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Paleoenvironmental significance investigation of loess magnetic fabric in a semiarid region 被引量:1
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作者 WANGYong PANBaotian GUANQingyu GAOHongshan ,ZHANGHui LIQiong LIUXiaofeng 《Journal of Geographical Sciences》 SCIE CSCD 2005年第2期210-216,共7页
Here we report our recent magnetic fabric investigation of loess deposition in Shagou section, located at the northeastern Qilian Mountains, the northeastern rim of the Tibetan Plateau. On the basis of environmental m... Here we report our recent magnetic fabric investigation of loess deposition in Shagou section, located at the northeastern Qilian Mountains, the northeastern rim of the Tibetan Plateau. On the basis of environmental magnetism data, we indicate that the variation of anisotropy of magnetic susceptibility (AMS) parameters, especially the foliation (F) and degree of anisotropy (P), might be more sensitive to the environmental change in the arid and semiarid regions than the magnetic susceptibility fluctuation. During the investigated interval, from 0.83 to 0.128 Ma, most of the middle to late Pleistocene significant climate change can be unraveled by the AMS parameters, such as the strengthening of cold/dry climate, the step drying event occurred nearly 250 ka, and the severe environmental change in MIS16. Our results also suggest that there is strong correlation between median diameter (Md) of grain size, F, and P. We propose that the AMS parameters can act as an important paleoenvironmental change indicator in the arid and semiarid regions. 展开更多
关键词 magnetic fabric environmental variation Qilian Mountains
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Magnetic Solid-Phase Extraction of Phthalate Esters from Environmental Water Samples using Fibrous Phenyl-functionalized Fe3O4@SiO2@KCC-1 被引量:2
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作者 Xue-zheng Zhou Xiang-yang Yan +6 位作者 Ling Zhu Ming Ma Ya Dai Chang-guo Wang Li-jun Zhu Ke-jie Yu Shao-min Liu 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2020年第6期749-756,I0003,共9页
A new kind of phenyl-functionalized magnetic fibrous mesoporous silica(Fe3 O4@Si O2@KCC-1-phenyl) was prepared by copolymerization as an efficient adsorbent for the magnetic extraction of phthalate esters from environ... A new kind of phenyl-functionalized magnetic fibrous mesoporous silica(Fe3 O4@Si O2@KCC-1-phenyl) was prepared by copolymerization as an efficient adsorbent for the magnetic extraction of phthalate esters from environmental water samples. The obtained Fe3 O4@Si O2@KCC-1-phenyl showed monodisperse fibrous spherical morphology, fairly strong magnetic response(29 emu/g), and an abundant π-electron system, which allowed rapid isolation of the Fe3 O4@Si O2@KCC-1-phenyl from solutions upon applying an appropriate magnetic field. Several variables that affect the extraction efficiency of the analytes,including the type of the elution solvent, amount of adsorbent, extraction time and reusability, were investigated and optimized. Under optimum conditions, the Fe3 O4@Si O2@KCC-1-phenyl was used for the extraction of four phthalate esters from environmental water samples followed by high-performance liquid chromatographic analysis. Validation experiments indicated that the developed method presented good linearity(0.1-20 ng/m L), low limit of detection(7.5-29 μg/L, S/N =3). The proposed method was applied to the determination of phthalate esters in different real water samples, with relative recoveries of 93%-103.4%and relative standard deviation of 0.8%-8.3%. 展开更多
关键词 Fibrous mesoporous silica Phenyl-functionalized magnetic solid-phase ex-traction High performance liquid chromatography Phthalate esters environmental water
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Environmental magnetic measurements of marine sediments from Antarctica: implications to paleoclimate changes during the past 15 ka
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作者 侯红明 王保贵 +2 位作者 汤贤赞 罗又郎 郑洪汉 《Chinese Journal of Polar Science》 1997年第1期39-49,共11页
In this paper, authors report some results obtained from systematic rock magnetic measurements on Core NP95 1 and Core NG93 1 , which were collected from the Prydz Bay, Eastern Antarctica and Great Wall Bay (Maxwell... In this paper, authors report some results obtained from systematic rock magnetic measurements on Core NP95 1 and Core NG93 1 , which were collected from the Prydz Bay, Eastern Antarctica and Great Wall Bay (Maxwell Bay), Western Antarctica respectively during the 11th and 9th CHINARE and a sequence of paleoclimate variations is well established based on sediment rock magnetic properties. In Antarctica, the magnetic properties show a close linkage to paleoenvironmental variations. The Core NP95 1 well recorded several paleoclimatic events, such as Heinrich event 1, Bolling Allerod warm period and Younger Dryas cold event. The Heinrich event 1 occurred at about 14 2 ka B.P., Younger Dryas cold event occurred between 11 7 ka B.P. and 10 3 ka B.P., and the boundary of Pleistocene and Holocene in Antarctica is 10 3 ka B.P.. In Holocene, two warm periods were recorded at about 10 0 ka B.P. and 6 0 ka B.P. with a little cold period between them. After 6 0 ka B.P. , two cores both recorded a cold climatic oscillation. Paleoclimate described by two cores rock magnetic measurements was simultaneously changed in Eastern and Western Antarctica during the same period two cores commonly covered. 展开更多
关键词 paleoclimatic variation environmental magnetism Younger Dryas Heinrich event 1 marine sediment rock magnetism Antarctica.
