Construction of core@double-shell structured energetic composites with simultaneously enhanced thermal stability and safety performance

The poor thermal stability and high sensitivity severely hinder the practical application of hexanitrohexaazaisowurtzitane(CL-20).Herein,a kind of novel core@double-shell CL-20 based energetic composites were fabricated to address the above issues.The coordination complexes which consist of natural polyphenol tannic acid(TA) and Fe~Ⅲ were chosen to construct the inner shell,while the graphene sheets were used to build the outer shell.The resulting CL-20/TA-Fe~Ⅲ/graphene composites exhibited simultaneously improved thermal stability and safety performance with only 1 wt% double-shell content,which should be ascribed to the intense physical encapsulation effect from inner shell combined with the desensitization effect of carbon nano-materials from outer shell.The phase transition(ε to γ) temperature increased from 173.70 ℃ of pure CL-20 to 191.87℃ of CL-20/TA-Fe~Ⅲ/graphene composites.Meanwhile,the characteristic drop height(H_(50)) dramatically increased from 14.7 cm of pure CL-20 to112.8 cm of CL-20/TA-Fe~Ⅲ/graphene composites,indicating much superior safety performance after the construction of the double-shell structure.In general,this work has provided an effective and versatile strategy to conquer the thermal stability and safety issues of CL-20 and contributes to the future application of high energy density energetic materials.

Design,preparation,application of advanced array structured materials and their action mechanism analyses for high performance lithium-sulfur batteries

Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage systems.The widely commercial application and development of LSB is mainly hindered by serious“shuttle effect”of lithium polysulfides(Li PSs),slow reaction kinetics,notorious lithium dendrites,etc.In various structures of LSB materials,array structured materials,possessing the composition of ordered micro units with the same or similar characteristics of each unit,present excellent application potential for various secondary cells due to some merits such as immobilization of active substances,high specific surface area,appropriate pore sizes,easy modification of functional material surface,accommodated huge volume change,enough facilitated transportation for electrons/lithium ions,and special functional groups strongly adsorbing Li PSs.Thus many novel array structured materials are applied to battery for tackling thorny problems mentioned above.In this review,recent progresses and developments on array structured materials applied in LSBs including preparation ways,collaborative structural designs based on array structures,and action mechanism analyses in improving electrochemical performance and safety are summarized.Meanwhile,we also have detailed discussion for array structured materials in LSBs and constructed the structure-function relationships between array structured materials and battery performances.Lastly,some directions and prospects about preparation ways,functional modifications,and practical applications of array structured materials in LSBs are generalized.We hope the review can attract more researchers'attention and bring more studying on array structured materials for other secondary batteries including LSB.

Work Hard to Ensure Food,Drugs Safety for the People——An interview with Shao Mingli,director-general of the State Food and Drug Administration(SFDA)

Following is an interview given by Shao Mingli, director-general of China＇s State Food and Drug Administration to our reporter on what is being done to ensure food and drug safety in China. As everybody knows, food and drug safety is vital to people＇s lives.

Assessment of electrostatic discharge sensitivity of nitrogen-rich heterocyclic energetic compounds and their salts as high energy-density dangerous compounds:A study of structural variables

Nitrogen-rich heterocyclic energetic compounds(NRHECs)and their salts have witnessed widespread synthesis in recent years.The substantial energy-density content within these compounds can lead to potentially dangerous explosive reactions when subjected to external stimuli such as electrical discharge.Therefore,developing a reliable model for predicting their electrostatic discharge sensitivity(ESD)becomes imperative.This study proposes a novel and straightforward model based on the presence of specific groups(-NH_(2) or-NH-,-N=N^(+)-O^(-)and-NNO_(2),-ONO_(2) or-NO_(2))under certain conditions to assess the ESD of NRHECs and their salts,employing interpretable structural parameters.Utilizing a comprehensive dataset comprising 54 ESD measurements of NRHECs and their salts,divided into 49/5 training/test sets,the model achieves promising results.The Root Mean Square Error(RMSE),Mean Absolute Error(MAE),and Maximum Error for the training set are reported as 0.16 J,0.12 J,and 0.5 J,respectively.Notably,the ratios RMSE(training)/RMSE(test),MAE(training)/MAE(test),and Max Error(training)/Max Error(test)are all greater than 1.0,indicating the robust predictive capabilities of the model.The presented model demonstrates its efficacy in providing a reliable assessment of ESD for the targeted NRHECs and their salts,without the need for intricate computer codes or expert involvement.

