Crust-Mantle Interaction in Dabie Orogenic Belt, Central China: Geochemical Evidence from Late Cretaceous Basalts

It has been suggested that eclogites in the Dabie orogenic be lt are exhumation products, which had subducted into the deep-seated mantle and undergone ultra-high pressure metamorphism during the Triassic. But no direct evidence supports this process except the calculated p-T conditions from mineral thermobarometers. The Late Cretaceous basalts studied in the prese nt paper, however, have provided some geochemical evidence for crust-mantle int eraction in the area. These basalts are distributed in Mesozoic faulted basins i n central and southern Dabie orogenic belt. Since little obvious contamination f rom continental crust and differentiation-crystallization were observed, it is suggested, based on a study of trace elements, that the basalts are alkaline and resultant from batch partial melting of the regional mantle rocks, and share th e same or similar geochemical features with respect to their magma source. In th e spider diagram normalized by the primitive mantle, trace element geochemistry data show that their mantle sources are enriched in certain elements concentrate d in the continental crust, such as Pb, K, Rb and Ba, and slightly depleted in s ome HFSE such as Hf, P and Nb. Pb-Sr-Nd isotopic compositions further suggest the mantle is the mixture of depleted mantle and enriched one . T his interaction can explain the trace element characteristics of basaltic magmas , i.e., the enrichment of Pb and the depletion of Hf, P and Nb in basalts can be interpreted by the blending of the eclogites in DOB (enriched in Pb and deplete d in Hf, P and Nd) with the East China depleted mantle (As compared to the primi tive mantle, it is neither enriched in Pb nor depleted in Hf, P and Nb). It is a lso indicated that the eclogites in the Dabie orogenic belt were surely derived from the exhumation materials, which had delaminated into the deep-seated mantl e. Moreover, the process subsequently resulted in compositional variation of the mantle (especially in trace elements and isotopes), as revealed by the late man tle-derived basalts in the Dabie orogenic belt.

EM菌富集培养及降解污水试验研究

利用有效微生物EM分别进行了EM富集培养、EM降解污水的试验研究 .研究表明 :(a)用糖蜜、蜂蜜及高浓度污水均能有效地富集培养EM ;(b)与活性污泥降解污水相比 ,EM富集培养液降解污水可以显著提高处理效率 ;(c)

滇中中-上二叠统峨眉山组关键金属勘查新线索及地质意义

通过1∶5万区域地质调查及典型剖面研究,在滇中禄劝地区二叠系峨眉山组顶部识别出一套厚约20~50 m不等的Nb、Co、Ga、Zr及REE超常富集层。富集层主要岩性为灰紫色泥岩、凝灰质泥岩、凝灰岩,局部夹杏仁状玄武岩。通过对禄劝万鲁布、撒角海一带的富集层刻槽分析显示,Nb_(2)O^(5)含量在82.4×10^(-6)~120.1×10^(-6),平均值为100.3×10^(-6),大于风化壳型矿床一般工业指标80×10^(-6);Ga含量28.8×10^(-6)~35.6×10^(-6),平均值为32.1×10^(-6),高于现行的Ga矿资源工业指标要求30×10-6;REE含量在360×10^(-6)~510×10^(-6),平均值为440.6×10^(-6),接近风化壳型矿床一般工业指标500×10^(-6);并呈现出泥岩→凝灰质泥岩→凝灰岩关键金属含量依次升高,与火山灰含量呈正相关的特征,峨眉山玄武岩的风化作用可能造成了关键金属的富集;同时富集层中伴有Co、Zr、Li等关键金属矿化现象;由此,二叠系峨眉山组红顶层是一个关键金属的富集层,鉴于滇中地区二叠系峨眉山组分布范围较广,是一个极具Nb、Ga、Co、Zr及REE等多种关键金属找矿前景的地区,值得找矿工作者关注。峨眉山组各段玄武岩间富集关键金属的火山碎屑岩-沉积岩夹层(10~120 cm)、沥青杏仁体的发现,佐证了峨眉山玄武岩是地幔柱幕式喷发,为峨眉山玄武岩地幔柱演化、喷发时限及其与二叠纪生物灭绝的关系、寻找常规油气提供了新的研究方向及资料。

