Urban areas face significant challenges in maintaining water quality amidst increasing urbanization and changing climatic patterns. This study investigates the complex interplay between meteorological variables and wa...Urban areas face significant challenges in maintaining water quality amidst increasing urbanization and changing climatic patterns. This study investigates the complex interplay between meteorological variables and water quality parameters in Nairobi City, focusing on the impacts of rainfall and temperature on surface water quality. Data from multiple sources, including the Water Resources Authority, Nairobi Water and Sewerage Company, and the World Bank’s Climate Change Knowledge Portal, were analyzed to assess the relationships between meteorological variables (rainfall and temperature) and water quality parameters (such as electroconductivity, biochemical oxygen demand, chloride, and pH). The analysis reveals varying impacts of rainfall and temperature on different water quality parameters. While parameters like iron and pH show strong relationships with both rainfall and temperature, others such as ammonia and nitrate exhibit moderate relationships. Additionally, the study highlights the influence of runoff, urbanization, and industrial activities on water quality, emphasizing the need for holistic management approaches. Recommendations encompass the establishment of annual publications on Nairobi River water quality, online accessibility of water quality data, development of hydrological models, spatial analysis, and fostering cross-disciplinary research collaborations. Implementing these recommendations can enhance water quality management practices, mitigate risks, and safeguard environmental integrity in Nairobi City.展开更多
The primary objective of this study was to design and size a sustainable sanitation solution for the Ndiebene Gandiol 1 school located in the eponymous commune in northern Senegal. Field investigations led to the coll...The primary objective of this study was to design and size a sustainable sanitation solution for the Ndiebene Gandiol 1 school located in the eponymous commune in northern Senegal. Field investigations led to the collection of wastewater samples. Their analysis revealed specific pollutant loads, including loads of BOD5 3.6966 kgO<sub>2</sub>/day and COD of 12.8775 kgO<sub>2</sub>/day, which were central to the design phase. Following a rigorous assessment of the existing sanitation infrastructure, constructed wetland (CWs) emerged as the most appropriate ecological solution. This system, valued for its ability to effectively remove contaminants, was tailored to the specific needs of the site. Consequently, the final design of the filter extends over 217.16 m<sup>2</sup>, divided into two cells of 108.58 m<sup>2</sup> each, with dimensions of 12.77 m in length and 8.5 m in width. The depth of the filtering medium is approximately 0.60 m, meeting the standards while ensuring maximized purification. Typha, an indigenous and prolific plant known for its purification abilities, was selected as the filtering agent. Concurrently, non-crushed gravel was chosen for its proven filtration capacity. This study is the result of a combination of scientific rigor and design expertise. It provides a holistic view of sanitation for Ndiebene Gandiol. The technical specifications and dimensions of the constructed wetland filter embody an approach that marries indepth analysis and practical application, all aimed at delivering an effective and long-lasting solution to the local sanitation challenges. By integrating precise scientific data with sanitation design expertise, this study delivers a holistic solution for Ndiebene Gandiol. The detailed dimensions and specifications of the constructed wetland filter reflect a methodology that combines meticulous analysis with practical adaptation, aiming to provide an effective and sustainable response to the challenges of rural and school sanitation in the northern region of Senegal.展开更多
The small and scattered enterprise pattern in the county economy has formed numerous sporadic pollution sources, hindering the centralized treatment of the water environment, increasing the cost and difficulty of trea...The small and scattered enterprise pattern in the county economy has formed numerous sporadic pollution sources, hindering the centralized treatment of the water environment, increasing the cost and difficulty of treatment. How enterprises can make reasonable decisions on their water environment behavior based on the external environment and their own factors is of great significance for scientifically and effectively designing water environment regulation mechanisms. Based on optimal control theory, this study investigates the design of contractual mechanisms for water environmental regulation for small and medium-sized enterprises. The enterprise is regarded as an independent economic entity that can adopt optimal control strategies to maximize its own interests. Based on the participation of multiple subjects including the government, enterprises, and the public, an optimal control strategy model for enterprises under contractual water environmental regulation is constructed using optimal control theory, and a method for calculating the amount of unit pollutant penalties is derived. The water pollutant treatment cost data of a paper company is selected to conduct empirical numerical analysis on the model. The results show that the increase in the probability of government regulation and public participation, as well as the decrease in local government protection for enterprises, can achieve the same regulatory effect while reducing the number of administrative penalties per unit. Finally, the implementation process of contractual water environmental regulation for small and medium-sized enterprises is designed.展开更多
At present,the major problems facing the water resource environment worldwide include water pollution,water resource shortage,and water ecosystem degradation.The discharge of industrial wastewater,agricultural non-poi...At present,the major problems facing the water resource environment worldwide include water pollution,water resource shortage,and water ecosystem degradation.The discharge of industrial wastewater,agricultural non-point source pollution,and the discharge of urban sewage lead to a serious decline in water quality,which directly affects the safety of human drinking water and the living environment of aquatic organisms.Additionally,the unbalanced distribution and excessive exploitation of water resources lead to the problem of water shortage in many areas,which then leads to social and economic contradictions and ecological crises.In terms of ecosystems,the phenomena of water ecological degradation and reduction of biodiversity are increasingly obvious,and the carrying capacity of aquatic ecosystems are gradually declining.This paper aims to analyze the natural,social,and economic factors affecting the water resource environment,and propose effective strategies to protect the water ecology.To provide a theoretical basis and practical guidance for the sustainable utilization of water resources and the long-term development of the water ecosystem.展开更多
Interbasin water-transfer schemes provide an engineering solution for reconciling the conflict between water demand and availability.In the context of climate change,which brings great uncertainties to water resource ...Interbasin water-transfer schemes provide an engineering solution for reconciling the conflict between water demand and availability.In the context of climate change,which brings great uncertainties to water resource distribution,interbasin water transfer plays an increasingly important role in the global water–food–energy nexus.However,the transfer of water resources simultaneously changes the hydrological regime and the characteristics of local water bodies,affecting biotic communities accordingly.Compared with high economic and technical inputs water-transfer projects require,the environmental and ecological implications of water-transfer schemes have been inadequately addressed.This work selects the largest water-transfer project in China,the South-to-North Water Diversion(SNWD)Project,to critically review its eco-environmental impacts on donor and recipient basins,as well as on regions along the diversion route.The two operated routes of the SNWD Project represent two typical water diversion approaches:The Middle Route uses an excavated canal,while the East Route connects existent river channels.An overview of the eco-environmental implications of these two routes is valuable for the design and optimization of future water-transfer megaprojects.展开更多