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Manipulating coupling state and magnetism of Mn-doped ZnO nanocrystals by changing the coordination environment of Mn via hydrogen annealing
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作者 程岩 李文献 +6 位作者 郝维昌 许怀哲 徐忠菲 郑离荣 张静 窦士学 王天民 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第1期762-769,共8页
Mn-doped ZnO nanocrystals are synthesized by a wet chemical route and treated in H2/Ar atmosphere with different H2/Ar ratios. It is found that hydrogen annealing could change the coordination environment of Mn in ZnO... Mn-doped ZnO nanocrystals are synthesized by a wet chemical route and treated in H2/Ar atmosphere with different H2/Ar ratios. It is found that hydrogen annealing could change the coordination environment of Mn in ZnO lattice and manipulate the magnetic properties of Mn-doped ZnO. Mn ions initially enter into interstitial sites and a Mn3+ 06 octahedral coordination is produced in the prepared Mn-doped ZnO sample, in which the nearest neighbor Mn3+ and 02 ions could form a Mn3+-O2--Mn3+ complex. After H2 annealing, interstitial Mn ions can substitute for Zn to generate the Mn2+O4 tetrahedral coordination in the nanocrystals, in which neighboring Mn2+ ions and H atoms could form a Mn2+-O2--Mn2+ complex and Mn-H-Mn bridge structure. The magnetic measurement of the as-prepared sample shows room temperature paramagnetic behavior due to the Mn3+-O2--Mn3+ complex, while the annealed samples exhibit their ferromagnetism, which originates from the Mn-H-Mn bridge structure and the Mn-Mn exchange interaction in the Mn2+-O2--Mn2+ complex. 展开更多
关键词 coordination environment magnetic coupling x-ray absorption fine structure
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Atmospheric particulate pollution of Lanzhou using magnetic measurements 被引量:14
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作者 Chen Fa\|hu, Yang Li\|ping, Wang Jian\|min, Zhang Jia\|wu Institute of Environment & Hazards, Lanzhou University, Lanzhou 730000, China. E\|mail: fhchen@lzu.edu.cn 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 1999年第3期373-377,共5页
To differentiate between natural and anthropogenic particulate sources in the atmosphere in Lanzhou City, samples were collected in different sites. The dust flux was calculated and magnetic measurements were conducte... To differentiate between natural and anthropogenic particulate sources in the atmosphere in Lanzhou City, samples were collected in different sites. The dust flux was calculated and magnetic measurements were conducted. Results show a distinct pattern of variation of dust flux within a year and it agrees with the shifts of atmospheric circulation regime. The magnetic parameters indicate that natural sources are the major components of atmospheric particulate during late spring and early summer, while anthropogenic sources contribute much more during winter months. The data also support the earlier findings that magnetic parameters are effective for differentiating between particulate arising from natural sources such as soil erosion and from anthropogenic sources such as coal combustion. 展开更多
关键词 atmospheric particulate dust flux magnetic measurement lanzhou of China.
