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Flexible, Transparent and Conductive Metal Mesh Films with Ultra‑High FoM for Stretchable Heating and Electromagnetic Interference Shielding 被引量:1
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作者 Zibo Chen Shaodian Yang +9 位作者 Junhua Huang Yifan Gu Weibo Huang Shaoyong Liu Zhiqiang Lin Zhiping Zeng Yougen Hu Zimin Chen Boru Yang Xuchun Gui 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期201-213,共13页
Despite the growing demand for transparent conductive films in smart and wearable electronics for electromagnetic interference(EMI)shielding,achieving a flexible EMI shielding film,while maintaining a high transmittan... Despite the growing demand for transparent conductive films in smart and wearable electronics for electromagnetic interference(EMI)shielding,achieving a flexible EMI shielding film,while maintaining a high transmittance remains a significant challenge.Herein,a flexible,transparent,and conductive copper(Cu)metal mesh film for EMI shielding is fabricated by self-forming crackle template method and electroplating technique.The Cu mesh film shows an ultra-low sheet resistance(0.18Ω□^(-1)),high transmittance(85.8%@550 nm),and ultra-high figure of merit(>13,000).It also has satisfactory stretchability and mechanical stability,with a resistance increases of only 1.3%after 1,000 bending cycles.As a stretchable heater(ε>30%),the saturation temperature of the film can reach over 110°C within 60 s at 1.00 V applied voltage.Moreover,the metal mesh film exhibits outstanding average EMI shielding effectiveness of 40.4 dB in the X-band at the thickness of 2.5μm.As a demonstration,it is used as a transparent window for shielding the wireless communication electromagnetic waves.Therefore,the flexible and transparent conductive Cu mesh film proposed in this work provides a promising candidate for the next-generation EMI shielding applications. 展开更多
关键词 Metal mesh Transparent conductive film Stretchable heater electromagnetic interference shielding
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Layered Structural PBAT Composite Foams for Efficient Electromagnetic Interference Shielding 被引量:1
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作者 Jianming Yang Hu Wang +2 位作者 Yali Zhang Hexin Zhang Junwei Gu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期273-286,共14页
The utilization of eco-friendly,lightweight,high-efficiency and high-absorbing electromagnetic interference(EMI)shielding composites is imperative in light of the worldwide promotion of sustainable manufacturing.In th... The utilization of eco-friendly,lightweight,high-efficiency and high-absorbing electromagnetic interference(EMI)shielding composites is imperative in light of the worldwide promotion of sustainable manufacturing.In this work,magnetic poly(butyleneadipate-coterephthalate)(PBAT)microspheres were firstly synthesized via phase separation method,then PBAT composite foams with layered structure was constructed through the supercritical carbon dioxide foaming and scraping techniques.The merits of integrating ferroferric oxideloaded multi-walled carbon nanotubes(Fe3O4@MWCNTs)nanoparticles,a microcellular framework,and a highly conductive silver layer have been judiciously orchestrated within this distinctive layered configuration.Microwaves are consumed throughout the process of“absorption-reflection-reabsorption”as much as possible,which greatly declines the secondary radiation pollution.The biodegradable PBAT composite foams achieved an EMI shielding effectiveness of up to 68 dB and an absorptivity of 77%,and authenticated favorable stabilization after the tape adhesion experiment. 展开更多
关键词 electromagnetic interference shielding Layered structure Supercritical carbon dioxide foaming Poly(butyleneadipateco-terephthalate) MICROCELLULAR
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3D‑Printed Carbon‑Based Conformal Electromagnetic Interference Shielding Module for Integrated Electronics 被引量:1
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作者 Shaohong Shi Yuheng Jiang +5 位作者 Hao Ren Siwen Deng Jianping Sun Fangchao Cheng Jingjing Jing Yinghong Chen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期87-101,共15页
Electromagnetic interference shielding(EMI SE)modules are the core com-ponent of modern electronics.However,the tra-ditional metal-based SE modules always take up indispensable three-dimensional space inside electroni... Electromagnetic interference shielding(EMI SE)modules are the core com-ponent of modern electronics.However,the tra-ditional metal-based SE modules always take up indispensable three-dimensional space inside electronics,posing a major obstacle to the integra-tion of electronics.The innovation of integrating 3D-printed conformal shielding(c-SE)modules with packaging materials onto core electronics offers infinite possibilities to satisfy ideal SE func-tion without occupying additional space.Herein,the 3D printable carbon-based inks with various proportions of graphene and carbon nanotube nanoparticles are well-formulated by manipulating their rheological peculiarity.Accordingly,the free-constructed architectures with arbitrarily-customized structure and multifunctionality are created via 3D printing.In particular,the SE performance of 3D-printed frame is up to 61.4 dB,simultaneously accompanied with an ultralight architecture of 0.076 g cm^(-3) and a superhigh specific shielding of 802.4 dB cm3 g^(-1).Moreover,as a proof-of-concept,the 3D-printed c-SE module is in situ integrated into core electronics,successfully replacing the traditional metal-based module to afford multiple functions for electromagnetic compatibility and thermal dissipa-tion.Thus,this scientific innovation completely makes up the blank for assembling carbon-based c-SE modules and sheds a brilliant light on developing the next generation of high-performance shielding materials with arbitrarily-customized structure for integrated electronics. 展开更多