EM在污水生物降解中的试验研究

利用有效微生物EM富集培养液进行污水处理试验 ,试验结果表明 :(1)EM富集培养液能有效处理高浓度污水 ;(2 )与单独的活性污泥处理相比 。

磁矢量势的全球电磁感应时间域三维有限元正演计算方法

全球电磁感应测深方法能获得地球深部电导率结构分布,目前被广泛应用于地球内部结构与热状态研究.地磁台站与地磁卫星观测的电磁感应数据为时间序列信号,在时间域分析全球电磁感应数据,特别是分析频谱极宽的磁暴脉冲响应,具有天然的优势.然而,当前的全球电磁感应数据解释技术一般在频率域进行,缺少时间域中的研究成果.为了弥补缺少时间域全球电磁感应数据解释方法的问题,本文开发了一种基于磁场矢量势的全球电磁感应时间域三维有限元并行正演求解方法,具备高精度快速计算源于地球外部时变电流源的地球感应电磁场时间序列的能力,特别适合于计算与分析频谱极宽的磁暴脉冲电磁感应时变响应.首先,建立基于磁场矢量势的全球电磁感应时间域微分控制方程,结合磁层外部电流源的物理属性建立边界条件和初始条件,从而构建出全球电磁感应时间域初始边界值问题.然后,利用四面体矢量有限元技术和无条件稳定的隐式后退欧拉公式,分别实现磁场矢量势的空间域和时间域离散,进而获得不同时刻的实系数大型有限元线性方程组,借助于高性能并行直接求解器,快速高精度地求解不同时刻的磁场矢量势与感应磁场.最后,利用理论模型验证本文算法的正确性.利用Dst磁暴环电流指数建立的时间域电流源与真实地球三维电性模型,研究"澳科一号"后续卫星200 km轨道对中国和澳大利亚下方地幔转换带高导体的探测能力,结果表明这些地幔转换带异常体在200 km卫星轨道高度能产生明显异常.综上所述,本文开发的时间域全球电磁感应方法不仅具备精确快速计算全球感应电磁场时间序列响应的能力,还能为反演与解释"澳科一号"等我国地磁卫星观测数据提供技术支持.

胶东地区早白垩世周官高镁闪长岩体年代学、地球化学特征及其构造意义

胶东地区是我国最重要的金矿集区,金矿床的时空分布与晚中生代花岗岩类密切相关,其中早白垩世伟德山期花岗岩侵位时间与大规模金成矿时间一致,是重要的成矿期地质体。隶属于伟德山期花岗岩的周官岩体与金成矿时空关系密切。选择周官岩体作为研究对象,系统开展了岩石学、锆石U-Pb同位素测年和全岩地球化学研究工作。结果表明:周官岩体侵位时代为(119.4±1.1)~(118±1.0)Ma,与金成矿同期;岩体具有低硅、高镁和富钠,以及相对高的Cr、Ni、Co、Sc含量、Sr/Y比值和明显贫化的Zr含量特征,Mg#值介于55.83~59.26,表现为高镁闪长岩特征。岩石属高钾钙碱性系列,为高镁闪长岩类,岩浆源于富集岩石圈地幔的部分熔融,并混染了部分地壳物质;周官高镁闪长岩体和伟德山期花岗岩的岩浆侵位导致地壳浅部发生剧烈隆起,形成伸展构造,为成矿流体运移、成矿物质富集和矿体定位提供了良好通道和有利空间。

EM的富集培养及絮凝特性实验研究

通过对有效微生物群(EM)的富集培养液的絮凝试验,从中挑选出酵母菌、光和菌有较好的絮凝性能。进一步实验结果表明,酵母菌的最佳培养条件为:好氧条件下,30℃恒温培养,絮凝培养24 h即可达到最大絮凝率94.58％,培养基的最佳初始pH值为6.5。光和菌的最佳培养条件为:厌氧条件下,30℃恒温培养,絮凝培养36 h即可达到最大絮凝率93.48％。光和菌、酵母菌发酵液最佳的投加体积百分数均为2％。

Insight of enriched basalts into the nature and evolution of mantle lithosphere beneath craton margins

