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The Driftless Electromigration Theory(Diffusion-Generation-Recombination-Trapping Theory) 被引量:4
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作者 薩支唐 揭斌斌 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2008年第5期815-821,共7页
Electromigration is the transport of atoms in metal conductors at high electronic current-densities which creates voids in the conductors and increases the conductors' electrical resistance. It was delineated in 1961... Electromigration is the transport of atoms in metal conductors at high electronic current-densities which creates voids in the conductors and increases the conductors' electrical resistance. It was delineated in 1961 by Huntington; then modeled by the empirical electrical resistance formula derived by Black in 1969 to fit the dependences of the experimental electrical resistance and failure data on the electrical current density and temperature. Tan in 2007 reviewed 40-years' ap- plications of the empirical Black formula to conductor lines interconnecting transistors and other devices in silicon integrated circuits. Since the first Landauer theory in 1957,theorists have attempted for 50 years to justify the drift force or electron momentum transfer assumed by Black as some electron-wind force to impart on the metal atoms and ions to move them. Landauer concluded in 1989 that the electron wind force is untenable even considering the most fundamental and complete many-body quantum transport theory. A driftless or electron-windless atomic void model for metal conductor lines is reviewed in this article. It was developed in the mid-1980 and described in 1996 by Sah in a homework solution. This model accounts for all the current and temperature dependences of experimental resistance data fitted to the empiri- cal Black formula. Exact analytical solutions were obtained for the metal conductor line resistance or current, R (t)/R (0) = J(t)/J(0) = [1-2(t/τα)^1/α]^-1/2 ,in the bond-breaking limit with α = 1 to 2 and diffusion limit with α = 2 to 4,from low to high current densities, where τα is the characteristic time constant of the mechanism, containing bond breaking and diffusion rates and activation energies of the metal. 展开更多
关键词 electromigration driftless void model empirical Black formula diffusion-generation-recombinationtrapping
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水溶液-有机溶液双相体系电迁移分离锂同位素
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作者 居慧群 王明勇 +6 位作者 张鹏瑞 邵斐 毛连婧 周小龙 景燕 贾永忠 孙进贺 《盐湖研究》 CAS CSCD 2024年第3期94-101,共8页
锂同位素的分离对于核工业的发展具有至关重要的意义。本文基于“水溶液|有机溶液|水溶液”电迁移体系,通过在有机溶液中引入阴离子,系统考察了电场强度、冠醚、时间等因素对锂同位素分离效应的影响。研究发现,电场的引入提高了有机溶... 锂同位素的分离对于核工业的发展具有至关重要的意义。本文基于“水溶液|有机溶液|水溶液”电迁移体系,通过在有机溶液中引入阴离子,系统考察了电场强度、冠醚、时间等因素对锂同位素分离效应的影响。研究发现,电场的引入提高了有机溶液中锂离子的迁出能力,并且,随着电场强度的增强,阳极液和有机溶液逐渐倾向于富集锂-7,而阴极液逐渐倾向于富集锂-6。冠醚的引入显著增强了体系各段料液的锂同位素富集效应,在10 V及更高强度电场下,阳极液和有机溶液倾向于富集锂-7,阴极液倾向于富集锂-6。经分析,电迁移作用、螯合作用和扩散作用在体系电迁移分离锂同位素过程中存在协同效应,有机溶液中锂离子与冠醚络合、未与冠醚络合的两种化学形态存在对高压(≥10 V)电场不同的响应方式,这些因素都决定了体系各段料液的锂同位素富集效应。 展开更多
关键词 电迁移 冠醚 锂同位素分离
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电迁移诱导W纳米晶表面原子尺度结构演变
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作者 曹海镟 赵培丽 +2 位作者 贾双凤 郑赫 王建波 《电子显微学报》 CAS CSCD 北大核心 2024年第5期532-539,共8页
体心立方(body⁃centered cubic,BCC)金属W作为微型化器件中重要的互连材料,其电迁移行为对小尺寸集成电路的稳定性至关重要。本文利用原位透射电子显微(transmission electron microscopy,TEM)技术,在原子尺度下研究了电迁移诱导BCC金属... 体心立方(body⁃centered cubic,BCC)金属W作为微型化器件中重要的互连材料,其电迁移行为对小尺寸集成电路的稳定性至关重要。本文利用原位透射电子显微(transmission electron microscopy,TEM)技术,在原子尺度下研究了电迁移诱导BCC金属W表面结构动态演变过程。结果表明,自由表面是主要电迁移路径;而{110}面和<111>方向分别是优选的迁移面迁移方向;电迁移过程中W表面形成特定的原子台阶或锯齿状结构。对于非低能晶面{002},在电流作用下仍能发生定向迁移,形成新的台阶结构。研究结果揭示了电迁移过程中表面结构的演化规律,为优化BCC金属材料的微观结构设计、提高其在高电流密度环境下的结构性能稳定性提供借鉴。 展开更多
