A new deformable cable for rock support in high stress tunnel:Steel pipe shrinkable energy-absorbing cable

High stress in surrounding rock will lead to serious problems,e.g.,rock burst in hard rock and large deformation in soft rock.The applied support system under high in-situ stress conditions should be able to carry high load and also accommodate large deformation without experiencing severe damage.In this paper,a specially designed energy-absorbing component for rock bolt and cable that can solve the above problems was proposed.The energy-absorbing component can provide support resistance by plastic deformation of the metal including constraint annulus and compression pipe.For practical engineering,two forms were proposed.One was installed in the surrounding rock by reaming,and the other was installed directly outside the surrounding rock.During the dilation of the surrounding rock,the relative displacement of constraint annulus and compression pipe occurs,resulting in deformation resistance.Deformation resistance is transmitted to the rock bolt or cable,providing support resistance.The lab test and numerical simulation showed that the energy-absorbing component can perfectly achieve the large deformation effect,the deformation amount is as high as 694 mm,and the bearing capacity is stable at 367 kN.The field application tests were carried out in the mining roadway of Xinjulong coal mine,and the results showed that the new type of cable can ensure itself not to break under the condition of large deformation of the surrounding rock.The energy-absorbing component has the superiorities of performing large constant resistance and controllable deformation to effectively control the unpredictable disasters such as large deformation in soft rock and rock burst in hard rock encountered in deep strata.

The low-latitude sodium layer:comparative data from lidar observations at Hainan,China and São Paulo,Brazil

Physical and chemical processes observed in the mesosphere and thermosphere above the Earth’s low latitudes are complex and highly interrelated to activity in the low-latitude ionosphere.Metallic sodium detected by lidar can yield clues to dynamic and chemical processes in these spatial layers above the Earth’s atmosphere.This paper is based on sodium layer data collected at two low-latitude stations,one in the northern hemisphere and one in the southern.The low-latitude sodium layer exhibits conspicuous seasonal variations in shape,density,and altitude;these variations are similar between Earth’s hemispheres:sodium layer density at both stations reaches its seasonal maximum in autumn and minimum in summer.However,maximal Na density over Brazil is greater than that over Hainan.Nocturnal variations of Na density above the two low-latitude stations are also similar;at both,maxima are observed before sunrise.Some variations of the Na layer over Brazil that differ from those observed in the northern hemisphere may be related to the South Atlantic Magnetic Anomaly(SAMA)or fountain effect.We suggest that low-latitude Na layer data may provide useful additional evidence that could significantly improve the low-latitude part of the WACCM-Na model.

Comparative analysis of empirical and deep learning models for ionospheric sporadic E layer prediction

Sporadic E(Es)layers in the ionosphere are characterized by intense plasma irregularities in the E region at altitudes of 90-130 km.Because they can significantly influence radio communications and navigation systems,accurate forecasting of Es layers is crucial for ensuring the precision and dependability of navigation satellite systems.In this study,we present Es predictions made by an empirical model and by a deep learning model,and analyze their differences comprehensively by comparing the model predictions to satellite RO measurements and ground-based ionosonde observations.The deep learning model exhibited significantly better performance,as indicated by its high coefficient of correlation(r=0.87)with RO observations and predictions,than did the empirical model(r=0.53).This study highlights the importance of integrating artificial intelligence technology into ionosphere modelling generally,and into predicting Es layer occurrences and characteristics,in particular.