关键词 3D printing Carbon-based nanoparticles Conformal electromagnetic interference shielding Integrated electronics
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Liquid Metal Grid Patterned Thin Film Devices Toward Absorption‑Dominant and Strain‑Tunable Electromagnetic Interference Shielding
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作者 Yuwen Wei Priyanuj Bhuyan +9 位作者 Suk Jin Kwon Sihyun Kim Yejin Bae Mukesh Singh Duy Thanh Tran Minjeong Ha Kwang‑Un Jeong Xing Ma Byeongjin Park Sungjune Park 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第11期541-553,共13页
The demand of high-performance thin-film-shaped deformable electromagnetic interference(EMI)shielding devices is increasing for the next generation of wearable and miniaturized soft electronics.Although highly reflect... The demand of high-performance thin-film-shaped deformable electromagnetic interference(EMI)shielding devices is increasing for the next generation of wearable and miniaturized soft electronics.Although highly reflective conductive materials can effectively shield EMI,they prevent deformation of the devices owing to rigidity and generate secondary electromagnetic pollution simultaneously.Herein,soft and stretchable EMI shielding thin film devices with absorption-dominant EMI shielding behavior is presented.The devices consist of liquid metal(LM)layer and LM grid-patterned layer separated by a thin elastomeric film,fabricated by leveraging superior adhesion of aerosol-deposited LM on elastomer.The devices demonstrate high electromagnetic shielding effectiveness(SE)(SE_(T) of up to 75 dB)with low reflectance(SER of 1.5 dB at the resonant frequency)owing to EMI absorption induced by multiple internal reflection generated in the LM grid architectures.Remarkably,the excellent stretchability of the LM-based devices facilitates tunable EMI shielding abilities through grid space adjustment upon strain(resonant frequency shift from 81.3 to 71.3 GHz@33%strain)and is also capable of retaining shielding effectiveness even after multiple strain cycles.This newly explored device presents an advanced paradigm for powerful EMI shielding performance for next-generation smart electronics. 展开更多
关键词 Absorption-dominant electromagnetic interference shielding Liquid metals Soft and stretchable electronics Thin film devices Tunable electromagnetic interference shielding
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Hollow Metal-Organic Framework/MXene/Nanocellulose Composite Films for Giga/Terahertz Electromagnetic Shielding and Photothermal Conversion
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作者 Tian Mai Lei Chen +2 位作者 Pei‑Lin Wang Qi Liu Ming‑Guo Ma 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第9期161-179,共19页
With the continuous advancement of communication technology,the escalating demand for electromagnetic shielding interference(EMI)materials with multifunctional and wideband EMI performance has become urgent.Controllin... With the continuous advancement of communication technology,the escalating demand for electromagnetic shielding interference(EMI)materials with multifunctional and wideband EMI performance has become urgent.Controlling the electrical and magnetic components and designing the EMI material structure have attracted extensive interest,but remain a huge challenge.Herein,we reported the alternating electromagnetic structure composite films composed of hollow metal-organic frameworks/layered MXene/nanocellulose(HMN)by alternating vacuum-assisted filtration process.The HMN composite films exhibit excellent EMI shielding effectiveness performance in the GHz frequency(66.8 dB at Kaband)and THz frequency(114.6 dB at 0.1-4.0 THz).Besides,the HMN composite films also exhibit a high reflection loss of 39.7 dB at 0.7 THz with an effective absorption bandwidth up to 2.1 THz.Moreover,HMN composite films show remarkable photothermal conversion performance,which can reach 104.6℃under 2.0 Sun and 235.4℃under 0.8 W cm^(−2),respectively.The unique micro-and macrostructural design structures will absorb more incident electromagnetic waves via interfacial polarization/multiple scattering and produce more heat energy via the local surface plasmon resonance effect.These features make the HMN composite film a promising candidate for advanced EMI devices for future 6G communication and the protection of electronic equipment in cold environments. 展开更多
关键词 Metal-organic frameworks MXene NANOCELLULOSE electromagnetic shielding Photothermal conversion
