Depositional Environment and Lithofacies Analyses of Eocene Lacustrine Shale in the Bohai Bay Basin:Insights from Mineralogy and Elemental Geochemistry

The effect of various depositional parameters including paleoclimate,paleosalinity and provenance,on the depositional mechanism of lacustrine shale is very important in reconstructing the depositional environment.The classification of shale lithofacies and the interpretation of shale depositional environment are key features used in shale oil and gas exploration and development activity.The lower 3rd member of the Eocene Shahejie Formation(Es_(3)^(x)shale)was selected for this study,as one of the main prospective intervals for shale oil exploration and development in the intracratonic Bohai Bay Basin.Mineralogically,it is composed of quartz(avg.9.6%),calcite(avg.58.5%),dolomite(avg.7%),pyrite(avg.3.3%)and clay minerals(avg.20%).An advanced methodology(thin-section petrography,total organic carbon and total organic sulfur contents analysis,X-ray diffraction(XRD),X-ray fluorescence(XRF),field-emission scanning electron microscopy(FE-SEM))was adopted to establish shale lithofacies and to interpret the depositional environment in the lacustrine basin.Six different types of lithofacies were recognized,based on mineral composition,total organic carbon(TOC)content and sedimentary structures.Various inorganic geochemical proxies(Rb/Sr,Ca/(Ca+Fe),Ti/Al,Al/Ca,Al/Ti,Zr/Rb)have been used to interpret and screen variations in depositional environmental parameters during the deposition of the Es_(3)^(x)shale.The experimental results indicate that the environment during the deposition of the Es_(3)^(x)shale was warm and humid with heightened salinities,moderate to limited detrital input,higher paleohydrodynamic settings and strong oxygen deficient(reducing)conditions.A comprehensive depositional model of the lacustrine shale was developed.The interpretations deduced from this research work are expected to not only expand the knowledge of shale lithofacies classification for lacustrine fine-grained rocks,but can also offer a theoretical foundation for lacustrine shale oil exploration and development.

Trace-element geochemistry and S–O isotopes in the fluorite-barite mineralization of Merguechoum,Moroccan eastern Meseta:insights into ore genesis to the Pangea rifting

The Merguechoum fluorite-barite mineralization,located in the Eastern Meseta of Morocco,is hosted in the Late Hercynian granite.The ore consists of fine crystals of fluorite 1,massive barite 1,euhedral crystals of fluorite 2,and barite 2 with calcite and minor quartz and sulfides.The Merguechoum ore deposits have never been investigated.This study was the first contribution that studied the genesis of fluorite and barite.The ore occurs as dissemination within granite intrusion and also fills the NE-SWtrending meter-sized fractures and faults.The values of the total Rare Earth Elements and Yttrium(REY)and the ratios of LREY/HREY,Y/Ho,Tb/Ca,and Tb/La indicate that the Merguechoum fluorite precipitated from hydrothermal fluids,likely basinal brines,which interacted with the Hercynian granite.The REY data indicate that the ore-forming fluids of the early stage have intensely interacted with the Hercynian granite compared to those of the late ore stage.The gradual decrease in the europium(Eu/Eu^(*)),yttrium(Y/Y^(*)),and cerium(Ce/Ce^(*))anomalies and a low concentration ofΣREY observed in the second ore stage compared to the first ore stage suggest an increase in p H and fO_(2)and by inference a decrease in temperature during the evolution of the hydrothermal system.This evolution could be explained by fluid mixing between the ascending basinal hydrothermal fluids and the diluted sulfate-rich meteoric water barite separates from selected samples reveal that the dissolved sulfates(SO_(4)^(2-))were derived from Permian–Triassic sulfates and/or coeval poreseawater sulfates.The proposed fluid mixing triggered the precipitation of an early-stage F-Ba assemblage followed by the second-stage F-Ba mineralization.Geologic fieldwork,REY inventories,and isotope data point to the ore genesis during the Permian–Triassic extensional tectonic activity concerning the Pangea rifting.This extensional tectonic environment is likely the driving force that mobilized a large amount of the ore-forming basinal brines along the available faults and fractures to the loci of ore deposition.