Müller cells are activated in response to retinal outer nuclear layer degeneration in rats subjected to simulated weightlessness conditions

A microgravity environment has been shown to cause ocular damage and affect visual acuity,but the underlying mechanisms remain unclear.Therefore,we established an animal model of weightlessness via tail suspension to examine the pathological changes and molecular mechanisms of retinal damage under microgravity.After 4 weeks of tail suspension,there were no notable alterations in retinal function and morphology,while after 8 weeks of tail suspension,significant reductions in retinal function were observed,and the outer nuclear layer was thinner,with abundant apoptotic cells.To investigate the mechanism underlying the degenerative changes that occurred in the outer nuclear layer of the retina,proteomics was used to analyze differentially expressed proteins in rat retinas after 8 weeks of tail suspension.The results showed that the expression levels of fibroblast growth factor 2(also known as basic fibroblast growth factor)and glial fibrillary acidic protein,which are closely related to Müller cell activation,were significantly upregulated.In addition,Müller cell regeneration and Müller cell gliosis were observed after 4 and 8 weeks,respectively,of simulated weightlessness.These findings indicate that Müller cells play an important regulatory role in retinal outer nuclear layer degeneration during weightlessness.

Anchoring effect and energy-absorbing support mechanism of large deformation bolt

To research the anchoring effect of large deformation bolt,tensile and drawing models are established.Then,the evolution laws of drawing force,bolt axial force and interfacial shear stress are analyzed.Additionally,the influence of structure element position on the anchoring effect of large deformation bolt is discussed.At last,the energy-absorbing support mechanism is discussed.Results show that during the drawing process of normal bolt,drawing force,bolt axial force and interfacial shear stress all gradually increase as increasing the drawing displacement,but when the large deformation bolt enters the structural deformation stage,these three values will keep stable;when the structure element of large deformation bolt approaches the drawing end,the fluctuation range of drawing force decreases,the distributions of bolt axial force and interfacial shear stress of anchorage section are steady and the increasing rate of interfacial shear stress decreases,which are advantageous for keeping the stress stability of the anchorage body.During the working process of large deformation bolt,the strain of bolt body is small,the working resistance is stable and the distributions of bolt axial force and interfacial shear stress are steady.When a rock burst event occurs,the bolt and bonding interface cannot easily break,which weakens the dynamic disaster degree.

Dynamic mechanical characteristics and application of constant resistance energy-absorbing supporting material

In deep underground engineering,rock burst and other dynamic disasters are prone to occur due to stress concentration and energy accumulation in surrounding rock.The control of dynamic disasters requires bolts and cables with high strength,high elongation,and high energy-absorbing capacity.Therefore,a constant resistance energy-absorbing(CREA)material is developed.In this study,the dynamic characteristics of the new material are obtained via the drop hammer tests and the Split Hopkinson Pressure Bar(SHPB)tests of the new material and two common bolt(CB)materials widely used in the field.The test results of drop hammer test and SHPB test show that the percentage elongation of CREA material is more than 2.64 and 3.22 times those of the CB material,and the total impact energy acting on CREA material is more than 18.50 and 21.84 times,respectively,indicating that the new material has high elongation and high energy-absorbing capacity.Subsequently,the CREA bolts and cables using the new material are developed,which are applied in roadways with high stress and strong dynamic disturbance.The field monitoring results show that CREA bolts and cables can effectively control the surrounding rock deformation and ensure engineering safety.

A new energy-absorbing bolt used for large deformation control of tunnel surrounding rock

In order to control the large deformation of tunnel surrounding rock,a new energy-absorbing bolt is developed.This bolt can be transformed into a rigid support when the deformation of the surrounding rock reaches the length of the sleeve tube,thus preventing the surrounding rock from continuing to deform.Moreover,this bolt has a simple structure and is easy to manufacture and assemble.Then the static tensile test is conducted on the bolt specimen to test its working performance.The test results show that when the cone angle of the cone block is small,the load–displacement curve of the bolt contains three stages;when the cone angle is large,the load–displacement curve contains only two stages.Meanwhile,both the average constant resistance and the maximum absorbed energy increase linearly with the increase of cone angle.On this basis,ignoring the influence of shear stress,and it is supposed that the thickness of the sleeve tube is constant,then the theoretical calculation formula of constant resistance for the new bolt is derived,and the rationality of the formula is verified using the static tensile test results.It is found that the error of the calculated result is less than 15%when the cone angle does not exceed 15.At last,the numerical simulation method is used to analyze the performance of the new bolt.The simulation results indicate that the generation of shear stress and the change of tube thickness during the movement of the cone block are two important factors that cause theoretical errors.

