Carbonization mechanism of bamboo (phyllostachys) by means of Fourier Transform Infrared and elemental analysis

通过测定在200-600℃炭化竹材得到的固体产物的碳、氢、氧元素的含量及它们的红外光谱,研究了在炭化过程中竹材中半纤维素、纤维素及木素的变化规律。结果表明,结合元素分析,红外光谱分析方法是研究竹材炭化机理的有效手段。在200℃以前,竹材中的半纤维素和纤维素的大量羟基断裂,并结合成水而失去。在200-250℃之间,竹材中的纤维素被降解,其中的吡喃型环也遭到破坏。并且木素中的甲氧基也被脱去。竹材中的木素网状结构在250-400℃之间遭到完全的破坏。竹炭中的碳原子在600℃已基本上完成了芳环化。图3表2参15。

Method to measure tree-ring width,density,elemental composition,and stable carbon and oxygen isotopes using one sample

Tree-ring width(RW),density,elemental com-position,and stable carbon and oxygen isotope(δ^(13)C,δ^(18)O)are widely used as proxies to assess climate change,ecology,and environmental pollution;however,a specific pretreat-ment has been needed for each proxy.Here,we developed a method by which each proxy can be measured in the same sample.First,the sample is polished for ring width meas-urement.After obtaining the ring width data,the sample is cut to form a 1-mm-thick wood plate.The sample is then mounted in a vertical sample holder,and gradually scanned by an X-ray beam.Simultaneously,the count rates of the fluorescent photons of elements(for chemical characteriza-tion)and a radiographic grayscale image(for wood density)are obtained,i.e.the density and the element content are obtained.Then,cellulose is isolated from the 1-mm wood plate by removal of lignin,and hemicellulose.After producing this cellulose plate,cellulose subsamples are separated by knife under the microscope for inter-annual and intra-annual stable carbon and oxygen isotope(δ^(13)C,δ^(18)O)analysis.Based on this method,RW,density,elemental composition,δ^(13)C,and δ^(18)O can be measured from the same sample,which reduces sample amount and treatment time,and is helpful for multi-proxy comparison and combination research.

Organic and Elemental Carbon in Atmospheric Fine Particulate Matter in an Animal Agriculture Intensive Area in North Carolina: Estimation of Secondary Organic Carbon Concentrations

Carbonaceous components contribute significant fraction of fine particulate matter (PM2.5). Study of organic carbon (OC) and elemental carbon (EC) in PM2.5 may lead to better understanding of secondary organic carbon (SOC) formation. This year-long (December 2008 to December 2009) field study was conducted in an animal agriculture intensive area in North Carolina of United States. Samples of PM2.5 were collected from five stations located in an egg production facility and its vicinities. Concentrations of OC/EC and thermograms were obtained using a thermal-optical carbon analyzer. Average levels of OC in the egg production house and at ambient stations were 42.7 μg/m3 and 3.26 - 3.47 μg/m3, respectively. Average levels of EC in the house and at ambient stations were 1.14 μg/m3 and 0.36 - 0.42 μg/m3, respectively. The OC to total carbon (TC) ratios at ambient stations exceeded 0.67, indicating a significant fraction of SOC presented in PM2.5. Principal factor analysis results suggested that possible major source of in-house PM2.5 was from poultry feed and possible major sources of ambient PM2.5 was from contributions of secondary inorganic and organic PM. Using the OC/EC primary ratio analysis method, ambient stations SOC fractions ranged from 68% to 87%. These findings suggested that SOC could appreciably contribute to total PM2.5 mass concentrations in this agriculture intensive area.

