The exponentially expanded space grid was incorporated into the network approach to overcome the problem of low simulation efficiency during the simulations of electrochemical problems with stiff kinetics or wide disp...The exponentially expanded space grid was incorporated into the network approach to overcome the problem of low simulation efficiency during the simulations of electrochemical problems with stiff kinetics or wide dispersion of diffusion coefficients, resulting in an effective electrochemical simulation method: exponentially expanded grid network approach (EEGNA). The stability and accuracy of the EEGNA for the simulation of various electrode processes coupled with different types of homogeneous reactions were investigated.展开更多
A universal simulator capable of simulating virtually any user-defined electrochemical/chemical problems in one-dimensional diffusion geometry was developed based on an exponentially expanding grid modification of the...A universal simulator capable of simulating virtually any user-defined electrochemical/chemical problems in one-dimensional diffusion geometry was developed based on an exponentially expanding grid modification of the existing network approach. Some generalized reaction-diffusion governing equations of an arbitrary electrochemical/chemical process were derived, and program controlled automatic generation of the corresponding PSPICE netlist file was realized. On the basis of the above techniques, a universal simulator package was realized, which is capable of dealing with arbitrarily complex electrochemical/chemical problems with one-dimensional diffusion geometry such as planar diffusion, spherical diffusion, cylindrical diffusion and rotational disk diffusion-convection processes. The building of such a simulator is easy and thus it would be very convenient to have it updated for simulations of newly raised electrochemical problems.展开更多
文摘The exponentially expanded space grid was incorporated into the network approach to overcome the problem of low simulation efficiency during the simulations of electrochemical problems with stiff kinetics or wide dispersion of diffusion coefficients, resulting in an effective electrochemical simulation method: exponentially expanded grid network approach (EEGNA). The stability and accuracy of the EEGNA for the simulation of various electrode processes coupled with different types of homogeneous reactions were investigated.
基金Project supported by the National Natural Science Foundation of China (No. 20173054).
文摘A universal simulator capable of simulating virtually any user-defined electrochemical/chemical problems in one-dimensional diffusion geometry was developed based on an exponentially expanding grid modification of the existing network approach. Some generalized reaction-diffusion governing equations of an arbitrary electrochemical/chemical process were derived, and program controlled automatic generation of the corresponding PSPICE netlist file was realized. On the basis of the above techniques, a universal simulator package was realized, which is capable of dealing with arbitrarily complex electrochemical/chemical problems with one-dimensional diffusion geometry such as planar diffusion, spherical diffusion, cylindrical diffusion and rotational disk diffusion-convection processes. The building of such a simulator is easy and thus it would be very convenient to have it updated for simulations of newly raised electrochemical problems.
