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An Energy-Efficient Routing Algorithm for UAV Formation Based on Time-Aggregated Graph
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作者 Wang Gaifang Li Bo +1 位作者 Yang Hongjuan Jiang Xu 《China Communications》 SCIE CSCD 2024年第11期28-39,共12页
The limited energy and high mobility of unmanned aerial vehicles(UAVs)lead to drastic topology changes in UAV formation.The existing routing protocols necessitate a large number of messages for route discovery and mai... The limited energy and high mobility of unmanned aerial vehicles(UAVs)lead to drastic topology changes in UAV formation.The existing routing protocols necessitate a large number of messages for route discovery and maintenance,greatly increasing network delay and control overhead.A energyefficient routing method based on the discrete timeaggregated graph(TAG)theory is proposed since UAV formation is a defined time-varying network.The network is characterized using the TAG,which utilizes the prior knowledge in UAV formation.An energyefficient routing algorithm is designed based on TAG,considering the link delay,relative mobility,and residual energy of UAVs.The routing path is determined with global network information before requesting communication.Simulation results demonstrate that the routing method can improve the end-to-end delay,packet delivery ratio,routing control overhead,and residual energy.Consequently,introducing timevarying graphs to design routing algorithms is more effective for UAV formation. 展开更多
关键词 energy-efficient route time-aggregated graph UAV formation
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A Discrete Multi-Objective Squirrel Search Algorithm for Energy-Efficient Distributed Heterogeneous Permutation Flowshop with Variable Processing Speed
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作者 Liang Zeng Ziyang Ding +1 位作者 Junyang Shi Shanshan Wang 《Computers, Materials & Continua》 SCIE EI 2024年第10期1757-1787,共31页
In the manufacturing industry,reasonable scheduling can greatly improve production efficiency,while excessive resource consumption highlights the growing significance of energy conservation in production.This paper st... In the manufacturing industry,reasonable scheduling can greatly improve production efficiency,while excessive resource consumption highlights the growing significance of energy conservation in production.This paper studies the problem of energy-efficient distributed heterogeneous permutation flowshop problem with variable processing speed(DHPFSP-VPS),considering both the minimum makespan and total energy consumption(TEC)as objectives.A discrete multi-objective squirrel search algorithm(DMSSA)is proposed to solve the DHPFSPVPS.DMSSA makes four improvements based on the squirrel search algorithm.Firstly,in terms of the population initialization strategy,four hybrid initialization methods targeting different objectives are proposed to enhance the quality of initial solutions.Secondly,enhancements are made to the population hierarchy system and position updating methods of the squirrel search algorithm,making it more suitable for discrete scheduling problems.Additionally,regarding the search strategy,six local searches are designed based on problem characteristics to enhance search capability.Moreover,a dynamic predator strategy based on Q-learning is devised to effectively balance DMSSA’s capability for global exploration and local exploitation.Finally,two speed control energy-efficient strategies are designed to reduce TEC.Extensive comparative experiments are conducted in this paper to validate the effectiveness of the proposed strategies.The results of comparing DMSSA with other algorithms demonstrate its superior performance and its potential for efficient solving of the DHPFSP-VPS problem. 展开更多
关键词 Distributed heterogeneous permutation flowshop problem squirrel search algorithm muli-objective optimization energy-efficient variable processing speed
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Increasing realism in modelling energy losses in railway vehicles and their impact to energy-efficient train control
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作者 Michael Nold Francesco Corman 《Railway Engineering Science》 EI 2024年第3期257-285,共29页