For a long time,China's regional water resource imbalance has restricted the development of coal chemical industry,and it is imperative to achieve zero liquid discharge(ZLD).Therefore,the game relationship between...For a long time,China's regional water resource imbalance has restricted the development of coal chemical industry,and it is imperative to achieve zero liquid discharge(ZLD).Therefore,the game relationship between technical indicators,costs and emissions in ZLD process of fixed-bed coal gasification wastewater treatment process should be explored in detail.According to the accurate model,the simulation for ZLD of fixed-bed coal gasification wastewater treatment process is established,and this process is assessed from the perspective of thermodynamics,economy,and environment.The total energy consumption of ZLD process before optimization is 4.032×10^(8)W.The results of exergy analysis show exergy destruction of ZLD process is 94.55%.For economic and environmental results,the total annual cost is 1.892×10^(7)USD·a^(-1)and the total environmental impact is 4.782×10^(-8).The total energy consumption of the optimal six-step ZLD process based on multi-objective optimization is 4.028×10^(8)W.The CO_(2)content in the treated wastewater is 0.1%.This study will have an important role in promoting the establishment of the ZLD process for coal chemistry industry.展开更多
Water risk early warning systems based on the water environmental carrying capacity(WECC)are powerful and effective tools to guarantee the sustainability of rivers.Existing work on the early warning of WECC has mainly...Water risk early warning systems based on the water environmental carrying capacity(WECC)are powerful and effective tools to guarantee the sustainability of rivers.Existing work on the early warning of WECC has mainly concerned the comprehensive evaluation of the status quo and lacked a quantitative prejudgement and warning of future overload.In addition,existing quantitative methods for short-term early warning have rarely focused on the integrated change trends of the early warning indicators.Given the periodicity of the socioeconomic system,however,the water environmental system also follows a trend of cyclical fluctuations.Thus,it is meaningful to monitor and use this periodicity for the early warning of the WECC.In this study,we first adopted and improved the prosperity index method to develop an integrated water risk early warning framework.We also constructed a forecast model to qualitatively and quantitatively prejudge and warn about the development trends of the water environmental system.We selected the North Canal Basin(an essential connection among the Beijing-Tianjin-Hebei region)in China as a case study and predicted the WECC in 25 water environmental management units of the basin in 2018–2023.We found that the analysis of the prosperity index was helpful in predicting the WECC,to some extent.The result demonstrated that the early warning system provided reliable prediction(root mean square error of 0.0651 and mean absolute error of 0.1418),and the calculation results of the comprehensive early warning index(CEWI)conformed to the actual situation and related research in the river basin.From 2008 to 2023,the WECC of most water environmental management units in the basin had improved but with some spatial differences:the CEWI was generally poor in areas with many human disturbances,while it was relatively good in the upstream regions with higher forest and grass covers as well as in the downstream areas with larger water volume.Finally,through a sensitivity analysis of the indicators,we proposed specific management measures for the sustainability of the water environmental system in the North Canal Basin.Overall,the integrated water risk early warning framework could provide an appropriate method for the water environmental administration department to predict the WECC of the basin in the future.This framework could also assist in implementing corresponding management measures in advance,especially for the performance evaluation and the arrangement of key short-term tasks in the River Chief System in China.展开更多
In recent years, the beer industry is a biological food industry that consumes a lot of water, and it has developed rapidly in China. The sewage discharged from the mass production of beer poses a huge threat to the e...In recent years, the beer industry is a biological food industry that consumes a lot of water, and it has developed rapidly in China. The sewage discharged from the mass production of beer poses a huge threat to the environment. In order to evaluate and better solve the possible environmental impacts of beer treatment engineering projects, a brewery project in Foshan City is taken as an example to investigate the water pollution generation links of the engineering process including surface water and groundwater. According to the relevant technical methods and standards, water pollution factors are screened, and concentration and discharge are monitored. Through comprehensive analysis, predictive evaluation is obtained. It is confirmed that the project meets the requirements of national laws and regulations and environmental protection standards.展开更多
Environmental endocrine disrupting chemicals (EDCs), commonly found in the environment, come from industry and agriculture, including pesticides, fungicides, insecticides, herbicides, and other chemicals. Nowadays, ...Environmental endocrine disrupting chemicals (EDCs), commonly found in the environment, come from industry and agriculture, including pesticides, fungicides, insecticides, herbicides, and other chemicals. Nowadays, more and more EDCs were released into the environment. EDCs go into water body via atmosphere sedi-mentation, surface runoff, soil eluviation, etc., so water body becomes the main place for existing. In order to attract scientific and public attention worldwide and to prevent EDCs pol ution, in this study we reviewed the classification of EDCs and their concentrations in natural water bodies, drinking water sources and water plants, and the reproductive toxicity of EDCs to fish were reviewed. EDCs could disturb the endocrine system and make reproductive organs and reproduction abnor-mal, resulting in fertility descending, reproduction function damage, community quan-tity decrease and even species extinction. In addition, EDCs could disrupt the homeostasis maintained by hormones, which would result in defects of neural de-velopment and abnormalities of the endocrine and reproductive systems. The exact molecular mechanisms have not been completely reported, but researches have suggested that multiple mechanisms were involved in the action of EDCs. Although there have been researches on the biohazard of EDCs, there stil exist problems of weakness in fundamental researches, difficulties in recognizing and identifying EDCs and high cost, which restraint the knowledge on them.展开更多
[Objective] The aim was to evaluate heavy metal environmental quality of irrigation water in vegetable farmlands of Shandong Province. [Method] Heavy metal contents including Hg,Cd,As,Cr (+6),Pb,Cu and Zn in irrigatio...[Objective] The aim was to evaluate heavy metal environmental quality of irrigation water in vegetable farmlands of Shandong Province. [Method] Heavy metal contents including Hg,Cd,As,Cr (+6),Pb,Cu and Zn in irrigation water of main vegetable farmlands of Shandong Province were investigated by randomly sampling,and the environmental quality conditions of these heavy metals were evaluated by methods of single quality index and complex quality index. [Result] The results showed that the average contents of heavy metals in irrigation water of Shouguang,Laiyang,Jinxiang and Zhangqiu were all far lower than the limit values prescribed by 'Farmland Environmental Quality Evaluation Standards for Edible Agricultural Products' (HJ332-2006),and no heavy metal was found beyond the limit value in every sample. The single quality indices of the 7 elements in the studied 4 places were all lower than 0.5. The comprehensive quality index of the seven elements was 0.317 8 in Shouguang,0.320 4 in Laiyang,0.232 6 in Jinxiang,and 0.260 7 in Zhangqiu. The environmental quality of irrigation water in the studied four places were all set at the first class. [Conclusion] The environmental quality of irrigation water in the 4 places belonged to clean level and were fit for the plantation of no pollution vegetables.展开更多
Analysis of environmental significance and hydrochemical characteristics of river water in mountainous regions is vital for ensuring water security.In this study,we collected a total of 164 water samples in the wester...Analysis of environmental significance and hydrochemical characteristics of river water in mountainous regions is vital for ensuring water security.In this study,we collected a total of 164 water samples in the western region of the Altay Mountains,China,in 2021.We used principal component analysis and enrichment factor analysis to examine the chemical properties and spatiotemporal variations of major ions(including F-,Cl-,NO_(3)-,SO_(4)^(2-),Li+,Na+,NH4+,K+,Mg^(2+),and Ca^(2+))present in river water,as well as to identify the factors influencing these variations.Additionally,we assessed the suitability of river water for drinking and irrigation purposes based on the total dissolved solids,soluble sodium percentage,sodium adsorption ratio,and total hardness.Results revealed that river water had an alkaline aquatic environment with a mean pH value of 8.00.The mean ion concentration was ranked as follows:Ca^(2+)>SO_(4)^(2-)>Na+>NO_(3)->Mg^(2+)>K+>Cl->F->NH_(4)+>Li+.Ca^(2+),SO_(4)^(2-),Na+,and NO_(3)-occupied 83%of the total ion concentration.In addition,compared with other seasons,the spatial variation of the ion concentration in spring was obvious.An analysis of the sources of major ions revealed that these ions originated mainly from carbonate dissolution and silicate weathering.The recharge impact of precipitation and snowmelt merely influenced the concentration of Cl-,NO_(3)-,SO_(4)^(2-),Ca^(2+),and Na+.Overall,river water was in pristine condition in terms of quality and was suitable for both irrigation and drinking.This study provides a scientific basis for sustainable management of water quality in rivers of the Altay Mountains.展开更多