Technical Analysis of Safety Monitoring and Evaluation of Existing Bridge Structures

Bridge structure safety monitoring and assessment has been a great concern for the government and the public,and bridge structure safety monitoring and assessment technology has also developed rapidly over the years.Its goal is to equip relevant organizations and professionals with a deep understanding of the principles and practical applications of these technologies.By doing so,it seeks to facilitate the effective implementation of safety monitoring and assessment practices in bridge management.Ultimately,the aim is to foster the constructive development of road and bridge construction and operational management at a broader level.

Pressure waves acting on wall of a tunnel and their impact on the tunnel's structural safety

The transient pressures induced by trains passing through a tunnel and their impact on the structural safety of the tunnel lining were numerically analyzed.The results show that the pressure change increases rapidly along the tunnel length,and the maximum value is observed at around 200 m from the entrance,while the maximum pressure amplitude is detected at 250 m from the entrance when two trains meeting in a double-track tunnel.The maximum peak pressure on the tunnel induced by a train passing through a 70 m^(2) single-track tunnel,100 m^(2) double-track tunnel and two trains meeting in the 100 m^(2) double-track tunnel at 350 km/h,are−4544 Pa,−3137 Pa and−5909 Pa,respectively.The aerodynamic pressure induced axial forces acting on the tunnel lining are only 8%,5%and 9%,respectively,of those generated by the earth pressure.It seems that the aerodynamic loads exert little underlying influence on the static strength safety of the tunnel lining providing that the existing cracks and defects are not considered.

Mechanical Behavior and Shape Optimization of Lining Structure for Subsea Tunnel Excavated in Weathered Slot

Subsea tunnel lining structures should be designed to sustain the loads transmitted from surrounding ground and groundwater during excavation. Extremely high pore-water pressure reduces the effective strength of the country rock that surrounds a tunnel, thereby lowering the arching effect and stratum stability of the structure. In this paper, the mechanical behavior and shape optimization of the lining structure for the Xiang＇an tunnel excavated in weathered slots are examined. Eight cross sections with different geometric parameters are adopted to study the mechanical behavior and shape optimization of the lining structure. The hyperstatic reaction method is used through finite element analysis software ANSYS. The mechanical behavior of the lining structure is evidently affected by the geometric parameters of crosssectional shape. The minimum safety factor of the lining structure elements is set to be the objective function. The efficient tunnel shape to maximize the minimum safety factor is identified. The minimum safety factor increases significantly after optimization. The optimized cross section significantly improves the mechanical characteristics of the lining structure and effectively reduces its deformation. Force analyses of optimization process and program are conducted parametrically so that the method can be applied to the optimization design of other similar structures. The results obtained from this study enhance our understanding of the mechanical behavior of the lining structure for subsea tunnels. These results are also beneficial to the optimal design of lining structures in general.

Research on the Seepage Safety Monitoring Indexes of the High Core Rockfill Dam

The study on developing the reasonable safety monitoring indexes plays a most importantly role in the health monitoring of high core rockfill dams. However, researches on this topic are relatively scarce both at home and abroad. In this paper, the characteristics and failure modes of seepage in high core rockfill dam are analyzed firstly. Then, a safety monitoring index based on seepage quantity, which reflects the overall seepage behavior, is developed, using the real-time monitoring data and its safety monitoring model. Moreover, another safety monitoring index based on seepage gradient, reflecting the local seepage behavior, is proposed, combining the spatial layout of osmo- meters and local failure mechanisms of core wall. Additionally, one more safety monitoring index based on permeability coefficient, which considers the overall and local seepage behaviors, is developed, on the basis of establishing the finite element analysis model and real-time seepage coefficient inversion analysis model of high core rockfill dam. A case study on these indexes of Nuozhadu high core rockfill dam is developed, which improves the reliability of seepage safety evaluation of the dam.