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Statistical landslide susceptibility assessment in a dynamic environment:A case study for Lanzhou City,Gansu Province,NW China 被引量:1
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作者 TORIZIN Jewgenij WANG Li-chao +6 位作者 FUCHS Michael TONG Bin BALZER Dirk WAN Li-qin KUHN Dirk LI Ang CHEN Liang 《Journal of Mountain Science》 SCIE CSCD 2018年第6期1299-1318,共20页
This study presents a statistical landslide susceptibility assessment(LSA) in a dynamic environment. The study area is located in the eastern part of Lanzhou, NW China. The Lanzhou area has exhibited rapid urbanizatio... This study presents a statistical landslide susceptibility assessment(LSA) in a dynamic environment. The study area is located in the eastern part of Lanzhou, NW China. The Lanzhou area has exhibited rapid urbanization rates over the past decade associated with greening, continuous land use change, and geomorphic reshaping activities. To consider the dynamics of the environment in the LSA, multitemporal data for landslide inventories and the corresponding causal factors were collected. The weights of evidence(Wof E) method was used to perform the LSA. Three time stamps, i.e., 2000, 2012, and 2016, were selected to assess the state of landslide susceptibility over time. The results show a clear evolution of the landslide susceptibility patterns that was mainly governed by anthropogenic activities directed toward generating safer building grounds for civil infrastructure. The low and very low susceptibility areas increased by approximately 10% between 2000 and 2016. At the same time, areas of medium, high and very high susceptibility zones decreased proportionally. Based on the results, an approach to design the statistical LSA under dynamic conditions is proposed, the issues and limitations of this approach are also discussed. The study shows that under dynamic conditions, the requirements for data quantity and quality increase significantly. A dynamic environment requires greater effort to estimate the causal relations between the landslides and controlling factors as well as for model validation. 展开更多
关键词 Landslide susceptibility assessment Dynamic environment Weights of evidence method VALIDATION URBANIZATION lanzhou City
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Assessment tools of nursing work environment in magnet hospitals: A review 被引量:1
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作者 Li-Yan Gu Ling-Juan Zhang 《International Journal of Nursing Sciences》 2014年第4期437-440,共4页
In the 1990s,the American Nurses Association established a certification program called the Magnet Recognition Program through the American Nurses Credentialing Centre(ANCC)to complement the quality care provided to p... In the 1990s,the American Nurses Association established a certification program called the Magnet Recognition Program through the American Nurses Credentialing Centre(ANCC)to complement the quality care provided to patients by hospitals.After the program was recognised,hospitals were identified as magnet hospitals[1].Some studies show that magnet hospitals provide a healthier working environment for nurses,accompanied by higher nurse satisfaction and better patient prognosis than non-magnet hospitals[2e5].The nursing work environment is the sum of various elements that directly or indirectly affect the patient care system[6].Improving the nursing work environment is a focal point and challenge for nursing administrators.Therefore,administrators in magnet hospitals usually apply a variety of assessment tools for effective evaluation of the nursing work environment to maintain and improve the health of the environment. 展开更多
