Semi-empirical AMI method was used to study 1：1 and 1：2 hydrogen bond complexes formed with perylene dianhydride and pyridine derivatives. The weak interaction energy become bigger as the number of hydrogen bonds in...Semi-empirical AMI method was used to study 1：1 and 1：2 hydrogen bond complexes formed with perylene dianhydride and pyridine derivatives. The weak interaction energy become bigger as the number of hydrogen bonds increases. The donor groups on the host and electron-withdrawing groups on the guest molecules favor hydrogen bonding interactions, and the formation of hydrogen bonding leads to electron density flow from the host to the guest molecules. Electronic spectra of these complexes were computed using INDO/SCI method. Blue-shift of the clectronic absorption spectra for the complexes, comparing that of the host, takes place, and the first peaks for different complexes changed slightly. These are in agreement with the experimcntal results. The cause of blue-shift was discussed, and the electronic transitions were assigned based on theoretical calculations. The potential curve of double proton transfer in the complex was calculated, and the transition state and activated energy relative to the N H bond were obtained.展开更多
This study aimed at designing and assembling an improvised Logic Gates Simulator that can be utilized as an instructional device in basic digital electronics instruction at Caraga State University Cabadbaran Campus, P...This study aimed at designing and assembling an improvised Logic Gates Simulator that can be utilized as an instructional device in basic digital electronics instruction at Caraga State University Cabadbaran Campus, Philippines. This instructional device is believed to enhance the teaching-learning process and would also help address the scarcity of instructional equipment in the school and in the country. Descriptive method of research was employed to come up with the design of the simulator based on the course content of basic digital electronics subject. Acceptability of the improvised simulator based on standards set in this study was?gathered from the experts as respondents using a self-made questionnaire. The data were treated using average weighted mean utilizing parametric scales with verbal descriptions. Findings revealed that the improvised logic gates simulator is highly acceptable in terms of its cost and availability of components,?design and construction,operations, and troubleshooting features. It is concluded that the improvised logic gates simulator is at par in terms of standards on instructional devices based on the evaluation results of experts and is therefore recommended to be used in basic digital electronics instruction. The simulator is an innovative answer and an alternate solution to the scarcity of instructional materials and devices at Caraga State University Cabadbaran Campus.展开更多
Skin is the largest organ of the human body and can perceive and respond to complex environmental stimulations.Recently,the development of electronic skin(E-skin)for the mimicry of the human sensory system has drawn g...Skin is the largest organ of the human body and can perceive and respond to complex environmental stimulations.Recently,the development of electronic skin(E-skin)for the mimicry of the human sensory system has drawn great attention due to its potential applications in wearable human health monitoring and care systems,advanced robotics,artificial intelligence,and human-machine interfaces.Tactile sense is one of the most important senses of human skin that has attracted special attention.The ability to obtain unique functions using diverse assembly processible methods has rapidly advanced the use of graphene,the most celebrated two-dimensional material,in electronic tactile sensing devices.With a special emphasis on the works achieved since 2016,this review begins with the assembly and modification of graphene materials and then critically and comprehensively summarizes the most advanced material assembly methods,device construction technologies and signal characterization approaches in pressure and strain detection based on graphene and its derivative materials.This review emphasizes on:(1)the underlying working principles of these types of sensors and the unique roles and advantages of graphene materials;(2)state-of-the-art protocols recently developed for high-performance tactile sensing,including representative examples;and(3)perspectives and current challenges for graphene-based tactile sensors in E-skin applications.A summary of these cutting-edge developments intends to provide readers with a deep understanding of the future design of high-quality tactile sensing devices and paves a path for their future commercial applications in the field of E-skin.展开更多
The effect of buried misfit dislocation on the distribution of Ge self-assembled quantum dots (SAQDs) grown on a relaxed SiGe buffer layer was investigated. The strain field of arrays of buried dislocations in a relax...The effect of buried misfit dislocation on the distribution of Ge self-assembled quantum dots (SAQDs) grown on a relaxed SiGe buffer layer was investigated. The strain field of arrays of buried dislocations in a relaxed SiGe buffer layer provided preferential nucleation sites for quantum dots. Burgers vector analysis using plan-view transmission electron microscopy (TEM) verified that the preferential nucleation sites of Ge SAQDs depended on the Burgers vector direction of corresponding dislocations. The measurement of the lateral distance between SAQDs and dislocations together with crosssection TEM observation clarified that the location of SAQDs was at the intersection of the dislocation slip plane and the top surface. The misfit strain should be an additional factor governing the uniformity in size, shape and distribution of Ge SAQDs.展开更多
The intermolecular interaction in an azobenzene self-assembled monolayers (SAMs) on gold electrode was investigated by controlling the assembling time and using mixed self-assembled techniques, and the variation of ap...The intermolecular interaction in an azobenzene self-assembled monolayers (SAMs) on gold electrode was investigated by controlling the assembling time and using mixed self-assembled techniques, and the variation of apparent electron transfer rate constant (k(s)) of azobenzene SAMs with different molecular packing density is reported.展开更多
With the increasing miniaturisation and integration of electronic products and the increase of heat, it is necessary to design and introduce heat sinks and install fans. The volume of electronic components, especially...With the increasing miniaturisation and integration of electronic products and the increase of heat, it is necessary to design and introduce heat sinks and install fans. The volume of electronic components, especially the height, is very important for the structural and thermal design of electronic devices. This paper presents a design scheme of an online height measurement device based on laser triangulation and commercial charge coupled device(CCD). It analyzes the principles of electronic component height measurement, and expounds the composition and working principle of the laser measurement system. In addition, the commonly used methods to determine the center position are compared and analysed. These methods include circle fitting, gray centroid and extension method or Gaussian fitting. These methods usually lead to different results. The experimental results show that the fitting speed of the gray centroid is faster. The 3 D model of components is given through measurement, and the error factors affecting measurement are analysed.展开更多
文摘Semi-empirical AMI method was used to study 1：1 and 1：2 hydrogen bond complexes formed with perylene dianhydride and pyridine derivatives. The weak interaction energy become bigger as the number of hydrogen bonds increases. The donor groups on the host and electron-withdrawing groups on the guest molecules favor hydrogen bonding interactions, and the formation of hydrogen bonding leads to electron density flow from the host to the guest molecules. Electronic spectra of these complexes were computed using INDO/SCI method. Blue-shift of the clectronic absorption spectra for the complexes, comparing that of the host, takes place, and the first peaks for different complexes changed slightly. These are in agreement with the experimcntal results. The cause of blue-shift was discussed, and the electronic transitions were assigned based on theoretical calculations. The potential curve of double proton transfer in the complex was calculated, and the transition state and activated energy relative to the N H bond were obtained.