The elemental geochemical characteristics of Late Quaternary rock core from Yanwo Lake in the Great Wall Station area， King George Island， Southwest Antarctica

This paper is manily to treat the change regularity of the contens,distributions, enrich coefficients and correlative coefficients of some trace and constant elements in the sediments of Late Quaternary rock core from Yanwo Lake in the Great Wall Station area, King George Island and to discuss the sedimentary sources in Yanwo Lake and the periodical changes of Late Quaternary climate and the environment in the area. It is concluded that the elastic sedimentary rocks, including volcanic sedimentary rocks, around Yanwo Lake are the major sources of Yanwo Lake sedimentsi the mantle material is also one of its sources and what is more, the continent-sourced materials are transported by the Antarctic glacier.

Geochemistry and zircon U-Pb ages of the Oligocene sediments in the Baiyun Sag, Zhujiang River Mouth Basin

In this study,element geochemistry and zircon chronology are used to analyze the Oligocene sediments in the Baiyun Sag,Zhujiang River Mouth Basin.The experimental results are discussed with respect to weathering conditions,parent rock lithologies,and provenances.The chemical index of alteration and the chemical index of weathering values of mudstone samples from the lower Oligocene Enping Formation indicate that clastic particles in the study area underwent moderate weathering.Mudstone samples exhibit relatively enriched light rare earth elements and depleted heavy rare earth elements,"V"-shaped negative Eu anomalies,and negligible Ce anomalies.The rare earth element distribution curves are obviously right-inclined,with shapes and contents similar to those of post-Archean Australian shale and upper continental crust,indicating that the samples originated from acid rocks in the upper crust.The Hf-La/Th and La/Sc-Co/Th diagrams show this same origin for the sediments in the study area.For the samples from the upper Enping deltas,the overall age spectrum shows four major age peaks ca.59–68 Ma,98–136 Ma,153–168 Ma and 239–260 Ma.For the Zhuhai Formation samples,the overall age spectrum shows three major age peaks ca.149 Ma,252 Ma and 380 Ma.The detrital zircon shapes and U-Pb ages reveal that during Oligocene sedimentation,the sediments on the northwestern margin of the Baiyun Sag were supplied jointly from two provenances:Precambrian-Paleozoic metamorphic rocks in the extrabasinal South China fold zone and Mesozoic volcanic rocks in the intrabasinal Panyu Low Uplift,and the former supply became stronger through time.Thus,the provenance of the Oligocene deltas experienced a transition from an early proximal intrabasinal source to a late distal extrabasinal source.

Rare earth element(REE) geochemistry of different colored fluorites from the Baoshan Cu–Pb–Zn deposit, Southern Hunan,South China

The Baoshan Cu–Pb–Zn deposit, located in the central part of the Qin–Hang belt in South China, is closely related to the granodiorite-porphyry. However, the characteristics and the source of the ore-forming fluid are still ubiquitous. According to the crosscutting relationships between veinlets and their mineral assemblages, three stages of hydrothermal mineralization in this deposit were previously distinguished. In this contribution, two different colored fluorites from the major sulfide mineralization stage are recognized:(1) green fluorites coexisting with Pb–Zn ores;and(2) violet fluorites coexisting with pyrite ores. Y/Ho ratios verify the green fluorites and violet fluorites were co-genetic. The fluorites display elevated(La/Yb)Nratios, which decrease from 1201 to 5710 for green fluorites to 689–1568 for violet fluorites, indicating that they precipitated at the early hydrothermal sulfide stage,and Pb–Zn ores crystallized earlier than pyrite ores. The similar Tb/La ratios of the fluorites also indicate that they precipitated at an early stage within a short time. From the green fluorites to violet fluorites, the total rare earth element(ΣREE)concentrationsdecreasefrom1052–1680 ppm to 148–350 ppm, indicating that the green fluorites precipitated from a more acidic fluid. The Eu/Eu*ratios increase from 0.17 to 0.30 for green fluorites to0.29–0.48 for violet fluorites, and the Ce/Ce* ratios decrease from 1.08–1.13 to 0.93–1.11, suggesting a gradual increase in oxygen fugacity(fO_(2)) and pH value of the mineralization fluid. Though the fluorites display similar REE patterns to the granodiorite-porphyry and limestone,the ΣREE concentrations of the fluorites are significantly higher than those of limestone and the granodiorite-porphyry, suggesting that an important undetected non-magmatic source is involved to provide sufficient REE for fluorites. The most plausible mechanism is fluid mixing between magma fluid and an undetected non-magmatic fluid.

