In order to simulate and study the mechanism of cement stabilized soils polluted by different contents of magnesium sulfate(MS), a series of tests were conducted on the cemented soil samples, including unconfined comp...In order to simulate and study the mechanism of cement stabilized soils polluted by different contents of magnesium sulfate(MS), a series of tests were conducted on the cemented soil samples, including unconfined compression strength(UCS) tests of blocks, X-ray diffraction(XRD) phase analysis of powder samples, microstructure by scanning electronic microscopy(SEM),element composition by energy dispersive spectrometry(EDS), and pore distribution analysis by Image Processed Plus 6.0(IPP 6.0)software. The UCS test results show that UCS of cemented soils reaches the peak value when the MS content is 4.5 g/kg. While, the UCS for Sample MS4 having the MS content of 18.0 g/kg is the lowest among all tested samples. Based on the EDS analysis results,Sample MS4 has the greater contents for the three elements, oxygen(O), magnesium(Mg) and sulfur(S), than Sample MS1. From the XRD phase analysis, C-A-S-H(3Ca O·Al2O3·3Ca SO4·32H2O and 3Ca O·Al2O3·Ca SO4·18H2O), M-A-H(Mg O·Al2O3·H2O), M-S-H(Mg O·Si O2·H2O), Mg(OH)2 and Ca SO4 phase diffraction peaks are obviously intense due to the chemical action associated with the MS. The pore distribution analysis shows that the hydrated products change the distribution of cemented soil pores and the pores with average diameter(AD) of 2-50 μm play a key role in terms of the whole structure of cemented soil. The microscopic structure of the cemented soil with MS exhibits the intertwined and embedded characteristics between the cement and granular soils from the SEM images of cemented soils. The microstructure analysis shows that the magnesium sulfate acts as the additive, which is beneficial to the soil strength when the MS content is low(i.e., Sample MS2). However, higher MS amount involving a chemical action makes samples crystallize and expand, which is adverse to the UCS of cemented soils(i.e., Sample MS4).展开更多
The chemical compositions,mineralogical characteristics,as well as dissemination of iron-and phosphorus-based minerals were studied for the E’xi oolitic hematite from western Hubei Province in China by using chemical...The chemical compositions,mineralogical characteristics,as well as dissemination of iron-and phosphorus-based minerals were studied for the E’xi oolitic hematite from western Hubei Province in China by using chemical analysis,optical microscope,electron probe micro-analyzer(EPMA)and energy dispersive spectroscopy(EDS).It is found that this kind of oolitic hematite ore contains 47.71%TFe,10.96%SiO_2,as well as 0.874%P,with hematite as the dominant Fe-bearing minerals,and quartz,chamosite,illite and cellophane as main gangue minerals.The microscope examination showed that the ore has an oolitic structure,with some ooids principally formed by a series of concentric layers of hematite collophanite around nucleus that is hematite in the association with collophanite.Based on the EPMA and EDS analysis,it can be known that some ooids are primarily composed of hematite and collophanite.The separation can be achieved through fine grinding for those collophanite laminae with a higher P content.However,the dissemination of two minerals at the interface will result in the difficulty in effective separation.Besides,some ooids are made of chamosite with some nucleus formed of quartz,which is principally finely disseminated with hematite.In view of the close association and dissemination of iron-and phosphorus-based minerals in the ooids,it is found that the process of stage-grindings and stage-separations can be adopted to effectively increase the iron recovery and decrease the P content in the concentrate to some extent.展开更多
Diesel engines is an internal combustion engine with high thermal efficiency,which also uses biodiesel fuel,an environmentally friendly,non-toxic,and low sulfur content.Biodiesel has been around for a long time due to...Diesel engines is an internal combustion engine with high thermal efficiency,which also uses biodiesel fuel,an environmentally friendly,non-toxic,and low sulfur content.Biodiesel has been around for a long time due to its similar characteristics to diesel fuels which has limited availability.However,several disadvantages are associated with biodiesel,such as poor volatility and high viscosity,which reduces engine performance.Therefore,this study was carried out to improve the diesel engine performance by mixing biodiesel with ecodiesel(ED),an additive produced from natural ingredients that is dissolvable in biodiesel.The biodiesel fuel properties used are density 860 kg/m3,dynamic viscosity 4.50E-06 m2/s,cetane number 45,and flashpoint 52°C.The results showed that biodiesel-ED mixture could improve engine performance and the optimum performance was at a speed of 3000 rpm on 43.30(kW),124.93(N.m)of the engine torque,and 2.45E–5(kg/kW.s)of the specific fuel consumption.According to paired sample t-test,the difference in the engine performance is only experienced in the torque,which has a significant increase in the composition of the biodiesel+ED by 0.07 gr mixture.展开更多