NiCoZn/C@melamine sponge-derived carbon composites with highperformance electromagnetic wave absorption

NiMZn/C@melamine sponge-derived carbon(MSDC)composites(M=Co,Fe,and Mn)were prepared by a vacuum pump-ing solution method followed by carbonization.A large number of carbon nanotubes(CNTs)homogeneously attached to the surfaces of the three-dimensional cross-linked of the sponge-derived carbon in the NiCoZn/C@MSDC composite,and CNTs were detected in the NiFeZn/C@MSDC and NiMnZn/C@MSDC composites.Ni_(3)ZnC_(0.7),Ni_(3)Fe,and MnO in-situ formed in the NiFeZn/C@MSDC and NiMnZn/C@MSDC composites.The CNTs in the NiCoZn/C@MSDC composite efficiently modulated its complex permittivity.Thus,the composite exhibited the best performance among the composites,with the minimum reflection loss(RL_(min))of-33.1 dB at 18 GHz and thickness of 1.4 mm.The bandwidth for RL of≤-10 dB was up to 5.04 GHz at the thickness of 1.7 mm and loading of 25wt%.The op-timized impedance matching,enhanced interfacial and dipole polarization,remarkable conduction loss,and multiple reflections and scat-tering of the incident microwaves improved the microwave absorption performance.The effects of Co,Ni,and Fe on the phase and mor-phology provided an alternative way for developing highly efficient and broadband microwave absorbers.

Effect of stabilizing elements Nb and Ti on the microstructure and properties of low carbon ferritic stainless steel

The effect of stabilizing elements, such as Nb and Ti, on the microstructure and properties of low carbon ferritic stainless steel （FSS） has been investigated. The results of the Thermo-calc simulation have shown that the interstitial elements, such as C and N, may be completely stabilized by the addition of Nb and Ti. With the increase of Nb and Ti contents ,the α ＋ γ two phases gradually transfer to a single α-phase under a high temperature condition ,and the content of the carbide M23 C6 gradually decreases. The microstructure has indicated that the combined addition of Nb and Ti can promote the recrystallization of the band structure and form more uniform equiaxed grains. Also, with the increase of Nb and Ti contents,the elongation, the r-value and the corrosion resistance of cold-rolled and annealed sheets are improved prominently. In comparison with the effect of Ti ,the addition of Nb is more beneficial to the increase of r-value and the corrosion resistance.

Effects of Copper-Zinc Alloy Doped with Rare Earth Elements on Crystal of Calcium Carbonate

A copper-zinc alloy doped with rare earth elements was prepared and the mechanism was demonstrated in a simulating boiler and circulating cooling water with rigidity 1 mmol·L-1. The polar curve and scale inhibiting ability of the alloy was tested by a corrosion measurement system and a scale inhibition evaluation system, respectively. Scale samples were characterized with SEM and XRD. It is found that the transfer of cations could be promoted by doping with proper rare earth elements, and the corrosion potentials descend by 25～126 mV. The results indicated that the copper-zinc alloy doped with rare earth elements has higher scale inhibiting ability of CaCO3. The growth of calcite was affected by zinc ions dissolved because of primary battery reaction, and the transition of calcium carbonate from aragonite to calcite was hampered resulting in the proportion of aragonite to calcite is changed from 1.7∶1 to 2.7∶1.

Origin of Shallow Jurassic Heavy Oils in the Northwestern Margin of the Junggar Basin,NW China:Constraints from Molecular,Isotopic and Elemental Geochemistry

Oil group separation,gas chromatography-mass spectrometry analysis of saturated hydrocarbons,carbon isotope analysis of fractions and tests on trace elements were all carried out to determine the origin of shallow Jurassic heavy oils in the northwestern margin of the Junggar Basin,northwestern China.Results showed that all the crude oils had been subjected to different degrees of biodegradation,on an order ranging from PM 6 to 9,which yielded many unresolved complex mixtures(UCM)and formed a huge spike in the mass chromatogram(M/Z=85).Two heavy oils from the Karamay area underwent slight biodegradation,characterized by the consistent ratios of biomarker parameters.C_(21)/C_(23)and C_(23)/H of the two samples were 0.81 and 0.85,while G/H,C_(27)/C_(29)and C_(28)/C_(29)were 0.38 and 0.40,0.16 and 0.27,0.87 and 0.86,respectively.The isomerization parameters of terpane and steranes were 0.50-0.53,and 0.48-0.49,respectively.The above geochemical indices indicated that the crude oils in the study area were in the marginally mature stage.The parent materials were a mixture,consisting of bacteria,algae and some higher plants,formed under reducing depositional conditions,which is in agreement with the source rocks of the Fengcheng Formation in the Mahu depression.The carbon isotopic compositions of saturated hydrocarbon,aromatic hydrocarbon,NSO and asphaltene were−31‰−to−30.3‰,−29.5‰to−29.03‰,−29.4‰to−28.78‰and−28.62‰to−28.61‰,respectively.These findings are in agreement with the light carbon isotope of kerogen from the lower Permian Fengcheng Formation.Furthermore,V/Ni and Cr/Mo of all the crude oils were 0.01 to 0.032,0.837 to 10.649,which is in good agreement with the ratios of the corresponding elements of the extracts from the Fengcheng Fm.carbonate source rock.As a result,a two-stage formation model was established:(1)the oil generated from the carbonate source rocks of the Fengcheng Formation migrated to the Carboniferous,Permian and Triassic traps during the Late Triassic,forming the primary oil reservoirs;(2)during the Late Jurassic period,the intense tectonic activity of Yanshan Episode II resulted in the readjustment of early deep primary reservoirs,the escaped oils gradually migrating to the shallow Jurassic reservoir through cross-cutting faults,unconformities and sand body layers.The oils then finally formed secondary heavy oil reservoirs,due to long-term biodegradation in the later stage.Therefore,joint methods of organic,isotopic and element geochemistry should be extensively applied in order to confirm the source of biodegradation oils.