Zircon Geochronology and Trace Element Geochemistry from the Xiaozhen Copper Deposit, North Daba Mountain: Constraints on Albitites Petrogenesis

Albitite often accompanies with various metal and gem mineral deposits and a large number of occurrences have been reported globally, including the South Qinling orogen, China. The Xiaozhen copper deposit is a typical deposit in the North Daba Mountain area of the South Qinling orogen whose distribution is controlled by albitite veins and fractures. As there are few studies on the petrogenesis of albitite in Xiaozhen copper deposit, this paper focuses on the petrogenesis of albitite and its mineralization age. Detailed fieldwork and mineral microscopic observations initially suggest that albitite from the Xiaozhen copper deposit is igneous in origin. Further zircon trace element geochemistry studies indicate that these zircons have high Th/U ratios（〉0.5）, low La content, high（Sm/La）N and Ce/Ce＊values, and a strong negative Eu anomaly, which are commonly seen in magmatic zircons. The chondrite–normalized rare earth element（REE） patterns are consistent with magmatic zircons from throughout the world, and they fall within or near the field of magmatic zircons on discriminant diagrams. The calculated average apparent Ti–in–zircon temperature for young zircons is 780°C, consistent with magmatic zircon crystallization temperatures. Therefore, zircon geochemistry indicates that the albitite origin is magmatic. SIMS U–Pb dating on nine magmatic zircons yielded a concordia age of 154.8±2.2 Ma, which represents the formation of albitite and the metallogenic age. More importantly, it is consistent with the ages of Yanshanian magmatism and metallogenesis in the South Qinling orogen, so formation of the Xiaozhen copper deposit may be a closely related geological event.

Petrogenesis of the Shadegai Pluton in Inner Mongolia:Evidence from Petrography,Element Geochemistry and Geochronology

Objective The widely exposed granites in the Wulashan area of Inner Mongolia are an important component of intermediate-acidic magma belt at the northern margin of the North China Craton, and are also a natural laboratory to research the origin of granite bodies. The Shadegai pluton, a representative intrusion, intruded into the Wulashan Group metamorphic rocks, occurring as stock, and was controlled by the Linhe-Jining deep fracture. This pluton is composed of dominant K-feldspar granites and less biotite moyite, with abundant mafic microgranular enclaves （MMEs） dominated by gray black monzonite. Most MMEs have a sharp contact zone with their host granite, and few have a gradual contact relationship. Previous researches have described the characteristics of petrology and chronology of the Shadegai pluton, but few have focused on the characteristics of the petrography,

Trace Element Geochemistry of Devonian Strata in the Shizhuyuan Ore District, Hunan Province

1 Introduction Both the Qiziqiao Formation and Shetianqiao Formation,which controls the occurrence and distribution of a great deal of metal mineral resources,are extensively developed in southern Hunan province(Liu et al.,1998),showing quite important indicative significance to deep concealed metal mineral resources(Yu et al.,2003).The geochemistry characteristics of Devonian strata could not affect the spatial occurrence shape of orebody

U-Pb Geochronology and Geochemistry of Stratiform Garnet from the Aqishan Pb-Zn Deposit,Eastern Tianshan,Xinjiang,NW China:Constraints on Genesis of the Deposit