Safety-efficiency trade-offs in the cotton xylem：acclimatization to different soil textures

The acclimatization of plant xylem to altered environmental conditions has attracted considerable attention from researchers over several decades. Plants growing in natural environments must seek a balance between water uptake and the water loss of leaves from evaporation. Thus, the adaptation of xylem to different soil textures is important in maintaining plant water balance. In this study, we investigated the xylem changes of cotton（Gossypium herbaceum L.） xylem in sandy, clay and mixed soils. Results showed that soil texture had a significant effect on xylem vessel diameter and length of stems and roots. Compared with G. herbaceum growing in the clay soil, those plants growing in the sandy soil developed narrower and shorter xylem vessels in their roots, and had a higher percentage of narrow vessels in their stems. These changes resulted in a safer（i.e. less vulnerable to cavitation）, but less-efficient water transport system when soil water availability was low, supporting the hydraulic safety versus efficiency trade-off hypothesis. Furthermore, in sandy and mixed soils, the root： shoot ratio of G. herbaceum increased twofold, which ensures the same efficiency of leaves. In summary, our finding indicates that the morphological plasticity of xylem structure in G. herbaceum has a major role in the acclimatization of this plant species to different soil textures.

Current State of Numerical Simulations and Testing for the Blast and Impact Protection of the Build Civil Engineering Infrastructure

The identification of the critical infrastructure has shown that the build civil engineering infrastructure is almost involved everywhere, even with the IT-infrastructure. Therefore, the passive safety of structures is demanded. Security associations have analysed that most assaults came along with explosion and impact scenarios, which amount in 80% of assaults. Consequently, these are the extraordinary loads the structures have to be planned and designed for. To carry out such an engineering job, the engineer has to be educated in multiple disciplines as physics, material science , continuum mechanics, numerical mechanics, testing, structural engineering and related specific fields as wave propagation etc. In this paper we will concentrate on the subjects of numerical simulation and testing.

As Could We Assure Safety in Large-Scale Manufacturing of Nanoparticles for the Biomedical Use

Nanoparticles provide great advantages but also great risks. Risks associating with nanoparticles are the problem of all technologies, but they increase in many times in nanotechnologies. Adequate methods of outgoing production inspection are necessary to solve the problem of risks, and the inspection must be based on the safety standard. Existing safety standard results from a principle of “maximum permissible concentrations or MPC”. This principle is not applicable to nanoparticles, but a safety standard reflecting risks inherent in nanoparticles doesn’t exist. Essence of the risks is illustrated by the example from pharmacology, since its safety assurance is conceptually based on MPC and it has already come against this problem. Possible formula of safety standard for nanoparticles is reflected in many publications, but conventional inspection methods cannot provide its realization, and this gap is an obstacle to assumption of similar formulas. Therefore the development of nanoparticle industry as a whole (also development of the pharmacology in particular) is impossible without the creation of an adequate inspection method. There are suggested new inspection methods founded on the new physical principle and satisfying to the adequate safety standard for nanoparticles. These methods demonstrate that creation of the adequate safety standard and the outgoing production inspection in a large-scale manufacturing of nanoparticles are the solvable problems. However there is a great distance between the physical principle and its hardware realization, and a transition from the principle to the hardware demands great intellectual and material costs. Therefore it is desirable to call attention of the public at large to the necessity of urgent expansions of investigations associated with outgoing inspections in nanoparticles technologies. It is necessary also to attract attention, first, of representatives of state structures controlling approvals of the adequate safety standard to this problem, since it is impossible to compel producers providing the safety without the similar standard, and, second, of leaders of pharmacological industry, since their industry already entered into the nanotechnology era, and they have taken an interest in a forthcoming development of inspection methods.

APPLICATION OF SINTAP TO THE SAFETY ASSESSMENT OF X65 PIPELINE STEEL

The recently developed European flaw assessment procedure, structural integrity assessment procedure（SiNTAP） is applied to assessment for welded joints of the API 5L X65 pipeline steel with an assumed embedded flaw and surface flaw at the weld toe. As one of the basic input data, fracture toughness crack tip opening displacement （CTOD） tests are conducted at 0℃ and performed according to the requirements of the standard of BS7448. For the heat affected zone （HAZ） specimens, the microstructure observation is performed to insure that the tip of the crack is located in the coarse grain zone. The result explains the dispersity of the test values. In structural integrity assessment procedure-fracture assessment diagram（SINTAP FAD） method, the failure curves of welded joints at level 1 and 3 are derived from the tensile test results. The results of the assessment show that all assessment points are located within the failure lines of analysis level 1 and 3. So the welded joint of the pipeline is safe. This study laid the foundation of application of SINTAP to pipeline structure assessment.