The reduction of energy consumption is an increasingly important topic of the railway system.Energy-efficient train control(EETC)is one solution,which refers to mathematically computing when to accelerate,which cruisi... The reduction of energy consumption is an increasingly important topic of the railway system.Energy-efficient train control(EETC)is one solution,which refers to mathematically computing when to accelerate,which cruising speed to hold,how long one should coast over a suitable space,and when to brake.Most approaches in literature and industry greatly simplify a lot of nonlinear effects,such that they ignore mostly the losses due to energy conversion in traction components and auxiliaries.To fill this research gap,a series of increasingly detailed nonlinear losses is described and modelled.We categorize an increasing detail in this representation as four levels.We study the impact of those levels of detail on the energy optimal speed trajectory.To do this,a standard approach based on dynamic programming is used,given constraints on total travel time.This evaluation of multiple test cases highlights the influence of the dynamic losses and the power consumption of auxiliary components on railway trajectories,also compared to multiple benchmarks.The results show how the losses can make up 50%of the total energy consumption for an exemplary trip.Ignoring them would though result in consistent but limited errors in the optimal trajectory.Overall,more complex trajectories can result in less energy consumption when including the complexity of nonlinear losses than when a simpler model is considered.Those effects are stronger when the trajectory includes many acceleration and braking phases. 展开更多
关键词 Train trajectory optimization energy-efficient train control(EETC) Dynamic efficiency Power losses in railway vehicles
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Model of Next Generation Energy-Efficient Design Software for Buildings 被引量:2
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作者 马智亮 赵毅立 《Tsinghua Science and Technology》 SCIE EI CAS 2008年第S1期298-304,共7页
Energy-efficient design for buildings (EEDB) is a vital step towards building energy-saving. In order to greatly improve the EEDB, the next generation EEDB software that makes use of latest technologies needs to be de... Energy-efficient design for buildings (EEDB) is a vital step towards building energy-saving. In order to greatly improve the EEDB, the next generation EEDB software that makes use of latest technologies needs to be developed. This paper mainly focuses on establishing the model of the next generation EEDB software. Based on the investigation of literatures and the interviews to the designers, the requirements on the next generation EEDB software were identified, where the lifecycle assessment on both energy consumption and environmental impacts, 3D graphics support, and building information modeling (BIM) support were stressed. Then the workflow for using the next generation EEDB software was established. Finally, based on the workflow, the framework model for the software was proposed, and the partial models and the corresponding functions were systematically analyzed. The model lays a solid foundation for developing the next generation EEDB software. 展开更多
关键词 energy-efficient design for buildings framework model partial models building information modeling (BIM) industry foundation classes (IFC)
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水田动力底盘逆向建模与质心验证——基于Geomagic Design X
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作者 何剑飞 曾志浩 +5 位作者 郭梓游 李贵蓉 钟文能 钟顺 王在满 李庆 《农机化研究》 北大核心 2024年第10期248-253,共6页
针对目前农业机械仿真和优化模型精度不高的问题,提出了一种构建精确模型的逆向建模方法。应用光学扫描仪采集点云数据,基于Geomagic Design X处理点云数据并重构零部件模型,在SolidWorks中完成水田动力底盘的装配。以VP6D-CQ型水田动... 针对目前农业机械仿真和优化模型精度不高的问题,提出了一种构建精确模型的逆向建模方法。应用光学扫描仪采集点云数据,基于Geomagic Design X处理点云数据并重构零部件模型,在SolidWorks中完成水田动力底盘的装配。以VP6D-CQ型水田动力底盘为例,将测得的实际质心位置与所建的模型质心位置进行比较,并对提出的逆向建模方法进行了试验验证以及误差分析。结果表明:总质量、x坐标、y坐标、z坐标的误差值分别为4.55%、3.62%、2.23%、4.81%,误差值均在5%内。此方法可构建准确的三维模型,为后续仿真优化数据精确性奠定了基础,与传统的研发相比较,可缩短农业机械研发周期、降低设计成本。 展开更多
关键词 水田 动力底盘 逆向建模 质心验证 Geomagic design X 数字样机
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App Designer辅助教学方法探索与实践——以软件无线电课程为例
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作者 向新 刘宇峰 +2 位作者 梁源 王瑞 何林远 《中国现代教育装备》 2024年第19期148-151,共4页
软件无线电作为通信学科的必修课程,具有承上启下的重要作用。因课程原理抽象、理论公式复杂,学员在学习过程存在理解掌握难、实践应用难等问题。通过对当前软件无线电教学过程中存在的不足与困难进行分析,提出利用MATLAB App Designer... 软件无线电作为通信学科的必修课程,具有承上启下的重要作用。因课程原理抽象、理论公式复杂,学员在学习过程存在理解掌握难、实践应用难等问题。通过对当前软件无线电教学过程中存在的不足与困难进行分析,提出利用MATLAB App Designer辅助课程教学,从教学准备、课堂互动、自主实验、反馈提升四个方面开展课程教学改革。实践表明,该方法对于提升学员的工程思维、系统思维具有显著效果,同时可以增强学员理论联系实际的能力。 展开更多
关键词 软件无线电 MATLAB App designer 教学方法改革 理实结合
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Energy-Efficient UAV Trajectory Design for Backscatter Communication: A Deep Reinforcement Learning Approach 被引量:5
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作者 Yiwen Nie Junhui Zhao +2 位作者 Jun Liu Jing Jiang Ruijin Ding 《China Communications》 SCIE CSCD 2020年第10期129-141,共13页