Numerical modeling on strain energy evolution in rock system interaction with energy-absorbing prop and rock bolt

The interaction mechanism between coal and rock masses with supporting materials is significant in roadway control, especially in deep underground mining situations where dynamic hazards frequently happened due to high geo-stress and strong disturbed effects. This paper is to investigate the strain energy evolution in the interaction between coal and rock masses with self-designed energy-absorbing props and rock bolts by numerical modeling with the finite difference method. The interaction between rock and rock bolt/prop is accomplished by the cables element and the interface between the inner and outer props. Roadway excavation and coal extraction conditions in deep mining are numerically employed to investigate deformation, plastic zone ranges, strain energy input, accumulation, dissipation,and release. The effect on strain energy input, accumulation, dissipation, and release with rock deformation, and the plastic zone is addressed. A ratio of strain energy accumulation, dissipation, and release with energy input a, β, γ is to assess the dynamic hazards. The effects on roadway excavation and coal extraction steps of a, β, γ are discussed. The results show that:(1) In deep high geo-stress roadways, the energyabsorbing support system plays a dual role in resisting deformation and reducing the scope of plastic zones in surrounding rock, as well as absorbing energy release in the surrounding rock, especially in the coal extraction state to mitigate disturbed effects.(2) The strain energy input, accumulation is dependent on roadway deformation, the strain energy dissipation is relied on plastic zone area and disturbed effects, and strain energy release density is the difference among the three. The function of energyabsorbing rock bolts and props play a key role to mitigate strain energy release density and amount, especially in coal extraction condition, with a peak density value from 4×10^(4) to 1×10^(4)J/m^(3), and amount value from 3.57×10^(8) to 1.90×10^(6)J.(3) When mining is advanced in small steps, the strain energy accumulation is dominated. While in a large step, the released energy is dominant, thus a more dynamic hazards proneness. The energy-absorbing rock bolt and prop can reduce three times strain energy release amount, thus reducing the dynamic hazards. The results suggest that energy-absorbing props and rock bolts can effectively reduce the strain energy in the coal and rock masses, and prevent rock bursts and other hazards.The numerical model developed in this study can also be used to optimize the design of energyabsorbing props and rock bolts for specific mining conditions.

Effect of dynamic loading conditions on the dynamic performance of MP1 energy-absorbing rockbolts:Insight from laboratory drop test

Energy-absorbing rockbolts have been widely adopted in burst-prone excavation support, and their serviceability is closely related to the frequency and magnitude of seismic events. In this research, the splittube drop test with varying impact energy was conducted to reproduce the dynamic performance of MP1rockbolts under a wide range of seismic event magnitudes. The test results showed that the impact process could be subdivided into four distinct stages, i.e. mobilization, strain hardening, plastic flow(ductile), and rebound stage, of which strain hardening and plastic flow are the primary energy absorbing stages. As the impact energy per drop increases from 8.1 to 46.7 k J, the strain rate of the shank varies between 1.20 and 2.70 s^(-1), and the average impact load is between 240 and 270kN, which may be considered as constant. The MP1 rockbolt has a cumulative maximum energy absorption(CMEA) of 31.9–40.0 k J/m, with an average of 35.0 k J/m, and the elongation rate is 11.4%–14.7%, with an average of 12.7%, both of which are negatively correlated with the impact energy per drop. Regression analysis shows that energy absorption and shank elongation, as well as momentum input and impact duration,conform to the linear relationship. The complete dynamic capacity envelope of MP1 rockbolts is proposed, which reflects the dynamic bearing capacity, elongation, and distinct stages. This study is helpful to better understand the dynamic characteristics of energy-absorbing rockbolts and assist design engineers in robust reinforcement systems design to mitigate rockburst damage in seismically active underground excavations.