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Trunk‑Inspired SWCNT‑Based Wrinkled Films for Highly‑Stretchable Electromagnetic Interference Shielding and Wearable Thermotherapy
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作者 Xiaofeng Gong Tianjiao Hu +8 位作者 You Zhang Yanan Zeng Ye Zhang Zhenhua Jiang Yinlong Tan Yanhong Zou Jing Wang Jiayu Dai Zengyong Chu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第11期429-444,共16页
Nowadays,the increasing electromagnetic waves generated by wearable devices are becoming an emerging issue for human health,so stretchable electromagnetic interference(EMI)shielding materials are highly demanded.Eleph... Nowadays,the increasing electromagnetic waves generated by wearable devices are becoming an emerging issue for human health,so stretchable electromagnetic interference(EMI)shielding materials are highly demanded.Elephant trunks are capable of grabbing fragile vegetation and tearing trees thanks not only to their muscles but also to their folded skins.Inspired by the wrinkled skin of the elephant trunks,herein,we propose a winkled conductive film based on single-walled carbon nanotubes(SWCNTs)for multifunctional EMI applications.The conductive film has a sandwich structure,which was prepared by coating SWCNTs on both sides of the stretched elastic latex cylindrical substrate.The shrinking-induced winkled conductive network could withstand up to 200%tensile strain.Typically,when the stretching direction is parallel to the polarization direction of the electric field,the total EMI shielding effectiveness could surprisingly increase from 38.4 to 52.7 dB at 200%tensile strain.It is mainly contributed by the increased connection of the SWCNTs.In addition,the film also has good Joule heating performance at several voltages,capable of releasing pains in injured joints.This unique property makes it possible for strain-adjustable multifunctional EMI shielding and wearable thermotherapy applications. 展开更多
关键词 electromagnetic interference shielding Single-walled carbon nanotubes WRINKLES STRETCHABLE THERMOTHERAPY
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Multifunctional MXene/Carbon Nanotube Janus Film for Electromagnetic Shielding and Infrared Shielding/Detection in Harsh Environments
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作者 Tufail Hassan Aamir Iqbal +14 位作者 Byungkwon Yoo Jun Young Jo Nilufer Cakmakci Shabbir Madad Naqvi Hyerim Kim Sungmin Jung Noushad Hussain Ujala Zafar Soo Yeong Cho Seunghwan Jeong Jaewoo Kim Jung Min Oh Sangwoon Park Youngjin Jeong Chong Min Koo 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第10期543-560,共18页
Multifunctional,flexible,and robust thin films capable of operating in demanding harsh temperature environments are crucial for various cutting-edge applications.This study presents a multifunctional Janus film integr... Multifunctional,flexible,and robust thin films capable of operating in demanding harsh temperature environments are crucial for various cutting-edge applications.This study presents a multifunctional Janus film integrating highly-crystalline Ti_(3)C_(2)T_(x) MXene and mechanically-robust carbon nanotube(CNT)film through strong hydrogen bonding.The hybrid film not only exhibits high electrical conductivity(4250 S cm^(-1)),but also demonstrates robust mechanical strength and durability in both extremely low and high temperature environments,showing exceptional resistance to thermal shock.This hybrid Janus film of 15μm thickness reveals remarkable multifunctionality,including efficient electromagnetic shielding effectiveness of 72 dB in X band frequency range,excellent infrared(IR)shielding capability with an average emissivity of 0.09(a minimal value of 0.02),superior thermal camouflage performance over a wide temperature range(−1 to 300℃)achieving a notable reduction in the radiated temperature by 243℃ against a background temperature of 300℃,and outstanding IR detection capability characterized by a 44%increase in resistance when exposed to 250 W IR radiation.This multifunctional MXene/CNT Janus film offers a feasible solution for electromagnetic shielding and IR shielding/detection under challenging conditions. 展开更多
关键词 MXene/carbon nanotube Janus film electromagnetic interference shielding Infrared shielding Thermal camouflage Infrared detection
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Self‑Assembly of Binderless MXene Aerogel for Multiple‑Scenario and Responsive Phase Change Composites with Ultrahigh Thermal Energy Storage Density and Exceptional Electromagnetic Interference Shielding
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作者 Chuanbiao Zhu Yurong Hao +8 位作者 Hao Wu Mengni Chen Bingqing Quan Shuang Liu Xinpeng Hu Shilong Liu Qinghong Ji Xiang Lu Jinping Qu 《Nano-Micro Letters》 SCIE EI CSCD 2024年第3期367-382,共16页