The chemical and isotopic characteristics of the water and suspended particulate materials(SPM) in the Yangtze River were investigated on the samples collected from 25 hydrological monitoring stations in the mainste...The chemical and isotopic characteristics of the water and suspended particulate materials(SPM) in the Yangtze River were investigated on the samples collected from 25 hydrological monitoring stations in the mainsteam and 13 hydrological monitoring stations in the major tributaries during 2003 to 2007. The water samples show a large variation in both δD( 30‰ to 112‰) and δ18O( 3.8‰ to 15.4‰) values. Both δD and δ18O values show a decrease from the river head to the Jinsha Jiang section and then increase downstream to the river mouth. It is found that the oxygen and hydrogen isotopic compositions of the Yangtze water are controlled by meteoric precipitation, evaporation, ice(and snow) melting and dam building. The Yangtze SPM concentrations show a large variation and are well corresponded to the spatial and temporal changes of flow speed, runoff and SPM supply, which are affected by the slope of the river bed, local precipitation rate, weathering intensity, erosion condition and anthropogenic activity. The Yangtze SPM consists of clay minerals, clastic silicate and carbonate minerals, heavy minerals, iron hydroxide and organic compounds. From the upper to lower reaches, the clay and clastic silicate components in SPM increase gradually, but the carbonate components decrease gradually, which may reflect changes of climate and weathering intensity in the drainage area. Compared to those of the upper crust rocks, the Yangtze SPM has lower contents of SiO2, CaO, K2 O and Na2 O and higher contents of TFe2 O3 and trace metals of Co, Ni, Cu, Zn, Pb and Cd. The ΣREE in the Yangtze SPM is also slightly higher than that of the upper crust. From the upper to lower reaches, the CaO and MgO contents in SPM decrease gradually, but the SiO2 content increases gradually, corresponding to the increase of clay minerals and decrease of the carbonates. The δ30SiSPM values( 1.1‰ to 0.3‰) of the Yangtze SPM are similar to those of the average shale, but lower than those of the granite rocks( 0.3‰ to 0.3‰), reflecting the effect of silicon isotope fractionation in silicate weathering process. The δ30SiSPM values of the Yangtze SPM show a decreasing trend from the upper to the middle and lower reaches, responding to the variation of the clay content. The major anions of the river water are HCO 3, SO 4 2, Cl, NO 3, SiO 4 4 and F and the major cations include Ca2+, Na+, Mg2+, K+ and Sr2+. The good correlation between HCO3-content and the content of Ca2+may suggest that carbonate dissolution is the dominate contributor to the total dissolved solid(TDS) of the Yangtze River. Very good correlations are also found among contents of Cl, SO4 2, Na+, Mg2+, K+and Sr2+, indicating the important contribution of evaporite dissolution to the TDS of the Yangtze River. High TDS contents are generally found in the head water, reflecting a strong effect of evaporation in the Qinghai-Tibet Plateau. A small increase of the TDS is generally observed in the river mouth, indicating the influence of tidal intrusion. The F and NO3 contents show a clear increase trend from the upstream to downstream, reflecting the contribution of pesticides and fertilizers in the Chuan Jiang section and the middle and lower reaches. The DSi shows a decrease trend from the upstream to downstream, reflecting the effect of rice and grass growth along the Chuan Jiang section and the middle and lower reaches. The dissolved Cu, Zn and Cd in the Yangtze water are all higher than those in world large rivers, reflecting the effect of intensive mining activity along the Yangtze drainage area. The Yangtze water generally shows similar REE distribution pattern to the global shale. The δ30SiDiss values of the dissolved silicon vary from 0.5‰ to 3.7‰, which is the highest among those of the rivers studied. The δ30SiDiss values of the water in the Yangtze mainsteam show an increase trend from the upper stream to downstream. Its DSi and δ30SiDiss are influenced by multiple processes, such as weathering process, phytolith growth in plants, evaporation, phytolith dissolution, growth of fresh water diatom, adsorption and desorption of aqueous monosilicic acid on iron oxide, precipitation of silcretes and formation of clays coatings in aquifers, and human activity. The δ34SSO4 values of the Yangtze water range from 1.7‰ to 9.0‰. The SO4 in the Yangtze water are mainly from the SO4 in meteoric water, the dissolved sulfate from evaporite, and oxidation of sulfide in rocks, coal and ore deposits. The sulfate reduction and precipitation process can also affect the sulfur isotope composition of the Yangtze water. The87Sr/86Sr ratios of the Yangtze water range from 0.70823 to 0.71590, with an average value of 0.71084. The87Sr/86Sr ratio and Sr concentration are primary controlled by mixing of various sources with different87Sr/86Sr ratios and Sr contents, including the limestone, evaporite and the silicate rocks. The atmospheric precipitation and anthropogenic inputs can also contribute some Sr to the river. The δ11B values of the dissolved B in the Yangtze water range from 2.0‰ to 18.3‰, which is affected by multifactors, such as silicate weathering, carbonate weathering, evaporite dissolution, atmospheric deposition, and anthropogenic inputs.展开更多
Visible-light-responsive ternary metal tungstate(MWO_4) photocatalysts are being increasingly investigated for energy conversion and environmental purification applications owing to their striking features, including ...Visible-light-responsive ternary metal tungstate(MWO_4) photocatalysts are being increasingly investigated for energy conversion and environmental purification applications owing to their striking features, including low cost,eco-friendliness, and high stability under acidic and oxidative conditions. However, rapid recombination of photoinduced electron–hole pairs and a narrow light response range to the solar spectrum lead to low photocatalytic activity of MWO_4-based materials, thus significantly hampering their wide usage in practice. To enable their widespread practical usage, significant efforts have been devoted, by developing new concepts and innovative strategies. In this review, we aim to provide an integrated overview of the fundamentals and recent progress of MWO_4-based photocatalysts. Furthermore, different strategies, including morphological control, surface modification, heteroatom doping, and heterojunction fabrication, which are employed to promote the photocatalyticactivities of MWO_4-based materials, are systematically summarized and discussed. Finally, existing challenges and a future perspective are also provided to shed light on the development of highly efficient MWO_4-based photocatalysts.展开更多
In order to reduce the environmental and ecological problems induced by water resources development and utilization, this paper proposes a concept of environmental and ecological water requirement. It is defined as th...In order to reduce the environmental and ecological problems induced by water resources development and utilization, this paper proposes a concept of environmental and ecological water requirement. It is defined as the minimum water amount to be consumed by the natural water bodies to conserve its environmental and ecological functions. Based on the definition, the methods on calculating the amount of environmental and ecological water requirement are determined. In the case study on Haihe-Luanhe river system, the water requirement is divided into three parts, i.e., the basic in-stream flow, water requirement for sediment transfer and water consumption by evaporation of the lakes or everglades. The results of the calculation show that the environmental and ecological water requirement in the river system is about 124×108 m3, including 57×108 m3 for basic in-stream flow, 63×108 m3 for sediment transfer and 4×108 m3 for net evaporation loss of lakes. The total amount of environmental and ecological water requirement accounts for 54% of the amount of runoff (228×108 m3). However, it should be realized that the amount of environmental and ecological water requirement must be more than that we have calculated. According to this result, we consider that the rational utilization rate of the runoff in the river systems must not be more than 40%. Since the current utilization rate of the river system, which is over 80%, has been far beyond the limitation, the problems of environment and ecology are quite serious. It is imperative to control and adjust water development and utilization to eliminate the existing problems and to avoid the potential ecological or environmental crisis.展开更多