EFFECT OF TRACE ELEMENTS WITH ZERO SELF－INTERACTIONCOEFFICIENT ON CRYSTALLIZATION TEMPERATUREOF IRON CARBON ALLOYS

The effect of trace elements with zero self-interaction coefficient on crystallization temperature of iron carbon alloys was studied and the mathematic equation was developed based on thermodynamics in the present researeh. With the equation developed in this paper, the effects of nitrogen on crystallization temperature of Fe-3.45C-2.15Si0. 16Mn and Fe-3.45C-2. 15Si-0. 80Mn alloys were discussed.

Analysis of the elemental spectral characteristics of single elemental capture spectrum log using Monte-Carlo simulation

In this study,the gamma-ray spectrum of single elemental capture spectrum log was simulated.By numerical simulation we obtain a single-element neutron capture gamma spectrum.The neutron and photon transportable processes were simulated using the Monte Carlo N-Particle Transport Code System(MCNP),where an Am–Be neutron source generated the neutrons and thermal neutron capture reactions with the stratigraphic elements.The characteristic gamma rays and the standard gamma spectra were recorded,from analyzing of the characteristic spectra analysis we obtain the ten elements in the stratum,such as Si,Ca,Fe,S,Ti,Al,K,Na,Cl,and Ba.Comparing with single elemental capture gamma spectrum of Schlumberger,the simulated characteristic peak and the spectral change results are in good agreement with Schlumberger.The characteristic peak positions observed also consistent with the data obtained from the National Nuclear Data Center of the International Atomic Energy Agency.The neutron gamma spectrum results calculated using this simple method have practical applications.They also serve as an reference for data processing using other types of element logging tools.

Seasonal variation of atmospheric elemental carbon aerosols at Zhongshan Station,East Antarctica

Elemental carbon(or black carbon)(EC or BC)aerosols emitted by biomass burning and fossil fuel combustion could cause notable climate forcing.Southern Hemisphere biomass burning emissions have contributed substantially to EC deposition in Antarctica.Here,we present the seasonal variation of EC determined from aerosol samples acquired at Zhongshan Station(ZSS),East Antarctica.The concentration of EC in the atmosphere varied between 0.02 and 257.81 ng·m^(-3)with a mean value of 44.87±48.92 ng·m^(-3).The concentration of EC aerosols reached its peak in winter(59.04 ng·m^(-3))and was lowest(27.26 ng·m^(-3))in summer.Back trajectory analysis showed that biomass burning in southern South America was the major source of the EC found at ZSS,although some of it was derived from southern Australia,especially during winter.The 2019–2020 Australian bush fires had some influence on EC deposition at ZSS,especially during 2019,but the contribution diminished in 2020,leaving southern South America as the dominant source of EC.