The severe dependence of traditional phase change materials(PCMs)on the temperature-response and lattice deficiencies in versatility cannot satisfy demand for using such materials in complex application scenarios.Here... The severe dependence of traditional phase change materials(PCMs)on the temperature-response and lattice deficiencies in versatility cannot satisfy demand for using such materials in complex application scenarios.Here,we introduced metal ions to induce the self-assembly of MXene nanosheets and achieve their ordered arrangement by combining suction filtration and rapid freezing.Subsequently,a series of MXene/K^(+)/paraffin wax(PW)phase change composites(PCCs)were obtained via vacuum impregnation in molten PW.The prepared MXene-based PCCs showed versatile applications from macroscale technologies,successfully transforming solar,electric,and magnetic energy into thermal energy stored as latent heat in the PCCs.Moreover,due to the absence of binder in the MXene-based aerogel,MK3@PW exhibits a prime solar-thermal conversion efficiency(98.4%).Notably,MK3@PW can further convert the collected heat energy into electric energy through thermoelectric equipment and realize favorable solar-thermal-electric conversion(producing 206 mV of voltage with light radiation intensity of 200 mw cm^(−2)).An excellent Joule heat performance(reaching 105℃with an input voltage of 2.5 V)and responsive magnetic-thermal conversion behavior(a charging time of 11.8 s can achieve a thermal insulation effect of 285 s)for contactless thermotherapy were also demonstrated by the MK3@PW.Specifically,as a result of the ordered arrangement of MXene nanosheet self-assembly induced by potassium ions,MK3@PW PCC exhibits a higher electromagnetic shielding efficiency value(57.7 dB)than pure MXene aerogel/PW PCC(29.8 dB)with the same MXene mass.This work presents an opportunity for the multi-scene response and practical application of PCMs that satisfy demand of next-generation multifunctional PCCs. 展开更多
关键词 Self-assembly Multiple-scenario Phase change composites Thermal energy storage electromagnetic interference shielding
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3D Printing of Periodic Porous Metamaterials for Tunable Electromagnetic Shielding Across Broad Frequencies
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作者 Qinniu Lv Zilin Peng +5 位作者 Haoran Pei Xinxing Zhang Yinghong Chen Huarong Zhang Xu Zhu Shulong Wu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第12期533-552,共20页
The new-generation electronic components require a balance between electromagnetic interference shielding efficiency and open structure factors such as ventilation and heat dissipation.In addition,realizing the tunabl... The new-generation electronic components require a balance between electromagnetic interference shielding efficiency and open structure factors such as ventilation and heat dissipation.In addition,realizing the tunable shielding of porous shields over a wide range of wavelengths is even more challenging.In this study,the well-prepared thermoplastic polyurethane/carbon nanotubes composites were used to fabricate the novel periodic porous flexible metamaterials using fused deposition modeling 3D printing.Particularly,the investigation focuses on optimization of pore geometry,size,dislocation configuration and material thickness,thus establishing a clear correlation between structural parameters and shielding property.Both experimental and simulation results have validated the superior shielding performance of hexagon derived honeycomb structure over other designs,and proposed the failure shielding size(D_(f)≈λ/8-λ/5)and critical inclined angle(θf≈43°-48°),which could be used as new benchmarks for tunable electromagnetic shielding.In addition,the proper regulation of the material thickness could remarkably enhance the maximum shielding capability(85-95 dB)and absorption coefficient A(over 0.83).The final innovative design of the porous shielding box also exhibits good shielding effectiveness across a broad frequency range(over 2.4 GHz),opening up novel pathways for individualized and diversified shielding solutions. 展开更多
关键词 Polymeric component 3D printing Tunable electromagnetic shielding Periodic porous metamaterials Honeycomb pore structure
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MXene@c-MWCNT Adhesive Silica Nanofiber Membranes Enhancing Electromagnetic Interference Shielding and Thermal Insulation Performance in Extreme Environments
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作者 Ziyuan Han Yutao Niu +11 位作者 Xuetao Shi Duo Pan Hu Liu Hua Qiu Weihua Chen Ben Bin Xu Zeinhom MEl-Bahy Hua Hou Eman Ramadan Elsharkawy Mohammed AAmin Chuntai Liu Zhanhu Guo 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第10期82-98,共17页
A lightweight flexible thermally stable composite is fabricated by com-bining silica nanofiber membranes(SNM)with MXene@c-MWCNT hybrid film.The flexible SNM with outstanding thermal insulation are prepared from tetrae... A lightweight flexible thermally stable composite is fabricated by com-bining silica nanofiber membranes(SNM)with MXene@c-MWCNT hybrid film.The flexible SNM with outstanding thermal insulation are prepared from tetraethyl orthosilicate hydrolysis and condensation by electrospinning and high-temperature calcination;the MXene@c-MWCNT_(x:y)films are prepared by vacuum filtration tech-nology.In particular,the SNM and MXene@c-MWCNT_(6:4)as one unit layer(SMC_(1))are bonded together with 5 wt%polyvinyl alcohol(PVA)solution,which exhibits low thermal conductivity(0.066 W m^(-1)K^(-1))and good electromagnetic interference(EMI)shielding performance(average EMI SE_(T),37.8 dB).With the increase in func-tional unit layer,the overall thermal insulation performance of the whole composite film(SMC_(x))remains stable,and EMI shielding performance is greatly improved,especially for SMC_(3)with three unit layers,the average EMI SET is as high as 55.4 dB.In addition,the organic combination of rigid SNM and tough MXene@c-MWCNT_(6:4)makes SMC_(x)exhibit good mechanical tensile strength.Importantly,SMC_(x)exhibit stable EMI shielding and excellent thermal insulation even in extreme heat and cold environment.Therefore,this work provides a novel design idea and important reference value for EMI shielding and thermal insulation components used in extreme environmental protection equipment in the future. 展开更多
