Recent advances in core-shell organic framework-based photocatalysts for energy conversion and environmental remediation

Direct conversion of solar energy into chemical energy in an environmentally friendly manner is one of the most promising strategies to deal with the environmental pollution and energy crisis.Among a variety of materials developed as photocatalysts,the core-shell metal/covalent-organic framework(MOF or COF)photocatalysts have garnered significant attention due to their highly porous structure and the adjustability in both structure and functionality.The existing reviews on core-shell organic framework photocatalytic materials have mainly focused on core-shell MOF materials.However,there is still a lack of indepth reviews specifically addressing the photocatalytic performance of core-shell COFs and MOFs@COFs.Simultaneously,there is an urgent need for a comprehensive review encompassing these three types of core-shell structures.Based on this,this review aims to provide a comprehensive understanding and useful guidelines for the exploration of suitable core-shell organic framework photocatalysts towards appropriate photocatalytic energy conversion and environmental governance.Firstly,the classification,synthesis,formation mechanisms,and reasonable regulation of core-shell organic framework were summarized.Then,the photocatalytic applications of these three kinds of core-shell structures in different areas,such as H_(2)evolution,CO_(2)reduction,and pollutants degradation are emphasized.Finally,the main challenges and development prospects of core-shell organic framework photocatalysts were introduced.This review aims to provide insights into the development of a novel generation of efficient and stable core-shell organic framework materials for energy conversion and environmental remediation.

Environmental dynamics of nitrogen and phosphorus release from river sediments of arid areas

Human activities lead to the accumulation of a large amount of nitrogen and phosphorus in sediments in rivers.Simultaneously,nitrogen and phosphorus can be affected by environment and re-enter the upper water body,causing secondary pollution of the river water.In this study,laboratory simulation experiments were conducted initially to investigate the release of nitrogen and phosphorus from river sediments in Urumqi City and the surrounding areas in Xinjiang Uygur Autonomous Region of China and determine the factors that influence their release.The results of this study showed significant short-term differences in nitrogen and phosphorus release characteristics from sediments at different sampling points.The proposed secondary kinetics model(i.e.,pseudo-second-order kinetics model)better fitted the release process of sediment nitrogen and phosphorus.The release of nitrogen and phosphorus from sediments is a complex process driven by multiple factors,therefore,we tested the influence of three factors(pH,temperature,and disturbance intensity)on the release of nitrogen and phosphorus from sediments in this study.The most amount of nitrate nitrogen(NO_(3)^(–)-N)was released under neutral conditions,while the most significant release of ammonia nitrogen(NH_(4)^(+)-N)occurred under acidic and alkaline conditions.The release of nitrite nitrogen(NO_(2)^(-)-N)was less affected by pH.The dissolved total phosphorus(DTP)released significantly in the alkaline water environment,while the release of dissolved organic phosphorus(DOP)was more significant in acidic water.The release amount of soluble reactive phosphorus(SRP)increased with an increase in pH.The sediments released nitrogen and phosphorus at higher temperatures,particularly NH_(4)^(+)-N,NO_(3)^(–)-N,and SRP.The highest amount of DOP was released at 15.0℃.An increase in disturbance intensity exacerbated the release of nitrogen and phosphorus from sediments.NH_(4)^(+)-N,DTP,and SRP levels increased linearly with the intensity of disturbance,while NO_(3)^(–)-N and NO_(2)^(–)-N were more stable.This study provides valuable information for protecting and restoring the water environment in arid areas and has significant practical reference value.

Environmental Effects on Differential Organic Matter Enrichment of the Lower Cambrian Shale,Tarim Basin,NW China

Early Cambrian shale is an important petroleum source rock around the world.Because of little drilling data and poor seismic data,until recently,organic matter enrichment of the Lower Cambrian Yuertusi and Xishanbulake formations shale is still an enigma in the Tarim Basin,northwestern China.Total organic carbon(TOC),major and trace element data of Cambrian shale samples from five boreholes have been analyzed to decipher the mechanism of the organic matter enrichment.The results show that the shales deposited in the western restricted intraplatform have much higher TOC contents(3.2%-19.8%,on average 11.0%)than those from the eastern basin(2.2%-10.2%,on average 4.5%).The paleoproductivity proxies(Ba,Ba/Al,P/Al)in the western restricted platform are much higher than those in the eastern basin.The trace element indicators such as V/Cr,Ni/Co,Mo-TOC and Mo_(EF)-U_(EF)suggest an anoxic environment across the basin,but a more restricted environment in the western intraplatform.The paleoproductivity rather than anoxic condition and hydrothermal activity are concluded to have resulted in the differentiation of the organic matter enrichment from the western intraplatform to eastern basin in the early Cambrian shales;the restricted environment was favorable for paleoproductivity and preservation of organic matter.