Refractory lithospheric deep roots are the cornerstone for the prolonged stability of cratons and mantle xenoliths are normally the key targets for study on the evolution of such deep roots. In regions with few mantle xenoliths, the basalts enriched in radiogenic isotopic compositions due to marked lithospheric mantle contribution are crucial to unmask the lithospheric mantle evolution based on a comprehensive study involving petrology, geochemistry and thermodynamic modelling. Here, the Early Cretaceous basalts from the northwest North China Craton with few mantle xenoliths are taken as an example to show the significance of enriched basalts on the study of lithospheric mantle. These basalts are characterized by high silica and alkali contents(SiO_(2)=45.8–59.8 wt.%, K_(2)O+Na_(2)O=4.81–9.88 wt.%), arc-type trace-element patterns and enriched radiogenic isotope compositions(e.g., ε_(Nd)=-2.64–-12.88,^(87)Sr/^(86)Sr=0.7063–0.7093). The TiO_(2) and FeO(total) contents are higher than those of natural and experimental melts from refractory mantle peridotite but comparable to those of partial melts of fertile mantle rocks.The high contents of fluid-loving elements(e.g., Rb and Ba) suggest source metasomatism by aqueous fluids. Combined with thermodynamic modelling and regional tectonic history, these enriched basalts likely record simultaneous decompression melting of asthenosphere and low-extent melting of thin and fertile lithospheric mantle fluxed by aqueous fluids from the subducted Paleo-Asian oceanic slab. The newly unmasked lithospheric mantle under the western NCC contrasts with the coeval thick and refractory one supporting the eastern NCC, and highlights that the craton destruction, especially the loss of its ancient refractory mantle root, should take place in a diachronous manner related to the craton-girded subduction episodes. Our study illustrates the potential of enriched basalts to recover the nature and evolution of mantle lithosphere beneath craton margins and associated tectonic histories.

Petrogenesis of Oligocene Granitoids and its Implications on Beryllium Mineralization at Pagele,Nianqingtanggula Mountain(Central Tibet)

The newly discovered Oligocene granitoids(33.1-28.7 Ma)at Pagele are magmatic rocks related to beryllium mineralization during the India-Asia late-collisional stage.This discovery provides an ideal example to study the latecollisional orogeny and beryllium prospecting in the Lhasa terrane.The Oligocene granitoids include porphyritic granodiorite,StageⅠ,ⅡandⅢgranites,and granitic pegmatite.Geochemical analysis shows that the porphyritic granodiorite is characterized by high SiO_(2),K_(2)O,totalΣREE contents,and(La/Yb)N ratios;while the latter two by higher SiO_(2),lowerΣREE and(La/Yb)N ratios.Notably,the granitic pegmatite has extremely high Y/Ho,low K/Rb and Zr/Hf,and distinct REE tetrad effect(1.14-1.21).This study suggests that the porphyritic granodiorite may be derived from partial melting of beryllium-rich materials composed of Lhasa ancient crust(70%-80%)and enriched Lhasa lithospheric mantle(20%-30%)under the tearing subduction of Indian slab.The three-stage granites and granitic pegmatite,which contain higher beryllium contents or beryls,were likely generated by highly fractionation of the porphyritic granodioritic magma or other homologous magma.Considering the possible genetic and spatial link between Indian slab tear and rifts,we suggest that highly-fractionated granites in rifting systems represent important Be prospecting targets in the Lhasa terrane.

Geochemistry and petrogenesis of Quaternary volcanism from the islets in the eastern Beibu Gulf: evidence for Hainan plume

Some of the islets in the eastern Beibu Gulf are covered by Quaternary volcano strata. The rock samples from these islets mainly consist of quartz tholeiites （at Shenjiandao）, olivine tholeiites （at Linshidao and Xieyang- dao） and alkali basalts （at Yangpubi and Jianshidao）, and basically represent four periods of the Quaternary volcanism of Hainan Island and its adjacent regions. Except for the samples from Shenjiandao, most of the Quaternary volcanics of these islets belong to alkali magma series. The trace element characteristics of all of these samples show they are OIB （oceanic island basalt） -like, which implies that their deep geodynamic setting may be related to a mantle plume. The Sr-Nd-Pb isotopic compositions show that the mantle source beneath the Quaternary strata can be regarded as a result of binary mixing between a depleted, DMM （de- pleted MORB mantle）-like source and an enriched mantle type 2 （EM2）. The EM2 may be originated from the Hainan mantle plume, and has been metasomatized by carbonaceous fluids released from ancient re- cycled oceanic crust at an asthenospheric mantle level. These features, together with typical trace element ratios, reflect that the parent magma was not subjected to crustal contamination during its ascent to the surface. This study provides further petrological and geochemical evidence for the existence of the Hainan mantle plume.

