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A numerical study of coupled maps representing energy exchange processes between two environmental interfaces regarded as biophysical complex systems 被引量:1
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作者 Dragutin Mihailovic Mirko Budincevic +2 位作者 Darko Kapor Igor Balaz Dusanka Perisic 《Natural Science》 2011年第1期75-84,共10页
The field of environmental sciences is abundant with various interfaces and is the right place for the application of new fundamental approaches leading towards a better understanding of environmental phenomena. Follo... The field of environmental sciences is abundant with various interfaces and is the right place for the application of new fundamental approaches leading towards a better understanding of environmental phenomena. Following the definition of environmental interface by Mihailovic and Bala? [1], such interface can be, for example, placed between: human or animal bodies and surrounding air, aquatic species and water and air around them, and natural or artificially built surfaces (vegetation, ice, snow, barren soil, water, urban communities) and the atmosphere, cells and surrounding environment, etc. Complex environmental interface systems are (i) open and hierarchically organised (ii) interactions between their constituent parts are nonlinear, and (iii) their interaction with the surrounding environment is noisy. These systems are therefore very sensitive to initial conditions, deterministic external perturbations and random fluctuations always present in nature. The study of noisy non-equilibrium processes is fundamental for modelling the dynamics of environmental interface regarded as biophysical complex system and for understanding the mechanisms of spatio-temporal pattern formation in contemporary environmental sciences. In this paper we will investigate an aspect of dynamics of energy flow based on the energy balance equation. The energy exchange between interacting environmen- tal interfaces regarded as biophysical complex systems can be represented by coupled maps. Therefore, we will numerically investigate coupled maps representing that exchange. In ana- lysis of behaviour of these maps we applied Lyapunov exponent and cross sample entropy. 展开更多
关键词 environmental interface NONLINEARITY CHAOS Logistic Equation Energy Balance Equation Coupled Maps HIERARCHY Biophysical Complex Systems
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具有丰富孤对电子的亲锌超分子分子通道实现高度稳定锌阳极
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作者 孟超 谭昊 +1 位作者 刘宏 王建军 《Science China Materials》 SCIE EI CAS CSCD 2024年第5期1455-1463,共9页
在柔性设备和静态储能电网应用中,可充电水性锌离子电池展现出巨大的潜力.但其发展受到界面不稳定性引起的副反应及枝晶生长的阻碍.本研究中,我们采用了一种新颖的电解液设计,通过含大量孤电子对的亲锌葫芦[7]超分子来应对这一挑战.这... 在柔性设备和静态储能电网应用中,可充电水性锌离子电池展现出巨大的潜力.但其发展受到界面不稳定性引起的副反应及枝晶生长的阻碍.本研究中,我们采用了一种新颖的电解液设计,通过含大量孤电子对的亲锌葫芦[7]超分子来应对这一挑战.这些超分子因其独特的分子结构,能够在电化学循环中有效地吸纳和固定Zn离子,从而有效避免了Zn离子的无序迁移和枝晶的形成.超分子中丰富的孤对电子提供的Lewis碱性位点(如叔胺和羰基氧)作为Zn离子的供电子成核位点,促进了紧密成核.这些超分子与Zn离子之间的强烈相互作用,不仅提高了系统的稳定性,还显著抑制了不良副反应.因此,我们组装的对称电池和Zn//V_(2)O_(5)全电池均展示了长效的循环稳定性和卓越的库仑效率. 展开更多
关键词 supermolecules molecular channel lone-pair electrons interface chemical environment regulation Zn ion battery
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