Layered Structural PBAT Composite Foams for Efficient Electromagnetic Interference Shielding

The utilization of eco-friendly,lightweight,high-efficiency and high-absorbing electromagnetic interference(EMI)shielding composites is imperative in light of the worldwide promotion of sustainable manufacturing.In this work,magnetic poly(butyleneadipate-coterephthalate)(PBAT)microspheres were firstly synthesized via phase separation method,then PBAT composite foams with layered structure was constructed through the supercritical carbon dioxide foaming and scraping techniques.The merits of integrating ferroferric oxideloaded multi-walled carbon nanotubes(Fe3O4@MWCNTs)nanoparticles,a microcellular framework,and a highly conductive silver layer have been judiciously orchestrated within this distinctive layered configuration.Microwaves are consumed throughout the process of“absorption-reflection-reabsorption”as much as possible,which greatly declines the secondary radiation pollution.The biodegradable PBAT composite foams achieved an EMI shielding effectiveness of up to 68 dB and an absorptivity of 77%,and authenticated favorable stabilization after the tape adhesion experiment.

Significantly Improved High-Temperature Energy Storage Performance of BOPP Films by Coating Nanoscale Inorganic Layer

Biaxially oriented polypropylene(BOPP)is one of the most commonly used commercial capacitor films,but its upper operating temperature is below 105℃due to the sharply increased electrical conduction loss at high temperature.In this study,growing an inorganic nanoscale coating layer onto the BOPP film's surface is proposed to suppress electrical conduction loss at high temperature,as well as increase its upper operating temperature.Four kinds of inorganic coating layers that have different energy band structure and dielectric property are grown onto the both surface of BOPP films,respectively.The effect of inorganic coating layer on the high-temperature energy storage performance has been systematically investigated.The favorable coating layer materials and appropriate thickness enable the BOPP films to have a significant improvement in high-temperature energy storage performance.Specifically,when the aluminum nitride(AIN)acts as a coating layer,the AIN-BOPP-AIN sandwich-structured films possess a discharged energy density of 1.5 J cm^(-3)with an efficiency of 90%at 125℃,accompanying an outstandingly cyclic property.Both the discharged energy density and operation temperature are significantly enhanced,indicating that this efficient and facile method provides an important reference to improve the high-temperature energy storage performance of polymer-based dielectric films.

High‑Entropy Layered Oxide Cathode Enabling High‑Rate for Solid‑State Sodium‑Ion Batteries

Na-ion O3-type layered oxides are prospective cathodes for Na-ion batteries due to high energy density and low-cost.Nevertheless,such cathodes usually suffer from phase transitions,sluggish kinetics and air instability,making it difficult to achieve high performance solid-state sodium-ion batteries.Herein,the high-entropy design and Li doping strategy alleviate lattice stress and enhance ionic conductivity,achieving high-rate performance,air stability and electrochemically thermal stability for Na_(0.95)Li_(0.06)Ni_(0.25)Cu_(0.05)Fe_(0.15)Mn_(0.49)O_(2).This cathode delivers a high reversible capacity(141 mAh g^(−1)at 0.2C),excellent rate capability(111 mAh g^(−1)at 8C,85 mAh g^(−1)even at 20C),and long-term stability(over 85%capacity retention after 1000 cycles),which is attributed to a rapid and reversible O3–P3 phase transition in regions of low voltage and suppresses phase transition.Moreover,the compound remains unchanged over seven days and keeps thermal stability until 279℃.Remarkably,the polymer solid-state sodium battery assembled by this cathode provides a capacity of 92 mAh g^(−1)at 5C and keeps retention of 96%after 400 cycles.This strategy inspires more rational designs and could be applied to a series of O3 cathodes to improve the performance of solid-state Na-ion batteries.