EFFECTS OF RARE EARTH ELEMENTS ON THE CHARACTERISTICS OF AUTO-TEMPERING AND DECOMPOSITION OF MARTENSITE FOR A LOW CARBON Si-Mn-V STEELS

The effect of rare earth metals(REM)on the characteristics of auto-tempering and decomposition of martensite for low-carbon and low-alloy steels(20SiMn2V and 20SiMn2VRE)was investigated using TEM,dilatometer and microhardness test.Results show that both ε.and θ carbides,during auto-tempering, may precipitate from the low-carbon martensite matrix at the same time in the 20SiMn2V steel,however,the precipitation of the ε-carbides can be inhibited by the REM contained in the 20SiMn2 VRE steel,resulting in change of the type of precipitated carbides and decrease of the extent of auto-tempering.The“in-situ”ob- servations show that the decomposition of martensite is also inhibited by the REM contained in the 20SiMn2 VRE steel during low temperature tempering.

Effects of Elemental Sulphur and Farmyard Manure on pH and Salinity of Calcareous Sandy Loam Soil and Some Nutrient Elements in Tomato Plant

The objective of this study was to evaluate the effects of elemental sulphur （S） and farmyard manure on soil pH, EC and N, S, P concentrations of tomato grown in a calcareous sandy loam soil. For this purpose, a pot experiment was conducted in greenhouse conditions. Sulphur was applied at 0, 50, 100, 150, 200, 400 mg kg~ and farmyard manure at 0, 3 ton da^-1 to the soil. Three weeks after applications, tomato seedlings were planted and 8 weeks later, the plants were harvested to determine N, S, P concentrations and dry matter yield. Soil pH and EC were determined in the soil samples taken at 3 different periods. Effects of sulphur and farmyard manure applications were not significant on N, P concentrations and dry matter yield of tomato plant. S concentration of tomato plant was increased by sulphur alone. Soil pH was decreased and soil EC was increased in both 2^nd and 3^rd soil sampling period by the sulphur applications. As a result of farmyard manure application, soil pH decreased in the 2^nd soil sampling period but increased in the 3^rd soil sampling period. Also, soil EC was significantly increased in 1^st and 3^rd soil sampling period. Farmyard manure had no significant effect on S supply to tomato plant. The N：S ratio of tomato plant was decreased by sulphur alone. However, the sulphur with farmyard manure applications decreased N：S ratio in lesser extend compared to the S applications.

Separation and enrichment of elemental sulfur and mercury from hydrometallurgical zinc residue using sodium sulfide

The separation and enrichment of mercury and the recovery of elemental sulfur from flotation sulfur concentrate in zinc pressure leaching process were carried out by sodium sulfide leaching and carbon dioxide precipitating. The results show that the leaching rate of elemental sulfur is more than 98%, and 98.13% of mercury is enriched in the residue, under the optimized conditions of sodium sulfide concentration 1.5 mol/L, liquid/solid ratio 6：1 and leaching time 30 min at room temperature. In addition, the content of mercury is enriched 5.23 times that in the leaching residue. The elemental sulfur is precipitated from leaching solution under conditions of carbon dioxide flow rate 200 mL/min and blowing time 150 min, while solution is stirred adequately. The recovery efficiency of elemental sulfur reaches 97.67%, and the purity of elemental sulfur is 99.75%, meeting the requirements of industrial first-rate product standard according to the national standard of GB/T 2449-2006 （PRC）.

Microstructure of Surface Layer Formed at Low Temperature and High Carbon Concentration Carburizing with Rare Earth Element

A suitable carburized microstructure with fine granular dispersed carbides in hypereutectoid zone,ultra fine martensite in matrix and recrystallized austenite to be refined to the grain size of 12～14 has been obtained by a new process,which is a high carbon concentration carburizing with rare earth element at low temperature(860～880℃)in a discontinuous gas carburization furnace.There was not much difference for the microstructure in eutectic zone between this and conventional process.Forming mechanism of granular carbides has been also studied in this paper.

