Electrothermal Model Based Remaining Charging Time Prediction of Lithium-Ion Batteries against Wide Temperature Range

Battery remaining charging time(RCT)prediction can facilitate charging management and alleviate mileage anxiety for electric vehicles(EVs).Also,it is of great significance to improve EV users’experience.However,the RCT for a lithiumion battery pack in EVs changes with temperature and other battery parameters.This study proposes an electrothermal model-based method to accurately predict battery RCT.Firstly,a characteristic battery cell is adopted to represent the battery pack,thus an equivalent circuit model(ECM)of the characteristic battery cell is established to describe the electrical behaviors of a battery pack.Secondly,an equivalent thermal model(ETM)of the battery pack is developed by considering the influence of ambient temperature,thermal management,and battery connectors in the battery pack to calculate the temperature which is then fed back to the ECM to realize electrothermal coupling.Finally,the RCT prediction method is proposed based on the electrothermal model and validated in the wide temperature range from-20℃to 45℃.The experimental results show that the prediction error of the RCT in the whole temperature range is less than 1.5%.

Determination of Ultratrace Amounts of Copper(Ⅱ) in Water Samples by Electrothermal Atomic Absorption Spectrometry After Cloud Point Extraction

A novel approach was developed for the determination of ultratrace amounts of copper in water samples by using electrothermal atomic absorption spectrometry （ETAAS） after cloud point extraction （ CPE ）. 1-（ 2-Pyridylazo ） -2- naphthol was used as the chelating reagent and Triton X-114 as the mieellar-forming surfactant. CPE was conducted in a pH 8. 0 medium at 40 ℃ for 10 rain. After the separation of the phases by contrifugafion, the surfactant-rieh phase was diluted with 1 mL of a methanol solution of 0. 1 mol/L HNO3. Then 20μL of the diluted surfactant-rieh phase was injected into the graphite furnace for atomization in the absence of any matrix modifier. Various experimental conditions that affect the extraction and atomization processes were optimized. A detection limit of 5 ng/L was obtained after preconeentration. The linear dynamic range of the copper mass concentration was found to be 0-2.0 ng/mL, and the relative standard deviation was found to be less than 3. 1% for a sample containing 1.0 ng/mL Cu （ Ⅱ ）. This developed method was successfully applied to the determination of uhratraee amounts of Cu in drinking water, tap water, and seawater samples.

Preliminary investigation on electrothermal instabilities in early phases of cylindrical foil implosions on primary test stand facility

Recent experiments on the implosions of 15-mm long and 2-μm thick aluminum liners having a diameter of 12.8 mm have been performed on the primary test stand(PTS) facility. The stratified structures are observed as alternating dark and light transverse stripes in the laser shadowgraph images. These striations perpendicular to the current flow are formed early in the implosion, i.e., at the stage when the bulk of the material mass was almost at rest. A two-dimensional(2 D)magnetohydrodynamics(MHD) code is employed to simulate the behavior of liner dynamics in the early phases. It is found that the striations may be produced by the electrothermal instability(ETI) that results from non-uniform Joule heating due to the characteristic relation between the resistivity and the temperature. In 2 D simulations, the stratified structures can be seen obviously in both density and temperature contours as the liner expands rapidly. By analyzing instability spectrum, the dominant wavelengths of the perturbations are 8.33 μm–20.0 μm, which agree qualitatively with the theoretical predictions.It is also interesting to show that ETI provides a significant seed to the subsequent magneto Rayleigh–Taylor(MRT)instability.

Determination of total arsenic by photo-decomposition of organoarsenic compounds and hydride generation electrothermal atomic absorption spectrometry

A method was developed for the determination of total arsenic concentration in less than ng/ml level by decomposition of organoarsenicals using photo -oxidation combined with in situ trapping of arsenic hydride on a palladium coated graphite tube with subsequent atomization and detection by AAS. The organoarsenicals include monomethylarsenic, dimethylarsenic, arsenobetaine, arsenocholine, o -aminobenzenarsenate and p -aminobenzenarsenate. The method is simple and sensitive. Detection limit was obtained from different arsenic compounds over the range from 0. 058 to 0.063 ng/ml as As (based on three times of the standard deviation of 10 blank measurements) and the relative standard deviations for ten replicate measurements were from 2.0 to 3.8%. The calibration curves of arsenic compounds including inorganic and organic arsenicals were linear over the range from 0.1 to 3.0 ng/ml as As. The recommended method has been applied to the determination of total arsenic in tap and lake water samples at ng/ml levels.