关键词 Evaluation studies magnet hospitals Nursing work environment Literature review
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The magnetic properties of sediment and sedimentary environment in the Huanghe Delta area after the last glacial maximum 被引量:1
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作者 PENG Jun LI Ping CHEN Hongquan 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2016年第5期113-123,共11页
On the basis of measuring the magnetic parameters of sediment in Core YDZ1, combined with a grain size analysis and Carbon-14 dating, the magnetic properties of sediment and sedimentary environment in the Huanghe(Yel... On the basis of measuring the magnetic parameters of sediment in Core YDZ1, combined with a grain size analysis and Carbon-14 dating, the magnetic properties of sediment and sedimentary environment in the Huanghe(Yellow River) Delta area after the last glacial maximum have been studied. The results show that the ferrimagnetic minerals of a pseudo single domain and multi domain particles dominate the magnetic properties of sediment in Core YDZ1. The imperfect anti ferrimagnetic minerals have more contribution on sediment in a depth of 24.0–22.1 m, and more stable-single domain and pseudo single domain particles exist. The susceptibility of anhysteretic remanent magnetization and the ratio of the susceptibility of anhysteretic remanent magnetization to saturation isothermal remanent magnetization show a decrease trend below depth of 24 m, a marked increase trend in a depth of 24.0–13.5 m, and a rapid decrease at depth of 13.5 m, then a fluctuation trend upward. The above two magnetic parameters and the ratio of the susceptibility of anhysteretic remanent magnetization to the mass susceptibility can be regarded as the proxy indicators for the content of clay(〈4 μm)and the fine-grained size(〈32 μm). The sedimentary environment after the last glacial maximum in the Huanghe Delta area has experienced the fluvial facies, the tidal flat facies, the neritic facies, the pro delta facies, the delta front facies and the floodplain facies. Thickness of the Holocene transgression layer is 10.5 m and the depth of substrate is about 24 m according to the YDZ1 core. The sedimentary dynamic has a variation trend with strongweak-strong, which has been proved by the Flemming triangular schema. 展开更多
关键词 the Huanghe(Yellow River) Delta magnetic properties sedimentary environment grain size dating
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The Holocene Environmental Evolution of the Inner Hangzhou Bay and Its Significance
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作者 LIU Yan MA Chunyan +4 位作者 FAN Daidu SUN Qianli CHEN Jing LI Maotian CHEN Zhongyuan 《Journal of Ocean University of China》 SCIE CAS CSCD 2018年第6期1301-1308,共8页
The Holocene environmental evolution in coastal area, including deltas and estuaries, is vital to the Neolithic colonization in the eastern China. A 29-m long sediment core XL was obtained from the region between the ... The Holocene environmental evolution in coastal area, including deltas and estuaries, is vital to the Neolithic colonization in the eastern China. A 29-m long sediment core XL was obtained from the region between the Taihu Lake and Qiantang Estuary, and multiple analyses on the core sediments have been done to investigate the evolution history of the inner coastal zone of Hangzhou Bay during the Holocene. Six sedimentary facies are identified since the late Pleistocene, including the paleosol