关键词 电迁移 低能面 表面原子 原位透射电子显微镜
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双杂环月桂基咪唑啉季铵盐阻锈剂的阻锈效果
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作者 刘军 叶国林 +4 位作者 易于 陈晶晶 张蕊 李龙梓 张立力 《新型建筑材料》 2024年第5期133-136,143,共5页
为了探究双杂环月桂基咪唑啉季铵盐阻锈剂(IQS)的阻锈效果,采用双向电迁移(ECE)技术、动电位极化法、总有机碳法、离子色谱法测试IQS的缓蚀率(η)、钢筋表面吸附量及钢筋附近自由Cl^(-)浓度,并与氨基醇复合内掺型阻锈剂(DCI)、可溶性羧... 为了探究双杂环月桂基咪唑啉季铵盐阻锈剂(IQS)的阻锈效果,采用双向电迁移(ECE)技术、动电位极化法、总有机碳法、离子色谱法测试IQS的缓蚀率(η)、钢筋表面吸附量及钢筋附近自由Cl^(-)浓度,并与氨基醇复合内掺型阻锈剂(DCI)、可溶性羧酸铵盐外涂型阻锈剂(MCI)的阻锈效果进行对比。结果表明:3组钢筋缓蚀率分别为η_(DCI)(20.0%)>η_(IQS)(13.5%)>η_(MCI)(6.5%),3组钢筋附近阻锈剂含量分别为c_(DCI)(2.0 mg/g)>c_(IQS)(1.5 mg/g)>c_(MCI)(0.8 mg/g),IQS组钢筋附近自由Cl^(-)浓度最低;ECE处理使得IQS解离出的-R_(4)N^(+)内迁效率优于MCI自由迁移效率,并促进了钢筋附近自由Cl^(-)外迁,但η_(IQS)仍低于η_(DCI),可通过优化电流密度和通电时间提升IQS的阻锈效果。 展开更多
关键词 双杂环月桂基咪唑啉季铵盐 双向电迁移 缓蚀率 动电位极化 阻锈剂
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封装基板埋容材料THB可靠性监控方法的研究
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作者 唐灵峰 迟美慧 +1 位作者 朱冠军 单海丹 《印制电路信息》 2024年第S02期110-118,共9页
封装成品测试过程中,不定期会发生因基板的加偏压恒温恒湿测试(bias High Accelerate Stress Test,THB)失效,导致板厂经济赔偿、降低品牌信誉度的问题,THB失效一直是困扰业界的难题。本文基于消费品市场中传统的主要是驻极体麦克风产品M... 封装成品测试过程中,不定期会发生因基板的加偏压恒温恒湿测试(bias High Accelerate Stress Test,THB)失效,导致板厂经济赔偿、降低品牌信誉度的问题,THB失效一直是困扰业界的难题。本文基于消费品市场中传统的主要是驻极体麦克风产品MEMS(Micro Electro MeganeticSystem,微机电系统),探究了埋容材料,结合THB测试,确定埋容材料内部的空洞是影响失效的关键因子。埋容异物还是影响失效的关键因子,同步利用显微镜、开短路量测仪、热成像分析仪、X射线检测仪、研磨机、扫描电镜、能谱仪等工具研究了THB失效分析方法,将THB监控失效分析成功率从20%提升至80%,为基板裸板生产加工工艺提供了改善方向。 展开更多
关键词 THB 电迁移 埋容 失效分析
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封装基板阻焊bHAST失效影响因素研究
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作者 陈佳 朱冠军 +1 位作者 迟美慧 单海丹 《印制电路信息》 2024年第S01期288-295,共8页
封装成品测试过程中,不定期会发生因基板的加偏压高加速应力测试(bias High AccelerateStress Test,bHAST)失效导致板厂经济赔偿、降低品牌信誉度的问题,bHAST失效一直是困扰业界的难题。本文基于高阶改进型半加成工艺(Advanced Modifie... 封装成品测试过程中,不定期会发生因基板的加偏压高加速应力测试(bias High AccelerateStress Test,bHAST)失效导致板厂经济赔偿、降低品牌信誉度的问题,bHAST失效一直是困扰业界的难题。本文基于高阶改进型半加成工艺(Advanced Modified Semi AddictiveProcess,AMSAP)制程,研究了介层(core)为HL832NS的材料,结合bHAST测试,确定油墨类型是影响失效的关键因子,油墨厚度对bHAST失效率的贡献不明显,同步利用显微镜,开短路量测仪,热成像分析仪,X射线检测仪,研磨机,扫描电镜,能谱仪等工具研究了bHAST失效分析方法,将bHAST失效分析成功率从20%提升至80%,为基板裸板生产加工工艺提供了改善方向。 展开更多
关键词 bHAST 电迁移 油墨 失效分析
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Electromigration induced microstructure evolution and damage in asymmetric Cu/Sn-58Bi/Cu solder interconnect under current stressing
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作者 岳武 秦红波 +2 位作者 周敏波 马骁 张新平 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第5期1619-1628,共10页
The electromigration induced microstructure evolution and damage in asymmetric Cu/Sn-58Bi/Cu solder interconnects were investigated by in-situ SEM observation, focused ion beam (FIB) microanalysis and finite element... The electromigration induced microstructure evolution and damage in asymmetric Cu/Sn-58Bi/Cu solder interconnects were investigated by in-situ SEM observation, focused ion beam (FIB) microanalysis and finite element (FE) simulation. The SEM results show that the electromigration-induced local degradation of microstructures, i.e., segregation of Bi-rich phase and formation of microcracks, in the asymmetric solder interconnects is much severer than that in the symmetrical ones. FIB-SEM microanalysis reveals that the microregional heterogeneity in electrical resistance along different electron flowing paths is the key factor leading to non-uniform current distribution and the resultant electromigration damage. Theoretical analysis and FE simulation results manifest that the current crowding easily occurs at the local part with smaller resistance in an asymmetric solder interconnect. All results indicate that the asymmetric shape of the solder interconnect brings about the difference of the electrical resistance between the different microregions and further results in the severe electromigration damage. 展开更多