The present work studies the environmental isotopes assess groundwater characteristics of the different parts of the main aquifer in the northeast Missan Province in south of Iraq. Water samples of groundwater and sur...The present work studies the environmental isotopes assess groundwater characteristics of the different parts of the main aquifer in the northeast Missan Province in south of Iraq. Water samples of groundwater and surface water were collected for two dry and wet seasons during the water year of 2011-2012. The study shows that most of the groundwater in the aquifer falls above the global meteoric water line, and all the samples fall below the Mediterranean meteoric water line, indicating that these samples are a mixture of two water types. The tritium content of these samples supports this conclusion. The overall conclusion of this study indicates that there are two sources of groundwater recharge in the studied area: the ephemeral streams (Teeb and Dewerge) and major precipitation sources. According to the tritium levels at or below one tritium unit (TU) obtained from the water, supply wells are highly confined or "not vulnerable". Overall, the 3^H results imply that recent recharge has taken place during the last four to five decades. In the recharge area, the high tritium content in the southern part of the Teeb area suggests that the recharge originates from rapid infiltration of surface runoff. Therefore, the groundwater resources in the study area should be protected from contamination, because it will influence the aquifer in a relatively short period of time if any contamination enters the recharge areas of the aquifer.展开更多
The chemical and isotopic characteristics of the water and suspended particulate materials (SPM) in the Yellow River were investigated on the samples collected from 29 hydrological monitoring stations in the mainste...The chemical and isotopic characteristics of the water and suspended particulate materials (SPM) in the Yellow River were investigated on the samples collected from 29 hydrological monitoring stations in the mainstem and several major tributaries during 2004 to 2007. The JD and δ^18O values of the Yellow River water vary in large ranges from -32%0 to -91‰ and from -3.1‰ to -12.5‰, respectively. The characters of H and O isotope variations indicate that the major sources of the Yellow River water are meteoric water and snow melting water, and water cycle in the Yellow River basin is affected strongly by evaporation process and human activity. The average SPM content (9.635 g/L) of the Yellow River is the highest among the world large rivers. Compared with the Yangtze River, the Yellow River SPM has much lower clay content and significantly higher contents of clastic silicates and carbonates. In comparison to the upper crust rocks, the Yellow River SPM contains less SiO2, CaO, K2O and Na2O, but more TFe203, Co, Ni, Cu, Zn, Pb and Cd. The abnormal high Cd contents found in some sample may be related to local industrial activity. The REE contents and distribution pattern of the Yellow River SPM are very close to the average value of the global shale. The average δ^30Sisp in the Yellow River (-0.11‰) is slightly higher than the average value (-0.22‰) of the Yangtze River SPM. The major factors controlling the δ^30Si SPM of the Yellow River are the soil supply, the isotopic composition of the soil and the climate conditions. The TDS in the Yellow River are the highest among those of world large rivers. Fair correlations are observed among Cl, Na^+, K^+, and Mg^2+ contents of the Yellow River water, indicating the effect of evaporation. The Ca^2+ and Sr^2+ concentrations show good correlation to the SO42 concentration rather than HCO3-concentration, reflecting its origin from evaporates. The NO3-contents are affected by farmland fertilization. The Cu, Zn and Cd contents in dissolved load of the Yellow River water are all higher than those of average world large rivers, reflecting the effect of human activity. The dissolved load in the Yellow River water generally shows a REE distribution pattern parallel to those for the Yangtze River and the Xijiang River. The δ^30Si values of the dissolved silicon vary in a range from 0.4%0 to 2.9%0, averaging 1.34%o. The major processes controlling the Dsi weathering process of silicate rocks, growth of and δ^30SiDiss of the Yellow River water are the phytolith in plants, evaporation, dissolution of phytolith in soil, growth of fresh water diatom, adsorption and desorption of aqueous monosilicic acid on iron oxide and human activities. The average δ^30^SiDiss value of the Yellow River is significantly lower than that of the Nile River, Yangtze River and Siberia rivers, but higher than those of other rivers, reflecting their differences in chemical weathering and biological activity. The δ^34SSO4 values of the Yellow River water range from -3.8%0 to 14.1%o, averaging 7.97%0. There is some correlation between SO4^2- content and δ^34SSO4. The factors controlling the δ^34SSO4 of the Yellow River water are the SO4 in the meteoric water, the SO4 from gypsum or anhydrite in evaporite rocks, oxidation and dissolution of sulfides in the mineral deposits, magmatic rocks and sedimentary rocks, the sulfate reduction and precipitation process and the sulfate from fertilizer. The ^87Sr/^86Sr ratios of all samples range from 0.71041 to 0.71237, averaging 0.71128. The variations in the ^87Sr/^86Sr ratio and Sr concentration of river water are primarily caused by mixing of waters of various origins with different 87Sr/S6Sr ratios and Sr contents resulting from water-rock interaction with different rock types.展开更多
The purpose of this paper is to present a brief concept of the ecological and environmental water demand of lake. The present situation and affecting factors of lake ecological system in the Haihe\|Luanhe Basin of Nor...The purpose of this paper is to present a brief concept of the ecological and environmental water demand of lake. The present situation and affecting factors of lake ecological system in the Haihe\|Luanhe Basin of North China was analyzed. The calculating method of the ecological and environmental water demand of the lake basis on the water body and the calculating method of the ecological and environmental water demand of the lake basis on the aquatic ecosystem, wetland and vegetation were compared and discussed. As the examples of Baiyangdian Lake and Beidagang Lake in Haihe\|Luanhe river basin, the ecological and environmental water demand of the two lakes was calculated to be 27×10\+8m\+3. It is 6.75 times to the water demand according to the calculating method of the ecological and environmental water demand of the lake basis on the water body. The research result indicated: (1) The calculating methods of the ecological and environmental water demand of the lake basis on the aquatic ecosystem should be better than only basis on the water body of lake. (2) The data, such as area of the vegetation kind around and in the lake, the vegetation coefficient, the evaporating amount of the vegetation and the vegetation water demand itself around and in the lake are lack and urgent need. Some suggestions for controlling and regulating the water resource of the lake in North China were proposed.展开更多
[Objective] The aim was to study the variation characteristics of water environmental capacity in Poyang Lake under the scheduling of Three Gorges Reservoir.[Method] Choosing chemical oxygen demand (COD),total nitroge...[Objective] The aim was to study the variation characteristics of water environmental capacity in Poyang Lake under the scheduling of Three Gorges Reservoir.[Method] Choosing chemical oxygen demand (COD),total nitrogen (TN) and total phosphorus (TP) as the control indexes of pollutants in Poyang Lake,the variation characteristics of water environmental capacity in Poyang Lake under the scheduling of Three Gorges Reservoir were analyzed based on the water environment mathematical models of organic compounds and nutrients.[Result] After the operation of Three Gorges Project,high water level in Poyang Lake lasted for a long time in flood season when Three Gorges Reservoir increased discharge volume,while water level went down obviously with the accelerating of recession flow when reservoir decreased discharge volume to store water,so Three Gorges Project had obvious effects on the hydrological regime of Poyang Lake.In 2009,when Three Gorges Reservoir stored water,the water environmental capacity of COD,TN and TP in Poyang Lake in October decreased by 14.0%,15.4% and 15.4% compared with those before operation,while they increased by 3.64%,4.88% and 4.88% in August when reservoir discharged water to prevent flood.[Conclusion] The study could provide scientific foundation for the water pollution control and water environment management of lakes.展开更多