关键词 SiO_(2)nanofiber membranes MXene@c-MWCNT Composite film Thermal insulation electromagnetic interference shielding
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Preparation and electromagnetic shielding properties of PET/rGO/SWCNT composite fabric
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作者 ZHANG Xu LIU Xuejiao YAN Yehai 《合成纤维工业》 CAS 2024年第5期58-62,68,共6页
Graphene oxide(GO)with excellent dispersion ability can assist the dispersion of single-walled carbon nanotube(SWCNT)and promote the formation of uniform and stable GO/SWCNT coating liquid.The highly conductive polyet... Graphene oxide(GO)with excellent dispersion ability can assist the dispersion of single-walled carbon nanotube(SWCNT)and promote the formation of uniform and stable GO/SWCNT coating liquid.The highly conductive polyethylene terephthalate/reduced graphene oxide/SWCNT(PET/rGO/SWCNT)electromagnetic shielding composite fabric was successfully prepared by anchoring rGO/SWCNT on PET fabric via dip-coating piror to low-temperature thermal reduction.The results showed that the carboxyl groups and hydroxyl groups formed of hydrophilic-treated PET were conducive to the formation of hydrogen bonds with that of GO,which enhanced the interaction between PET fabric and GO/SWCNT coating;the loading of GO/SWCNT increased with the number of dip-coating,the unit area loading of rGO/SWCNT in the final composite fabric was 2.7 mg/cm^(2) after 10 dip-coating cycles and thermal reduction;the PET/rGO/SWCNT composite fabric had a continuous and dense conductive network,with a conductivity of up to 41.6 S/m and the average electromagnetic interference shielding effectiveness in X-band was 22 dB;the flexible PET/rGO/SWCNT composite fabric was not only easy to process,but also exhibited excellent conductivity and shielding efficiency,showing great potential in the application of electromagnetic shielding fabrics. 展开更多
关键词 electromagnetic interference shielding graphene oxide single-walled carbon nanotubes conductive fabric thermal reduction
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Leakage Proof,Flame-Retardant,and Electromagnetic Shield Wood Morphology Genetic Composite Phase Change Materials for Solar Thermal Energy Harvesting
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作者 Yuhui Chen Yang Meng +7 位作者 Jiangyu Zhang Yuhui Xie Hua Guo Mukun He Xuetao Shi Yi Mei Xinxin Sheng Delong Xie 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第10期99-120,共22页
Phase change materials(PCMs)offer a promising solution to address the challenges posed by intermittency and fluctuations in solar thermal utilization.However,for organic solid-liquid PCMs,issues such as leakage,low th... Phase change materials(PCMs)offer a promising solution to address the challenges posed by intermittency and fluctuations in solar thermal utilization.However,for organic solid-liquid PCMs,issues such as leakage,low thermal conductivity,lack of efficient solar-thermal media,and flamma-bility have constrained their broad applications.Herein,we present an innova-tive class of versatile composite phase change materials(CPCMs)developed through a facile and environmentally friendly synthesis approach,leveraging the inherent anisotropy and unidirectional porosity of wood aerogel(nanowood)to support polyethylene glycol(PEG).The wood modification process involves the incorporation of phytic acid(PA)and MXene hybrid structure through an evaporation-induced assembly method,which could impart non-leaking PEG filling while concurrently facilitating thermal conduction,light absorption,and flame-retardant.Consequently,the as-prepared wood-based CPCMs showcase enhanced thermal conductivity(0.82 W m^(-1)K^(-1),about 4.6 times than PEG)as well as high latent heat of 135.5 kJ kg^(-1)(91.5%encapsula-tion)with thermal durability and stability throughout at least 200 heating and cooling cycles,featuring dramatic solar-thermal conversion efficiency up to 98.58%.In addition,with the synergistic effect of phytic acid and MXene,the flame-retardant performance of the CPCMs has been significantly enhanced,showing a self-extinguishing behavior.Moreover,the excellent electromagnetic shielding of 44.45 dB was endowed to the CPCMs,relieving contemporary health hazards associated with electromagnetic waves.Overall,we capitalize on the exquisite wood cell structure with unidirectional transport inherent in the development of multifunctional CPCMs,showcasing the operational principle through a proof-of-concept prototype system. 展开更多
关键词 Wood PCMs MXene Solar thermal storage and conversion FLAME-RETARDANT electromagnetic shielding