The Aqishan lead-zinc deposit,located in the Jueluotag metallogenic belt of eastern Tianshan,Xinjiang,Northwest China,has a stratiform occurrence in the marine volcanic tuff of the Yamansu Formation.The ore body has a typical double-layer structure,having a stratified,stratoid,lenticular upper part and a veined,stockwork-like lower part.The occurrence of the upper orebody is consistent with that of the volcanic tuff wall rock.The ore minerals are mainly chalcopyrite,pyrite,sphalerite,galena and magnetite,the altered minerals mainly being silicified,such as sericite,chlorite,epidote,garnet.The garnetized skarn,being stratiform and stratoid,is closely related to the upper part of the orebody.Geological observations show that the limestone in the ore-bearing Yamansu Formation is not marbleized and skarnized.Spatially,it is associated with the ferromanganese deposits in the marine volcanic rocks of the Yamansu Formation.These geological features reflect the likelihood that the Aqishan lead-zinc deposit is a hydrothermal exhalation sedimentary deposit.The results from the EPMA show that the garnet is mainly composed of grossular-andradite series,contents being in a range of 34.791-37.8%SiO_(2),32.493-34.274%CaO,8.454-27.275%FeO,0.012-15.293%Al_(2)O_(3),0.351-1.413%MnO,and lower values of 0.013-1.057%TiO_(2).The content of SiO_(2) vs.CaO and FeO vs.Al_(2)O_(3) has a significant positive correlation.The results of ICP-MS analysis for the garnet show that the REE pattern is oblique to right in general.The total amount of rare earth elements is relatively low,ΣREE=71.045-826.52 ppm,which is relatively enriched for LREE and depleted for HREE.LREE/HREE=8.66-4157.75,La_(N)/Yb_(N)=23.51-984.34,with obvious positive Eu and Ce anomalies(δEu=2.27-76.15,δCe=0.94-1.85).This result is similar to the REE characteristics of ore-bearing rhyolite volcanic rocks,showing that the garnet was formed in an oxidizing environment and affected by clear hydrothermal activity.The U-Pb isotopic dating of garnet by fs-LA-HR-ICP-MS gives an age of 316.3±4.4 Ma(MSWD=1.4),which is consistent with the formation time of the Yamansu Formation.According to the study of deposit characteristics and geochemical characteristics,this study concludes that the Aqishan lead-zinc deposit is a hydrothermal exhalation sedimentary deposit,the garnet being caused by hydrothermal exhalative sedimentation.

Trace Element Geochemistry of the Baishiquan and Pobei Intrusions,Xinjiang,NW China:Petrogenisis Implications

The Baishiquan and Pobei Early Permian mafic-ultramafic intrusions were emplaced into Proterozoic metamorphic rocks in the Central Tianshan and the Beishan Fold Belt,northern Xinjiang,NW China.The Baishiquan intrusion comprises mainly gabbro,and mela-gabbro sills occur within and along the margins of the gabbro body.In the Pobei intrusion,two distinct gabbroic packages,a lower gabbro and the main gabbro,are intruded and overlain by small cumulate wehrlite bodies.

Stable Isotope and Element Geochemistry of Saline Springs in Evaporite-bearing Mengla Basin,South Yunnan,China

1 Introduction Mengla Basin is a sub-basin in southern evaporitebearing Lanping-Simao Basin.There are many salt springs in the basin.In 2012,11 spring samples were collected for analyses of chemistry and boron,hydrogen and oxygen

Multiple grain-size fraction analysis of heavy minerals and the provenance identification of sediments from the abandoned Huanghe River,eastern China

