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变温下荧光猝灭和加强理论公式合理性的比较 被引量:29
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作者 杨曼曼 席小莉 杨频 《化学学报》 SCIE CAS CSCD 北大核心 2006年第14期1437-1445,共9页
通过荧光和紫外方法研究盐酸左氧氟沙星、氟罗沙星、加替沙星和沃氟沙星四种喹诺酮类药物与人血清白蛋白(HSA)的作用,在不同温度下对荧光加强和猝灭理论公式的等价性和精细差异进行了比较,结果表明:在不同温度下两种理论公式尽管在求取... 通过荧光和紫外方法研究盐酸左氧氟沙星、氟罗沙星、加替沙星和沃氟沙星四种喹诺酮类药物与人血清白蛋白(HSA)的作用,在不同温度下对荧光加强和猝灭理论公式的等价性和精细差异进行了比较,结果表明:在不同温度下两种理论公式尽管在求取解离常数上所得结果都可视为有效,但猝灭方程的双倒数图反而不及荧光加强方程的双倒数图与体现动态、静态猝灭机理的猝灭曲线一致.对于能量转移效率E,我们首次定义:按自由荧光体白蛋白的荧光强度F0和加入药物至荧光不再变化时的荧光强度F值计算F/F0,进而将F/F0代入0E1F=-F计算能量转移效率E.它标示出每个体系发生能量转移的最大限度,向体系中再添加药物,已不能发生进一步的猝灭,这一新定义的引入,使得能量转移效率E这一量值有可能推广到估算白蛋白运载药物能力的最大限度. 展开更多
关键词 荧光猝灭和加强 能量转移效率 人血清白蛋白 喹诺酮类药物
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A preliminary snapshot of the trophic model and ecosystem attributes of Kaptai reservoir ecosystem, Bangladesh 被引量:1
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作者 Mst Halima KHATUN Partho Protim BARMAN +3 位作者 YI Jundong Saymuna Tarin LUPA Md Mahiuddin ZAHANGIR Qun LIU 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2021年第1期223-241,共19页
A mass-balanced Ecopath model presents a quantitative description of the trophic structure,fl ow of energy and trophic interaction among ecological groups of an ecosystem.The Ecopath with Ecosim(EwE)modeling program(V... A mass-balanced Ecopath model presents a quantitative description of the trophic structure,fl ow of energy and trophic interaction among ecological groups of an ecosystem.The Ecopath with Ecosim(EwE)modeling program(Version 6.5)was used to develop a preliminary trophic model for a tropical freshwater reservoir.The total fi sh biomass was 6.245 t/km 2 and the highest trophic level of the reservoir was 3.362(for snakehead).The ecosystem is phytoplankton based because primary producers originated 68%and detritus originated 32%of the total fl ow from lower trophic level.The gross effi ciency of the fi shery was 0.004,suggesting the ineffi ciency of the system.The positive eff ect of phytoplankton and detritus on most of the other groups were evident from mixed trophic analysis while moderately higher ecotrophic effi ciency(EE)of phytoplankton shows the ecosystem’s potential bottom-up control.The competition for the same resources among diff erent groups was also obvious.The ratio of primary production/respiration(1.969)suggests that the ecosystem is at the developing stage and utmost contemplation should be given to concerned human activities.The low value of relative ascendancy(30.13)and overhead(69.87)reveals the stability of the ecosystem and some degrees of maturity.It also predicts the presence of signifi cant strength in reserve of the system to withstand or overcome any perturbation.However,ecologically sustainable resource management plans should be implemented to ensure the sustainability of this reservoir resources. 展开更多
关键词 ECOPATH Kaptai reservoir trophic interaction transfer effi ciency energy flow
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Influence of flange location on axial deformation stability of double-hat structure
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作者 武雪原 夏勇 周青 《Journal of Beijing Institute of Technology》 EI CAS 2012年第1期41-49,共9页
A new structural configuration with better impact stability for increasing energy absorbing efficiency is found. Based on finite element analysis, deformation modes of double-hat structure under axial impact loading a... A new structural configuration with better impact stability for increasing energy absorbing efficiency is found. Based on finite element analysis, deformation modes of double-hat structure under axial impact loading are categorized to find the main reasons that affect deformation stability. It is revealed that, in a double-hat structure, the location of the flanges is highly related to the deform- ation mode and energy absorbing efficiency. Moving the flanges away from their traditional mid-loca- tion may result in more regular and stable deformation mode and achieve higher energy absorbing ef- ficiency. The flange offset value needs to be controlled within a certain range, otherwise, the doub- le-hat structure would tend to deform like a top-hat structure and the energy absorbing efficiency could be compromised. These findings and analyses lead to a new structural design configuration- asymmetric flange locations--for enhancing the deformation mode stability in double-hat structures. 展开更多
关键词 double-hat structure structural stability plastic deformation energy absorbing effi- ciency
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