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3D Printed Integrated Gradient-Conductive MXene/CNT/Polyimide Aerogel Frames for Electromagnetic Interference Shielding with Ultra-Low Reflection 被引量:15
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作者 Tiantian Xue Yi Yang +5 位作者 Dingyi Yu Qamar Wali Zhenyu Wang Xuesong Cao Wei Fan Tianxi Liu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第3期332-345,共14页
Construction of advanced electromagnetic interference(EMI)shielding materials with miniaturized,programmable structure and low reflection are promising but challenging.Herein,an integrated transition-metal carbides/ca... Construction of advanced electromagnetic interference(EMI)shielding materials with miniaturized,programmable structure and low reflection are promising but challenging.Herein,an integrated transition-metal carbides/carbon nanotube/polyimide(gradient-conductive MXene/CNT/PI,GCMCP)aerogel frame with hierarchical porous structure and gradient-conductivity has been constructed to achieve EMI shielding with ultra-low reflection.The gradient-conductive structures are obtained by continuous 3D printing of MXene/CNT/poly(amic acid)inks with different CNT contents,where the slightly conductive top layer serves as EM absorption layer and the highly conductive bottom layer as reflection layer.In addition,the hierarchical porous structure could extend the EM dissipation path and dissipate EM by multiple reflections.Consequently,the GCMCP aerogel frames exhibit an excellent average EMI shielding efficiency(68.2 dB)and low reflection(R=0.23).Furthermore,the GCMCP aerogel frames with miniaturized and programmable structures can be used as EMI shielding gaskets and effectively block wireless power transmission,which shows a prosperous application prospect in defense industry and aerospace. 展开更多
关键词 3D printing MXene/CNT/Polyimide aerogel Gradient-conductive electromagnetic interference shielding
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Green,Sustainable Architectural Bamboo with High Light Transmission and Excellent Electromagnetic Shielding as a Candidate for Energy-Saving Buildings 被引量:6
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作者 Jing Wang Xinyu Wu +5 位作者 Yajing Wang Weiying Zhao Yue Zhao Ming Zhou Yan Wu Guangbin Ji 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第1期209-224,共16页
Currently,light-transmitting,energy-saving,and electromagnetic shielding materials are essential for reducing indoor energy consumption and improving the electromagnetic environment.Here,we developed a cellulose compo... Currently,light-transmitting,energy-saving,and electromagnetic shielding materials are essential for reducing indoor energy consumption and improving the electromagnetic environment.Here,we developed a cellulose composite with excellent optical transmittance that retained the natural shape and fiber structure of bamboo.The modified whole bamboo possessed an impressive optical transmittance of approximately 60%at 6.23 mm,illuminance of 1000 luminance(lux),water absorption stability(mass change rate less than 4%),longitudinal tensile strength(46.40 MPa),and surface properties(80.2 HD).These were attributed to not only the retention of the natural circular hollow structure of the bamboo rod on the macro,but also the complete bamboo fiber skeleton template impregnated with UV resin on the micro.Moreover,a multilayered device consisting of translucent whole bamboo,transparent bamboo sheets,and electromagnetic shielding film exhibited remarkable heat insulation and heat preservation performance as well as an electromagnetic shielding performance of 46.3 dB.The impressive optical transmittance,mechanical properties,thermal performance,and electromagnetic shielding abilities combined with the renewable and sustainable nature,as well as the fast and efficient manufacturing process,make this bamboo composite material suitable for effective application in transparent,energy-saving,and electromagnetic shielding buildings. 展开更多
关键词 electromagnetic interference shielding Biomass material TRANSMITTANCE ENERGY-SAVING BAMBOO
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Highly Ordered Thermoplastic Polyurethane/Aramid Nanofiber Conductive Foams Modulated by Kevlar Polyanion for Piezoresistive Sensing and Electromagnetic Interference Shielding 被引量:6
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作者 Kunpeng Qian Jianyu Zhou +4 位作者 Miao Miao Hongmin Wu Sineenat Thaiboonrod Jianhui Fang Xin Feng 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第6期335-352,共18页