at the bottom, overlain by tidal-flat-channel complex(TFC), tidal-distributary-channel(TDC), inner estuarine basin(IEB), subtidal-to-intertidal-flat, and fluvial-plain facies. The TFC and TDC facies are dated to be formed before 8500 cal yr BP, featured by relatively coarse sediments, high magnetic properties and less abundant foraminifera, denoting the tide-influenced setting with large terrestrial inputs. The IEB facies characterized by the most abundant foraminifera fossils and the lowest sediment magnetic properties, is inferred to be deposited during the maximum flooding period between 8500 and 7900 cal yr BP. The branch estuary was then infilled by local sediments with a shallowing-upward subtidal-to-intertidal sequence during 7900–4300 cal yr BP. At last the fluvial plain system developed since no later than 4300 cal yr BP, favouring the rapid development of Neolithic cultures in the region. 展开更多
关键词 FACIES analysis grain size Hangzhou Bay environmental magnetism FORAMINIFERA NEOLITHIC CULTURES
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Environmental simulation platform and its application to geodesic instruments for a performance study
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作者 Tu Hai-Bo Sun Heng +4 位作者 Liu Kun Zhang Jun-Gang He Jian-Gang Tian Wei Wang Yong 《Applied Geophysics》 SCIE CSCD 2020年第5期756-763,902,共9页
In this study,an environmental simulation platform(ETS-02)was constructed for high-precision geodesic instruments(e.g.,absolute/relative gravimeters and inclinometers),to test the disturbances caused by environmental ... In this study,an environmental simulation platform(ETS-02)was constructed for high-precision geodesic instruments(e.g.,absolute/relative gravimeters and inclinometers),to test the disturbances caused by environmental fl uctuations.The outer layer of the platform was constructed with two sets of rectangular electromagnetic coils,which generated the required magnetic fi eld when current was applied.The inner layer was a closed cabin in which radiators were distributed such that the temperature of the experimental space inside the cabin could be controlled,by energy exchange between the radiators and a thermal controller through the fl owing liquid.A high-precision hexapod was used to simulate the tilt-related eff ect.The platform was capable of adjusting temperatures within a dynamic range of 0℃-70℃ at a resolution of 0.01℃.The noise of the power-spectrum density when the cabin was set to room temperature was measured as 0.03℃/Hz^(1/2) at 1 mHz.The magnetic field simulation had a dynamic range of±300μT and stability of 20 nT.The resolution of the ground-tilt simulation was 1 arc s.The inner space of the platform had a volume of approximately 5 m^(3),which is sufficient for most types of instruments to be tested for a general environmental coupling effect.To illustrate the application of the platform,a dual-axis inclinometer was built and tested carefully with the platform,and the accuracy of the calibration factors was found to be signifi cantly improved. 展开更多
关键词 environmental simulation platform temperature magnetic fi eld ground tilt dual-axis inclinometer test of geodesic instruments
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Magnetic Susceptibility and Natural Gamma Radioactivity as Indirect Indicators of Impurities in Limestones of the Sabinas Basin: Possible Relationships with the Sedimentation Environment
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作者 José A. Batista Rodríguez Joaquín A. Proenza Fernández +2 位作者 Gloria I. Dávila Pulido Mitzué Garza García Itzayana Y. Zamora Medellín 《Journal of Geoscience and Environment Protection》 2017年第10期77-91,共15页