A comparative review of petrogenetic processes beneath the Cameroon Volcanic Line: Geochemical constraints

The origin and petrogenesis of the Cameroon Volcanic Line （CVL）, composed of volcanoes that form on both the ocean floor and the continental crust, are difficult to understand because of the diversity, het- erogeneity, and nature of available data. Major and trace elements, and Sr-Nd-Pb isotope data of volcanic rocks of the CVL spanning four decades have been compiled to reinterpret their origin and petrogenesis. Volcanic rocks range from nephelinite, basanite and alkali basalts to phonolite, trachyte and rhyolite with the presence of a compositional gap between Si02 58-64 wt.%. Similarities in geochemical characteristics, modeled results for two component mixing, and the existence of mantle xenoliths in most mafic rocks argue against significant crustal contamination. Major and trace element evidences indicate that the melting of mantle rocks to generate the CVL magma occurred dominantly in the garnet lherzolite stability feld. Melting models suggest small degree （〈3%） partial melting of mantle bearing （6-10%） garnet for Mr. Etinde, the Ngaoundere Plateau and the Biu Plateau, and 〈5% of garnet for the oceanic sector of the CVL, Mr. Cameroon, Mt. Bambouto, Mt. Manengouba and the Oku Volcanic Group. The Sr-Nd-Pb isotope sys- tematics suggest that mixing in various proportions of Depleted MORB Mantle （DMM） with enriched mantle 1 and 2 （EM1 and EM2） could account for the complex isotopic characteristics of the CVL lavas. Low Mg number （Mg# - 100 x MgO/（MgO ＋FeO）） and Ni, Cr and Co contents of the CVL mafic lavas reveal their crystallization from fractionated melts. The absence of systematic variation in NbJTa and Zr/Hf ratios, and Sr-Nd isotope compositions between the mafic and felsic lavas indicates progressive evolution of magmas by fractional crystallization. Trace element ratios and their plots corroborate mantle het- erogeneity and reveal distinct geochemical signatures for individual the CVL volcanoes.

High-Field-Strength Elements in Mafic Volcanics from North China Craton: Implications for Archean-Proterozoic Boundary and Source Composition

Archean to Cenozoic mafic volcanic rocks from the North China craton are studied. They show Archean Proterozoic (Ar Pt) boundary and geochemical anomalies in Cenozoic basalts. Proterozoic mafic volcanics are enriched in most of the high field strength elements (HFSE) compared with Archean ones. Nb, Ta and Th show a distinct sequence of incompatibility in Archean and Proterozoic. The Cenozoic basalts are enriched in HFSE and Ni and their REEs are strongly differentiated with positive Eu anomalies ( δ (Eu)=1.14). The Ar Pt boundary could be related to change in oxygen fugacity and requires an increasing importance of enriched mantle source. The geochemistry of Cenozoic basalts implies a mantle source similar to OIB. Residuum from subducting partial melting of old basaltic oceanic crust and continental crust is likely to contribute to the formation of the enriched mantle.

Signatures of the source for the Emeishan flood basalts in the Ertan area: Pb isotope evidence

The Emeishan flood basalts can be divided into high-Ti (HT) basalt (Ti/Y>500) and low-Ti (LT) basalt (Ti/Y<500). Sr, Nd isotopic characteristics of the lavas indicate that the LT- and the HT-type magmas originated from distinct mantle sources and parental magmas. The LT-type magma was derived from a shallower lithospheric mantle, whereas the HT-type magma was derived from a deeper mantle source that may be possibly a mantle plume. However, few studies on the Emeishan flood basalts involved their Pb isotopes, especially the Ertan basalts. In this paper, the authors investigated basalt samples from the Ertan area in terms of Pb isotopes, in order to constrain the source of the Emeishan flood basalts. The ratios of 206Pb/204Pb (18.31–18.41), 207Pb/204Pb (15.55–15.56) and 208Pb/204Pb (38.81–38.94) are significantly higher than those of the depleted mantle, just lying between EM I and EM II. This indicates that the Emeishan HT basalts (in the Ertan area) are the result of mixing of EMI end-member and EMII end-member.