The Study of Farmland Information Management System based on Wireless Sensor Networks

To satisfy the need of good quality and high yield primary production,the farmland information management system based on wireless Sensor Network has been proposed.We give priority to analyzing the basic function of the system,building the systematic structure of applied system and network system,and implementing the energy control and safety design of system.The system can reduce manpower operation and the error of manual measuration in the course of practical production,reduce the cost of agricultural production,and realize automatization of agricultural production to the largest extent to provide an effective way to realize good quality and high yield primary production,which has an important realistic meaning.

Investigation of the role of personal factors on work injury in underground mines using structural equation modeling

Work injuries in mines are complex and generally characterized by several factors starting from personal to technical and technical to social characteristics.In this paper,investigation was made through the application of structural equation modeling to study the nature of relationships between the influencing/associating personal factors and work injury and their sequential relationships leading towards work injury occurrences in underground coal mines.Six variables namely,rebelliousness,negative affectivity,job boredom,job dissatisfaction and work injury were considered in this study.Instruments were developed to quantify them through a questionnaire survey.Underground mine workers were randomly selected for the survey.Responses from 300 participants were used for the analysis.The structural model of LISREL was used to estimate the interrelationships amongst the variables.The case study results show that negative affectivity and job boredom induce more job dissatisfaction to the workers whereas risk taking attitude of the individual is positively influenced by job dissatisfaction as well as by rebelliousness characteristics of the individual.Finally,risk taking and job dissatisfaction are having positive significant direct relationship with work injury.The findings of this study clearly reveal that rebelliousness,negative affectivity and job boredom are the three key personal factors influencing work related injuries in mines that need to be addressed properly through effective safety programs.

Activation characteristics of candidate structural materials for a near-term Indian fusion reactor and the impact of their impurities on design considerations

Activation analyses play a vital role in nuclear reactor design.Activation analyses,along with nuclear analyses,provide important information for nuclear safety and maintenance strategies.Activation analyses also help in the selection of materials for a nuclear reactor,by providing the radioactivity and dose rate levels after irradiation.This information is important to help define maintenance activity for different parts of the reactor,and to plan decommissioning and radioactive waste disposal strategies.The study of activation analyses of candidate structural materials for near-term fusion reactors or ITER is equally essential,due to the presence of a highenergy neutron environment which makes decisive demands on material selection.This study comprises two parts; in the first part the activation characteristics,in a fusion radiation environment,of several elements which are widely present in structural materials,are studied.It reveals that the presence of a few specific elements in a material can diminish its feasibility for use in the nuclear environment.The second part of the study concentrates on activation analyses of candidate structural materials for near-term fusion reactors and their comparison in fusion radiation conditions.The structural materials selected for this study,i.e.India-specific Reduced Activation Ferritic-Martensitic steel（IN-RAFMS）,P91-grade steel,stainless steel 316 LN ITER-grade（SS-316 LN-IG）,stainless steel 316 L and stainless steel 304,are candidates for use in ITER either in vessel components or test blanket systems.Tungsten is also included in this study because of its use for ITER plasma-facing components.The study is carried out using the reference parameters of the ITER fusion reactor.The activation characteristics of the materials are assessed considering the irradiation at an ITER equatorial port.The presence of elements like Nb,Mo,Co and Ta in a structural material enhance the activity level as well as the dose level,which has an impact on design considerations.IN-RAFMS was shown to be a more effective low-activation material than SS-316 LN-IG.

Characteristics of fault zones and their control on remaining oil distribution at the fault edge: a case study from the northern Xingshugang Anticline in the Daqing Oilfield, China

Most major oil zones in the Daqing Oilfield have reached a later,high water cut stage,but oil recovery is still only approximately 35%,and 50%of reserves remain to be recovered.The remaining oil is primarily distributed at the edge of faults,in poor sand bodies,and in insufficiently injected and produced areas.Therefore,the edge of faults is a major target for remaining oil enrichment and potential tapping.Based on the dynamic change of production from development wells determined by the injection-recovery relationship at the edge of faults,we analyzed the control of structural features of faults on remaining oil enrichment at the edge.Our results show that the macroscopic structural features and their geometric relationship with sand bodies controlled remaining oil enrichment zones like the edges of NNE-striking faults,the footwalls of antithetic faults,the hard linkage segments（two faults had linked together with each other to form a bigger through-going fault）,the tips of faults,and the oblique anticlines of soft linkages.Fault edges formed two types of forward microamplitude structures：（1） the tilted uplift of footwalls controlled by inverse fault sections and（2） the hanging-wall horizontal anticlines controlled by synthetic fault points.The remaining oil distribution was controlled by microamplitude structures.Consequently,such zones as the tilted uplift of the footwall of the NNW-striking antithetic faults with a fault throw larger than 40 m,the hard linkage segments,the tips of faults,and the oblique anticlines of soft linkage were favorable for tapping the remaining oil potential.Multi-target directional drilling was used for remaining oil development at fault edges.Reasonable fault spacing was determined on the basis of fault combinations and width of the shattered zone.Well core and log data revealed that the width of the shattered zone on the side of the fault core was less than 15 m in general;therefore,the distance from a fault to the development target should be larger than 15 m.Vertically segmented growth faults should take the separation of the lateral overlap of faults into account.Therefore,the safe distance of remaining oil well deployment at the fault edge should be larger than the sum of the width of shattered zone in faults and the separation of growth faults by vertical segmentation.