Highly ordered and uniformly porous structure of conductive foams is a vital issue for various functional purposes such as piezoresistive sensing and electromagnetic interference(EMI) shielding. With the aids of Kevla... Highly ordered and uniformly porous structure of conductive foams is a vital issue for various functional purposes such as piezoresistive sensing and electromagnetic interference(EMI) shielding. With the aids of Kevlar polyanionic chains, thermoplastic polyurethane(TPU) foams reinforced by aramid nanofibers(ANF) with adjustable pore-size distribution were successfully obtained via a nonsolvent-induced phase separation. In this regard, the most outstanding result is the in situ formation of ANF in TPU foams after protonation of Kevlar polyanion during the NIPS process. Furthermore, in situ growth of copper nanoparticles(Cu NPs) on TPU/ANF foams was performed according to the electroless deposition by using the tiny amount of pre-blended Ti_(3)C_(2)T_(x) MXene as reducing agents. Particularly, the existence of Cu NPs layers significantly promoted the storage modulus in 2,932% increments, and the well-designed TPU/ANF/Ti_(3)C_(2)T_(x) MXene(PAM-Cu) composite foams showed distinguished compressive cycle stability. Taking virtues of the highly ordered and elastic porous architectures, the PAM-Cu foams were utilized as piezoresistive sensor exhibiting board compressive interval of 0–344.5 kPa(50% strain) with good sensitivity at 0.46 kPa^(-1). Meanwhile,the PAM-Cu foams displayed remarkable EMI shielding effectiveness at 79.09 dB in X band. This work provides an ideal strategy to fabricate highly ordered TPU foams with outstanding elastic recovery and excellent EMI shielding performance, which can be used as a promising candidate in integration of satisfactory piezoresistive sensor and EMI shielding applications for human–machine interfaces. 展开更多
关键词 Highly ordered conductive foams MXene NANOFIBER Thermoplastic Kevlar polyanion Piezoresistive sensing electromagnetic interference shielding
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Diverse Structural Design Strategies of MXene‑Based Macrostructure for High‑Performance Electromagnetic Interference Shielding 被引量:3
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作者 Yue Liu Yadi Wang +4 位作者 Na Wu Mingrui Han Wei Liu Jiurong Liu Zhihui Zeng 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第12期419-448,共30页
There is an urgent demand for flexible,lightweight,mechanically robust,excellent electromagnetic interference(EMI)shielding materials.Two-dimensional(2D)transition metal carbides/nitrides(MXenes)have been potential ca... There is an urgent demand for flexible,lightweight,mechanically robust,excellent electromagnetic interference(EMI)shielding materials.Two-dimensional(2D)transition metal carbides/nitrides(MXenes)have been potential candidates for the construction of excellent EMI shielding materials due to their great electrical electroconductibility,favorable mechanical nature such as flexibility,large aspect ratios,and simple processability in aqueous media.The applicability of MXenes for EMI shielding has been intensively explored;thus,reviewing the relevant research is beneficial for advancing the design of high-performance MXene-based EMI shields.Herein,recent progress in MXene-based macrostructure development is reviewed,including the associated EMI shielding mechanisms.In particular,various structural design strategies for MXene-based EMI shielding materials are highlighted and explored.In the end,the difficulties and views for the future growth of MXene-based EMI shields are proposed.This review aims to drive the growth of high-performance MXene-based EMI shielding macrostructures on basis of rational structural design and the future high-efficiency utilization of MXene. 展开更多
关键词 MXene COMPOSITE electromagnetic interference shielding MICROSTRUCTURE ELECTRONICS
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Regulating the Electrical and Mechanical Properties of TaS_(2) Films via van der Waals and Electrostatic Interaction for High Performance Electromagnetic Interference Shielding 被引量:3
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作者 Fukang Deng Jianhong Wei +6 位作者 Yadong Xu Zhiqiang Lin Xi Lu Yan-Jun Wan Rong Sun Ching-Ping Wong Yougen Hu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第7期278-292,共15页
Low-dimensional transition metal dichalcogenides(TMDs) have unique electronic structure, vibration modes, and physicochemical properties, making them suitable for fundamental studies and cutting-edge applications such... Low-dimensional transition metal dichalcogenides(TMDs) have unique electronic structure, vibration modes, and physicochemical properties, making them suitable for fundamental studies and cutting-edge applications such as silicon electronics, optoelectronics, and bioelectronics. However, the brittleness, low toughness,and poor mechanical and electrical stabilities of TMD-based films limit their application. Herein, a TaS_(2) freestanding film with ultralow void ratio of 6.01% is restacked under the effect of bond-free van der Waals(vdW) interactions within the staggered 2H-TaS_(2) nanosheets.The restacked films demonstrated an exceptionally high electrical conductivity of 2,666 S cm^(-1), electromagnetic interference shielding effectiveness(EMI SE) of 41.8 dB, and absolute EMI SE(SSE/t) of 27,859 dB cm^(2) g^(-1), which is the highest value reported for TMD-based materials. The bond-free vdW interactions between the adjacent 2H-TaS_(2) nanosheets provide a natural interfacial strain relaxation, achieving excellent flexibility without rupture after 1,000 bends. In addition, the TaS_(2) nanosheets are further combined with the polymer fibers of bacterial cellulose and aramid nanofibers via electrostatic interactions to significantly enhance the tensile strength and flexibility of the films while maintaining their high electrical conductivity and EMI SE.This work provides promising alternatives for conventional materials used in EMI shielding and nanodevices. 展开更多