关键词 microregional electrical resistance asymmetric solder interconnect electromigration damage current crowding geometry effect
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A theoretical analysis of the electromigration-induced void morphological evolution under high current density 被引量:7
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作者 Yuexing Wang Yao Yao 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2017年第5期868-878,共11页
In this work, analysis of electromigration-induced void morphological evolution in solder interconnects is performed based on mass diffusion theory. The analysis is conducted for three typical experimentally observed ... In this work, analysis of electromigration-induced void morphological evolution in solder interconnects is performed based on mass diffusion theory. The analysis is conducted for three typical experimentally observed void shapes: circular, ellipse, and cardioid. Void morphological evolution is governed by the competition between the electric field and surface capillary force. In the developed model, both the electric field and capillary force on the void's surface are solved analytically. Based on the mass conversation principle, the normal velocity on the void surface during diffusion is obtained. The void morphological evolution behavior is investigated, and a physical model is developed to predict void collapse to a crack or to split into sub-voids under electric current. It is noted that when the electric current is being applied from the horizontal direction, a circular void may either move stably along the electric current direction or collapse to a finger shape, depending on the relative magnitude of the electric current and surface capillary force. However, the elliptical-shaped void will elongate along the electric current direction and finally collapse to the finger shape. On the other hand, the cardioid-shaped void could bifurcate into two sub-voids when the electric current reaches a critical value. The theoretical predictions agree well with the experimental observations. 展开更多
关键词 electromigration Analytical solution Void evolution High current density Mass diffusion
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Effect of Interconnect Linewidth on Evolution of Intragranular Microcracks Due to Electromigration Analyzed by Finite Element Method 被引量:3
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作者 HE Dingni HUANG Peizhen 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2019年第2期290-297,共8页
The effect of interconnect linewidth on the evolution of intragranular microcracks due to surface diffusion induced by electromigration is analyzed by finite element method.The numerical results indicate that there ex... The effect of interconnect linewidth on the evolution of intragranular microcracks due to surface diffusion induced by electromigration is analyzed by finite element method.The numerical results indicate that there exists critical values of the linewidth hc,the electric fieldχc and the aspect ratioβc.When h>hc,χ<χc orβ<βc,the microcrack will evolve into a stable shape as it migrates along the interconnect line.When h≤hc,χ≥χc orβ≥βc,the microcrack will split into two smaller microcracks.The critical electric field,the critical aspect ratio and the splitting time have a stronger dependence on the linewidth when h≤6.In addition,the decrease of the linewidth,the increase of the electric field or the aspect ratio is beneficial to accelerate microcrack splitting,which may delay the open failure of the interconnect line. 展开更多