The mechanism of slope instability due to rainfall-induced structural decay of earthquake-damaged loess

Natural loess slopes are characterized by a strong geological structure,which is an important factor in maintaining slope stability.The magnitude and duration of the earthquake may disturb the soil structure at different levels degrees,locally changing the arrangement between soil particles.The process of rainfall humidification weakens the cementation between soil particles,and the disturbance and humidification change the structural state of the soil,which in turn causes sliding of the slope along with the decay of soil mechanical properties.As slope instability is often the result of a series of post-earthquake ripple effects,it is of great scientific significance to study the mechanism of slope instability due to the structural decay of earthquake-damaged loess exacerbated by rainfall.In this paper,the impact of structural decay of loess on slope stability is simulated by GEOSTUDIO software under three conditions:pre-earthquake rainfall,post-earthquake rainfall and earthquake,taking the landslide in Buzi Village,Min County,Gansu Province as an example.The comparative analysis of the calculation results shows that the structural properties of the slope without earthquake disturbance are influenced by infil-tration amount.When it is fully saturated,the structural properties are similar to those of saturated soil,and the safety factor is reduced by 12.9%.In addition,the earthquake intensity and duration have different degrees of structural damage to the soil.When the structure is fully damaged,it is similar to that of remodelled soil,and the safety factor is reduced by 45.84%.Notably,the process of the earthquake and the following humidification generates the most serious damage to the loess structure,with a reduction in the safety factor of up to 56.15%.The quantitative analysis above obviously illustrates that the post-earthquake rainfall causes the most severe damage to structural loess slopes,and the resulting landslide hazard should not be underestimated.

Safety analysis of optimal outriggers location in high-rise building structures

This paper presents the restraining moments of outriggers acting on the core wall and the equation of the horizontal top deflection based on a simplified outrigger model. The deformation compatibility conditions between outriggers and core wall as well as the finite rigidities of outriggers are also considered. One case study was carried out to analyze the horizontal top deflection and the mutation of the restraining moments caused by the variation of outrigger location. The results showed that the method adopted in the paper is simple and reasonable. Some conclusions are valuable to the safety design of high-rise building structures.

Long Undersea Tunnels： Recognizing and Overcoming the Logistics of Operation and Construction

Long undersea tunnels, and particularly those that are built for transportation purposes, are not commonplace infrastructure. Although their planning and construction take a considerable amount of time, they form important fixed links once in operation. The fact that these tunnels are located under the sea gen- erally involves unique challenges including complex issues with construction and operations, which relate to the lack of intermediate access points along the final route of the tunnel. Similar issues are asso- ciated with long under-land tunnels, such as those under mountain ranges such as the Alps. This paper identifies the key issues related to the design and construction of such tunnels, and suggests a potential solution using proven technology from another engineering discipline.

Design of crashworthy attenuator structures as a part of vehicle safetyagainst impact:Application of waste aluminum can-based material

The impact attenuator is an essential system in both race cars and urban vehicles.The structure of animpact attenuator serves as a safety barrier between the impacted surface and the driver in an accident.Attenuator materials tend to have a high price;thus,alternative materials were explored in the currentwork,i.e.,used cans from food and beverage containers.The study deployed a nonlinear finite elementalgorithm to calculate a series of impacts on the attenuator structures.The thickness of the cans andvelocity of the impact were considered as the main parameters.Analysis results concluded that the at-tenuator’s average energy was 16000 J for a can thickness of 1 mm.This value is more than two times the0.5 mm thick used cans.The attenuator’s new design was then matched with an attenuator regulation,and the results surpassed the standard value of 7350 J.