This study presents an analysis of magnetic susceptibility and natural gamma radioactivity as indirect indicators of impurities in Cretaceous limestones of the Sabinas basin, as well as of the possible relation of the... This study presents an analysis of magnetic susceptibility and natural gamma radioactivity as indirect indicators of impurities in Cretaceous limestones of the Sabinas basin, as well as of the possible relation of these physical properties with the changes in the sedimentation environment. Both of these physical properties indicate changes in the degree of impurities and the mineralogical composition of this rock, principally in its organic matter and detritus content. Considering that the sedimentation environment determines the impurities in these rocks, possible environmental conditions at different levels of the Cretaceous were suggested using the magnetic susceptibility, total gamma radiation and potassium values, as well as the uranium and thorium concentration in the limestones. The analyses suggest variations in the depth of water table of the basin, which are mainly related to transgressions and marine regressions. 展开更多
关键词 magnetic Susceptibility Natural Gamma RADIOACTIVITY LIMESTONES environment SEDIMENTATION Sabinas BASIN
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Influence of the 60 Hz Magnetic Field on the Airborne Microbial Distribution of Indoor Environments
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作者 Matilde Anaya Sofia F.Borrego +2 位作者 Miguel Castro Oderlaise Valdés Alian Molina 《Journal of Atmospheric Science Research》 2020年第3期23-32,共10页
The aim of this work was to analyze the effect of the magnetic field generated by the household appliances on the airborne microbial surrounding these equipment located on indoor environments with particular interest ... The aim of this work was to analyze the effect of the magnetic field generated by the household appliances on the airborne microbial surrounding these equipment located on indoor environments with particular interest in the environmental fungi.A simultaneous environmental study was carried out in locals of three different geographical places of Havana,Cuba,which have televisions,computers and an electric generator.The air samples were made by a sedimentation method using Malt Extract Agar.The concentration of total aerobic mesophilic as well as fungi and yeasts were determined in rainy and little rainy seasons by applying as factors:exposure time of dishes(5 to 60 min)and distance to the wall(0 and 1 m)at a height of 1 m above the floor.The predominant fungal genera were Cladosporium,Penicillium and Aspergillus.In the dishes that were placed at 0 and 0.5 m from the emitting sources were observed that some bacteria colonies formed inhibition halos,a great diversity of filamentous fungi and an increase in the mycelium pigmentation as well as the pigments excretion.In the rainy season,the highest amounts of fungi were obtained in all samples.In the little rain season the count of the Gram-negative bacilli increased three times the Gram-positive cocci. 展开更多
关键词 Non-ionizing radiation Appliances Airborne mycobiota Indoor environment Index of microbial air magnetic field
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磁改性生物质炭渣对酸性矿山废水中Cu^(2+)、Pb^(2+)的吸附研究
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作者 狄军贞 袁博夫 +3 位作者 阮浈 姜洋洋 高梦晴 李茹霜 《安全与环境学报》 CAS CSCD 北大核心 2024年第6期2370-2380,共11页