关键词 finite element method surface diffusion electromigration LINEWIDTH MICROCRACK EVOLUTION
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Effect of electromigration and isothermal aging on interfacial microstructure and tensile fracture behavior of SAC305/Cu solder joint 被引量:4
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作者 Wei Guoqiang Liu Henglin +1 位作者 Du Longchun Yao Jian 《China Welding》 EI CAS 2016年第3期42-48,共7页
The Cu/Sn-3. OAg-0.5Cu/Cu butting solder joints were fabricated to investigate the evolution of the interfacial intertnetaUic compound ( IMC ) and the degradation of the tensile strength of solder joints under the e... The Cu/Sn-3. OAg-0.5Cu/Cu butting solder joints were fabricated to investigate the evolution of the interfacial intertnetaUic compound ( IMC ) and the degradation of the tensile strength of solder joints under the effect of electromigration ( EM) and aging processes. Scanning electron microscopy(SEM) results indicated that the Cu6Sn5 interfacial IMC presented obvious asymmetrical growth with the increase of EM time under current density of l. 78 × 10^4 A/cm^2 at 100 ℃ , and the growth of anodic IMC presented a parabolic relationship with time while the cathodic IMC got thinner gradually. However, as for aging samples at 100℃ without current stressing, the Cu6Sn5 IMC presented a symmetrical growth with a slower rate than the anodic IMC of EM samples. The tensile results indicated that the tensile strength of the solder joints under current stress declined more drastic with time than the aging samples, and the fracture mode transformed from ductile fracture to brittle fracture quickly while the fracture mode of aging samples transformed from cup-cone shaped fracture to microporous gathering fracture in a slow way. 展开更多
关键词 electromigration isothermal aging intermetallic compound mechanical property
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A comparison of electromigration failure of metal lines with fracture mechanics 被引量:3
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作者 Hiroyuki Abé Mikio Muraoka +1 位作者 Kazuhiko Sasagawa Masumi Saka 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2012年第3期774-781,共8页
Atoms constructing an interconnecting metal line in a semiconductor device are transported by electron flow in high density. This phenomenon is called electromigration, which may cause the line failure. In order to ch... Atoms constructing an interconnecting metal line in a semiconductor device are transported by electron flow in high density. This phenomenon is called electromigration, which may cause the line failure. In order to characterize the electromigration failure, a comparison study is carded out with some typical phenomena treated by fracture mechanics for thin and large structures. An example of thin structures, which have been treated by fracture mechanics, is silica opti- cal fibers for communication systems. The damage growth in a metal line by electromigration is characterized in compar- ison with the crack growth in a silica optical fiber subjected to static fatigue. Also a brief comparison is made between the electromigration failure and some fracture phenomena in large structures. 展开更多
关键词 electromigration failure. Interconnecting line Comparison Fracture mechanics
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Prediction of electromigration failure in passivated polycrystalline line 被引量:1
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作者 Kazuhiko Sasagawa Masataka Hasegawa +1 位作者 Masumi Saka Hiroyuki Abé 《光学精密工程》 EI CAS CSCD 2003年第2期114-119,共6页