A Review of Metal–Organic Framework-Based Compounds for Environmental Applications

Metal–organic framework-based compounds have recently gained great attention because of their unique porous structure,ordered porosity,and high specific surface area.Benefiting from these superior properties,metal–organic framework-based compounds have been proven to be one of the most potential candidates for environmental governance and remediation.In this review,the different types of metal–organic framework-based compounds are first summarized.Further,the various environmental applications of metal–organic framework-based compounds including organic pollutant removal,toxic and hazardous gas capture,heavy metal ion detection,gas separation,water harvesting,air purification,and carbon dioxide reduction reactions are discussed in detail.In the end,the opportunities and challenges for the future development of metal–organic framework-based compounds for environmental applications are highlighted.

Chinese Anti-Cancer Association as a non-governmental organization undertakes systematic cancer prevention work in China

Cancer has become the first leading cause of death in the world, particularly in low- and middle-income countries. Facing the increasing trend of cancer incidence and mortality, China issued and implemented ＂three-early（early prevention, early diagnosis and early treatment）＂ national cancer prevention plan. As the main body and dependence of social governance, non-governmental organizations（NGOs） take over the role of government in the field of cancer prevention and treatment. American Cancer Society（ACS） made a research on cancer NGOs and civil society in cancer control and found that cancer NGOs in developing countries mobilize civil society to work together and advocate governments in their countries to develop policies to address the growing cancer burden. Union for International Cancer Control（UICC）, Cancer Council Australia（CCA）, and Malaysian cancer NGOs are the representatives of cancer NGOs in promoting cancer control. Selecting Chinese Anti-Cancer Association（CACA） as an example in China, this article is to investigate how NGOs undertake systematic cancer prevention work in China. By conducting real case study, we found that, as a NGO, CACA plays a significant role in intensifying the leading role of government in cancer control, optimizing cancer outcomes, decreasing cancer incidence and mortality rates and improving public health.

Non-governmental organizations'influence on tackling black carbon in the shipping industry

This paper reviews the achievements of some typical non-governmental organizations （NGOs） in reducing black carbon emissions from shipping which enjoy the consultative status offered by the International Maritime Organization. It discusses the roles of the specific NGOs in dealing with black carbon in the Arctic region from the perspective of global governance to gain insights to guide our involvements in the Arctic affairs and shipping in the region by taking the advantages of NGOs＇ influence on the proceedings of international negotiations, our national policy development, the improvement of industrial practices and public perceptions.

Exchanges between CAFIU and Non-Governmental Organizations in Europe

It has always been one of its major tasks for CAFIU to conduct non-governmental exchanges and contacts with European countries since CAFIU was founded more than thirty years ago.As in recent years,the China-Europe comprehensive strategic partnership has continuously deepened with exchanges and cooperation in various areas further

Geochemical Characteristics of the Upper Permian Longtan Formation from Northeastern Sichuan Basin:Implications for the Depositional Environment and Organic Matter Enrichment

A set of organic-rich shales of the upper Permian Longtan Formation,which is widely developed in the northeastern part of the Sichuan Basin,is a key formation for the next step of exploration and development.At present,most studies on this set of formations have focused on the reservoir characteristics and reservoir formation mechanism of the shales,and basic studies on the palaeoenvironment and organic matter(OM)enrichment mechanism have not been fully carried out.In this paper,we recovered the sedimentary palaeoenvironment by mineralogical,elemental geochemical and organic geochemical analyses,and explored the enrichment mechanism of OM under the constraints of palaeoenvironmental evolution.The shales can be divided into two stages of sedimentary evolution:compared with the shales of the Lower Longtan Formation,the shales of the Upper Longtan Formation are relatively rich in quartz,poor in clay and carbonate minerals,and the OM type changes from typeⅢto typeⅡ_(2).The depositional environment has undergone a change from sea level rise,from warm and wet climate to dry and cold climate,and from oxygen-poor condition restricted to open reduction environment;the land source input has decreased,the siliceous mineral content has increased,the biological productivity has improved,and the deposition rate has changed from high to low.A depositional model was established for the shales of the Longtan Formation,reflecting the differential reservoir formation pattern of organic matter.For the Lower Longtan Formation shales,the most important factors controlling OM content are terrestrial source input and deposition rate,followed by paleoclimate and paleooxygen conditions.For the Upper Longtan Formation shales,the most important controlling factor is paleo-productivity,followed by sedimentation rate.The depositional model constructed for the Upper and Lower Longtan Formation shales can reproduce the enrichment of organic matter and provide a basis for later exploration and development.

Metal–Organic Framework-Based Sensors for Environmental Contaminant Sensing

Increasing demand for timely and accurate environmental pollution monitoring and control requires new sensing techniques with outstanding performance, i.e.,high sensitivity, high selectivity, and reliability. Metal–organic frameworks(MOFs), also known as porous coordination polymers, are a fascinating class of highly ordered crystalline coordination polymers formed by the coordination of metal ions/clusters and organic bridging linkers/ligands. Owing to their unique structures and properties,i.e., high surface area, tailorable pore size, high density of active sites, and high catalytic activity, various MOF-based sensing platforms have been reported for environmental contaminant detection including anions, heavy metal ions,organic compounds, and gases. In this review, recent progress in MOF-based environmental sensors is introduced with a focus on optical, electrochemical, and field-effect transistor sensors. The sensors have shown unique and promising performance in water and gas contaminant sensing. Moreover, by incorporation with other functional materials, MOF-based composites can greatly improve the sensor performance. The current limitations and future directions of MOF-based sensors are also discussed.