Jurassic Hornblende Gabbros in Dongga,Eastern Gangdese,Tibet:Partial Melting of Mantle Wedge and Implications for Crustal Growth

The Gangdese batholith, more than 2500 km in length, is composed mainly of JurassicMiocene igneous rocks. This batholith is one of the most important constituents of the Tibetan orogenesis and provides an ideal place for study of Neo-Tethyan ocean geodynamic evolution and plateau uplift. Recent studies on the Gangdese Jurassic felsic magmatism highlight its juvenile source. However, important aspects concerning the genesis of the juvenile magmatism and related deep geodynamic evolution are still unclear. Here, we report detailed petrological, geochronological, geochemical, whole-rock Sr-Nd isotopic, and in situ Sr-Hf isotopic data for a recently identified hornblende gabbro in the Dongga area, southern Lhasa sub-block. This hornblende gabbro is dominated by hornblende and plagioclase, dated at Early Jurassic（ca. 180–190 Ma）, and characterized by a narrow compositional range in SiO2（49.38wt%–52.27wt%）, MgO（4.08wt%–7.00wt%）, FeO（10.43wt%–11.77wt%）, Na2O（2.58wt%–3.51wt%）, and K2O（0.48wt%–1.53wt%）. It has depleted isotopic signatures, with whole-rock（87Sr/86Sr）i ratios of 0.7033–0.7043, εNd（t） values of ＋4.90 to ＋6.99, in situ plagioclase（87Sr/86Sr）i ratios of 0.7034–0.7042, and zircon εHf（t） of ＋12.2 to ＋16.8. Our results integrated with published data suggest a model of Gangdese juvenile crustal growth by a subduction-related water-enriched mantle wedge. The hydrous partial melting of the lithosphere mantle was triggered by the dehydration of a Neo-Tethyan oceanic slab. This mafic magmatism emplaced in the middle-lower crust of intraoceanic arcs or active continental margins, leading to Jurassic juvenile crustal growth in southern Tibet.

Geochemistry and petrogenesis of Rajahmundry trap basalts of Krishna-Godavari Basin,India

The Rajahmundry Trap Basalts （RTB） are erupted through fault-controlled fissures in the Krishna-Godavari Basin （K-G Basin） of Godavari Triple Junction, occurring as a unique outcrop sandwiched between Cretaceous and Tertiary sediments along the east coast of India. Detailed geochemical studies have revealed that RTB are mid-Ti （1.74-1.92） to high-Ti （2.04-2.81） basalts with a distinct quartz tholeiitic parentage. MgO （6.2-13.12 wt.%）, Mg# （29-50） and Zr （109-202 ppm） suggest that these basalts evolved by fractional crystallization during the ascent of the parent magma along deep-seated fractures. Mod- erate to high fractionation of HREE, as indicated by （Gd/Yb）N ratios （1.71-2.31） of RTB, suggest their generation through 3-5% melting of a Fe-rich mantle corresponding to the stability fields of spinel and garnet peridotite at depths of 60-100 km. Low K2O/P2O5 （0.26-1.26）, high TiO2/P2O5 （6.74-16.79）, La/Nb （0.89-1.45）, Nb/Th 〉 8 （8.35-13）, negative anomalies at Rb reflect minimum contamination by granitic continental crust. （Nb/La）PM ratios （0.66-1.1） of RTB are attributed to endogenic contamination resulted through recycling of subducted oceanic slab into the mantle. Pronounced Ba enrichment with relative depletion in Rb indicates assimilation of Infra- and Inter-trappean sediments of estuarine to shallow marine character. Geochemical compositions such as A1203/TiO2 （3.88-6.83）, medium to high TiO2 （1.74 -2.81 wt.%）, positive Nb anomalies and LREE enrichment of these RTB attest to their mantle plume origin and indicate the generation of parent magma from a plume-related enriched mantle source with EM 1 signature. Ba/Th （46-247）, Ba/La （3.96-28.51） and Th/Nb （0.08-0.13） ratios suggest that the source enrichment process was marked by recycling of subduction-processed oceanic crust and lithospheric components into the mantle. Zr/Hf （37-41） and Zr/Ba （0.51-3.24） indicate involvement of an asthenospheric mantle source. The Rajahmundry basalts show affinity towards FOZO （focal zone mantle） and PSCL （post-Archaean subcontinental lithosphere） which reflect mixing between asthenospheric and lithospheric mantle components in their source. Origin of RTB magma is attributed to plume-lithosphere interaction and the upward movement of melt is facilitated by intrabasinal deep-seated faults in the K-G Basin.