Recently, a governing parameter for electromigration damage in passivated polycrystalline lines, AFD*gen, was formulated considering the effect of the atomic density gradient. In this study, a prediction metho... Recently, a governing parameter for electromigration damage in passivated polycrystalline lines, AFD*gen, was formulated considering the effect of the atomic density gradient. In this study, a prediction method for electromigration failure in a passivated polycrystalline line was proposed using AFD*gen. The characteristics of film used for prediction is established in advance using a method based on AFD*gen. The film characteristics of metal lines with different lengths were determined experimentally by AFD*gen_based method. From the film characteristics obtained, both lifetime and location of failure in the passivated polycrystalline lines were predicted through numerical simulation of failure process. Good agreement has been shown between the predicted and the experimental results concerning both lifetime and location of failure. 展开更多
关键词 多晶线 钝化 失效 电迁移 预报
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An energy approach to predict electromigration induced grain rotation under high current density
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作者 Yuexing Wang Yao Yao 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2019年第1期21-26,I0004,共7页
An energy approach is proposed to describe the electromigration induced grain rotation under high current density. The driving force is assumed to arise from the grain-boundary energy reduction and increase of the inn... An energy approach is proposed to describe the electromigration induced grain rotation under high current density. The driving force is assumed to arise from the grain-boundary energy reduction and increase of the inner energy from the joule heating. Energy dissipates by the grain boundary diffusion under electromigration and viscous boundary sliding is considered. Based on the conservation of energy production and dissipation, an equilibrium equation is developed to predict the grain rotation rate analytically. It is recognized that the grain rotates with the reducing of electrical resistivity and inversely proportional to the grain length. The theoretical prediction is compared with the experimental data, which shows good accuracy on the rotation trend and the specific rotation rate. 展开更多
关键词 electromigration GRAIN ROTATION ENERGY ANALYTICAL model
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Electromigration in eutectic SnAg solder reaction couples with various ambient temperatures and current densities
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作者 Guang-chen Xu Fu Guo Wan-rong Zhu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2009年第6期685-690,共6页
The electromigration behavior of eutectic SnAg solder reaction couples was studied at various temperature (25 and 120℃ when the current density was held constant at 104 A/cm^2 or 5×10^3 A/cm^2. Under the curren... The electromigration behavior of eutectic SnAg solder reaction couples was studied at various temperature (25 and 120℃ when the current density was held constant at 104 A/cm^2 or 5×10^3 A/cm^2. Under the current density of 104 A/cm^2, scallop type Cu6Sn5 spalls and migrates towards the direction of electron flow at room ambient temperature (25℃), but transforms to layer type Cu3Sn and leaves Kirkendall voids in it at high ambient temperature (120℃). Under the current density of 5×10^3 A/cm^2 plus room ambient temperature, no obvious directional migration of metal atoms/ions is found. Instead, the thermal stress induced by mismatch of dissimilar materials causes the formation of superficial valley at both interfaces. However, when the ambient temperature increases to 120℃, the mobility of metal atoms/ions is enhanced, and then the grains rotate due to the anisotropic property of β-Sn. 展开更多