The Tai and Chao Lake basins are currently facing a serious water pollution crisis associated with the absence of an effective environmental governance system. The water pollution and the water governance system of th...The Tai and Chao Lake basins are currently facing a serious water pollution crisis associated with the absence of an effective environmental governance system. The water pollution and the water governance system of the two basins will be compared. The reasons for water pollution in both basins are similar, namely the weak current water environmental governance system cannot deal with the consequences of the rapidly growing economy. China’s water governance system is a complicated combination of basin management with both departmental management and regional management. There is an absence of legal support and sound coordination mechanisms, resulting in fragmented management practices in the existing water environmental governance system. A comparison is made for the Tai and Chao Lake basins and Canada, France, the United Kingdom and the United States. Based on China’s present central-local governance structure and departmental system, an integrated reform of basin level and water environmental governance in China should learn from international experiences. The reforms could consist of improved governance structures, rebuilding authoritative and powerful agencies for basin management, strengthening the organizational structure of the basin administrations, improving legislation and regulatory systems for basin management and enhancing public participation mechanisms.展开更多
There exists abundant thermal water recourses in Guanzhong basin, Shaanxi province (northwestern China). With the deepening of exploitation for thermal aquifer nowadays, the information about the origin and movement o...There exists abundant thermal water recourses in Guanzhong basin, Shaanxi province (northwestern China). With the deepening of exploitation for thermal aquifer nowadays, the information about the origin and movement of thermal water is limited by using traditional methods. This paper applies environmental isotope techniques to offer direct constraints on the recharge and movement of thermal water and improve the geological and hydrogeological data- base in Guanzhong Basin. The research on the environmental isotopes shows that the geothermal water of the area is mainly recharged by meteoric water. The temperature of meteoric water which replenishes geothermal water in the study area is -16 ℃. The estimated age of recharging the geothermal water is 13.3-28.2 ka based on the isotope analysis, belonging to the last glacial period in Late Quaternary. The source of replenishment of the geothermal water is thought to have been derived from glacial snow-melt water with an elevation higher than 1 500 m (ASL) in the north side of Qinling Mountain. The isotopic analysis denotes that the geothermal water in the southern Guanzhong basin is the mixture of net thermal water and normal temperature groundwater. Based on calculating the percentage of the mixture, nearly half of cold groundwater had participated the circulating of the geothermal water. However, in the center part of the basin, some artificial factors such as mismanage of pumping are probably the reason for the mixturing. The temperature range of the geothermal reservoirs in the basin is estimated at about 80-121 ℃ based on calculation of both SiO2 geothermometer and thermal water saturation index, which are basically in accordance with the measured temperature of thermal water. Based on the replenishment time and mixture extent with cold water, the thermal water in the studied area can be classified into three parts: mixed thermal water replenished by modern meteoric water; mixed thermal water replenished by both modern and ancient meteoric water, and deep circulating thermal water replenished by ancient meteoric water without mixture.展开更多
文摘Urban areas face significant challenges in maintaining water quality amidst increasing urbanization and changing climatic patterns. This study investigates the complex interplay between meteorological variables and water quality parameters in Nairobi City, focusing on the impacts of rainfall and temperature on surface water quality. Data from multiple sources, including the Water Resources Authority, Nairobi Water and Sewerage Company, and the World Bank’s Climate Change Knowledge Portal, were analyzed to assess the relationships between meteorological variables (rainfall and temperature) and water quality parameters (such as electroconductivity, biochemical oxygen demand, chloride, and pH). The analysis reveals varying impacts of rainfall and temperature on different water quality parameters. While parameters like iron and pH show strong relationships with both rainfall and temperature, others such as ammonia and nitrate exhibit moderate relationships. Additionally, the study highlights the influence of runoff, urbanization, and industrial activities on water quality, emphasizing the need for holistic management approaches. Recommendations encompass the establishment of annual publications on Nairobi River water quality, online accessibility of water quality data, development of hydrological models, spatial analysis, and fostering cross-disciplinary research collaborations. Implementing these recommendations can enhance water quality management practices, mitigate risks, and safeguard environmental integrity in Nairobi City.
文摘The primary objective of this study was to design and size a sustainable sanitation solution for the Ndiebene Gandiol 1 school located in the eponymous commune in northern Senegal. Field investigations led to the collection of wastewater samples. Their analysis revealed specific pollutant loads, including loads of BOD5 3.6966 kgO<sub>2</sub>/day and COD of 12.8775 kgO<sub>2</sub>/day, which were central to the design phase. Following a rigorous assessment of the existing sanitation infrastructure, constructed wetland (CWs) emerged as the most appropriate ecological solution. This system, valued for its ability to effectively remove contaminants, was tailored to the specific needs of the site. Consequently, the final design of the filter extends over 217.16 m<sup>2</sup>, divided into two cells of 108.58 m<sup>2</sup> each, with dimensions of 12.77 m in length and 8.5 m in width. The depth of the filtering medium is approximately 0.60 m, meeting the standards while ensuring maximized purification. Typha, an indigenous and prolific plant known for its purification abilities, was selected as the filtering agent. Concurrently, non-crushed gravel was chosen for its proven filtration capacity. This study is the result of a combination of scientific rigor and design expertise. It provides a holistic view of sanitation for Ndiebene Gandiol. The technical specifications and dimensions of the constructed wetland filter embody an approach that marries indepth analysis and practical application, all aimed at delivering an effective and long-lasting solution to the local sanitation challenges. By integrating precise scientific data with sanitation design expertise, this study delivers a holistic solution for Ndiebene Gandiol. The detailed dimensions and specifications of the constructed wetland filter reflect a methodology that combines meticulous analysis with practical adaptation, aiming to provide an effective and sustainable response to the challenges of rural and school sanitation in the northern region of Senegal.
文摘The small and scattered enterprise pattern in the county economy has formed numerous sporadic pollution sources, hindering the centralized treatment of the water environment, increasing the cost and difficulty of treatment. How enterprises can make reasonable decisions on their water environment behavior based on the external environment and their own factors is of great significance for scientifically and effectively designing water environment regulation mechanisms. Based on optimal control theory, this study investigates the design of contractual mechanisms for water environmental regulation for small and medium-sized enterprises. The enterprise is regarded as an independent economic entity that can adopt optimal control strategies to maximize its own interests. Based on the participation of multiple subjects including the government, enterprises, and the public, an optimal control strategy model for enterprises under contractual water environmental regulation is constructed using optimal control theory, and a method for calculating the amount of unit pollutant penalties is derived. The water pollutant treatment cost data of a paper company is selected to conduct empirical numerical analysis on the model. The results show that the increase in the probability of government regulation and public participation, as well as the decrease in local government protection for enterprises, can achieve the same regulatory effect while reducing the number of administrative penalties per unit. Finally, the implementation process of contractual water environmental regulation for small and medium-sized enterprises is designed.
基金The Knowledge Innovation Program of Wuhan-Shuguang Project(Project No.2023020201020361).