Recently,backscatter communication(BC)has been introduced as a green paradigm for Internet of Things(IoT).Meanwhile,unmanned aerial vehicles(UAVs)can serve as aerial base stations(BSs)to enhance the performance of BC ... Recently,backscatter communication(BC)has been introduced as a green paradigm for Internet of Things(IoT).Meanwhile,unmanned aerial vehicles(UAVs)can serve as aerial base stations(BSs)to enhance the performance of BC system thanks to their high mobility and flexibility.In this paper,we investigate the problem of energy efficiency(EE)for an energy-limited backscatter communication(BC)network,where backscatter devices(BDs)on the ground harvest energy from the wireless signal of a flying rotary-wing quadrotor.Specifically,we first reformulate the EE optimization problem as a Markov decision process(MDP)and then propose a deep reinforcement learning(DRL)algorithm to design the UAV trajectory with the constraints of the BD scheduling,the power reflection coefficients,the transmission power,and the fairness among BDs.Simulation results show the proposed DRL algorithm achieves close-to-optimal performance and significant EE gains compared to the benchmark schemes. 展开更多
关键词 unmanned aerial vehicle(UAV) trajectory design backscatter communication deep reinforcement learning energy-efficient
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Web Layout Design of Large Cavity Structures Based on Topology Optimization 被引量:1
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作者 Xiaoqiao Yang Jialiang Sun Dongping Jin 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第3期2665-2689,共25页
Large cavity structures are widely employed in aerospace engineering, such as thin-walled cylinders, blades andwings. Enhancing performance of aerial vehicles while reducing manufacturing costs and fuel consumptionhas... Large cavity structures are widely employed in aerospace engineering, such as thin-walled cylinders, blades andwings. Enhancing performance of aerial vehicles while reducing manufacturing costs and fuel consumptionhas become a focal point for contemporary researchers. Therefore, this paper aims to investigate the topologyoptimization of large cavity structures as a means to enhance their performance, safety, and efficiency. By usingthe variable density method, lightweight design is achieved without compromising structural strength. Theoptimization model considers both concentrated and distributed loads, and utilizes techniques like sensitivityfiltering and projection to obtain a robust optimized configuration. The mechanical properties are checked bycomparing the stress distribution and displacement of the unoptimized and optimized structures under the sameload. The results confirm that the optimized structures exhibit improved mechanical properties, thus offering keyinsights for engineering lightweight, high-strength large cavity structures. 展开更多
关键词 Topology optimization lightweight design web layout design cavity structure
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Accelerated design of high-performance Mg-Mn-based magnesium alloys based on novel bayesian optimization 被引量:2
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作者 Xiaoxi Mi Lili Dai +4 位作者 Xuerui Jing Jia She Bjørn Holmedal Aitao Tang Fusheng Pan 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第2期750-766,共17页
Magnesium(Mg),being the lightest structural metal,holds immense potential for widespread applications in various fields.The development of high-performance and cost-effective Mg alloys is crucial to further advancing ... Magnesium(Mg),being the lightest structural metal,holds immense potential for widespread applications in various fields.The development of high-performance and cost-effective Mg alloys is crucial to further advancing their commercial utilization.With the rapid advancement of machine learning(ML)technology in recent years,the“data-driven''approach for alloy design has provided new perspectives and opportunities for enhancing the performance of Mg alloys.This paper introduces a novel regression-based Bayesian optimization active learning model(RBOALM)for the development of high-performance Mg-Mn-based wrought alloys.RBOALM employs active learning to automatically explore optimal alloy compositions and process parameters within predefined ranges,facilitating the discovery of superior alloy combinations.This model further integrates pre-established regression models as surrogate functions in Bayesian optimization,significantly enhancing the precision of the design process.Leveraging RBOALM,several new high-performance alloys have been successfully designed and prepared.Notably,after mechanical property testing of the designed alloys,the Mg-2.1Zn-2.0Mn-0.5Sn-0.1Ca alloy demonstrates exceptional mechanical properties,including an ultimate tensile strength of 406 MPa,a yield strength of 287 MPa,and a 23%fracture elongation.Furthermore,the Mg-2.7Mn-0.5Al-0.1Ca alloy exhibits an ultimate tensile strength of 211 MPa,coupled with a remarkable 41%fracture elongation. 展开更多
关键词 Mg-Mn-based alloys HIGH-PERFORMANCE Alloy design Machine learning Bayesian optimization
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Inverse design of mechanical metamaterial achieving a prescribedconstitutive curve 被引量:1