On-line Preconcentration of Trace Nickel from Electrolytic Manganese Using Minicolumn Packed Activated Carbon for Electrothermal Atomic Absorption Spectrometry

The online flow injection preconcentration and electrothermal atomic absorption spectrometry method were used for the determination of trace nickel in electrolytic manganese samples by sorption on a conical minicolumn packed with activated carbon at pH 9.0. The nickel was eluted from the minicolumn with 10%(v/v) nitric acid. An enrichment factor of 190-fold for a sample volume of 10mL was obtained. The detection limit (DL) of nickel with the use of the preconcentration method was 13ng·g -1in the original solid sample. The precision for 10 replicate determinations at 150ng·g -1 nickel concentration was 5.2% relative standard deviation (RSD). The calibration graph was linear with a correlation coefficient of r=0.9996 up to concentration of 660ng·g -1 nickel.

Numerical Simulation of an Airfoil Electrothermal-Deicing-System in the Framework of a Coupled Moving-Boundary Method

A numerical method for the analysis of the electrothermal deicing system for an airfoil is developed taking into account mass and heat exchange at the moving boundary that separates the water film created due to droplet impingement and the ice accretion region.The method relies on a Eulerian approach(used to capture droplet dynamics)and an unsteady heat transfer model(specifically conceived for a multilayer electrothermal problem on the basis of the enthalpy theory and a phase-change correction approach).Through application of the continuous boundary condition for temperature and heat flux at the coupled movingboundary,several simulations of ice accretion,melting and shedding,runback water flow and refreezing phenomena during the electrothermal deicing process are conducted.Finally,the results are verified via comparison with experimental data.A rich set of data concerning the dynamic evolution of the distribution of surface temperature,water film height and ice shape is presented and critically discussed.

Plume diagnostics of BUSTLab microwave electrothermal thruster using Langmuir and Faraday probes

This study presents the Langmuir and Faraday probe measurements conducted to determine the plume characteristics of the BUSTLab microwave electrothermal thruster(MET).The thruster,designed to operate at 2.45 GHz frequency,is run with helium,argon and nitrogen gases as the propellant.For the measurements,the propellant volume flow rate and the delivered microwave power levels are varied.Experiments with nitrogen gas revealed certain operation regimes where a very luminous plume is observed.With the use of in-house-built Langmuir probes and a Faraday probe with guard ring,thruster plume electron temperature,plasma density and ion current density values are measured,and the results are presented.The measurements show that MET thruster plume effects on spacecraft will likely be similar to those of the arcjet plume.It is observed that the measured plume ion flux levels are very low for the high volume flow rates used for the operation of this thruster.

Determination of Trace Rare Earth Elements in Biological Samples by ICP-AES with Tungsten-spiral Electrothermal Vaporization Sampling

A method for determination of trace rare earth elements in biological sample by ICP-AES with tungsten-spiral electrothermal vaporization(TETV-ICP-AES)sampling has been developed in this work. Several influencing factors including desolvation and vaporization parameters,carrier gas flow rate and ma- trix effect were investigated in detail.Under optimal experimental conditions,the detection limits for La,Nd, Gd,Dy,Ho,Yb,Lu and Y were obtained in the range of 10^(-9)～10^(-11) g,and they are comparable to and,in most instances,better than those for the GFAAS and conventional pneumatic nebulisation-ICP-AES.The precision(RSD)obtained for this method is less than 6%.

An Observation in 88 Cases of Epidermodyslasia Verruciforms Treated by Electrothermal Acupuncture

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Furnace bottom rise mechanism in preparation of Al Si alloys by electrothermal process

The experiments of preparation of Al Si alloys by electrothermal process were carried out respectively in 20 kW, 100 kW and 1 800 kW DC arc furnaces. The mechanism of furnace bottom rise was studied. It was found that the bottom rise can be divided into three types, including the low bottom temperature, abnormal reducing reaction and carbide deposition. The furnace bottom rise is related to the carbon ratio of the briquet, the heating speed of the briquet and the parameters and operation of furnace.