Trace and Rare Earth Element Geochemistry of Micrite Mound Carbonates and Other Related REE Mineralized Carbonates from Bayan Obo Area in Inner Mongolia

Geochemical study on trace and rare earth element geochemistry was carried out for different carbonates including the very REE-rich ones in the main ore bodies, a carbonatite dyke and two micrite mounds from Heilaobao far away from the Bayan Obo ore deposit, and Xishan in west Beijing. The results show that both carbonatite dyke and REE mineralized carbonates (dolomite and marble) in the main ore bodies and outside ore bodies have similarities to each other, with very extreme positive anomaly of Ba, Th, Nb, La, Ce, Nd, Sm, Pb, medium positive anomaly of Y, Ho, Tb, Er, Yb and negative anomaly of Sc, Ti and Cu. The REE concentration in the mineralized carbonates changes greatly, the total REE content changes from 262×10^(-6) in both east and west ore deposits to 104562 ×10^(-6) (10.46%), which is relatively lower than those samples of carbonatite dyke, whose REE contents vary greatly, from 1% up to 20 % of mass fraction. Light REE in the carbonatites are enriched and highly fractionated relative to heavy REE and there is no Eu anomaly. The REE distribution patterns of both mineralized carbonate and carbonatite dyke are of some similarities. However, the sedimentary carbonate micrite of Salinhudong Group in Heilaobao far outside the ore bodies and the pure carbonates from Xishan in Beijing, central part of North China plate, have the similarities in REE distributions with much lower REE contents, which are significantly different from those of carbonatite dyke and REE mineralized carbonate. In Bayan Obo district, both carbonates in the ore deposit and micrite mound outside the ore deposit underwent widespread metasomatism by fluids that resulted in formation of the superlager Fe-Nb-REE mineralization. It appears that the carbonates represent the evolution products of different geological stages.

Effect of Cr/Mn segregation on pearlite–martensite banded structure of high carbon bearing steel

The effect of Cr/Mn segregation on the abnormal banded structure of high carbon bearing steel was studied by reheating and hot rolling.With the use of an optical microscope, scanning electron microscope, transmission electron microscope, and electron probe microanalyzer, the segregation characteristics of alloying elements in cast billet and their relationship with hot-rolled plate banded structure were revealed.The formation causes of an abnormal banded structure and the elimination methods were analyzed.Results indicate the serious positive segregation of C, Cr, and Mn alloy elements in the billet.Even distribution of Cr/Mn elements could not be achieved after 10 h of heat preservation at 1200℃, and the spacing of the element aggregation area increased, but the segregation index of alloy elements decreased.Obvious alloying element segregation characteristics are present in the banded structure of the hot-rolled plate.This distinct white band is composed of martensitic phases.The formation of this abnormal pearlite–martensite banded structure is due to the interaction between the undercooled austenite transformation behavior of hot-rolled metal and the segregation of its alloying elements.Under the air cooling after rolling, controlling the segregation index of alloy elements can reduce or eliminate the abnormal banded structure.

Alloying elements characterization in a Ti-5.6Al-4.8Sn-2Zr-1Mo-0.35Si-1Nd titanium alloy by carbon addition

The effects of carbon addition (0.01wt%-0.43wt%) on a Ti-5.6Al-4.8Sn-2Zr-1Mo-0.35Si-1Nd (wt%) alloy with a bimodal microstructure were investigated. Electron probe microanalysis was carried out to examine the partitioning behavior of carbon and the relation of carbon content to the distributions of Al and Mo in the primary αp phase (α p) and β transformed structure (β). It was found that interstitial carbon is enriched in the α p phase and its content slightly reduces with the increase of the volume fraction of α p. The measurements of carbon content in the present alloy with an α p of 15vol% showed that the carbon content in the α p phase increases with the increment of carbon addition until a maximum but keeps almost constant in the β phase. The addition of carbon reduces the solubility of Al and Mo in the α p phase and leads to the increment of Mo partitioning to the β phase. When the carbon content is over 0.17wt% (0.67at%), carbide precipitation occurs in the matrix and its volume fraction is related to the volume fraction of α p which can be explained in term of the difference of carbon solubility in the α p and β phases.

