Metallic nanoparticle (NP) shapes have a significant influence on the property of composite embedded with metallic NPs. Swift heavy ion irradiation is an effective way to modify shapes of metallic NPs embedded in an...Metallic nanoparticle (NP) shapes have a significant influence on the property of composite embedded with metallic NPs. Swift heavy ion irradiation is an effective way to modify shapes of metallic NPs embedded in an amorphous matrix. We investigate the shape deformation of Ag NPs with irradiation fluence, and 357 MeV Ni ions are used to irradiate the silica containing Ag NPs, which are prepared by ion implantation and vacuum annealing. The UV-vis results show that the surface plasmon resonance (SPR) peak from Ag NPs shifts from 400 to 377nm. The SPR peak has a significant shift at fluence lower than 1 × 10^14 ions/cm2 and shows less shift at fluence higher than 1 × 10^14 ions/cm2. The TEM results reveal that the shapes of Ag NPs also show significant deformation at fluence lower than 1 × 10^14 ions/cm2 and show less deformation at fluence higher than 1 × 10^14 ions/cm2. The blue shift of the SPR peak is considered to be the consequence of defect production and Ag NP shape deformation, Based on the thermal spike model calculation, the temperature of the silica surrounding Ag particles first increases rapidly, then the region of Ag NPs close to the interface of Ag/silica is gradually heated. Therefore, the driven force of Ag NPs deformation is considered as the volume expansion of the first heated silica layer surrounding Ag NPs.展开更多
The series line-commutated converter(LCC)and modular multilevel converter(MMC)hybrid high-voltage direct current(HVDC)system provides a more economical and flexible alternative for ultra-HVDC(UHVDC)transmission,which ...The series line-commutated converter(LCC)and modular multilevel converter(MMC)hybrid high-voltage direct current(HVDC)system provides a more economical and flexible alternative for ultra-HVDC(UHVDC)transmission,which is the so-called Baihetan-Jiangsu HVDC(BJ-HVDC)project of China.In one LCC and two MMCs(1+2)operation mode,the sub-module(SM)capacitors suffer the most rigorous overvoltage induced by three-phase-to-ground fault at grid-side MMC and valve-side single-phase-to-ground fault in internal MMC.In order to suppress such huge overvoltage,this paper demonstrates a novel alternative by employing the MMC-based embedded battery energy storage system(MMC-BESS).Firstly,the inducements of SM overvoltage are analyzed.Then,coordinated with MMC-BESS,new fault ride-through(FRT)strategies are proposed to suppress the overvoltage and improve the FRT capability.Finally,several simulation scenarios are carried out on PSCAD/EMTDC.The overvoltage suppression is verified against auxiliary device used in the BJ-HVDC project in a monopolar BJ-HVDC system.Further,the proposed FRT strategies are validated in the southern Jiangsu power grid of China based on the planning data in the summer of 2025.Simulation results show that the MMC-BESS and proposed FRT strategies could effectively suppress the overvoltage and improve the FRT capability.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 11475230 and U1532262
文摘Metallic nanoparticle (NP) shapes have a significant influence on the property of composite embedded with metallic NPs. Swift heavy ion irradiation is an effective way to modify shapes of metallic NPs embedded in an amorphous matrix. We investigate the shape deformation of Ag NPs with irradiation fluence, and 357 MeV Ni ions are used to irradiate the silica containing Ag NPs, which are prepared by ion implantation and vacuum annealing. The UV-vis results show that the surface plasmon resonance (SPR) peak from Ag NPs shifts from 400 to 377nm. The SPR peak has a significant shift at fluence lower than 1 × 10^14 ions/cm2 and shows less shift at fluence higher than 1 × 10^14 ions/cm2. The TEM results reveal that the shapes of Ag NPs also show significant deformation at fluence lower than 1 × 10^14 ions/cm2 and show less deformation at fluence higher than 1 × 10^14 ions/cm2. The blue shift of the SPR peak is considered to be the consequence of defect production and Ag NP shape deformation, Based on the thermal spike model calculation, the temperature of the silica surrounding Ag particles first increases rapidly, then the region of Ag NPs close to the interface of Ag/silica is gradually heated. Therefore, the driven force of Ag NPs deformation is considered as the volume expansion of the first heated silica layer surrounding Ag NPs.
文摘The series line-commutated converter(LCC)and modular multilevel converter(MMC)hybrid high-voltage direct current(HVDC)system provides a more economical and flexible alternative for ultra-HVDC(UHVDC)transmission,which is the so-called Baihetan-Jiangsu HVDC(BJ-HVDC)project of China.In one LCC and two MMCs(1+2)operation mode,the sub-module(SM)capacitors suffer the most rigorous overvoltage induced by three-phase-to-ground fault at grid-side MMC and valve-side single-phase-to-ground fault in internal MMC.In order to suppress such huge overvoltage,this paper demonstrates a novel alternative by employing the MMC-based embedded battery energy storage system(MMC-BESS).Firstly,the inducements of SM overvoltage are analyzed.Then,coordinated with MMC-BESS,new fault ride-through(FRT)strategies are proposed to suppress the overvoltage and improve the FRT capability.Finally,several simulation scenarios are carried out on PSCAD/EMTDC.The overvoltage suppression is verified against auxiliary device used in the BJ-HVDC project in a monopolar BJ-HVDC system.Further,the proposed FRT strategies are validated in the southern Jiangsu power grid of China based on the planning data in the summer of 2025.Simulation results show that the MMC-BESS and proposed FRT strategies could effectively suppress the overvoltage and improve the FRT capability.