To explore ways to improve the accuracy of quantitative analysis of samples in the micrometer to nanometer range of magnitudes,we adopted analytical transmission electron microscopy(AEM/EDS)for qualitative and quantit...To explore ways to improve the accuracy of quantitative analysis of samples in the micrometer to nanometer range of magnitudes,we adopted analytical transmission electron microscopy(AEM/EDS)for qualitative and quantitative analysis of pyrite materials.Additionally,the k factor of pyrite is calculated experimentally.To develop an appropriate non-standard quantitative analysis model for pyrite materials,the experimentally calculated k factor is compared with that estimated from the non-standard quantitative analytical model of the instrument software.The experimental findings demonstrate that the EDS attached to a TEM can be employed for precise quantitative analysis of micro-and nanoscale regions of pyrite materials.Furthermore,it serves as a reference for improving the results of the EDS quantitative analysis of other sulfides.展开更多
The study indicates that public-private partnerships （PPPs） can play ＂strategic＂, ＂practical＂, or ＂regulative＂ roles by making use of ＂instrumental＂, ＂institutional＂, and ＂normative＂ approaches in tackli...The study indicates that public-private partnerships （PPPs） can play ＂strategic＂, ＂practical＂, or ＂regulative＂ roles by making use of ＂instrumental＂, ＂institutional＂, and ＂normative＂ approaches in tackling political issues between countries. PPPs have often been discussed in studies of urban development, service provision, health care, and so on, but they have rarely been analyzed in terms of international relations and political problems on global environmental issues. This study takes an environmental problena---Sino-US energy and climate change cooperation--as a case study to inspect the possible roles and approaches of PPPs. Sino-US cooperation has been launched such as under the Strategic ＆ Economic Dialogue （S＆ED） by both administrations, which has significantly contributed to their reconciliation of domestic abatement policies in climate change, environmental protection, and energy. The establishment of schemes such as the Ten-Year Framework for Cooperation on Energy and Environment （TYF）, the EcoPartnerships, and wide-ranging dialogues and initiatives on clean energy and clean vehicles, in which both public and private actors participate, are among the important approaches of facilitating bilateral cooperation. The study concludes that these schemes have played strategic and practical roles in strengthening the degree of mutual trust and in facilitating the progress of cooperation, although more investigations are needed to considerate their regulative roles. The application of instrumental, institutional, and normative approaches have been observed through the implementation of the TYF and EcoPartnerships.展开更多
The study of natural magnetic sands is instrumental to investigate the geological aspects of their formation and of the origin of their territory. In particular, Mossbauer spectroscopy provides unique information on t...The study of natural magnetic sands is instrumental to investigate the geological aspects of their formation and of the origin of their territory. In particular, Mossbauer spectroscopy provides unique information on their iron content and on the oxidation state of iron in their mineral composition. The Italian coast on the Mediterranean Sea near Rome is known for the presence of highly magnetic black sands of volcanic origin. A study of the room temperature Mossbauer spectrum, powder X-ray diffraction, energy dispersive X-ray spectroscopy, and magnetic measurements of a sample of black magnetic sand collected on the seashore of the town of Ladispoli is performed. This study reveals magnetite as main constituent with iron in both tetrahedral and octahedral sites. Minor constituents are the iron minerals hematite and ilmenite, the iron containing minerals diopsite, gossular, and allanite, as well as ubiquitous sanidine, quartz, and calcite.展开更多
基金Projects(51208333,51078253)supported by the National Natural Science Foundation of China
文摘In order to simulate and study the mechanism of cement stabilized soils polluted by different contents of magnesium sulfate(MS), a series of tests were conducted on the cemented soil samples, including unconfined compression strength(UCS) tests of blocks, X-ray diffraction(XRD) phase analysis of powder samples, microstructure by scanning electronic microscopy(SEM),element composition by energy dispersive spectrometry(EDS), and pore distribution analysis by Image Processed Plus 6.0(IPP 6.0)software. The UCS test results show that UCS of cemented soils reaches the peak value when the MS content is 4.5 g/kg. While, the UCS for Sample MS4 having the MS content of 18.0 g/kg is the lowest among all tested samples. Based on the EDS analysis results,Sample MS4 has the greater contents for the three elements, oxygen(O), magnesium(Mg) and sulfur(S), than Sample MS1. From the XRD phase analysis, C-A-S-H(3Ca O·Al2O3·3Ca SO4·32H2O and 3Ca O·Al2O3·Ca SO4·18H2O), M-A-H(Mg O·Al2O3·H2O), M-S-H(Mg O·Si O2·H2O), Mg(OH)2 and Ca SO4 phase diffraction peaks are obviously intense due to the chemical action associated with the MS. The pore distribution analysis shows that the hydrated products change the distribution of cemented soil pores and the pores with average diameter(AD) of 2-50 μm play a key role in terms of the whole structure of cemented soil. The microscopic structure of the cemented soil with MS exhibits the intertwined and embedded characteristics between the cement and granular soils from the SEM images of cemented soils. The microstructure analysis shows that the magnesium sulfate acts as the additive, which is beneficial to the soil strength when the MS content is low(i.e., Sample MS2). However, higher MS amount involving a chemical action makes samples crystallize and expand, which is adverse to the UCS of cemented soils(i.e., Sample MS4).
