Transparent Tm^3＋/Er^3＋/yb^3＋ co-doped oxyfluorogermanate glass ceramics containing BaF2 nanocrystals are prepared. Under excitation of a 980-nm laser diode （LD）, compared with the glass before heat treatment, th...Transparent Tm^3＋/Er^3＋/yb^3＋ co-doped oxyfluorogermanate glass ceramics containing BaF2 nanocrystals are prepared. Under excitation of a 980-nm laser diode （LD）, compared with the glass before heat treatment, the Tm^3＋/Er^3＋/yb^3＋ co-doped oxyfluorogermanate glass ceramics can emit intense blue, green and red up-conversion luminescence and Stark- split peaks; X-ray diffraction （XRD） and transmission electron microscope （TEM） results show that BaF2 nanocrystals with an average diameter of 20 nm are precipitated from the glass matrix. Stark splitting of the up-conversion luminescence peaks in the glass ceramics indicates that Tm^3＋, Er^3＋ and （or） Yb^3＋ ions are incorporated into the BaF2 nanocrystals. The up-conversion luminescence intensities of Tm^3＋, Er^3＋ and the splitting degree of luminescence peaks in the glass ceramics increase significantly with the increase of heat treat temperature and heat treat time extension. In addition, the possible energy transfer process between rare earth ions and the up-conversion luminescence mechanism are also proposed.展开更多
A method is presented that coordinates the calculation of the displacement, velocity and acceleration of structures within the time-steps of different types of step-by-step integration. The dynamic equation is solved ...A method is presented that coordinates the calculation of the displacement, velocity and acceleration of structures within the time-steps of different types of step-by-step integration. The dynamic equation is solved using an energy equation and the calculating data of the original method. The method presented is better than the original method in terms of calculating postulations and is in better conformity with the system's movement. Take the Wilson-θ method as an example. By using the coordination process, the calculation precision has been greatly im proved (reducing the errors by approximately 90% ), and the greater part of overshooting of the calculation result has been eliminated. The study suggests that the mal-coordination of the motion parameters within the time-step is the major factor that contributes to the result errors of step-by-step integration for the dynamic equation.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant Nos.61265004 and 51272097)the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No.20125314120018)
文摘Transparent Tm^3＋/Er^3＋/yb^3＋ co-doped oxyfluorogermanate glass ceramics containing BaF2 nanocrystals are prepared. Under excitation of a 980-nm laser diode （LD）, compared with the glass before heat treatment, the Tm^3＋/Er^3＋/yb^3＋ co-doped oxyfluorogermanate glass ceramics can emit intense blue, green and red up-conversion luminescence and Stark- split peaks; X-ray diffraction （XRD） and transmission electron microscope （TEM） results show that BaF2 nanocrystals with an average diameter of 20 nm are precipitated from the glass matrix. Stark splitting of the up-conversion luminescence peaks in the glass ceramics indicates that Tm^3＋, Er^3＋ and （or） Yb^3＋ ions are incorporated into the BaF2 nanocrystals. The up-conversion luminescence intensities of Tm^3＋, Er^3＋ and the splitting degree of luminescence peaks in the glass ceramics increase significantly with the increase of heat treat temperature and heat treat time extension. In addition, the possible energy transfer process between rare earth ions and the up-conversion luminescence mechanism are also proposed.
文摘A method is presented that coordinates the calculation of the displacement, velocity and acceleration of structures within the time-steps of different types of step-by-step integration. The dynamic equation is solved using an energy equation and the calculating data of the original method. The method presented is better than the original method in terms of calculating postulations and is in better conformity with the system's movement. Take the Wilson-θ method as an example. By using the coordination process, the calculation precision has been greatly im proved (reducing the errors by approximately 90% ), and the greater part of overshooting of the calculation result has been eliminated. The study suggests that the mal-coordination of the motion parameters within the time-step is the major factor that contributes to the result errors of step-by-step integration for the dynamic equation.