针对酸性矿山废水(Acid Mine Drainage, AMD)中Cu^(2+)和Pb^(2+)含量过高,生物质炭渣吸附能力有限等问题,以工业固体废弃物生物质炭渣为原材料,采用高锰酸钾和硫酸亚铁对生物质炭渣进行磁改性,制备生物质炭渣负载MnFe_(2)O_(4)的复合磁... 针对酸性矿山废水(Acid Mine Drainage, AMD)中Cu^(2+)和Pb^(2+)含量过高,生物质炭渣吸附能力有限等问题,以工业固体废弃物生物质炭渣为原材料,采用高锰酸钾和硫酸亚铁对生物质炭渣进行磁改性,制备生物质炭渣负载MnFe_(2)O_(4)的复合磁性材料(BC-MF),并将BC-MF作为去除酸性矿山废水环境中Cu^(2+)和Pb^(2+)的吸附剂。基于单因素试验方法,探究pH值、温度、初始质量浓度、吸附时间、共存金属离子等因素对BC-MF吸附Cu^(2+)和Pb^(2+)性能的影响,并将吸附动力学、吸附热力学、吸附等温线与扫描电子显微镜(Scanning Electron Microscopy, SEM)、X射线衍射(X-ray Diffraction, XRD)、傅里叶变换红外光谱(Fourier Transform Infrared Spectroscopy, FT-IR)、磁滞回线测试(Vibrating Sample Magnetometer, VSM)、Zeta电位(Zeta potential)等表征方法结合,研究MnFe_(2)O_(4)磁改性生物质炭渣吸附Cu^(2+)、Pb^(2+)的机理。结果显示,改性后的BC-MF对Cu^(2+)和Pb^(2+)的去除率均提升20百分点以上,且吸附饱和质量比分别为18.04 mg/g和24.98 mg/g。表征结果显示:MnFe_(2)O_(4)磁性颗粒成功负载到BC-MF上,并使之具有磁性;BC-MF对Cu^(2+)和Pb^(2+)吸附过程均符合Langmuir等温吸附方程和准二级动力学模型,吸附过程是为化学吸附为主的单层均相吸附;热力学结果表明该吸附过程属于自发进行的熵增过程。 展开更多
关键词 环境工程学 磁性 生物质炭 酸性矿山废水 重金属 吸附
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黄河上游城乡居民食物代谢过程及资源环境效应研究--以兰州市为例
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作者 马维兢 李小哲 +3 位作者 寇敬雯 张楚悦 杨海江 薛冰 《生态经济》 北大核心 2024年第5期171-180,共10页
基于环境足迹理论,以兰州市为例,对比分析了1990—2020年城镇和农村居民食物代谢过程及其资源环境效应的动态演变规律及城乡差异性,并结合相关文献,提出了融合四种环境足迹(水、碳、氮、磷)的综合评价指标“生态效率”,弥补了当前食物... 基于环境足迹理论,以兰州市为例,对比分析了1990—2020年城镇和农村居民食物代谢过程及其资源环境效应的动态演变规律及城乡差异性,并结合相关文献,提出了融合四种环境足迹(水、碳、氮、磷)的综合评价指标“生态效率”,弥补了当前食物消费环境影响研究中各个足迹独立评价的不足。结果表明:(1)1990—2020年,兰州市居民食物消费结构发生了巨大改变,由“温饱型”的植物源食物消费为主逐渐转变为“小康型”动植物源食物并重模式。(2)1990—2020年,城镇居民食物消费环境足迹大体呈上涨趋势,农村居民食物消费环境足迹却在下降。(3)相较于1990年,2020年城镇地区生态效率提高了0.9倍,农村地区提高了0.5倍,这主要得益于人们消费结构的改变和兰州市农业体系的调整和农业技术的优化。在此基础上,本研究提出一系列措施来进一步提高生态效率,优化代谢进程。 展开更多
关键词 食物代谢 环境足迹 生态效率 城乡融合 兰州市
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环保型植物复合油基Ni_(0.5)Zn_(0.5)Fe_(2)O_(4)磁流体的稳定性和低温流变性
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作者 龚湫 吴张永 +2 位作者 张刚 朱启晨 蒋佳骏 《功能材料》 CAS CSCD 北大核心 2024年第5期5195-5202,共8页
植物油作为纳米磁流体基载液存在不良冷流动行为问题,聚甲基丙烯酸酯的添加有望降低植物油倾点和提高植物油基磁流体低温流动性。以聚α-烯烃(PAO-8)和玉米油作为复合基载液,以聚甲基丙烯酸酯为降凝剂,制备新型环保型磁流体,研究其沉降... 植物油作为纳米磁流体基载液存在不良冷流动行为问题,聚甲基丙烯酸酯的添加有望降低植物油倾点和提高植物油基磁流体低温流动性。以聚α-烯烃(PAO-8)和玉米油作为复合基载液,以聚甲基丙烯酸酯为降凝剂,制备新型环保型磁流体,研究其沉降稳定性。从磁场、温度、Ni_(0.5)Zn_(0.5)Fe_(2)O_(4)质量分数、PAO-8、降凝剂添加量等角度,利用旋转粘度计研究了不同温度下纳米磁流体的低温流动性能。结果表明不采用表面活性剂、100 mL玉米油和25%的PAO-8的混合物作为复合基载液、Ni_(0.5)Zn_(0.5)Fe_(2)O_(4)质量分数为0.767%,制得的纳米磁流体沉降稳定性最佳。添加0.5%聚甲基丙烯酸酯的磁流体具有更好的低温流动性能,倾点达到-36℃。无磁场条件下,当温度低于-25℃时,磁流体黏度骤增,呈指数上升趋势,磁流体低温流动性变差;磁场条件下,纳米磁流体的黏度与磁场强度呈正相关,且磁场强度大于20 mT时黏度曲线变化明显。制备的纳米磁流体具有环保、低温流动性能好的特点,可应用于低温工况,研究有助于环保型磁流体低温应用的进一步发展。 展开更多
关键词 环保型磁流体 复合基载液 降凝剂 沉降稳定性 黏度
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黄土高原靖边剖面岩石磁学性质及其古环境意义
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作者 董良 沈中山 邓成龙 《地球物理学报》 SCIE EI CAS CSCD 北大核心 2024年第8期3060-3074,共15页
中国黄土在东亚第四纪气候环境变化研究领域占有重要地位,靖边黄土剖面位于黄土高原北部边缘,对东亚季风变化敏感.本文对靖边黄土剖面进行了详细的岩石磁学和环境磁学研究.剖面沉积物中的主要磁性矿物为磁铁矿、磁赤铁矿以及赤铁矿,黄... 中国黄土在东亚第四纪气候环境变化研究领域占有重要地位,靖边黄土剖面位于黄土高原北部边缘,对东亚季风变化敏感.本文对靖边黄土剖面进行了详细的岩石磁学和环境磁学研究.剖面沉积物中的主要磁性矿物为磁铁矿、磁赤铁矿以及赤铁矿,黄土中的碎屑磁铁矿普遍经历了低温氧化作用的初始阶段,形成磁赤铁矿外壳包裹磁铁矿内核的结构,导致矫顽力大幅增加.磁化率随温度变化曲线(X-T)指示成壤作用生成的单畴颗粒的亚铁磁性矿物(磁铁矿和磁赤铁矿)的含量在L15(约1.25Ma)后整体减少,表明东亚夏季风强度发生阶段性减弱.黄土层中的磁化率与非磁滞磁化率比值(X/X_(ARM))与来自物源区粗粒磁性矿物含量相关,冬季风增强则X/X_(ARM)值越高,靖边剖面黄土层X/X_(ARM)在L14以后整体增加,L6以来逐渐增加,表明东亚冬季风发生过两次增强.矫正后磁化率与非磁滞磁化率((X-X_(0))/X_(ARM))指示了来自物源区磁性矿物含量,靖边剖面自2.6Ma以来,(X-X_(0))/X_(ARM)逐渐增加,源区的磁性矿物含量增多表明冬季风逐渐增强.非磁滞剩磁与饱和等温剩磁中值退磁场比值(MDF_(ARM)/MDF_(SIRM))与样品相关,样品磁性矿物粒度越粗,低温氧化作用越弱,矫顽力越高,MDF_(ARM)/MDF_(SIRM)越高,靖边剖面MDF_(ARM)/MDF_(SIRM)分别在L14和L6后整体升高,表明磁性矿物粒度整体变粗,代表了沙漠两次向南扩张.综上磁学参数一致表明,靖边黄土剖面有效地记录了东亚季风演化过程,对研究亚洲内陆干旱环境演变有重要意义. 展开更多
关键词 黄土高原 靖边剖面 岩石磁学 环境磁学 东亚季风 沙漠扩张
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南昌市厚田沙地末次冰期风沙沉积的磁化率特征及其环境意义
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作者 钟颖 李志文 +4 位作者 陈琼 黄小兰 胡海平 孙丽 杨妙文 《地质论评》 CAS CSCD 北大核心 2024年第4期1366-1376,共11页