关键词 electromigration eutectic solder Joule heating intermetallic compound
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Improved electromigration reliability of surface acoustic wave devices using Ti/Al-Mo/Ti/Al-Mo electrodes
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作者 LI Dongmei LIU Ming 《Rare Metals》 SCIE EI CAS CSCD 2009年第6期554-558,共5页
In order to obtain both high electromigration (EM) reliability and free-dimensional control in high-frequency surface acoustic wave (SAW) devices, 4-layered Ti/Al-Mo/Ti/Al-Mo electrode films were investigated on 1... In order to obtain both high electromigration (EM) reliability and free-dimensional control in high-frequency surface acoustic wave (SAW) devices, 4-layered Ti/Al-Mo/Ti/Al-Mo electrode films were investigated on 128° Y-X LiNbO3 substrates by sputtering deposition. The resuits indicated that the 4-layered films had an improved EM reliability compared to conventional Al-0.5wt.%Cu films. Their lifetime is approximately three times longer than that of the Al-0.5wt.%Cu films tested at a current density of 5 x 107 A/cm^2 and a temperature of 200℃. Moreover, the 4-layered films were easily etched in reactive ion etching and fine-dimensional control was realized during the pattern replication for high-frequency SAW devices. For the 4-layered films, an optimum Mo quantity and sputtering parameters were very significant for high EM reliability. 展开更多
关键词 electrode films magnetron sputter electromigration surface acoustic wave devices
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Current sustainability and electromigration of Pd,Sc and Y thin-films as potential interconnects
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作者 Yong Yang Shengyong Xu +1 位作者 Sishen Xie Lian-Mao Peng 《Nano-Micro Letters》 SCIE EI CAS 2010年第3期184-189,共6页
The progress on novel interconnects for carbon nanotube(CNT)-based electronic circuit is by far behind the remarkable development of CNT-field effect transistors.The Cu interconnect material used in current integrated... The progress on novel interconnects for carbon nanotube(CNT)-based electronic circuit is by far behind the remarkable development of CNT-field effect transistors.The Cu interconnect material used in current integrated circuits seems not applicable for the novel interconnects,as it requires electrochemical deposition followed by chemical-mechanical polishing.We report our experimental results on the failure current density,resistivity,electromigration effect and failure mechanism of patterned stripes of Pd,Sc and Y thin-films,regarding them as the potential novel interconnects.The Pd stripes have a failure current density of(8~10)×106 A/cm^2(MA/cm^2),and they are stable when the working current density is as much as 90% of the failure current density.However,they show a resistivity around 210 μΩ·cm,which is 20 times of the bulk value and leaving room for improvement.Compared to Pd,the Sc stripes have a similar resistivity but smaller failure current density of 4~5 MA/cm^2.Y stripes seem not suitable for interconnects by showing even lower failure current density than that of Sc and evidence of oxidation.For comparison,Au stripes of the same dimensions show a failure current density of 30 MA/cm^2 and a resistivity around 4 μΩ·cm,making them also a good material as novel interconnects. 展开更多