基金Project(51474161)supported by the National Natural Science Foundation of China
文摘The chemical compositions,mineralogical characteristics,as well as dissemination of iron-and phosphorus-based minerals were studied for the E’xi oolitic hematite from western Hubei Province in China by using chemical analysis,optical microscope,electron probe micro-analyzer(EPMA)and energy dispersive spectroscopy(EDS).It is found that this kind of oolitic hematite ore contains 47.71%TFe,10.96%SiO_2,as well as 0.874%P,with hematite as the dominant Fe-bearing minerals,and quartz,chamosite,illite and cellophane as main gangue minerals.The microscope examination showed that the ore has an oolitic structure,with some ooids principally formed by a series of concentric layers of hematite collophanite around nucleus that is hematite in the association with collophanite.Based on the EPMA and EDS analysis,it can be known that some ooids are primarily composed of hematite and collophanite.The separation can be achieved through fine grinding for those collophanite laminae with a higher P content.However,the dissemination of two minerals at the interface will result in the difficulty in effective separation.Besides,some ooids are made of chamosite with some nucleus formed of quartz,which is principally finely disseminated with hematite.In view of the close association and dissemination of iron-and phosphorus-based minerals in the ooids,it is found that the process of stage-grindings and stage-separations can be adopted to effectively increase the iron recovery and decrease the P content in the concentrate to some extent.
文摘Diesel engines is an internal combustion engine with high thermal efficiency,which also uses biodiesel fuel,an environmentally friendly,non-toxic,and low sulfur content.Biodiesel has been around for a long time due to its similar characteristics to diesel fuels which has limited availability.However,several disadvantages are associated with biodiesel,such as poor volatility and high viscosity,which reduces engine performance.Therefore,this study was carried out to improve the diesel engine performance by mixing biodiesel with ecodiesel(ED),an additive produced from natural ingredients that is dissolvable in biodiesel.The biodiesel fuel properties used are density 860 kg/m3,dynamic viscosity 4.50E-06 m2/s,cetane number 45,and flashpoint 52°C.The results showed that biodiesel-ED mixture could improve engine performance and the optimum performance was at a speed of 3000 rpm on 43.30(kW),124.93(N.m)of the engine torque,and 2.45E–5(kg/kW.s)of the specific fuel consumption.According to paired sample t-test,the difference in the engine performance is only experienced in the torque,which has a significant increase in the composition of the biodiesel+ED by 0.07 gr mixture.
基金Funded by the International Science&Technology Cooperation Program of Hubei Province of China(No.2022EHB024)。
文摘To explore ways to improve the accuracy of quantitative analysis of samples in the micrometer to nanometer range of magnitudes,we adopted analytical transmission electron microscopy(AEM/EDS)for qualitative and quantitative analysis of pyrite materials.Additionally,the k factor of pyrite is calculated experimentally.To develop an appropriate non-standard quantitative analysis model for pyrite materials,the experimentally calculated k factor is compared with that estimated from the non-standard quantitative analytical model of the instrument software.The experimental findings demonstrate that the EDS attached to a TEM can be employed for precise quantitative analysis of micro-and nanoscale regions of pyrite materials.Furthermore,it serves as a reference for improving the results of the EDS quantitative analysis of other sulfides.
文摘The study indicates that public-private partnerships （PPPs） can play ＂strategic＂, ＂practical＂, or ＂regulative＂ roles by making use of ＂instrumental＂, ＂institutional＂, and ＂normative＂ approaches in tackling political issues between countries. PPPs have often been discussed in studies of urban development, service provision, health care, and so on, but they have rarely been analyzed in terms of international relations and political problems on global environmental issues. This study takes an environmental problena---Sino-US energy and climate change cooperation--as a case study to inspect the possible roles and approaches of PPPs. Sino-US cooperation has been launched such as under the Strategic ＆ Economic Dialogue （S＆ED） by both administrations, which has significantly contributed to their reconciliation of domestic abatement policies in climate change, environmental protection, and energy. The establishment of schemes such as the Ten-Year Framework for Cooperation on Energy and Environment （TYF）, the EcoPartnerships, and wide-ranging dialogues and initiatives on clean energy and clean vehicles, in which both public and private actors participate, are among the important approaches of facilitating bilateral cooperation. The study concludes that these schemes have played strategic and practical roles in strengthening the degree of mutual trust and in facilitating the progress of cooperation, although more investigations are needed to considerate their regulative roles. The application of instrumental, institutional, and normative approaches have been observed through the implementation of the TYF and EcoPartnerships.
文摘The study of natural magnetic sands is instrumental to investigate the geological aspects of their formation and of the origin of their territory. In particular, Mossbauer spectroscopy provides unique information on their iron content and on the oxidation state of iron in their mineral composition. The Italian coast on the Mediterranean Sea near Rome is known for the presence of highly magnetic black sands of volcanic origin. A study of the room temperature Mossbauer spectrum, powder X-ray diffraction, energy dispersive X-ray spectroscopy, and magnetic measurements of a sample of black magnetic sand collected on the seashore of the town of Ladispoli is performed. This study reveals magnetite as main constituent with iron in both tetrahedral and octahedral sites. Minor constituents are the iron minerals hematite and ilmenite, the iron containing minerals diopsite, gossular, and allanite, as well as ubiquitous sanidine, quartz, and calcite.