TWO TYPES OF CENOZOIC HIGH-K MAGMATINSM IN EASTERN TIBET:IMPLICATIONS FOR THE NATURE OF MANTLE SOURCES

Cenozoic high\|K igneous rocks are widely distributed in eastern Tibet. These rocks are exposed as flows, dykes and small intrusions along a narrow north\|south trending zone, which follows Tertiary fold belts and the Batang—Lijiang and Ailao Shan—Red River strike\|slip systems. Although several models were proposed to interpret their petrogenesis (Deng, 1989; Arnaud et al., 1991; Turner et al., 1996; Yin et al., 1995; Miller et al., 1999), their origin still remains hotly debated. Moreover, the published results were only focused on the high\|K igneous rocks resulted from partial melting of an enriched lithospheric mantle. Here, we present the detailed documents to testify the existence of a new kind of high\|K igneous rocks in eastern Tibet.Our new 39 Ar/ 40 Ar age data (Wang et al., 1999) and published age data for high\|K rocks in eastern Tibet show two distinctive magmatic episodes: one between 42Ma and 24Ma, and the other since ca.16Ma. They correspond to two types of high\|K magmatism in eastern Tibet. We name the older and younger groups as types Ⅰ and Ⅱ, respectively.

Petrogenesis and Geochemistry of Neogene Basalts in Eastern Anhui

The basalt terrain of the Neogene Huangguoshan and. Guiwu Formations of eastern Anhui on the east side of the Tancheng-Lujiang fault belt is one of a few Cenozoic basalt terrains in eastern China for which detailed geochemical study has not been conducted. This paper reports the abundances of major elements and more than 20 trace elements (including REE) of 22 samples and the Nd, Sr and Pb isotopic compositions of 11 samples from the eastern Anhui basalt terrain, thus more or less systematically revealing the geochemical characteristics of this continental basalt suite. The paper discusses the origin of the basalt suite and the character and process of its mantle source. The basalt suite was derived from a heterogeneous continental lithospheric mantle with end members characteristic of the EMI-type oceanic basalt mantle, which was affected by mantle metasomatism (or enrichment of trace elements) and was characterized by a multi-stage evolution under open conditions.

粤北长江铀矿田基性岩脉年代学、地球化学特征及其地质意义

粤北长江铀矿田位于诸广山复式岩体中南部,发育不同类型和期次基性岩脉。文章通过开展系统的岩石学、Ar-Ar年代学和地球化学分析,探究了基性岩脉类型、成岩年龄、构造背景、岩浆来源以及与铀成矿的关系。岩石学和年代学研究表明,该地区基性岩脉类型主要为辉绿岩、辉绿玢岩、闪斜煌岩及辉石煌斑岩等,基性岩脉至少分为三期:136.8 Ma、120.7 Ma、113.8~110.1 Ma,与华南中生代主要的地壳拉张活动时间相一致。地球化学研究结果表明,基性岩脉中大离子亲石元素Rb、Ba、K、Sr富集,高场元素Nb、Ta、Zr、Hf、Ti相对亏损,各类元素参数特征显示其具有拉张裂谷带玄武岩地球化学特征,可能为俯冲交代作用形成的富集地幔部分熔融形成。综合分析认为,该地区铀成矿作用是基性岩脉侵位后的地质事件,基性岩脉与铀成矿时空关系密切,受控于华南岩石圈伸展的动力学背景。

Deep seated magmas and their mantle roots:Introduction

In the last decade there has been a considerable effort to better understand the joint evolution of mafic and ultramafic magmatic systems and their deep mantle roots,through integrated petrological and thermo-barometric studies.Magma generation is regarded as the result of complex processes including melting,creation of channels for melt transfer,and interaction with the wall-rocks.

Geochemical characteristics and petrogenesis of volcanic rocks from Baiyingaolao Formation in northeastern Hailar Basin

The volcanic rocks from Baiyingaolao Formation in the northeastern Hailar Basin are mainly composed of rhyolite and trachydacite. U-Pb dating of zircon shows these volcanic rocks formed in Early Cretaceous( 128--124 Ma). Geochemical data indicate that they are sub-alkaline series in composition and rich in alkali and potassium. All samples have similar rare earth element patterns characterized by high total rare earth elements contents( ∑REE = 113. 96 × 10- 6-204. 33 × 10- 6),significant fractionation of heavy and light rare earth elements( ∑LREE / ∑HREE = 3. 10-4. 52) with middle negative Eu anomalies( δEu = 0. 46-0. 76).The trace elements are characterized by enrichment in large-ion lithophile elements such as K,Rb,LREE and depletion in high field strength elements e. g. Nb,Ta,HREE,P and Ti,while enriched in Th and U. Rhyolite and trachydacite contain low initial87 Sr /86 Sr ratios( 0. 704 9--0. 7 053) and positive εNd( t) values( ca. 4.15). These data suggest that the magma of rhyolite and trachydacite were derived from mafic lower crust newly accreted from mantle,with the evolutional trend of comagmatic fractional crystallization.