文摘This study aimed at designing and assembling an improvised Logic Gates Simulator that can be utilized as an instructional device in basic digital electronics instruction at Caraga State University Cabadbaran Campus, Philippines. This instructional device is believed to enhance the teaching-learning process and would also help address the scarcity of instructional equipment in the school and in the country. Descriptive method of research was employed to come up with the design of the simulator based on the course content of basic digital electronics subject. Acceptability of the improvised simulator based on standards set in this study was?gathered from the experts as respondents using a self-made questionnaire. The data were treated using average weighted mean utilizing parametric scales with verbal descriptions. Findings revealed that the improvised logic gates simulator is highly acceptable in terms of its cost and availability of components,?design and construction,operations, and troubleshooting features. It is concluded that the improvised logic gates simulator is at par in terms of standards on instructional devices based on the evaluation results of experts and is therefore recommended to be used in basic digital electronics instruction. The simulator is an innovative answer and an alternate solution to the scarcity of instructional materials and devices at Caraga State University Cabadbaran Campus.
基金supported by the National Key Research and Development Program of China(2017YFB0405400)National Natural Science Foundation of China(51732007)+1 种基金Major Innovation Projects in Shandong Province(2018YFJH0503)Natural Science Foundation of Shandong Province(ZR2018BEM010).
文摘Skin is the largest organ of the human body and can perceive and respond to complex environmental stimulations.Recently,the development of electronic skin(E-skin)for the mimicry of the human sensory system has drawn great attention due to its potential applications in wearable human health monitoring and care systems,advanced robotics,artificial intelligence,and human-machine interfaces.Tactile sense is one of the most important senses of human skin that has attracted special attention.The ability to obtain unique functions using diverse assembly processible methods has rapidly advanced the use of graphene,the most celebrated two-dimensional material,in electronic tactile sensing devices.With a special emphasis on the works achieved since 2016,this review begins with the assembly and modification of graphene materials and then critically and comprehensively summarizes the most advanced material assembly methods,device construction technologies and signal characterization approaches in pressure and strain detection based on graphene and its derivative materials.This review emphasizes on:(1)the underlying working principles of these types of sensors and the unique roles and advantages of graphene materials;(2)state-of-the-art protocols recently developed for high-performance tactile sensing,including representative examples;and(3)perspectives and current challenges for graphene-based tactile sensors in E-skin applications.A summary of these cutting-edge developments intends to provide readers with a deep understanding of the future design of high-quality tactile sensing devices and paves a path for their future commercial applications in the field of E-skin.
文摘The effect of buried misfit dislocation on the distribution of Ge self-assembled quantum dots (SAQDs) grown on a relaxed SiGe buffer layer was investigated. The strain field of arrays of buried dislocations in a relaxed SiGe buffer layer provided preferential nucleation sites for quantum dots. Burgers vector analysis using plan-view transmission electron microscopy (TEM) verified that the preferential nucleation sites of Ge SAQDs depended on the Burgers vector direction of corresponding dislocations. The measurement of the lateral distance between SAQDs and dislocations together with crosssection TEM observation clarified that the location of SAQDs was at the intersection of the dislocation slip plane and the top surface. The misfit strain should be an additional factor governing the uniformity in size, shape and distribution of Ge SAQDs.
文摘The intermolecular interaction in an azobenzene self-assembled monolayers (SAMs) on gold electrode was investigated by controlling the assembling time and using mixed self-assembled techniques, and the variation of apparent electron transfer rate constant (k(s)) of azobenzene SAMs with different molecular packing density is reported.
文摘With the increasing miniaturisation and integration of electronic products and the increase of heat, it is necessary to design and introduce heat sinks and install fans. The volume of electronic components, especially the height, is very important for the structural and thermal design of electronic devices. This paper presents a design scheme of an online height measurement device based on laser triangulation and commercial charge coupled device(CCD). It analyzes the principles of electronic component height measurement, and expounds the composition and working principle of the laser measurement system. In addition, the commonly used methods to determine the center position are compared and analysed. These methods include circle fitting, gray centroid and extension method or Gaussian fitting. These methods usually lead to different results. The experimental results show that the fitting speed of the gray centroid is faster. The 3 D model of components is given through measurement, and the error factors affecting measurement are analysed.
