Organic matter transformation ratio, hydrocarbon expulsion efficiency and shale oil enrichment type in Chang 7_(3) shale of Upper Triassic Yanchang Formation in Ordos Basin, NW China

The major enrichment type of shale oil in the Chang 7_(3) shale of Upper Triassic Yanchang Formation in the Ordos Basin is unknown.This paper analyzes the organic matter transformation ratio,hydrocarbon expulsion efficiency and roof/floor sealing conditions of the Chang 7_(3) shale,and evaluates the major enrichment type of shale oil in this interval.The average organic matter transformation ratio of the Chang 7_(3) shale is about 45%;in other words,more than 50%of the organic matters have not transformed to hydrocarbons,and the lower the maturity,the greater the proportion of untransformed organic matters.The cumulative hydrocarbon expulsion efficiency of the transformed hydrocarbon is 27.5% on average,and the total proportion of untransformed organic matters plus retained hydrocarbons is greater than 70%.The relative hydrocarbon expulsion efficiency of the Chang 7_(3) shale is 60%on average,that is,about 40% of hydrocarbons retain in the shale.The Chang 7_(3) shale corresponds to Chang 7_(1+2) and Chang 8 sandstones as the roof and floor,respectively,and is further overlaid by Chang 6 shale,where extensive low porosity and low permeability–tight oil reservoirs have formed in the parts with relatively good porosity and permeability.Moreover,the Chang 7_(3) shale is tested to be in a negative pressure system(the pressure coefficient of 0.80–0.85).Therefore,the roof/floor sealing conditions of the Chang 7_(3) shale are poor.The retained hydrocarbons appear mostly in absorbed status,with low mobility.It is concluded that the medium–high mature shale oil is not the major enrichment type of shale oil in the Chang 7_(3) shale,but there may be enrichment opportunity for shale oil with good mobility in the areas where the sealing conditions are good without faults and fractures and oil reservoirs are formed off Chang 7_(1+2),Chang 6 and Chang 8.Furthermore,low–medium mature shale oil is believed to have great potential and is the major enrichment type of shale oil in the Chang 7_(3) shale.It is recommended to prepare relevant in-situ conversion technologies by pilot test and figure out the resource availability and distribution.

The Features of Sedimentary Facies and Copper Enrichment Metallogenic Regularities of Kuzigongsu Group in Sareke Glutenite Type Copper Deposits,Wuqia,Xinjiang

1 Introduction Sareke glutenite-type copper deposit is the large size copper deposit discovered in recent years,and it is located Sarekebayi intracontinental pull-apart basin in the western margin of the Tarim basin.Conglomerate of

Geochemistry and petrogenesis of Quaternary volcanism from the islets in the eastern Beibu Gulf: evidence for Hainan plume

Some of the islets in the eastern Beibu Gulf are covered by Quaternary volcano strata. The rock samples from these islets mainly consist of quartz tholeiites （at Shenjiandao）, olivine tholeiites （at Linshidao and Xieyang- dao） and alkali basalts （at Yangpubi and Jianshidao）, and basically represent four periods of the Quaternary volcanism of Hainan Island and its adjacent regions. Except for the samples from Shenjiandao, most of the Quaternary volcanics of these islets belong to alkali magma series. The trace element characteristics of all of these samples show they are OIB （oceanic island basalt） -like, which implies that their deep geodynamic setting may be related to a mantle plume. The Sr-Nd-Pb isotopic compositions show that the mantle source beneath the Quaternary strata can be regarded as a result of binary mixing between a depleted, DMM （de- pleted MORB mantle）-like source and an enriched mantle type 2 （EM2）. The EM2 may be originated from the Hainan mantle plume, and has been metasomatized by carbonaceous fluids released from ancient re- cycled oceanic crust at an asthenospheric mantle level. These features, together with typical trace element ratios, reflect that the parent magma was not subjected to crustal contamination during its ascent to the surface. This study provides further petrological and geochemical evidence for the existence of the Hainan mantle plume.