The quantitative analysis of sediment sources in a sink is an important scientific topic and challenge in provenance research.The characteristics of heavy minerals,combined with the geochemical constituents of detrital grains,provide a reliable provenance-tracing approach.We developed a mineral identification method to analyze the multiple grain-size fraction of sediments,from which the elemental geochemistry of hornblende was used to compare the characteristics of sediments from the Huaihe River and Huanghe(Yellow)River in eastern China.Elements that were statistically identified as being able to discriminate sediment provenance were employed to perform a quantitative analysis of the sources of sediments of the abandoned Huanghe River.Results reveal that the Huaihe River is characterized by a high amphibole content of>60%and that the Huanghe and abandoned Huanghe rivers have greater abundances of limonite and carbonate minerals compared with those of the Huaihe River.The contents of trace elements and rare earth elements in hornblende show that the sediments of the abandoned Huanghe River are similar to those of the Huanghe River but different from those of the Huaihe River.Furthermore,chemical mass balance was used to calculate the relative contributions of different provenances of sediment from the abandoned Huanghe River,and nine trace elements of hornblende were identified as discriminators of provenance.Approximately 2%of the hornblende in the abandoned Huanghe River is derived from the Huaihe River and 98%from the Huanghe River.Considering the proportion of hornblende in the total sediment,it is inferred that the contribution of Huaihe River sediment to the abandoned Huanghe River is approximately 0.5%.This study shows that mineral analysis using multiple grain-size fractions(within the wide range of 1Φto 6Φ)with assessment in elemental geochemistry of hornblende can characterize the provenance of fluvial material in coastal zones.

Rutile to Titanite Transformation in Eclogites and its Geochemical Consequences:An Example from the Sumdo Eclogite,Tibet

The formation of titanite coronae after rutile is common in retrograde high-to ultrahigh-pressure meta-mafic rocks,which provides a good opportunity to address the geochemical behavior of HFSE in crustal environments.In the Sumdo eclogite,titanite occurs either as a corona around rutile grains or as semi-continuous veins cross-cutting the major foliation,whereas rutile grains occur either as inclusions in garnet or omphacite or as a relict core surrounded by titanite.Textural relationships and trace elements characteristics of rutile and titanite with different occurrences indicate that both minerals preferentially incorporate Nb and Hf over Ta and Zr in aqueous fluid.Moreover,the breakdown of omphacite and epidote could release substantial amounts of aqueous fluids enriched in Ca,Si,Fe and REE,which would react with rutile to form titanite coronae and veins.During this process,water-insoluble elements,like HFSE and HREE,behave like mobile elements,but they do not migrate substantially out of the system,instead,tending to react in situ.This suggests that the aqueous fluids released during the retrograde metamorphic reactions in mafic rocks could not substantially transfer fluidimmobile elements into the overlying mantle wedge in subduction environments.

Heavy Metal Distributions and Source Tracing in the Lacustrine Sediments of Dongdao Island,South China Sea

The levels and depth distributions of As, Cd, Cu, Zn, Pb, Hg, Fe and Mn in two sediment cores DY2 and DY4 collected from the ＂Cattle Pond＂ of Dongdao Island, South China Sea, were determined and analyzed with the main objective to identify the sources of these elements and evaluate the corresponding sedimentological and geochemical processes. Lithological characters and sedimentary parameters such as LOI950℃, CaO, LOI550℃ and TOC indicate that the depth of 96 cm and 87 cm are the critical points for DY2 and DY4 cores, respectively. As, Cd, Cu, Zn, Hg and P are remarkably enriched in the ornithogenic sediments above the critical depth points; their concentration-versus-depth profiles are similar to those of TOC and LOI550℃; the ratios of As, Cd, Cu, Zn, Hg over Ca are significantly correlated with P/Ca. Statistical and comparative analyses of these elements＇ levels in the ornithogenic sediments of DY2 and DY4 strongly suggest that seabird droppings are the main source of these elements. Additionally, for the upper sediment layers of DY2 and DY4 cores, Fe oxide sorption mechanism, like organic matter, may also play an important role in the abundances of heavy metals. Heavy metal Pb has geochemical characteristics distinctly different from those of As, Cd, Cu, Zn, Hg and P, and its isotope composition indicates an origin of anthropogenic emissions from the surrounding countries. These geochemical characteristics in the orinithogenic sediments of Xisha Islands are compared with the studies in the remote Antarctic and Arctic regions.

