. The results show that the bonding strength of plywood does not increase with increasing amounts of plastic film. When the hot-pressing temperature is increased to 150℃, the bonding strength does not necessarily increase any further. At a hot-pressing time of 6 min, the bonding strength reaches a maximum, after which it will decrease. The optimum hot-pressing parameters are as follows: 100 g·m^-2 of recycled plastic, a hot-pressing temperature of 150℃ and a hot-pressing time of 6 min. This study puts forward a new idea of making use of plastic waste, which, ultimately, may solve the problem of formaldehyde emission without damaging the environment. It has enormous potential market applications.
基金This research was supported by Forest Research Labora-tory, Oregon State University
文摘Hem-fir plywood were exposed to two brown rot fungi, Gloeophyllum trabeum and Postia placenta, and one white rot fungus, Trametes versicolor, to investigate the effect of fungal decay on mechanical properties of plywood. Results showed that modulus of rupture (MOR) and modulus of elasticity (MOE) of hem-fir plywood declined significantly by inoculating fungi, and weight loss of sample had a modest decrease. The fungi also made a greater effect on MOR than on MOE. Of three fungi, Postia placenta caused a most significant weight loss, and Gloeophyllum trabeum resulted in a largest flexural properties loss. Substantial declines in MOR and MOE of hem-fir plywood were also observed when the plywood samples were stored under wet conditions over 15 weeks, even in the absence of fungal attack.
文摘Adhesive for bamboo plywood prepared directly using lignin existing in the black liquor as a kind of material replacing phenol was proposed on the basis of the same structural properties of lignin and phenol. The results indicate that the reaction time of black liquor methylating is 30min, when the ratio of alkali to formaldehyde is controlled at approximately 0.20, decomposition rate of formaldehyde is the lowest and the effect of black liquor methylating is the best, the optimal molar ratio of phenol: formaldehyde to NaOH to H2O of preparing phenolic resin is 1.00 : 1.50 : 0.50 : 9.00, and the suitable viscosity is 27 - 30 Pa· s. At different mass ratios of methylated black liquor to phenolic resin, all terms of performance of black liquor phenolic resin are excellent and satisfy the requirement. All terms of performance of bamboo plywood prepared using this technique are hetter than that of excellent bamboo plywood of national criteria. Using this technique, the cost is depressed by 28.69% without altering the traditional adhesive producing technique flow, and without using additional equipment.
基金This work was supported by the 2020 Jiangsu Provincial Department of Science and Technology Policy Guidance Category(North Jiangsu Science and Technology Special SZ-L YG202014).
文摘In order to improve the fire resistance,water resistance and wear resistance of ordinary plywood products in the wood processing industry,three composite structures of plywood products S1,S2 and S3 were designed in this paper,and a reasonable production process was proposed.Through the physical and mechanical properties and fire resistance testing and technical and economic analysis,the applicability of composite plywood was evaluated.The results of the study showed that the physical mechanics of the three kinds of composite structure plywood met the standard requirements,and their fire resistance was far better than that of ordinary plywood.Among them,the S1 structural board had the best overall physical and mechanical properties.The S3 structural board showed the best fire resistance,which was about 1.9 times more than that of ordinary plywood,and the added cost was the lowest.The thin cork board added to the S2 structural board had poor fire performance since the air in the cork board cavities had a certain combustion-supporting effect,which inhibited the fire resistance of high-pressure laminate(HPL)layer.Moreover,the additional cost of the S2 board was the highest,and its comprehensive performance was the worst.The S3 structural plywood product composed of HPL fireproof board with a thickness of about 1 mm in the surface layer and ordinary plywood with a thickness of about 12 mm in the core layer was the most cost-effective product,which could meet the needs of various fields such as construction,home furnishing,decoration and transportation.
