A clay-like conductive material comprising polyaniline(PANI)-acetylene black particles is fabricated as a hole conductor for dye sensitized solar cell(DSSC).The results show that the introduction of acetylene blac...A clay-like conductive material comprising polyaniline(PANI)-acetylene black particles is fabricated as a hole conductor for dye sensitized solar cell(DSSC).The results show that the introduction of acetylene black into the polymer electrolyte improves the photovoltaic behavior of solid-state DSSC,owing to the increase of the hole mobility of PANI electrolyte,the improvement of the wetting quality of the composite electrolyte,and the reinforcement of interface contact between electrode and the electrolyte.Finally,the overall energy conversion efficiency of DSSC with PANI-50%(in weight)acetylene black electrolyte is 48% of that of liquid DSSC.Therefore,the PANI-acetylene black composition is a credible alternative to hole conductor in application of solid DSSC.展开更多
文摘A clay-like conductive material comprising polyaniline(PANI)-acetylene black particles is fabricated as a hole conductor for dye sensitized solar cell(DSSC).The results show that the introduction of acetylene black into the polymer electrolyte improves the photovoltaic behavior of solid-state DSSC,owing to the increase of the hole mobility of PANI electrolyte,the improvement of the wetting quality of the composite electrolyte,and the reinforcement of interface contact between electrode and the electrolyte.Finally,the overall energy conversion efficiency of DSSC with PANI-50%(in weight)acetylene black electrolyte is 48% of that of liquid DSSC.Therefore,the PANI-acetylene black composition is a credible alternative to hole conductor in application of solid DSSC.