Difficulties, strategies, and recent research and development of layered sodium transition metal oxide cathode materials for high-energy sodium-ion batteries

Energy-storage systems and their production have attracted significant interest for practical applications.Batteries are the foundation of sustainable energy sources for electric vehicles(EVs),portable electronic devices(PEDs),etc.In recent decades,Lithium-ion batteries(LIBs) have been extensively utilized in largescale energy storage devices owing to their long cycle life and high energy density.However,the high cost and limited availability of Li are the two main obstacles for LIBs.In this regard,sodium-ion batteries(SIBs) are attractive alternatives to LIBs for large-scale energy storage systems because of the abundance and low cost of sodium materials.Cathode is one of the most important components in the battery,which limits cost and performance of a battery.Among the classified cathode structures,layered structure materials have attracted attention because of their high ionic conductivity,fast diffusion rate,and high specific capacity.Here,we present a comprehensive review of the classification of layered structures and the preparation of layered materials.Furthermore,the review article discusses extensively about the issues of the layered materials,namely(1) electrochemical degradation,(2) irreversible structural changes,and(3) structural instability,and also it provides strategies to overcome the issues such as elemental phase composition,a small amount of elemental doping,structural design,and surface alteration for emerging SIBs.In addition,the article discusses about the recent research development on layered unary,binary,ternary,quaternary,quinary,and senary-based O3-and P2-type cathode materials for high-energy SIBs.This review article provides useful information for the development of high-energy layered sodium transition metal oxide P2 and O3-cathode materials for practical SIBs.

Influence of layer thickness on formation quality,microstructure,mechanical properties,and corrosion resistance of WE43 magnesium alloy fabricated by laser powder bed fusion

Laser powder bed fusion(L-PBF)of Mg alloys has provided tremendous opportunities for customized production of aeronautical and medical parts.Layer thickness(LT)is of great significance to the L-PBF process but has not been studied for Mg alloys.In this study,WE43 Mg alloy bulk cubes,porous scaffolds,and thin walls with layer thicknesses of 10,20,30,and 40μm were fabricated.The required laser energy input increased with increasing layer thickness and was different for the bulk cubes and porous scaffolds.Porosity tended to occur at the connection joints in porous scaffolds for LT40 and could be eliminated by reducing the laser energy input.For thin wall parts,a large overhang angle or a small wall thickness resulted in porosity when a large layer thicknesses was used,and the porosity disappeared by reducing the layer thickness or laser energy input.A deeper keyhole penetration was found in all occasions with porosity,explaining the influence of layer thickness,geometrical structure,and laser energy input on the porosity.All the samples achieved a high fusion quality with a relative density of over 99.5%using the optimized laser energy input.The increased layer thickness resulted to more precipitation phases,finer grain sizes and decreased grain texture.With the similar high fusion quality,the tensile strength and elongation of bulk samples were significantly improved from 257 MPa and 1.41%with the 10μm layer to 287 MPa and 15.12%with the 40μm layer,in accordance with the microstructural change.The effect of layer thickness on the compressive properties of porous scaffolds was limited.However,the corrosion rate of bulk samples accelerated with increasing the layer thickness,mainly attributed to the increased number of precipitation phases.

Impact of Transition Metal Layer Vacancy on the Structure and Performance of P2 Type Layered Sodium Cathode Material

This study explores the impact of introducing vacancy in the transition metal layer of rationally designed Na_(0.6)[Ni_(0.3)Ru_(0.3)Mn_(0.4)]O_(2)(NRM)cathode material.The incorporation of Ru,Ni,and vacancy enhances the structural stability during extensive cycling,increases the operation voltage,and induces a capacity increase while also activating oxygen redox,respectively,in Na_(0.7)[Ni_(0.2)V_(Ni0.1)Ru_(0.3)Mn_(0.4)]O_(2)(V-NRM)compound.Various analytical techniques including transmission electron microscopy,X-ray absorption near edge spectroscopy,operando X-ray diffraction,and operando differential electrochemical mass spectrometry are employed to assess changes in the average oxidation states and structural distortions.The results demonstrate that V-NRM exhibits higher capacity than NRM and maintains a moderate capacity retention of 81%after 100 cycles.Furthermore,the formation of additional lone-pair electrons in the O 2p orbital enables V-NRM to utilize more capacity from the oxygen redox validated by density functional calculation,leading to a widened dominance of the OP4 phase without releasing O_(2) gas.These findings offer valuable insights for the design of advanced high-capacity cathode materials with improved performance and sustainability in sodium-ion batteries.