文摘The curing behavior of lignin-based phenol-formaldehyde (LPF) resin with different contents of nano-crystalline cellulose (NCC) was studied by differential scanning calorimetry (DSC) at different heating rates (5, 10 and 20°C/min) and the bonding property was evaluated by the wet shear strength and wood failure of two-ply plywood panels after soaking in water (48 hours at room temperature and followed by 1-hour boiling). The test results indicated that the NCC content had little influence on the peak temperature, activation energy and the total heat of reaction of LPF resin at 5 and 10°C/min. But at 20°C/min, LPF0.00% (LPF resin without NCC) showed the highest total heat of reaction, while LPF0.25% (LPF resin containing 0.25% NCC content) and LPF0.50% (LPF resin containing 0.50% NCC content) gave the lowest value. The wet shear strength was affected by the NCC content to a certain extent. With regard to the results of one-way analysis of variance, the bonding quality could be improved by NCC and the optimum NCC content ranged from 0.25% to 0.50%. The wood failure was also affected by the NCC content, but the trend with respect to NCC content was not clear.
文摘Larix tannin-phenol-formaldehyde (TPF) adhesive, having 60% by weight of phenol bcing replaced, was evaluated for its utilization in plywood. The kinetic characteristic of the TPF resin was investigated through differential scanning calorimetry (DSC) and the results obtained from the DSC scans show that the resin has a little bit different thermochemical behavior from that of phenol-formaldehyde (PF) resin. Two kinds of plywood panels wcre produced using the TPF adhesive in laboratory. The desired test results met the Chinese GB 9846-88 and ZB B70006-88, respectively, and the long assembly time of TPF resin in preparing plywood can be improved by mixing with the filler.All the properties of plywoods bonded with the TPF adhesive were compared with those obtaincd with synthetic PF adhesive.
基金This work was supported by Science-technology Support Foundation of Guizhou Province of China(Nos.[2019]2308,[2020]1Y125,NY[2015]3027,and ZK[2021]162)National Natural Science Foundation of China(No.31800481)+1 种基金Forestry Department Foundation of Guizhou Province of China(No.[2018]13)Cultivation Project of Guizhou University of China(No.[2019]37).
文摘A flame retardant composition was prepared by using phosphoguanidine,guanidine sulfamate,disodium octaborate tetrahydrate and dodecyl dimethyl benzyl ammonium chloride.Veneers were immersed in such flame retardant mixture to prepare plywood.The combustion characteristics and thermal stability of plywood were assessed using a cone calorimeter and TG.Results showed that:(1)High concentration and loading of flame retardant were beneficial for the fire resistance of the plywood.(2)The limiting oxygen index(LOI)and residual mass of plywood processed using the flame retardant was increased by 87.52%and 58.66%compared to those of the untreated plywood,while the average heat release rate(av-HRR),total heat release(THR),effective heat of combustion(EHC),total smoke release(TSR),CO yield(COY),CO_(2) yield(CO_(2)Y)and oxygen consumption were decreased by 44.3%,82.9%,47.0%,86.0%,89.9%,50.1%and 83.1%,respectively.(3)Treated plywood which had a low fire growth index(FGI)displayed a later combustion heat release rate peak and slower flame spread than observed for the untreated material.Combustion of treated plywood displayed a higher fire performance index(FPI),indicating a longer time to ignition.This suggests that burning structures from this material would be subject to a longer time for escape from the structure and would present lower fire risk than similar structures containing treated plywood.(4)TG results demonstrated that the presence of the flame retardant can decrease the pyrolysis temperature for hemicellulose and cellulose,change the decomposition and reaction progress for plywood degradation and promote dehydration carbonization and accelerated charformation.Moreover,the formed char was more stable than that combustion of untreated plywood.(5)The flame retardant contains nitrogen(N),phosphorus(P),boron(B),chlorine(Cl)and guanidine(Gu)compounds.The adhesive also contains N and P compounds.These substances display flame resistance and supplement each other to generate flame retardance than any one used alone.By changing the thermolysis and thermal decomposition processes,the heat release and smoke release from plywood,undergoing combustion was reduced.This controlled generation of combustible substances and promoted dehydration and carbonization to form char.As a result,the flame resistance of plywood was improved significantly.The probability of smoke asphyxia or poisoning death of those trapped in structures containing treated plywood during fire accidents can be decreased dramatically.