Low-voltage soft robots based on carbon nanotube/polymer electrothermal composites

Nowadays,soft robots have become a research hot spot due to high degree of freedom,adaptability to the environment and safer interaction with humans.The carbon nanotube(CNT)/polydimethylsiloxane(PDMS)electrothermal composites have attracted wide attention in the field of flexible actuations due to large deformation at low voltages.Here,the preparation process of CNT/PDMS composites was designed and optimized,and electrothermal actuators(ETAs)were fabricated by cutting the CNT/PDMS composite films into a“U”shape and coating conductive adhesive.The deformation performance of the ETAs with different thicknesses at different voltages was studied.At a low voltage of about 7 V,the ETA has a deformation rate of up to 93%.Finally,two kinds of electrothermal soft robots(ETSRs)with four-legged and three-legged structures were fabricated,and their inchworm-like motion characteristics were studied.The ETSR2 has the best motion performance due to the moderate thickness and three-legged electrode structure.

Studies on Volatilization of Zirconium from Electrothermal Graphite Furnace for Sample Introduction into Inductively Coupled Plasma

Element zirconium reacted with polytetrafluoroethylene (PTFE) dispersed in isopropanol-water mixture to form volatile fluoride when heated in an electrothermal graphite furnace, and the fluorides formed subsequently were vaporized into ICP for atomization and excitation. The technique provides a picogram detectkm limit and adequate precision of 4% relative standard deviation. Linear dynamic range covers over three orders of magnitude. The process of sample preparation it very convenient. It is expected that the method proposed is suitable for determination of other refractory elements.

Determination of Trace Amount of Vanadium in High Purity Y_2O_3 by Electrothermal Vaporization－ICP－AES With Bi（PDC）_3 Coprecipitation

A new method for the determination of vanadium in high purity Y2O3 by fluorination assisted electrothermal vaporization-ICP-AES is presented in this paper. After the sample dissolved,the vanadium in the sample solution was coprecipitated with Bi(PDC)_3 at pH 3. 7. The precipitates were made into a slurry with the fluorinating agent PTFE and directly introduced into the graphite furnace for determination. The analytical results were obtained by aqueous calibration curve method. The detection limit of the method is 1. 1 ng/mL, the RSD is 2. 8% (n=10,1 5 ng/mL vanadium solution), and the recovery of vanadium added to real sample is more than 96%.

Determination of Cd,Pb and Sr by Microwave Plasma Torch Atomic Emision Spectrometry Using an Electrothermal Vaporization Sample Introduction System

A method for the determination of Cd,Pb and Sr by microwave plasma torch(MPT)atomic emission spectrometry(AES)was developed.Th e samples were introduced into the MPT with an elec trothermal vaporization(ETV)device.The effects of some experimental conditions on the de-termination of Cd,Pb and Sr were examined.The effects of easily ionized elements on the emis-sion intensity of Cd,Pb and Sr were studied in detail.The detection limits for Cd,Pb and Sr are 2.4,4.0 and 1.3 ng/mL,respectively.

Atomic Emission Spectrometry of Inductively Coupled Plasma with Sample Introduction by Electrothermal Vaporization

A system is described in which a graphite furnace electrothermal vaporization device is employed for the introduction of microlitre liquid sample into an inductively coupled argon plasma. The technique provides a picogram detection limit and an adequate precision with a relative standard deviation of 4%. Mechanism of analyte condensation in transport process is explored. As an application, the technique combined with DDTC/CCl4 extraction is used to enrich and determine non- rare earth impurities in highly pure La2O3.