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作者 Zongliang Du Tanghuai Bian +4 位作者 Xiaoqiang Ren Yibo Jia Shan Tang Tianchen Cui Xu Guo 《Theoretical & Applied Mechanics Letters》 CAS CSCD 2024年第1期16-22,共7页
Besides exhibiting excellent capabilities such as energy absorption,phase-transforming metamaterials offer a vast design space for achieving nonlinear constitutive relations.This is facilitated by switching between di... Besides exhibiting excellent capabilities such as energy absorption,phase-transforming metamaterials offer a vast design space for achieving nonlinear constitutive relations.This is facilitated by switching between different patterns under deformation.However,the related inverse design problem is quite challenging,due to the lack of appropriate mathematical formulation and the convergence issue in the post-buckling analysis of intermediate designs.In this work,periodic unit cells are explicitly described by the moving morphable voids method and effectively analyzed by eliminating the degrees of freedom in void regions.Furthermore,by exploring the Pareto frontiers between error and cost,an inverse design formulation is proposed for unit cells.This formulation aims to achieve a prescribed constitutive curve and is validated through numerical examples and experimental results.The design approach presented here can be extended to the inverse design of other types of mechanical metamaterials with prescribed nonlinear effective properties. 展开更多
关键词 METAMATERIAL Pattern-transformation Constitutive curve Inverse design
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Energy-efficient task allocation for reliable parallel computation of cluster-based wireless sensor network in edge computing
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作者 Jiabao Wen Jiachen Yang +2 位作者 Tianying Wang Yang Li Zhihan Lv 《Digital Communications and Networks》 SCIE CSCD 2023年第2期473-482,共10页
To efficiently complete a complex computation task,the complex task should be decomposed into subcomputation tasks that run parallel in edge computing.Wireless Sensor Network(WSN)is a typical application of parallel c... To efficiently complete a complex computation task,the complex task should be decomposed into subcomputation tasks that run parallel in edge computing.Wireless Sensor Network(WSN)is a typical application of parallel computation.To achieve highly reliable parallel computation for wireless sensor network,the network's lifetime needs to be extended.Therefore,a proper task allocation strategy is needed to reduce the energy consumption and balance the load of the network.This paper proposes a task model and a cluster-based WSN model in edge computing.In our model,different tasks require different types of resources and different sensors provide different types of resources,so our model is heterogeneous,which makes the model more practical.Then we propose a task allocation algorithm that combines the Genetic Algorithm(GA)and the Ant Colony Optimization(ACO)algorithm.The algorithm concentrates on energy conservation and load balancing so that the lifetime of the network can be extended.The experimental result shows the algorithm's effectiveness and advantages in energy conservation and load balancing. 展开更多
关键词 Wireless sensor network Parallel computation Task allocation Genetic algorithm Ant colony optimization algorithm energy-efficient Load balancing
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Design Principles and Mechanistic Understandings of Non-Noble-Metal Bifunctional Electrocatalysts for Zinc-Air Batteries 被引量:1
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作者 Yunnan Gao Ling Liu +10 位作者 Yi Jiang Dexin Yu Xiaomei Zheng Jiayi Wang Jingwei Liu Dan Luo Yongguang Zhang Zhenjia Shi Xin Wang Ya‑Ping Deng Zhongwei Chen 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第9期13-48,共36页
Zinc-air batteries(ZABs)are promising energy storage systems because of high theoretical energy density,safety,low cost,and abundance of zinc.However,the slow multi-step reaction of oxygen and heavy reliance on noble-... Zinc-air batteries(ZABs)are promising energy storage systems because of high theoretical energy density,safety,low cost,and abundance of zinc.However,the slow multi-step reaction of oxygen and heavy reliance on noble-metal catalysts hinder the practical applications of ZABs.Therefore,feasible and advanced non-noble-metal elec-trocatalysts for air cathodes need to be identified to promote the oxygen catalytic reaction.In this review,we initially introduced the advancement of ZABs in the past two decades and provided an overview of key developments in this field.Then,we discussed the work-ing mechanism and the design of bifunctional electrocatalysts from the perspective of morphology design,crystal structure tuning,interface strategy,and atomic engineering.We also included theoretical studies,machine learning,and advanced characterization technologies to provide a comprehensive understanding of the structure-performance relationship of electrocatalysts and the reaction pathways of the oxygen redox reactions.Finally,we discussed the challenges and prospects related to designing advanced non-noble-metal bifunctional electrocatalysts for ZABs. 展开更多