Investigation of anisotropic strength criteria for layered rock mass

Layered rock mass is a type of engineering rock mass with sound mechanical anisotropy,which is generally unfavorable to the stability of underground works.To investigate the strength anisotropy of layered rock,the Mohr-Coulomb and Hoek-Brown criteria are introduced to establish the two transverse isotropic strength criteria based on Jaeger's single weak plane theory and maximum axial strain theory,and parameter determination methods.Furthermore,the sensitivity of strength parameters(K 1,K 2,and K 3)that are used to characterize the anisotropy strength of non-sliding failure involved in the strength criteria and confining pressure are investigated.The results demonstrate that strength parameters K 1 and K 2 affect the strength of layered rock samples at all bedding angles except for the bedding angle of 90°and the angle range that can cause the shear sliding failure along the bedding plane.The strength of samples at any bedding angle decreases with increasing K 1,whereas the opposite is for K 2.Except for bedding angles of 0°and 90°and the bedding angle range that can cause the shear sliding along the bedding plane,K 3 has an impact on the strength of rock samples with other bedding angles that the specimens'strength increases with increase of K 3.In addition,the strength of the rock sample increases as confining pressure rises.Furthermore,the uniaxial and triaxial tests of chlorite schist samples were carried out to verify and evaluate the strength criteria proposed in the paper.It shows that the predicted strength is in good agreement with the experimental results.To test the applicability of the strength criterion,the strength data of several types of rock in the literature are compared.Finally,a comparison is made between the fitting effects of the two strength criteria and other available criteria for layered rocks.

Variation in the permafrost active layer over the Tibetan Plateau during 1980–2020

The active layer,acting as an intermediary of water and heat exchange between permafrost and atmosphere,greatly influences biogeochemical cycles in permafrost areas and is notably sensitive to climate fluctuations.Utilizing the Chinese Meteorological Forcing Dataset to drive the Community Land Model,version 5.0,this study simulates the spatial and temporal characteristics of active layer thickness(ALT)on the Tibetan Plateau(TP)from 1980 to 2020.Results show that the ALT,primarily observed in the central and western parts of the TP where there are insufficient station observations,exhibits significant interdecadal changes after 2000.The average thickness on the TP decreases from 2.54 m during 1980–1999 to 2.28 m during 2000–2020.This change is mainly observed in the western permafrost region,displaying a sharp regional inconsistency compared to the eastern region.A persistent increasing trend of ALT is found in the eastern permafrost region,rather than an interdecadal change.The aforementioned changes in ALT are closely tied to the variations in the surrounding atmospheric environment,particularly air temperature.Additionally,the area of the active layer on the TP displays a profound interdecadal change around 2000,arising from the permafrost thawing and forming.It consistently decreases before 2000 but barely changes after 2000.The regional variation in the permafrost active layer over the TP revealed in this study indicates a complex response of the contemporary climate under global warming.

Probabilistic analysis of tunnel face seismic stability in layered rock masses using Polynomial Chaos Kriging metamodel