Geochemical records of the sediments and their significance in Dongping Lake Area,the lower reach of Yellow River,North China

Dongping Lake area,located in the lower reaches of Yellow River,is an ideal place to study the changes of modern river and lake sedimentary environment.The sediment samples of Dawen River,Yellow River,and Dongping Lake were collected,and the major elements,trace elements and organic matter geochemical composition of the samples were analyzed.Cluster analysis,characteristic element ratio method and graphic method were used to explore the geochemical characteristics of sediments and their environmental implication.The results show that the contents of SiO_(2),Na_(2)O,TiO_(2) and Zr in sediments of Dawen River and Yellow River are relatively high,and the contents of iron and manganese oxides,organic matter,CaO,P2O5 and Sr in lake sediments are relatively high.That reveals the differences of sedimentary environments between the rivers and the lake.The contents of Sr and Zr in Dawen River are affected by the rapid migration of clastic materials in the upstream carbonate source area during the flood season;the δCe,ΣREE and REE’s ratios in the sediments of the Yellow River reflect the influence of the Loess source;and the distribution of elements changes along the flow direction during the flood season.The characteristics of pH,element composition and LREE&HREE fractionation of the lake sediments indicate that the sediment source is complex,and the lake environment is affected by the flood season.The study shows that the geochemical content and its variation characteristics of sediments effectively reveal the sedimentary environment,material composition and characteristics of flood season of rivers and the lake in the study area.

Geochemical Behaviors of REE and Other Trace Elements during the Formation of Strata-bound Skarns and Related Deposits:A Case Study of the Dongguashan Cu(Au)Deposit,Anhui Province,China

REE and other trace elements in the altered marbles, massive skarns and ores, as well as garnet and quartz were determined in order to examine the behaviors of trace elements during hydrothermal alteration. It is demonstrated that the high-field-strength (HFS) elements Zr, Hf, Th and Nb were immobile while other trace elements were mobile during the formation of skarns and related deposits. REE and ore-forming elements such as Cu and Ag in hydrothermally-altered marbles and skarns were provided primarily by hydrothermal fluids. In the direction transverse of the strata, the more deeply the marbles were altered, the higher the total REE abundance and the larger the negative Eu anomalies would be. The chondrite-normalized REE patterns of skarns are similar to those of the marbles, but the former are distinguished by much higher REE contents and more remarkable negative Eu anomalies. Those patterns were apparently not inherited from the marble protolith, but were controlled by garnets, which were determined by the hydrothermal solutions involved in the infiltration metasomatism. The hydrothermal fluids are characterized by having slightly right-hand dipping REE patterns, being enriched in LREE and having strongly negative Eu anomalies. The uptake of REE from hydrothermal fluids during the growth of garnet crystals resulted in the garnets having similar REE patterns to the hydrothermal fluids. Based on the spatial variation of REE in skarns and the structures of the hosting strata, we can get a better understanding of the transport path and pattern of the fluids involved in the formation of skarns and their related deposits. REE geochemistry investigation can help elucidate the genesis of skarns and skarn-related deposits.

Element and mineral characterization of dust emission from the saline land at Songnen Plain, Northeastern China

Recent observations of Asian dust storms show an eastern expansion of the source area to degraded lands, where dust emissions have been little studied. The dust concentrations over the saline land of the western Songnen Plain （SSL）, Northeastern China, are circumstantially higher than those from the northwestern Chinese deserts. These concentrations are sensitive to the surface soil conditions and wind velocity on the ground. The dust samples collected during dust storm events on the SSL contain abundant Na, Mg, A1, K, Ca, Fe and Ti, as well as toxic elements such as Cu, V, Zn and Ba. Individual particle analysis reveals that fine saline particles （〈 10 μm in diameter） on the saline land, consisting largely of carbonate, halite and sulfate together with lithogenic minerals such as SiO2 and aluminosilicate, are eventually uplifted during the interval from spring to autuum. The predominantly fine saline particles uplifted from the SSL are likely transported eastward by the winter monsoon circulation and westerlies. Recent degradation of saline lands in Northeastern China would not only increase the frequency of dust storm events in the downwind area, but also might change the chemical composition of the Asian dust emissions.