关键词 Zinc-air batteries Bifunctional electrocatalysts design principles Mechanistic understandings
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Machine learning for membrane design and discovery 被引量:1
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作者 Haoyu Yin Muzi Xu +4 位作者 Zhiyao Luo Xiaotian Bi Jiali Li Sui Zhang Xiaonan Wang 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第1期54-70,共17页
Membrane technologies are becoming increasingly versatile and helpful today for sustainable development.Machine Learning(ML),an essential branch of artificial intelligence(AI),has substantially impacted the research an... Membrane technologies are becoming increasingly versatile and helpful today for sustainable development.Machine Learning(ML),an essential branch of artificial intelligence(AI),has substantially impacted the research and development norm of new materials for energy and environment.This review provides an overview and perspectives on ML methodologies and their applications in membrane design and dis-covery.A brief overview of membrane technologies isfirst provided with the current bottlenecks and potential solutions.Through an appli-cations-based perspective of AI-aided membrane design and discovery,we further show how ML strategies are applied to the membrane discovery cycle(including membrane material design,membrane application,membrane process design,and knowledge extraction),in various membrane systems,ranging from gas,liquid,and fuel cell separation membranes.Furthermore,the best practices of integrating ML methods and specific application targets in membrane design and discovery are presented with an ideal paradigm proposed.The challenges to be addressed and prospects of AI applications in membrane discovery are also highlighted in the end. 展开更多
关键词 Machine learning Membranes AI for Membrane DATA-DRIVEN design
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Energy-Efficient Approaches for a Machine Tool Building in a University through Field Measurement and Energy Modelling
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作者 Kusnandar Win-Jet Luo +2 位作者 Indra Permana Fu-Jen Wang Gantulga Bayarkhuu 《Energy Engineering》 EI 2023年第6期1387-1399,共13页
The heating,ventilating,and air conditioning(HVAC)system consumes nearly 50%of the building’s energy,especially in Taiwan with a hot and humid climate.Due to the challenges in obtaining energy sources and the negativ... The heating,ventilating,and air conditioning(HVAC)system consumes nearly 50%of the building’s energy,especially in Taiwan with a hot and humid climate.Due to the challenges in obtaining energy sources and the negative impacts of excessive energy use on the environment,it is essential to employ an energy-efficient HVAC system.This study conducted the machine tools building in a university.The field measurement was carried out,and the data were used to conduct energymodelling with EnergyPlus(EP)in order to discover some improvements in energy-efficient design.The validation between fieldmeasurement and energymodelling was performed,and the error rate was less than 10%.The following strategies were proposed in this study based on several energy-efficient approaches,including room temperature settings,chilled water supply temperature settings,chiller coefficient of performance(COP),shading,and building location.Energy-efficient approaches have been evaluated and could reduce energy consumption annually.The results reveal that the proposed energy-efficient approaches of room temperature settings(3.8%),chilled water supply temperature settings(2.1%),chiller COP(5.9%),using shading(9.1%),and building location(3.0%),respectively,could reduce energy consumption.The analysis discovered that using a well-performing HVAC system and building shading were effective in lowering the amount of energy used,and the energy modelling method could be an effective and satisfactory tool in determining potential energy savings. 展开更多
关键词 energy-efficient energy modelling field measurement BEMS machine tools building
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Deep Insight of Design,Mechanism,and Cancer Theranostic Strategy of Nanozymes 被引量:1
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作者 Lu Yang Shuming Dong +6 位作者 Shili Gai Dan Yang He Ding Lili Feng Guixin Yang Ziaur Rehman Piaoping Yang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期165-217,共53页
Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction... Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction conditions,good stability,and suitable for large-scale production.Recently,with the cross fusion of nanomedicine and nanocatalysis,nanozyme-based theranostic strategies attract great attention,since the enzymatic reactions can be triggered in the tumor microenvironment to achieve good curative effect with substrate specificity and low side effects.Thus,various nanozymes have been developed and used for tumor therapy.In this review,more than 270 research articles are discussed systematically to present progress in the past five years.First,the discovery and development of nanozymes are summarized.Second,classification and catalytic mechanism of nanozymes are discussed.Third,activity prediction and rational design of nanozymes are focused by highlighting the methods of density functional theory,machine learning,biomimetic and chemical design.Then,synergistic theranostic strategy of nanozymes are introduced.Finally,current challenges and future prospects of nanozymes used for tumor theranostic are outlined,including selectivity,biosafety,repeatability and stability,in-depth catalytic mechanism,predicting and evaluating activities. 展开更多
关键词 Nanozymes Classification Prediction and design Catalytic mechanism Tumor theranostics
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Alloy design for laser powder bed fusion additive manufacturing:a critical review 被引量:1
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作者 Zhuangzhuang Liu Qihang Zhou +4 位作者 Xiaokang Liang Xiebin Wang Guichuan Li Kim Vanmeensel Jianxin Xie 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第2期29-63,共35页
Metal additive manufacturing(AM)has been extensively studied in recent decades.Despite the significant progress achieved in manufacturing complex shapes and structures,challenges such as severe cracking when using exi... Metal additive manufacturing(AM)has been extensively studied in recent decades.Despite the significant progress achieved in manufacturing complex shapes and structures,challenges such as severe cracking when using existing alloys for laser powder bed fusion(L-PBF)AM have persisted.These challenges arise because commercial alloys are primarily designed for conventional casting or forging processes,overlooking the fast cooling rates,steep temperature gradients and multiple thermal cycles of L-PBF.To address this,there is an urgent need to develop novel alloys specifically tailored for L-PBF technologies.This review provides a comprehensive summary of the strategies employed in alloy design for L-PBF.It aims to guide future research on designing novel alloys dedicated to L-PBF instead of adapting existing alloys.The review begins by discussing the features of the L-PBF processes,focusing on rapid solidification and intrinsic heat treatment.Next,the printability of the four main existing alloys(Fe-,Ni-,Al-and Ti-based alloys)is critically assessed,with a comparison of their conventional weldability.It was found that the weldability criteria are not always applicable in estimating printability.Furthermore,the review presents recent advances in alloy development and associated strategies,categorizing them into crack mitigation-oriented,microstructure manipulation-oriented and machine learning-assisted approaches.Lastly,an outlook and suggestions are given to highlight the issues that need to be addressed in future work. 展开更多
关键词 laser powder bed fusion alloy design PRINTABILITY crack mitigation
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Electrolyte Design for Low‑Temperature Li‑Metal Batteries:Challenges and Prospects 被引量:1
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作者 Siyu Sun Kehan Wang +3 位作者 Zhanglian Hong Mingjia Zhi Kai Zhang Jijian Xu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期365-382,共18页
Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements ... Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements in electrolyte chemistry need to be coupled with optimized electrode materials and tailored electrolyte/electrode interphases.Herein,this review critically outlines electrolytes’limiting factors,including reduced ionic conductivity,large de-solvation energy,sluggish charge transfer,and slow Li-ion transportation across the electrolyte/electrode interphases,which affect the low-temperature performance of Li-metal batteries.Detailed theoretical derivations that explain the explicit influence of temperature on battery performance are presented to deepen understanding.Emerging improvement strategies from the aspects of electrolyte design and electrolyte/electrode interphase engineering are summarized and rigorously compared.Perspectives on future research are proposed to guide the ongoing exploration for better low-temperature Li-metal batteries. 展开更多