Geochemical Characteristics of the Trace and Rare Earth Elements in Reef Carbonates from the Xisha Islands(South China Sea): Implications for Sediment Provenance and Paleoenvironment

Based on the concentrations of the trace elements,rare earth elements(REE),and Sr isotopic compositions in reef carbonates from the well‘Xike-1’reef core of the Xisha Islands,the constraints on sediment provenance and paleoenvironment were defined.Variations of the terrigenous input into the paleoseawater were traced in detail and the paleoenvironment and sediment provenance were further investigated.The results show that the HREE/LREE values in the reef carbonates are negatively associated with their Th and Al concentrations;however,their Al and Th concentrations show positive correlation.The lowest 87 Sr/86 Sr values in the reef carbonates generally coincide with the lowest values of Al,Th concentrations and the highest values of HREE/LREE.These data indicate that the HREE/LREE,Al concentrations,and Th concentrations of the reef carbonates are useful indexes for evaluating the influence of the terrigenous inputs on the seawater composition in the study area.From top to bottom,the changing process of the HREE/LREE values and Al,Th concentrations can be divided into 6 intervals;they are H1(0–89.30 m,about 0–0.11 Myr),L1(89.30–198.30 m,about 0.11–2.2 Myr),H2(198.30–374.95 m,about 2.2–5.3 Myr),D(374.95–758.40 m,about 5.3–13.6 Myr),L2(758.40–976.86 m,about 13.6–15.5 Myr),and H3(976.86–1200.00 m,about 15.5–21.5 Myr).Moreover,the changing trend of the HREE/LREE values coincides with that of the seawater δ^13C values recorded by benthonic foraminiferal skeletons from the drill core of ODP site 1148 in the South China Sea(SCS),but not with that of the seawaterδ18O values.The high uplifting rates of the Qinghai-Tibet Plateau coincide with the high Th and Al concentrations and the low HREE/LREE values in the reef carbonates.These data indicate that the main factors controlling the changes of terrigenous flux in the SCS are the tectonic activities associated with Qinghai-Tibet Plateau uplifting and the variations of uplifting rates rather than paleoclimatic changes.

An All‑In‑One Multifunctional Touch Sensor with Carbon‑Based Gradient Resistance Elements

Human–machine interactions using deep-learning methods are important in the research of virtual reality,augmented reality,and metaverse.Such research remains challenging as current interactive sensing interfaces for single-point or multipoint touch input are trapped by massive crossover electrodes,signal crosstalk,propagation delay,and demanding configuration requirements.Here,an all-inone multipoint touch sensor(AIOM touch sensor)with only two electrodes is reported.The AIOM touch sensor is efficiently constructed by gradient resistance elements,which can highly adapt to diverse application-dependent configurations.Combined with deep learning method,the AIOM touch sensor can be utilized to recognize,learn,and memorize human–machine interactions.A biometric verification system is built based on the AIOM touch sensor,which achieves a high identification accuracy of over 98%and offers a promising hybrid cyber security against password leaking.Diversiform human–machine interactions,including freely playing piano music and programmatically controlling a drone,demonstrate the high stability,rapid response time,and excellent spatiotemporally dynamic resolution of the AIOM touch sensor,which will promote significant development of interactive sensing interfaces between fingertips and virtual objects.

Investigating Catalase and Carbonic Anhydrase Enzyme Activities and Levels of Certain Trace Elements and Heavy Metals in Patients with Primary and Metastatic Hepatic Carcinoma

Hepatocellular carcinoma (HCC) is among most common terminal cancer types in the world. Primary etiological factors include cirrhosis, hepatitis, aflatoxin and alcohol. The current study was conducted to determine cytosolic erythrocyte carbonic anhydrase and catalase enzyme activities and levels of some trace elements. For this purpose, 40 patients with primary and metastatic hepatic cancer and 29 healthy volunteers enrolled to the study. Catalase and carbonic anhydrase enzyme activities and serum trace element levels were measured in patient and control groups. In the current study, serum copper, magnesium, manganese and zinc levels were lower in the primary and metastatic hepatic cancer group in comparison with the control group (P < 0.05). In contrast, serum iron, cobalt, cadmium and lead levels were higher in the patient relative to the control group (P < 0.05). In comparison with the control group, the catalase level was lower in primary and metastatic cancer group, while the carbonic anhydrase level was higher in the cancer group (P < 0.05). Changes in levels of trace elements and anti-oxidant enzymes may be the factors which influence the development and progression of liver cancer. The carbonic anhydrase enzyme can be a useful indicator in the diagnosis of cancer. However, this issue warrants further investigation.