鄱阳湖滨周围和赣江下游沿岸广泛分布着一系列风成砂山。为了探讨南方风沙沉积的磁化率特征及其环境意义,本研究对鄱阳湖南部之厚田剖面的古风沙沉积进行了光释光测年、磁化率、粒度和重矿物分析。结果表明:(1)沙丘砂层的磁化率整体较低... 鄱阳湖滨周围和赣江下游沿岸广泛分布着一系列风成砂山。为了探讨南方风沙沉积的磁化率特征及其环境意义,本研究对鄱阳湖南部之厚田剖面的古风沙沉积进行了光释光测年、磁化率、粒度和重矿物分析。结果表明:(1)沙丘砂层的磁化率整体较低,平均粒径(Mz)较粗,成熟度指数(ZTR)较低而风化指数(HW)较高,说明风化程度较低,形成于冬季风强盛、干燥寒冷的气候条件下;砂质古土壤层的磁化率较高,Mz较细,ZTR指数较高而HW指数较低,说明风化程度较高,形成于冬季风较弱、夏季风较强,温暖湿润的气候环境下。(2)厚田剖面第Ⅰ(77.0~57.1 ka)、Ⅲ(49.7~36.8 ka)、Ⅴ(29.7~14.9 ka)阶段依次对应深海氧同位素的MIS4、MIS3b、MIS2,指示为冷期,冬季风强盛,磁化率较低;第Ⅱ(57.1~49.7 ka)、Ⅳ(36.8~29.7 ka)阶段分别对应MIS3c和MIS3a,指示为暖期,夏季风强盛,磁化率较高。这些气候变化特征与黄土高原渭南剖面、深海氧同位素和中国亚热带洞穴石笋δ^(18)O记录具有良好的对比性。因此认为,磁化率在南方风沙沉积中可以有效揭示气候变化。 展开更多
关键词 厚田沙地 风沙沉积 磁化率 重矿物 环境变化
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基于玉米芯生物炭的磁性固相萃取-气相色谱-质谱法测定环境水中13种三嗪类除草剂的含量
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作者 田露 陈学国 +1 位作者 吴浩天 安国策 《理化检验(化学分册)》 CAS CSCD 北大核心 2024年第8期749-757,共9页
以玉米芯为母体,通过化学沉淀法制备磁性玉米芯生物炭材料,并采用扫描电子显微镜、透射电子显微镜和红外光谱仪表征。取环境水样5.0 mL,加入150 mg磁性玉米芯生物炭材料,涡旋4 min,在试管底部外壁放置磁铁,吸附磁性玉米芯生物炭材料,将... 以玉米芯为母体,通过化学沉淀法制备磁性玉米芯生物炭材料,并采用扫描电子显微镜、透射电子显微镜和红外光谱仪表征。取环境水样5.0 mL,加入150 mg磁性玉米芯生物炭材料,涡旋4 min,在试管底部外壁放置磁铁,吸附磁性玉米芯生物炭材料,将上层清液全部弃去。加入1.0 mL水,涡旋1 min,弃去溶液。加入1.0 mL乙酸乙酯(洗脱剂),涡旋4 min,收集乙酸乙酯洗脱液,按照气相色谱-质谱法测定。结果显示,合成的磁性玉米芯生物炭材料具有丰富的孔隙结构,近似球形的Fe3O4颗粒均匀分布在玉米芯生物炭的表面,对三嗪类除草剂的吸附过程符合朗缪尔等温吸附模型,其吸附机理为单层吸附,最大理论吸附容量为0.604 mg·g^(-1)。13种三嗪类除草剂的质量浓度分别在0.05~10.00 mg·L^(-1)(脱乙基莠去津、莠去通、莠去津、敌草净、嗪草酮、西草净、莠灭净、扑草净、特丁净、异丙净和氰草津)和0.02~10.00 mg·L^(-1)(特丁通和环嗪酮)内和峰面积呈线性关系,检出限(3S/N)为0.01~0.02 mg·L^(-1);按照标准加入法进行回收试验,回收率为87.1%~110%,测定值的相对标准偏差(n=6)为1.8%~5.6%(日内精密度试验结果)和2.9%~7.9%(日间精密度试验结果)。方法用于疑似投毒环境水样的分析,检出了扑草净,检出量为5.3 g·L^(-1)。 展开更多
关键词 磁性固相萃取 玉米芯生物炭 气相色谱-质谱法 三嗪类除草剂 环境水
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中中新世气候适宜期全球变暖背景下亚洲内陆干旱区古气候演化特征及驱动机制
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作者 吕壮壮 乔庆庆 +1 位作者 董孙艺 汪冬 《干旱区研究》 CSCD 北大核心 2024年第8期1309-1322,共14页
中中新世气候适宜期是新生代全球降温趋势下一次强烈的全球升温事件,其气候状态被认为是未来全球变暖最可能达到的状态。亚洲内陆干旱区是全球典型的中纬度干旱区,其干旱化过程对人类生存环境影响最为深刻、最为直接。在全球变暖背景下... 中中新世气候适宜期是新生代全球降温趋势下一次强烈的全球升温事件,其气候状态被认为是未来全球变暖最可能达到的状态。亚洲内陆干旱区是全球典型的中纬度干旱区,其干旱化过程对人类生存环境影响最为深刻、最为直接。在全球变暖背景下,叠加人类活动的影响,干旱区变得更加脆弱,其扩张或变迁都会直接影响人类的生存和可持续发展。探讨亚洲内陆干旱区在中中新世全球气候变暖背景下的气候演化历史,对未来气候变暖模式下干旱区的气候变化预估提供重要参考。本文梳理了亚洲内陆干旱区典型盆地现有中中新世期间古气候演化研究结果,通过环境磁学参数、孢粉、同位素等多种气候代用指标的综合分析,发现在中中新世期间,多数地区呈现湿润化,但开始的时间有所差异,同时,少量地区呈现持续干旱化的现象。另一方面,对中中新世适宜期形成的主控因素依然存在较大争议,有的学者认为哥伦比亚玄武岩喷发是主要因素,有的学者认为构造活动是主要因素。要解决上述争议,需要获取更多具有精确年代控制的高分辨率记录,以确定中中新世升温事件的起始响应时间。通过正确解译气候代用指标,特别是对古气候变化响应最为直接和敏感的孢粉,以及环境磁学参数和地球化学比值等蕴含的古环境信息,厘清各种因素对气候变化造成的影响,揭示亚洲内陆干旱区中中新世气候适宜期气候演化的驱动机制。 展开更多
关键词 中中新世气候适宜期 全球气候变化 气候代用指标 驱动机制 环境磁学 亚洲内陆干旱区
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基于共价有机骨架材料的磁固相萃取-气相色谱-负化学电离源质谱法测定环境水体中3种得克隆类物质
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作者 李原琨 黄超囡 +2 位作者 周乾 程嘉雯 马继平 《色谱》 CAS CSCD 北大核心 2024年第10期979-989,共11页
得克隆类物质是一类添加型阻燃剂,具有持久性、毒性和生物蓄积性,可在环境介质中长期存在,并通过多种途径进入人体,对人类健康造成危害。本研究将Fe_(3)O_(4)磁性纳米粒子与三醛基间苯三酚-联苯胺复合材料(TpBD)相结合,制备了磁性共价... 得克隆类物质是一类添加型阻燃剂,具有持久性、毒性和生物蓄积性,可在环境介质中长期存在,并通过多种途径进入人体,对人类健康造成危害。本研究将Fe_(3)O_(4)磁性纳米粒子与三醛基间苯三酚-联苯胺复合材料(TpBD)相结合,制备了磁性共价有机骨架材料(Fe_(3)O_(4)@TpBD),并将其作为磁固相萃取吸附剂,建立了环境水体中3种得克隆类物质的气相色谱-负化学电离源质谱分析方法。利用透射电子显微镜、扫描电子显微镜、傅里叶变换红外光谱、X射线衍射等手段对Fe_(3)O_(4)@TpBD的形貌、粒径、表面基团和结构等进行表征,并考察了Fe_(3)O_(4)@TpBD用量、水样pH、萃取时间、洗脱剂种类及体积、洗脱时间和离子强度等对目标分析物萃取效率的影响。结果表明,3种目标分析物在2~1000 ng/L范围内线性关系良好,方法的检出限为0.18~0.27 ng/L,定量限为0.60~0.92 ng/L,日内和日间精密度分别为4.2%~16.2%(n=6)和6.9%~15.7%(n=6)。将该方法应用于4种实际水样中得克隆类物质的分析检测,在低、中、高3个加标水平下,3种得克隆类物质的回收率为77.8%~113.4%,相对标准偏差为2.5%~16.3%。该方法的样品前处理过程简便,灵敏度高,重复性好,适用于环境水体中得克隆类物质的分析检测。 展开更多
关键词 共价有机骨架 磁固相萃取 气相色谱-负化学电离源质谱 得克隆类物质 环境水体
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