关键词 Solid electrolyte interphase Li metal Low temperature Electrolyte design BATTERIES
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Molecular Mechanism and Molecular Design of Lubricating Oil Antioxidants 被引量:1
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作者 Su Shuo Long Jun +2 位作者 Duan Qinghua Zhou Han Zhao Yi 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第2期135-145,共11页
To overcome the limitations of traditional experimental“trial and error”methods in lubricant additive design,a new molecular design method based on molecular structure parameters is established here.The molecular me... To overcome the limitations of traditional experimental“trial and error”methods in lubricant additive design,a new molecular design method based on molecular structure parameters is established here.The molecular mechanism of the antioxidant reaction of hindered phenol,diphenylamine,and alkyl sulfide are studied via molecular simulations.Calculation results show that the strong electron-donating ability and high hydrogen-donating activity of the antioxidant molecule and the low hydrogen-abstracting activity of free radicals formed after dehydrogenation are the internal molecular causes of the shielding of phenol and diphenylamine from scavenging peroxy free radicals,and the strong electron-donating ability is the internal molecular cause of the high activity of thioether in decomposing alkyl hydrogen peroxide.Based on this antioxidant molecular mechanism,a molecular design rule of antioxidant is proposed,namely“high EHOMO,large Q(S),low bond dissociation energy BDE(O—H)and BDE(N—H)”.Two new antioxidants,PAS-I and PAS-II,are designed and prepared by chemical bonding of hindered phenol,diphenylamine,and sulfur atoms.Experimental results show that these antioxidants both have excellent antioxidant effects in lubricating oil,and that PAS-II is the superior antioxidant,consistent with theoretical predictions. 展开更多
关键词 lubricating oil ANTIOXIDANT molecular mechanism molecular design antioxidant performance
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Recent advances in cobalt phosphide-based materials for electrocatalytic water splitting:From catalytic mechanism and synthesis method to optimization design 被引量:1
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作者 Rongrong Deng Mengwei Guo +1 位作者 Chaowu Wang Qibo Zhang 《Nano Materials Science》 EI CAS CSCD 2024年第2期139-173,共35页
Electrochemical water splitting has long been considered an effective energy conversion technology for trans-ferring intermittent renewable electricity into hydrogen fuel,and the exploration of cost-effective and high... Electrochemical water splitting has long been considered an effective energy conversion technology for trans-ferring intermittent renewable electricity into hydrogen fuel,and the exploration of cost-effective and high-performance electrocatalysts is crucial in making electrolyzed water technology commercially viable.Cobalt phosphide(Co-P)has emerged as a catalyst of high potential owing to its high catalytic activity and durability in water splitting.This paper systematically reviews the latest advances in the development of Co-P-based materials for use in water splitting.The essential effects of P in enhancing the catalytic performance of the hydrogen evolution reaction and oxygen evolution reaction are first outlined.Then,versatile synthesis techniques for Co-P electrocatalysts are summarized,followed by advanced strategies to enhance the electrocatalytic performance of Co-P materials,including heteroatom doping,composite construction,integration with well-conductive sub-strates,and structure control from the viewpoint of experiment.Along with these optimization strategies,the understanding of the inherent mechanism of enhanced catalytic performance is also discussed.Finally,some existing challenges in the development of highly active and stable Co-P-based materials are clarified,and pro-spective directions for prompting the wide commercialization of water electrolysis technology are proposed. 展开更多
关键词 Co-P electrocatalysts Water splitting Hydrogen production Catalytic mechanism Synthesis technique Optimization design
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双十字路口交通灯控制Stateflow和App Designer仿真
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作者 张悦 周泽震 +1 位作者 颜秀铭 杨燕 《电气电子教学学报》 2024年第3期218-224,共7页
为培养学生能够独立从事自动化相关领域的工程设计、应用研究,解决自动化领域复杂工程实施过程中遇到的关键技术问题,以双十字路口交通灯为研究对象,为计算机辅助建模与仿真类课程设计了一个综合性教学案例。教学案例主要内容为双十字路... 为培养学生能够独立从事自动化相关领域的工程设计、应用研究,解决自动化领域复杂工程实施过程中遇到的关键技术问题,以双十字路口交通灯为研究对象,为计算机辅助建模与仿真类课程设计了一个综合性教学案例。教学案例主要内容为双十字路口Simulink/Stateflow建模与基于Matlab App Designer的交通灯控制可视化仿真。通过此教学案例的实施,明显提高了学生对Matlab的综合应用和工程设计能力,并为后续课程“单片机原理及应用”和“电气控制和PLC”作铺垫。 展开更多
关键词 双十字路口 交通灯控制 SIMULINK STATEFLOW App designer
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