Idealized cycles of refrigerating machines with adiabatic and isothermal compression of refrigerant vapor were investigated. Energetic characteristics of cycles: specific mass and volume cooling capacity q0 and qv, w...Idealized cycles of refrigerating machines with adiabatic and isothermal compression of refrigerant vapor were investigated. Energetic characteristics of cycles: specific mass and volume cooling capacity q0 and qv, work of compression 1, refrigerating coefficient of performance e and power N for drive of compressor were compared. These characteristics were calculated for eight refrigerants at temperature of their condensation 30 ℃ and temperatures of boiling -15℃ and -30 ℃. The calculations show that the use of isothermal compression of refrigerant vapor ensures economy of energy during refrigerating machine operation.展开更多
The estimation of chemical particles reactivity and the determination of chemical reactions direction are the actual theme in new scientific trend-Chemical Mesoscopics.Paper includes the proposal about the using the t...The estimation of chemical particles reactivity and the determination of chemical reactions direction are the actual theme in new scientific trend-Chemical Mesoscopics.Paper includes the proposal about the using the theory of free energy linear dependence from physical organic chemistry and their applications for prognosis of reactions flowing.The semi-empiric constants is given according to mesoscopic physics definitions as well as the transformed Kolmogorov-Avrami equation is discussed.It is the development of Chemical Mesoscopics for organic reactivity estimation including nanostructures reactivity.展开更多
文摘Idealized cycles of refrigerating machines with adiabatic and isothermal compression of refrigerant vapor were investigated. Energetic characteristics of cycles: specific mass and volume cooling capacity q0 and qv, work of compression 1, refrigerating coefficient of performance e and power N for drive of compressor were compared. These characteristics were calculated for eight refrigerants at temperature of their condensation 30 ℃ and temperatures of boiling -15℃ and -30 ℃. The calculations show that the use of isothermal compression of refrigerant vapor ensures economy of energy during refrigerating machine operation.
文摘The estimation of chemical particles reactivity and the determination of chemical reactions direction are the actual theme in new scientific trend-Chemical Mesoscopics.Paper includes the proposal about the using the theory of free energy linear dependence from physical organic chemistry and their applications for prognosis of reactions flowing.The semi-empiric constants is given according to mesoscopic physics definitions as well as the transformed Kolmogorov-Avrami equation is discussed.It is the development of Chemical Mesoscopics for organic reactivity estimation including nanostructures reactivity.