Electrothermal analysis of radiofrequency tissue ablation with injectable flexible electrodes considering bio-heat transfer

Flexible electrodes have been widely focused on in recent years due to their special mechanical properties,which can be directly integrated onto human soft tissues to actively take effects on human body or passively monitor human vital signs.These flexible electrodes provide a new routine to realize clinical treatment of accurate thermal ablation in the biological tissues via radiofrequency ablation(RFA).Meanwhile,accurately controlling of thermal field is very significant for the thermal ablation in the clinical therapeutics to prevent the healthy tissue from excessive burning.In this paper,both one-dimensional and two-dimensional axisymmetric analytical models for the electrothermal analysis of radiofrequency ablation considering bio-heat transfer are established,which are verified by finite element analysis(FEA)and in vitro experiments on pig skins.In the model,the electrical field and thermal field are both derived analytically to accurately predict the temperature rise in the biological tissues.Furthermore,parameters,such as the blood flow convection in living tissues and thickness of tissue,have obvious effects on the thermal field in the tissues.They may pave the theoretical foundation and provide guidance of RFA with flexible electrodes in the future.

Research on Load Characteristic of Electrothermal Film Heating Community

In this paper, a case study of an electrothermal film heating community in Tianjin is carried out, in which the winter load characteristic and electricity use law are analyzed. In this community, every household installs two watt-hour meters, one of which is only used to measure the electrothermal heating power, so the interference factors are eliminated. The main factors influencing the residents’ power consumption are summarized, and a method for estimating the thermal load of the residents is given. The conclusions can provide important reference to generalize the electric heating technology.

Research on Operation of Electrothermal Integrated Energy System Including Heat Pump and Thermal Storage Units Based on Capacity Planning

In view of the Three North areas existing wind power absorption and environment pollution problems,the previous scholars have improved the wind abandon problem by adding electrothermal coupling equipment or optimizing power grid operation.In this paper,an electrothermal integrated energy system including heat pump and thermal storage units was proposed.The scheduling model was based on the load data and the output characteristics of power units,each power unit capacity was programmed without constraints,and the proposed scheduling model was compared with the traditional combined heat and power scheduling model.Results showed that the investment and pollutant discharge of the system was reduced respectively.Wind power was fully absorbed.Compared with the traditional thermal power unit,the proportion of the output was significantly decreased by the proposed model.The proposed system could provide a new prospect for wind power absorption and environment protection.

Determination of Impurity Silicon in Anticancer Drug (Ge-132) by Electrothermally Atomised Atomic Absorption Spectrometry with Optical Temperature Control Accessory

The present paper describes the ashing and atomization processes in silicon analysis by electrothermally atomised atomic absorption spectrometry(EAAAS) with an uncoat-ed graphite tube, a pyrolytically coated graphite tube and a tungsten-coated graphitetube. The sensitivity and linear range of three graphite tubes were compared. By using optical temperature control accessory, the signals are enhanced by a factor of 2 and the germanium interferences in the determination of silicon are eliminated. The effects of time constant and carrier gas flow-rate on the determination of silicon were also tested. The sample can be directly analyzed in its aqueous solution without any pretreatment. The measurements of samples containing 0. 2 μg/mL and 0. 4 μg/mL silicon were run ten times and the variation coefficient is 4. 9% and 2.6%, respectively. The recovery tests for carboxyethyl germanium sesquioxide(Ge-132) synthesized and imported were performed, and the recoveries are 97. 0% and 110%, respectively. Keywords Carboxyethyl germanium sesquioxide, Electrothermally atomised atomic absorption spectrometry, Silicon

Single-wall carbon nanotube fiber non-woven fabrics with a high electrothermal heating response

Carbon nanotube(CNT)fibers have great promise for constructing multifunctional fabrics with high electrical conductivity,good electro-heating ability,excellent flexibility,and a low density.However,the inter-fiber contacts in the fabric greatly reduce these advantages and limit their application.Herein,a simple pressure-fusing method to fabricate single-wall CNT(SWCNT)fiber non-woven fabrics(NWFs)that are composed of interconnected SWCNT fibers with fused joints is reported,which have good flexibility,a low density of 0.46 g/cm^(3),a high electrical conductivity of 3.7×10^(5)S/m,and a record high specific electrical conductivity of 803(S·m^(2))/kg.They also showed excellent electrical heating ability,so that a temperature of~160℃was rapidly reached at a low voltage of 2 V.Combined with their low density,the SWCNT fiber NWFs are promising for use as a heating unit for low temperature battery protection and de-icing applications.