文摘At present,the major problems facing the water resource environment worldwide include water pollution,water resource shortage,and water ecosystem degradation.The discharge of industrial wastewater,agricultural non-point source pollution,and the discharge of urban sewage lead to a serious decline in water quality,which directly affects the safety of human drinking water and the living environment of aquatic organisms.Additionally,the unbalanced distribution and excessive exploitation of water resources lead to the problem of water shortage in many areas,which then leads to social and economic contradictions and ecological crises.In terms of ecosystems,the phenomena of water ecological degradation and reduction of biodiversity are increasingly obvious,and the carrying capacity of aquatic ecosystems are gradually declining.This paper aims to analyze the natural,social,and economic factors affecting the water resource environment,and propose effective strategies to protect the water ecology.To provide a theoretical basis and practical guidance for the sustainable utilization of water resources and the long-term development of the water ecosystem.
基金supported by National Key Science and Technology Program of China(2022YFC3203802)National Natural Science Foundation of China(52121006,92047303,and 51879165)+1 种基金supported by the Xplorer Prizesupported by the Young Elite Scientists Sponsorship Program by China Association for Science and Technology(2021QNRC001)。
文摘Interbasin water-transfer schemes provide an engineering solution for reconciling the conflict between water demand and availability.In the context of climate change,which brings great uncertainties to water resource distribution,interbasin water transfer plays an increasingly important role in the global water–food–energy nexus.However,the transfer of water resources simultaneously changes the hydrological regime and the characteristics of local water bodies,affecting biotic communities accordingly.Compared with high economic and technical inputs water-transfer projects require,the environmental and ecological implications of water-transfer schemes have been inadequately addressed.This work selects the largest water-transfer project in China,the South-to-North Water Diversion(SNWD)Project,to critically review its eco-environmental impacts on donor and recipient basins,as well as on regions along the diversion route.The two operated routes of the SNWD Project represent two typical water diversion approaches:The Middle Route uses an excavated canal,while the East Route connects existent river channels.An overview of the eco-environmental implications of these two routes is valuable for the design and optimization of future water-transfer megaprojects.
基金supported by the National Natural Science Foundation of China(22078166,22178188)。
文摘For a long time,China's regional water resource imbalance has restricted the development of coal chemical industry,and it is imperative to achieve zero liquid discharge(ZLD).Therefore,the game relationship between technical indicators,costs and emissions in ZLD process of fixed-bed coal gasification wastewater treatment process should be explored in detail.According to the accurate model,the simulation for ZLD of fixed-bed coal gasification wastewater treatment process is established,and this process is assessed from the perspective of thermodynamics,economy,and environment.The total energy consumption of ZLD process before optimization is 4.032×10^(8)W.The results of exergy analysis show exergy destruction of ZLD process is 94.55%.For economic and environmental results,the total annual cost is 1.892×10^(7)USD·a^(-1)and the total environmental impact is 4.782×10^(-8).The total energy consumption of the optimal six-step ZLD process based on multi-objective optimization is 4.028×10^(8)W.The CO_(2)content in the treated wastewater is 0.1%.This study will have an important role in promoting the establishment of the ZLD process for coal chemistry industry.
基金supported by the National Key R&D Program of China(2021YFB3901104).
文摘Water risk early warning systems based on the water environmental carrying capacity(WECC)are powerful and effective tools to guarantee the sustainability of rivers.Existing work on the early warning of WECC has mainly concerned the comprehensive evaluation of the status quo and lacked a quantitative prejudgement and warning of future overload.In addition,existing quantitative methods for short-term early warning have rarely focused on the integrated change trends of the early warning indicators.Given the periodicity of the socioeconomic system,however,the water environmental system also follows a trend of cyclical fluctuations.Thus,it is meaningful to monitor and use this periodicity for the early warning of the WECC.In this study,we first adopted and improved the prosperity index method to develop an integrated water risk early warning framework.We also constructed a forecast model to qualitatively and quantitatively prejudge and warn about the development trends of the water environmental system.We selected the North Canal Basin(an essential connection among the Beijing-Tianjin-Hebei region)in China as a case study and predicted the WECC in 25 water environmental management units of the basin in 2018–2023.We found that the analysis of the prosperity index was helpful in predicting the WECC,to some extent.The result demonstrated that the early warning system provided reliable prediction(root mean square error of 0.0651 and mean absolute error of 0.1418),and the calculation results of the comprehensive early warning index(CEWI)conformed to the actual situation and related research in the river basin.From 2008 to 2023,the WECC of most water environmental management units in the basin had improved but with some spatial differences:the CEWI was generally poor in areas with many human disturbances,while it was relatively good in the upstream regions with higher forest and grass covers as well as in the downstream areas with larger water volume.Finally,through a sensitivity analysis of the indicators,we proposed specific management measures for the sustainability of the water environmental system in the North Canal Basin.Overall,the integrated water risk early warning framework could provide an appropriate method for the water environmental administration department to predict the WECC of the basin in the future.This framework could also assist in implementing corresponding management measures in advance,especially for the performance evaluation and the arrangement of key short-term tasks in the River Chief System in China.
基金Supported by Key Fields of Universities in Guangdong Province (Science and Technology Service for Rural Revitalization)(2021ZDZX4023)2021 Undergraduate Teaching Quality and Teaching Construction Project of Guangdong Province (Guangdong Education Gao Han [2021] 29)+1 种基金Zhaoqing University Quality Engineering and Teaching Reform Project (zlgc 201931)Zhaoqing University Students’Innovation and Entrepreneurship Training Program in 2022 (X 202210580130)。
文摘In recent years, the beer industry is a biological food industry that consumes a lot of water, and it has developed rapidly in China. The sewage discharged from the mass production of beer poses a huge threat to the environment. In order to evaluate and better solve the possible environmental impacts of beer treatment engineering projects, a brewery project in Foshan City is taken as an example to investigate the water pollution generation links of the engineering process including surface water and groundwater. According to the relevant technical methods and standards, water pollution factors are screened, and concentration and discharge are monitored. Through comprehensive analysis, predictive evaluation is obtained. It is confirmed that the project meets the requirements of national laws and regulations and environmental protection standards.
基金Supported by the China Agriculture Research System(CARS49)~~
文摘Environmental endocrine disrupting chemicals (EDCs), commonly found in the environment, come from industry and agriculture, including pesticides, fungicides, insecticides, herbicides, and other chemicals. Nowadays, more and more EDCs were released into the environment. EDCs go into water body via atmosphere sedi-mentation, surface runoff, soil eluviation, etc., so water body becomes the main place for existing. In order to attract scientific and public attention worldwide and to prevent EDCs pol ution, in this study we reviewed the classification of EDCs and their concentrations in natural water bodies, drinking water sources and water plants, and the reproductive toxicity of EDCs to fish were reviewed. EDCs could disturb the endocrine system and make reproductive organs and reproduction abnor-mal, resulting in fertility descending, reproduction function damage, community quan-tity decrease and even species extinction. In addition, EDCs could disrupt the homeostasis maintained by hormones, which would result in defects of neural de-velopment and abnormalities of the endocrine and reproductive systems. The exact molecular mechanisms have not been completely reported, but researches have suggested that multiple mechanisms were involved in the action of EDCs. Although there have been researches on the biohazard of EDCs, there stil exist problems of weakness in fundamental researches, difficulties in recognizing and identifying EDCs and high cost, which restraint the knowledge on them.