The sources and composition of organic matter in sediments of the Jiaozhou Bay：implications for environmental changes on a centennial time scale

The Jiaozhou Bay is characterized by heavy eutrophication that is associated with intensive anthropogenic activities. Four core sediments from the Jiaozhou Bay are analyzed using bulk technologies, including sedimentary total organic carbon（TOC）, total nitrogen（TN）, the stable carbon（δ13C） and nitrogen（δ15 N） isotopic composition to obtain the comprehensive understanding of the source and composition of sedimentary organic matter and further shed light on the environmental changes of the Jiaozhou Bay on a centennial time scale.Results suggest that the TOC and TN concentrations increase in the upper core, having indicated a probable eutrophication process since the 1920 s in the inner bay and the 2000 s in the bay mouth. The TOC and TN concentrations outside the bay have also changed since 1916 owing to the variation of terrigenous input.Considering TOC/TN ratio, δ13 C and δ15 N, it can be concluded there is a mixture of terrigenous and marine organic matter sources in the study area. A simple two end-member（terrigenous and marine） mixing model usingδ13 C indicats that 45%–79% of TOC in the Jiaozhou Bay is from the marine source. The environmental changes of the Jiaozhou Bay are recorded by geochemical proxies, which are influenced by the intensive anthropogenic activities（e.g., extensive use of fertilizers, and discharge of sewage） and climate changes（e.g., rainfall）.

Changes in Organic Carbon and Nutrient Contents of Highly Productive Paddy Soils in Yujiang County of Jiangxi Province,China and Their Environmental Application

Paddy field is an important land use in subtropical China. Development of high soil fertility and productivity is the management goal of paddy field, Fertilization and management practices have not only influenced the status of organic matter and nutrients in the soil but also affected the environmental quality. This article investigates the contents of organic carbon and the nutrients, and the change over the last 20 years in highly productive paddy soils and their environmental application. Field soils were sampled and the analytical results were compared with the corresponding values in the Second Soil Survey in Yujiang County of Jiangxi Province, China. The results showed that surface soils at a depth of 0-10 cm in highly productive paddy fields in Yujiang County of Jiangxi Province had contents of organic carbon （20.2 ±3.88） g kg^-1, total nitrogen （2.09±0.55） g kg^-1, and available phosphorus （42.7 ±32.7） mg kg^-1, respectively, which were all at very rich levels. Over the last 20 years, the organic carbon pool of the highly productive paddy soils reached a steady state. Total N and available P significantly increased, whereas available K changed a little. The amount and percentage of P immobilization in the surface soil （0-10 cm） of highly productive paddy fields were （142.7 ~ 41.1） mg kg-~ and （36.2~ 10.4）% of added P, and CEC （7.93 ~ 1.32） cmol kg-~. These two parameters were not higher than the mean values of paddy soils and upland red soils in the areas. Results also showed that fertilizer P in highly productive paddy soils had a high mobility and was prone to move toward a water body, which is the main source of nutrients causing eutrophication. Because of a weak K-fixing capacity, the available K content was not high in highly productive paddy soils. This suggests that attention should be paid to the K balance and the increase of soil K pool.

Soil Organic Carbon and Labile Carbon Along a Precipitation Gradient and Their Responses to Some Environmental Changes

Based on data from a field survey in 2001 along the Northeast China transect (NECT), a precipitation gradient,and a short-term simulation experiment under ambient CO2 of 350 μmol mol-1 and doubled CO2 of 700 μmol mol-1with different soil moisture contents of 30%-45%, 45%-60%, and 60%-80% soil water holding capacity, the distributionof soil organic carbon and labile carbon along the NECT, their relationships with precipitation and their responses toCO2 enrichment and soil moisture changes were analyzed. The results indicated that the soil labile carbon along thegradient was significantly related to soil organic carbon (r = 0.993, P < 0.001). The soil labile carbon decreased morerapidly with depth than organic carbon. The soil organic and labile carbon along the gradient decreased with decrease inlongitude in both the topsoils and subsoils, and the coefficient of variation for the labile carbon was greater than that forthe organic carbon. Both the soil organic carbon and labile carbon had significant linear relationships with precipitation,with the correlation coefficient of soil organic carbon being lower (0.677 at P < 0.001) than that of soil labile carbon(0.712 at P < 0.001). In the simulation experiment with doubled and ambient CO2 and different moisture contents, thecoefficient of variation for soil organic carbon was only 1.3%, while for soil labile carbon it was 29.7%. With doubled CO2concentration (700 μmol mol-1), soil labile carbon decreased significantly at 45% to 60% of soil moisture content. Theseindicated that soil labile carbon was relatively more sensitive to environmental changes than soil organic carbon.