Face stability is an essential issue in tunnel design and construction.Layered rock masses are typical and ubiquitous;uncertainties in rock properties always exist.In view of this,a comprehensive method,which combines the Upper bound Limit analysis of Tunnel face stability,the Polynomial Chaos Kriging,the Monte-Carlo Simulation and Analysis of Covariance method(ULT-PCK-MA),is proposed to investigate the seismic stability of tunnel faces.A two-dimensional analytical model of ULT is developed to evaluate the virtual support force based on the upper bound limit analysis.An efficient probabilistic analysis method PCK-MA based on the adaptive Polynomial Chaos Kriging metamodel is then implemented to investigate the parameter uncertainty effects.Ten input parameters,including geological strength indices,uniaxial compressive strengths and constants for three rock formations,and the horizontal seismic coefficients,are treated as random variables.The effects of these parameter uncertainties on the failure probability and sensitivity indices are discussed.In addition,the effects of weak layer position,the middle layer thickness and quality,the tunnel diameter,the parameters correlation,and the seismic loadings are investigated,respectively.The results show that the layer distributions significantly influence the tunnel face probabilistic stability,particularly when the weak rock is present in the bottom layer.The efficiency of the proposed ULT-PCK-MA is validated,which is expected to facilitate the engineering design and construction.

An ultrathin and robust single-ion conducting interfacial layer for dendrite-free lithium metal batteries

The practical application of rechargeable lithium metal batteries(LMBs) encounters significant challenges due to the notorious dendrite growth triggered by uneven Li deposition behaviors. In this work,a mechanically robust and single-ion-conducting interfacial layer, fulfilled by the strategic integration of flexible cellulose acetate(CA) matrix with rigid graphene oxide(GO) and Li F fillers(termed the CGL layer), is rationally devised to serve as a stabilizer for dendrite-free lithium(Li) metal batteries. The GCL film exhibits favorable mechanical properties with high modulus and flexibility that help to relieve interface fluctuations. More crucially, the electron-donating carbonyl groups(C=O) enriched in GCL foster a strengthened correlation with Li^(+), which availably aids the Li^(+)desolvation process and expedites facile Li^(+)mobility, yielding exceptional Li^(+) transference number of 0.87. Such single-ion conductive properties regulate rapid and uniform interfacial transport kinetics, mitigating the growth of Li dendrites and the decomposition of electrolytes. Consequently, stable Li anode with prolonged cycle stabilities and flat deposition morphologies are realized. The Li||LiFePO_(4) full cells with CGL protective layer render an outstanding cycling capability of 500 cycles at 3 C, and an ultrahigh capacity retention of 99.99% for over 220 cycles even under harsh conditions. This work affords valuable insights into the interfacial regulation for achieving high-performance LMBs.

Unique double-layer solid electrolyte interphase formed with fluorinated ether-based electrolytes for high-voltage lithium metal batteries

Li metal batteries using high-voltage layered oxides cathodes are of particular interest due to their high energy density.However,they suffer from short lifespan and extreme safety concerns,which are attributed to the degradation of layered oxides and the decomposition of electrolyte at high voltage,as well as the high reactivity of metallic Li.The key is the development of stable electrolytes against both highvoltage cathodes and Li with the formation of robust interphase films on the surfaces.Herein,we report a highly fluorinated ether,1,1,1-trifluoro-2-[(2,2,2-trifluoroethoxy)methoxy]ethane(TTME),as a cosolvent,which not only functions as a diluent forming a localized high concentration electrolyte(LHCE),but also participates in the construction of the inner solvation structure.The TTME-based electrolyte is stable itself at high voltage and induces the formation of a unique double-layer solid electrolyte interphase(SEI)film,which is embodied as one layer rich in crystalline structural components for enhanced mechanical strength and another amorphous layer with a higher concentration of organic components for enhanced flexibility.The Li||Cu cells display a noticeably high Coulombic efficiency of 99.28%after 300 cycles and Li symmetric cells maintain stable cycling more than 3200 h at 0.5 mA/cm^(2) and 1.0m Ah/cm^(2).In addition,lithium metal cells using LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) and Li CoO_(2) cathodes(both loadings~3.0 m Ah/cm^(2))realize capacity retentions of>85%over 240 cycles with a charge cut-off voltage of 4.4 V and 90%for 170 cycles with a charge cut-off voltage of 4.5 V,respectively.This study offers a bifunctional ether-based electrolyte solvent beneficial for high-voltage Li metal batteries.