关键词 Carbon nanotube-based field effect transistors Carbon nanotube-based circuit Interconnects Current density electromigration RESISTIVITY
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A new model for electromigration grain boundary noise based on free volume
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作者 何亮 杜磊 +4 位作者 庄奕琪 陈华 陈文豪 李伟华 孙鹏 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第9期525-530,共6页
Grain boundary plays a key role in electromigration process of polycrystal interconnection. We take a free volume to represent a 'vacancy-ion complex' as a function of grain boundary specific resistivity, and develo... Grain boundary plays a key role in electromigration process of polycrystal interconnection. We take a free volume to represent a 'vacancy-ion complex' as a function of grain boundary specific resistivity, and develop a new characterisation model for grain boundary noise. This model reveals the internal relation between the boundary scattering section and electromigration noise. Comparing the simulation result with our experimental result, we find the source as well as the form of noise change in the electromigration process. In order to describe the noise enhancement at grain boundary quantitatively, we propose a new parameter--grain boundary noise enhancement factor, which reflects that the grain boundary noise can characterise the electromigration damage sensitively. 展开更多
关键词 free volume electromigration grain boundary noise
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Ni-GNSs增强Sn2.5Ag0.7Cu0.1RE/Cu钎焊接头电迁移特性研究 被引量:2
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作者 张超 张柯柯 +1 位作者 高一杰 王钰茗 《河南科技大学学报(自然科学版)》 CAS 北大核心 2023年第5期1-7,15,M0002,共9页
针对微焊点服役下的电迁移可靠性检测,设计制造了满足焊点在理想电迁移环境下的试验装置。结果表明:通过热分解法制备Ni-GNSs增强相,得到的Ni-GNSs增强Sn2.5Ag0.7Cu0.1RE/Cu钎焊接头能有效抑制电迁移现象的发生。在电加载条件下,随电流... 针对微焊点服役下的电迁移可靠性检测,设计制造了满足焊点在理想电迁移环境下的试验装置。结果表明:通过热分解法制备Ni-GNSs增强相,得到的Ni-GNSs增强Sn2.5Ag0.7Cu0.1RE/Cu钎焊接头能有效抑制电迁移现象的发生。在电加载条件下,随电流密度升高,Ni-GNSs增强Sn2.5Ag0.7Cu0.1RE/Cu接头阳极区界面金属间化合物(IMC)由起伏扇贝状转变为平坦厚大的板状,并出现了明显Cu 3Sn;阴极区界面IMC由锯齿状转变为薄条状,且有明显空洞裂纹。钎焊接头断裂位置从阴极界面IMC/钎缝的过渡区向阴极界面IMC迁移,断裂方式由韧性断裂向脆性断裂转变,剪切强度明显下降。 展开更多
关键词 Ni-GNSs增强相 无铅钎焊接头 电迁移 界面金属间化合物 力学性能
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Ni-rGO增强Sn2.5Ag0.7Cu0.1RE/Cu钎焊接头的电迁移组织与性能
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作者 张超 张柯柯 +2 位作者 王钰茗 高一杰 高岩 《材料热处理学报》 CSCD 北大核心 2023年第12期185-195,共11页
研究了电流密度与温度对Ni-rGO增强Sn2.5Ag0.7Cu0.1RE/Cu钎焊接头电迁移界面组织与力学性能的影响。结果表明:当钎焊接头电流密度达7×10^(3)A/cm^(2)、温度为100℃以上,阳极侧界面金属间化合物(IMC)以Cu_(6)Sn_(5)相为主、厚度逐... 研究了电流密度与温度对Ni-rGO增强Sn2.5Ag0.7Cu0.1RE/Cu钎焊接头电迁移界面组织与力学性能的影响。结果表明:当钎焊接头电流密度达7×10^(3)A/cm^(2)、温度为100℃以上,阳极侧界面金属间化合物(IMC)以Cu_(6)Sn_(5)相为主、厚度逐渐增大并形成Cu_(3)Sn相,阴极侧界面的IMC Cu_(6)Sn_(5)逐渐溶解,且Cu_(3)Sn相伴随空洞形成;电流密度升高,促进了阴阳极区电迁移非对称生长;温度升高,促进了阳极区IMC生长,一定程度抑制了阴极区IMC的溶解;随电流密度与温度的增大,断裂位置由钎缝区向界面IMC方向移动,断口由呈韧窝为主的韧性断裂向解理刻面为主的韧脆混合断裂转变。通过热分解法制备的Ni-rGO增强相可有效提高钎焊接头的使役寿命。 展开更多
关键词 无铅钎料 钎焊接头 电迁移 金属间化合物 力学性能
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eFuse器件的电迁移三维有限元仿真
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作者 王锦任 王家佳 +2 位作者 赵晨阳 刘海南 李多力 《半导体技术》 CAS 北大核心 2023年第7期577-584,599,共9页
应用有限元分析软件建立了电可编程熔丝(eFuse)器件的三维有限元模型,通过离子流通量散度法和最小原子浓度法对eFuse器件的电迁移熔断过程进行了多物理场耦合有限元仿真,仿真结果能够较好地拟合器件的实际熔断效果。通过仿真对比了不同... 应用有限元分析软件建立了电可编程熔丝(eFuse)器件的三维有限元模型,通过离子流通量散度法和最小原子浓度法对eFuse器件的电迁移熔断过程进行了多物理场耦合有限元仿真,仿真结果能够较好地拟合器件的实际熔断效果。通过仿真对比了不同阴极面积和不同编程电压条件下的电迁移过程及熔断效果。结果表明,更大的阴极面积能够提高熔丝局部的温度梯度,从而提高熔断效率;更高的编程电压能够提供更高的电流密度和温度,从而加速电迁移的发生并增大了eFuse熔断区的面积。提出了一种具有外部辅助加热功能的eFuse器件结构,并在不同条件下进行了电迁移熔断仿真,结果表明该结构能够显著提高eFuse器件局部的离子流通量散度,从而提高eFuse存储单元的熔断效率和编程良率。 展开更多
关键词 电可编程熔丝(eFuse) 电迁移 有限元仿真 离子流通量散度 热断裂
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