The petrogenesis of modern and ophiolitic lavas reconsidered:Ti-V and Nb-Th

Tectonic discrimination diagrams are a key tool for understanding ancient volcanic rock origins.In this contribution we compile over 15,000 whole rock compositions to re-evaluate the Ti-V discrimination diagram and compare it to another commonly used tool,the Nb/Yb-Th/Yb diagram.We have reformulated the Ti-V diagram into a log-log plot to distinguish samples more clearly at lower concentrations.The compilation shows that MORB are dominated by Ti/V=20-43,whereas juvenile arc tholeiites and boninites are characterized by Ti/V<20 generally,although there is minor overlap at the boundary(Ti/V=20-22).Plume-related volcanic rocks(ocean island basalts,oceanic plateaux,and continental flood basalts)generally have Ti/V>43,although there may be significant overlap with MORB-like ratios for ridgecentered OIB and for some oceanic plateaux.About 56%of alkaline OIB have Ti/V>70.Back-arc basins are dominantly MORB-like.Melt models show that MORB and juvenile arc volcanics most likely formed under different fO;conditions,but are permissive of similar fO_(2)if the arc rocks form by much higher melt fractions.The Nb/Yb vs.Th/Yb plot clearly distinguishes most oceanic basalts(MORB,plateaux,OIB)from subduction-related volcanic rocks(boninite,juvenile arc tholeiite,calc-alkaline)and from flood basalts.We propose here a new two-proxy diagram of Ti/V vs.Th/Nb,which incorporates the advantages of both.

Distribution pattern and geochemical analysis of rare earth elements in deep-ocean sediments

The content and distribution pattern of rare earth elements(REEs)in surface sediments from the Eastern and Western Pacifi c Ocean,the Northern and Southern Atlantic Ocean,and the Southwestern Indian Ocean were explored and the resources and geochemical characteristics of REEs in deep-ocean sediments from diff erent oceans were studied.The total REE abundances(ΣREE)in the diff erent oceans ranged as follows:Eastern Pacifi c,56.88–500.02μg/g;Western Pacifi c,290.68–439.94μg/g;Northern Atlantic,55.33–154.90μg/g;Southern Atlantic,40.83–69.30μg/g;and Southwestern Indian Ocean,20.24–64.76μg/g.Their corresponding LREE(La-Eu)/HREE(Gd-Lu)average values were 5.18,5.86,9.01,5.21,and 4.59,which indicated that the light REEs were all evidently enriched.δEu andδCe showed slight Eu-negative anomalies and signifi cant Ce-positive anomalies in all sediments.Although the contents of REEs in the sediments varied among the diff erent oceans,the distribution patterns of REEs were similar,and the correlation coeffi cient was greater than 0.9290.In the Eastern Pacifi c sediments,ΣREE showed a signifi cantly positive correlation with Co,Cu,Zn,Mn,Mo and a weak correlation with Fe.In the Western Pacifi c and Southern Atlantic sediments,ΣREE presented no obvious correlation and a weakly negative correlation with Co,Cu,Zn,Mn,Mo and Fe,respectively.ΣREE in the Southwestern Indian Ocean sediments positively correlated with Cu,Zn,Mn,Mo,Fe,and had a weakly negative correlation with Co.

Sedimentary Records and Environmental Analysis of the Ximencuo Lake in Northeast Qinghai-Tibet Plateau in the Past 1,700 Years

Lake sediment is the recorder of historical climate fluctuation and basin environment change. This study collected the Ximencuo Lake sediment in source area of the Yellow River, analyzed organic matters and geochemical elements of the core, obtained nearly environment changes of the past 1,720 years. The results showed the environment evolution process of the 47-cm columnar core can be divided into four stages: below 32 cm(before 900 A.D.), corresponding to the cool and wet climate; 32–20 cm(900 A.D–1300 A.D.), corresponding to the warming temperature and decreasing precipitation; between 20–3.5 cm(1300–1900 A.D.), the stage is more consistent with the Little Ice Age, and precipitation gradually reduced; 3.5–0 cm(since 1900 A.D.), this is the twentieth Century warming period with increasing temperature and reduced precipitation. Phosphorus content increased rapidly in the last 20 years, reflecting the continuously increasing human interventions, but before this period, the P content was low and stable, indicating the natural background of regional phosphorus content.