基金Supported by National Science and Technology Project of "the Eleventh Five-year Plan" of China (2006BAD17B07)Doctoral Fund of Shandong Academy of Agricultural Sciences (2006YBS015)~~
文摘[Objective] The aim was to evaluate heavy metal environmental quality of irrigation water in vegetable farmlands of Shandong Province. [Method] Heavy metal contents including Hg,Cd,As,Cr (+6),Pb,Cu and Zn in irrigation water of main vegetable farmlands of Shandong Province were investigated by randomly sampling,and the environmental quality conditions of these heavy metals were evaluated by methods of single quality index and complex quality index. [Result] The results showed that the average contents of heavy metals in irrigation water of Shouguang,Laiyang,Jinxiang and Zhangqiu were all far lower than the limit values prescribed by 'Farmland Environmental Quality Evaluation Standards for Edible Agricultural Products' (HJ332-2006),and no heavy metal was found beyond the limit value in every sample. The single quality indices of the 7 elements in the studied 4 places were all lower than 0.5. The comprehensive quality index of the seven elements was 0.317 8 in Shouguang,0.320 4 in Laiyang,0.232 6 in Jinxiang,and 0.260 7 in Zhangqiu. The environmental quality of irrigation water in the studied four places were all set at the first class. [Conclusion] The environmental quality of irrigation water in the 4 places belonged to clean level and were fit for the plantation of no pollution vegetables.
基金supported by the State Key Laboratory of Cryospheric Science of China(SKLCS-ZZ-2022)the National Key Research and Development Research and Development Program of China(2020YFF0304400)the Third Scientific Expedition in Xinjiang Uygur Autonomous Region of China(2022xjkk0701).
文摘Analysis of environmental significance and hydrochemical characteristics of river water in mountainous regions is vital for ensuring water security.In this study,we collected a total of 164 water samples in the western region of the Altay Mountains,China,in 2021.We used principal component analysis and enrichment factor analysis to examine the chemical properties and spatiotemporal variations of major ions(including F-,Cl-,NO_(3)-,SO_(4)^(2-),Li+,Na+,NH4+,K+,Mg^(2+),and Ca^(2+))present in river water,as well as to identify the factors influencing these variations.Additionally,we assessed the suitability of river water for drinking and irrigation purposes based on the total dissolved solids,soluble sodium percentage,sodium adsorption ratio,and total hardness.Results revealed that river water had an alkaline aquatic environment with a mean pH value of 8.00.The mean ion concentration was ranked as follows:Ca^(2+)>SO_(4)^(2-)>Na+>NO_(3)->Mg^(2+)>K+>Cl->F->NH_(4)+>Li+.Ca^(2+),SO_(4)^(2-),Na+,and NO_(3)-occupied 83%of the total ion concentration.In addition,compared with other seasons,the spatial variation of the ion concentration in spring was obvious.An analysis of the sources of major ions revealed that these ions originated mainly from carbonate dissolution and silicate weathering.The recharge impact of precipitation and snowmelt merely influenced the concentration of Cl-,NO_(3)-,SO_(4)^(2-),Ca^(2+),and Na+.Overall,river water was in pristine condition in terms of quality and was suitable for both irrigation and drinking.This study provides a scientific basis for sustainable management of water quality in rivers of the Altay Mountains.
基金supported by the National Natural Science Foundation of China (Item No. 40673005)the Ministry of Science and Technology (2004DIB3J081)the Geological Survey of China (200320130-006)
文摘The chemical and isotopic characteristics of the water and suspended particulate materials(SPM) in the Yangtze River were investigated on the samples collected from 25 hydrological monitoring stations in the mainsteam and 13 hydrological monitoring stations in the major tributaries during 2003 to 2007. The water samples show a large variation in both δD( 30‰ to 112‰) and δ18O( 3.8‰ to 15.4‰) values. Both δD and δ18O values show a decrease from the river head to the Jinsha Jiang section and then increase downstream to the river mouth. It is found that the oxygen and hydrogen isotopic compositions of the Yangtze water are controlled by meteoric precipitation, evaporation, ice(and snow) melting and dam building. The Yangtze SPM concentrations show a large variation and are well corresponded to the spatial and temporal changes of flow speed, runoff and SPM supply, which are affected by the slope of the river bed, local precipitation rate, weathering intensity, erosion condition and anthropogenic activity. The Yangtze SPM consists of clay minerals, clastic silicate and carbonate minerals, heavy minerals, iron hydroxide and organic compounds. From the upper to lower reaches, the clay and clastic silicate components in SPM increase gradually, but the carbonate components decrease gradually, which may reflect changes of climate and weathering intensity in the drainage area. Compared to those of the upper crust rocks, the Yangtze SPM has lower contents of SiO2, CaO, K2 O and Na2 O and higher contents of TFe2 O3 and trace metals of Co, Ni, Cu, Zn, Pb and Cd. The ΣREE in the Yangtze SPM is also slightly higher than that of the upper crust. From the upper to lower reaches, the CaO and MgO contents in SPM decrease gradually, but the SiO2 content increases gradually, corresponding to the increase of clay minerals and decrease of the carbonates. The δ30SiSPM values( 1.1‰ to 0.3‰) of the Yangtze SPM are similar to those of the average shale, but lower than those of the granite rocks( 0.3‰ to 0.3‰), reflecting the effect of silicon isotope fractionation in silicate weathering process. The δ30SiSPM values of the Yangtze SPM show a decreasing trend from the upper to the middle and lower reaches, responding to the variation of the clay content. The major anions of the river water are HCO 3, SO 4 2, Cl, NO 3, SiO 4 4 and F and the major cations include Ca2+, Na+, Mg2+, K+ and Sr2+. The good correlation between HCO3-content and the content of Ca2+may suggest that carbonate dissolution is the dominate contributor to the total dissolved solid(TDS) of the Yangtze River. Very good correlations are also found among contents of Cl, SO4 2, Na+, Mg2+, K+and Sr2+, indicating the important contribution of evaporite dissolution to the TDS of the Yangtze River. High TDS contents are generally found in the head water, reflecting a strong effect of evaporation in the Qinghai-Tibet Plateau. A small increase of the TDS is generally observed in the river mouth, indicating the influence of tidal intrusion. The F and NO3 contents show a clear increase trend from the upstream to downstream, reflecting the contribution of pesticides and fertilizers in the Chuan Jiang section and the middle and lower reaches. The DSi shows a decrease trend from the upstream to downstream, reflecting the effect of rice and grass growth along the Chuan Jiang section and the middle and lower reaches. The dissolved Cu, Zn and Cd in the Yangtze water are all higher than those in world large rivers, reflecting the effect of intensive mining activity along the Yangtze drainage area. The Yangtze water generally shows similar REE distribution pattern to the global shale. The δ30SiDiss values of the dissolved silicon vary from 0.5‰ to 3.7‰, which is the highest among those of the rivers studied. The δ30SiDiss values of the water in the Yangtze mainsteam show an increase trend from the upper stream to downstream. Its DSi and δ30SiDiss are influenced by multiple processes, such as weathering process, phytolith growth in plants, evaporation, phytolith dissolution, growth of fresh water diatom, adsorption and desorption of aqueous monosilicic acid on iron oxide, precipitation of silcretes and formation of clays coatings in aquifers, and human activity. The δ34SSO4 values of the Yangtze water range from 1.7‰ to 9.0‰. The SO4 in the Yangtze water are mainly from the SO4 in meteoric water, the dissolved sulfate from evaporite, and oxidation of sulfide in rocks, coal and ore deposits. The sulfate reduction and precipitation process can also affect the sulfur isotope composition of the Yangtze water. The87Sr/86Sr ratios of the Yangtze water range from 0.70823 to 0.71590, with an average value of 0.71084. The87Sr/86Sr ratio and Sr concentration are primary controlled by mixing of various sources with different87Sr/86Sr ratios and Sr contents, including the limestone, evaporite and the silicate rocks. The atmospheric precipitation and anthropogenic inputs can also contribute some Sr to the river. The δ11B values of the dissolved B in the Yangtze water range from 2.0‰ to 18.3‰, which is affected by multifactors, such as silicate weathering, carbonate weathering, evaporite dissolution, atmospheric deposition, and anthropogenic inputs.