关键词 2D transition metal dichalcogenides 2H-TaS_(2) FLEXIBILITY electromagnetic interference shielding
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Flash‑Induced High‑Throughput Porous Graphene via Synergistic Photo‑Effects for Electromagnetic Interference Shielding 被引量:1
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作者 Jin Soo Lee Jeong‑Wook Kim +9 位作者 Jae Hee Lee Yong Koo Son Young Bin Kim Kyoohee Woo Chanhee Lee Il‑Doo Kim Jae Young Seok Jong Won Yu Jung Hwan Park Keon Jae Lee 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第11期1-18,共18页
Porous 2D materials with high conductivity and large surface area have been proposed for potential electromagnetic interference(EMI)shielding materials in future mobility and wearable applications to prevent signal no... Porous 2D materials with high conductivity and large surface area have been proposed for potential electromagnetic interference(EMI)shielding materials in future mobility and wearable applications to prevent signal noise,transmission inaccuracy,system malfunction,and health hazards.Here,we report on the synthesis of lightweight and flexible flash-induced porous graphene(FPG)with excellent EMI shielding performance.The broad spectrum of pulsed flashlight induces photo-chemical and photo-thermal reactions in polyimide films,forming 5×10 cm^(2)-size porous graphene with a hollow pillar structure in a few milliseconds.The resulting material demonstrated low density(0.0354 g cm^(−3))and outstanding absolute EMI shielding effectiveness of 1.12×10^(5) dB cm^(2) g^(−1).The FPG was characterized via thorough material analyses,and its mechanical durability and flexibility were confirmed by a bending cycle test.Finally,the FPG was utilized in drone and wearable applications,showing effective EMI shielding performance for internal/external EMI in a drone radar system and reducing the specific absorption rate in the human body. 展开更多
关键词 Porous graphene Flash lamp Photo-pyrolysis HIGH-THROUGHPUT electromagnetic interference shielding
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Flexible Nanocomposite Conductors for Electromagnetic Interference Shielding 被引量:1
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作者 Ze Nan Wei Wei +2 位作者 Zhenhua Lin Jingjing Chang Yue Hao 《Nano-Micro Letters》 SCIE EI CAS CSCD 2023年第10期210-259,共50页
With the extensive use of electronic communication technology in integrated circuit systems and wearable devices, electromagnetic interference(EMI) has increased dramatically. The shortcomings of conventional rigid EM... With the extensive use of electronic communication technology in integrated circuit systems and wearable devices, electromagnetic interference(EMI) has increased dramatically. The shortcomings of conventional rigid EMI shielding materials include high brittleness, poor comfort, and unsuitability for conforming and deformable applications. Hitherto, flexible(particularly elastic) nanocomposites have attracted enormous interest due to their excellent deformability. However, the current flexible shielding nanocomposites present low mechanical stability and resilience, relatively poor EMI shielding performance, and limited multifunctionality. Herein, the advances in low-dimensional EMI shielding nanomaterials-based elastomers are outlined and a selection of the most remarkable examples is discussed. And the corresponding modification strategies and deformability performance are summarized. Finally, expectations for this quickly increasing sector are discussed, as well as future challenges. 展开更多
关键词 electromagnetic interference shielding Intrinsically stretchable nanocomposites Compressible monolith Low-dimensional materials Flexible devices
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An analysis and preliminary experiment of the discharge characteristics of RF ion source with electromagnetic shielding 被引量:1
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作者 王娜 刘智民 +6 位作者 谢亚红 韦江龙 蒋才超 刘伟 彭旭峰 苏国建 谢俊炜 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第4期210-218,共9页
Combined with two-dimensional(2D)and three-dimensional(3D)finite element analysis and preliminary experimental tests,the effects of size and placement of the electromagnetic shield of the radio-frequency(RF)ion source... Combined with two-dimensional(2D)and three-dimensional(3D)finite element analysis and preliminary experimental tests,the effects of size and placement of the electromagnetic shield of the radio-frequency(RF)ion source with two drivers on plasma parameters and RF power transfer efficiency are analyzed.It is found that the same input direction of the current is better for the RF ion source with multiple drivers.The electromagnetic shield(EMS)should be placed symmetrically around the drivers,which is beneficial for the plasma to distribute uniformly and symmetrically in both drivers.Furthermore,the bigger the EMS shield radius is the better generating a higher electron density.These results will be of guiding significance to the design of electromagnetic shielding for RF ion sources with a multi-driver. 展开更多
关键词 RF ion source electromagnetic shielding RF transfer efficiency
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