基金support of NSFC 51702284Fundamental Research Funds for the Central Universities (112109*172210171)+2 种基金the Startup Foundation for Hundred-Talent Program of Zhejiang University (112100-193820101/001/022)support of the NSFC 21501138the Science Research Foundation of Wuhan Institute of Technology (K201513)
文摘Visible-light-responsive ternary metal tungstate(MWO_4) photocatalysts are being increasingly investigated for energy conversion and environmental purification applications owing to their striking features, including low cost,eco-friendliness, and high stability under acidic and oxidative conditions. However, rapid recombination of photoinduced electron–hole pairs and a narrow light response range to the solar spectrum lead to low photocatalytic activity of MWO_4-based materials, thus significantly hampering their wide usage in practice. To enable their widespread practical usage, significant efforts have been devoted, by developing new concepts and innovative strategies. In this review, we aim to provide an integrated overview of the fundamentals and recent progress of MWO_4-based photocatalysts. Furthermore, different strategies, including morphological control, surface modification, heteroatom doping, and heterojunction fabrication, which are employed to promote the photocatalyticactivities of MWO_4-based materials, are systematically summarized and discussed. Finally, existing challenges and a future perspective are also provided to shed light on the development of highly efficient MWO_4-based photocatalysts.
基金Key Project of Chinese Academy of Sciences, KZ951-A1-203 Knowledge Innovation Project of Institute of Geographic Sciences and N
文摘In order to reduce the environmental and ecological problems induced by water resources development and utilization, this paper proposes a concept of environmental and ecological water requirement. It is defined as the minimum water amount to be consumed by the natural water bodies to conserve its environmental and ecological functions. Based on the definition, the methods on calculating the amount of environmental and ecological water requirement are determined. In the case study on Haihe-Luanhe river system, the water requirement is divided into three parts, i.e., the basic in-stream flow, water requirement for sediment transfer and water consumption by evaporation of the lakes or everglades. The results of the calculation show that the environmental and ecological water requirement in the river system is about 124×108 m3, including 57×108 m3 for basic in-stream flow, 63×108 m3 for sediment transfer and 4×108 m3 for net evaporation loss of lakes. The total amount of environmental and ecological water requirement accounts for 54% of the amount of runoff (228×108 m3). However, it should be realized that the amount of environmental and ecological water requirement must be more than that we have calculated. According to this result, we consider that the rational utilization rate of the runoff in the river systems must not be more than 40%. Since the current utilization rate of the river system, which is over 80%, has been far beyond the limitation, the problems of environment and ecology are quite serious. It is imperative to control and adjust water development and utilization to eliminate the existing problems and to avoid the potential ecological or environmental crisis.
基金supported by Selcuk University Scientific Research Projects(BAP)under Grant no.12201045 for the Doctoral Program of Higher Education of Turkey(Konya)
文摘The present work studies the environmental isotopes assess groundwater characteristics of the different parts of the main aquifer in the northeast Missan Province in south of Iraq. Water samples of groundwater and surface water were collected for two dry and wet seasons during the water year of 2011-2012. The study shows that most of the groundwater in the aquifer falls above the global meteoric water line, and all the samples fall below the Mediterranean meteoric water line, indicating that these samples are a mixture of two water types. The tritium content of these samples supports this conclusion. The overall conclusion of this study indicates that there are two sources of groundwater recharge in the studied area: the ephemeral streams (Teeb and Dewerge) and major precipitation sources. According to the tritium levels at or below one tritium unit (TU) obtained from the water, supply wells are highly confined or "not vulnerable". Overall, the 3^H results imply that recent recharge has taken place during the last four to five decades. In the recharge area, the high tritium content in the southern part of the Teeb area suggests that the recharge originates from rapid infiltration of surface runoff. Therefore, the groundwater resources in the study area should be protected from contamination, because it will influence the aquifer in a relatively short period of time if any contamination enters the recharge areas of the aquifer.
基金supported by the National Natural Science Foundation of China(Item No.40673005)the Ministry of Science and Technology(Item No. 2004DIB3J081)the Geological Survey of China(Item No.200320130-006)
文摘The chemical and isotopic characteristics of the water and suspended particulate materials (SPM) in the Yellow River were investigated on the samples collected from 29 hydrological monitoring stations in the mainstem and several major tributaries during 2004 to 2007. The JD and δ^18O values of the Yellow River water vary in large ranges from -32%0 to -91‰ and from -3.1‰ to -12.5‰, respectively. The characters of H and O isotope variations indicate that the major sources of the Yellow River water are meteoric water and snow melting water, and water cycle in the Yellow River basin is affected strongly by evaporation process and human activity. The average SPM content (9.635 g/L) of the Yellow River is the highest among the world large rivers. Compared with the Yangtze River, the Yellow River SPM has much lower clay content and significantly higher contents of clastic silicates and carbonates. In comparison to the upper crust rocks, the Yellow River SPM contains less SiO2, CaO, K2O and Na2O, but more TFe203, Co, Ni, Cu, Zn, Pb and Cd. The abnormal high Cd contents found in some sample may be related to local industrial activity. The REE contents and distribution pattern of the Yellow River SPM are very close to the average value of the global shale. The average δ^30Sisp in the Yellow River (-0.11‰) is slightly higher than the average value (-0.22‰) of the Yangtze River SPM. The major factors controlling the δ^30Si SPM of the Yellow River are the soil supply, the isotopic composition of the soil and the climate conditions. The TDS in the Yellow River are the highest among those of world large rivers. Fair correlations are observed among Cl, Na^+, K^+, and Mg^2+ contents of the Yellow River water, indicating the effect of evaporation. The Ca^2+ and Sr^2+ concentrations show good correlation to the SO42 concentration rather than HCO3-concentration, reflecting its origin from evaporates. The NO3-contents are affected by farmland fertilization. The Cu, Zn and Cd contents in dissolved load of the Yellow River water are all higher than those of average world large rivers, reflecting the effect of human activity. The dissolved load in the Yellow River water generally shows a REE distribution pattern parallel to those for the Yangtze River and the Xijiang River. The δ^30Si values of the dissolved silicon vary in a range from 0.4%0 to 2.9%0, averaging 1.34%o. The major processes controlling the Dsi weathering process of silicate rocks, growth of and δ^30SiDiss of the Yellow River water are the phytolith in plants, evaporation, dissolution of phytolith in soil, growth of fresh water diatom, adsorption and desorption of aqueous monosilicic acid on iron oxide and human activities. The average δ^30^SiDiss value of the Yellow River is significantly lower than that of the Nile River, Yangtze River and Siberia rivers, but higher than those of other rivers, reflecting their differences in chemical weathering and biological activity. The δ^34SSO4 values of the Yellow River water range from -3.8%0 to 14.1%o, averaging 7.97%0. There is some correlation between SO4^2- content and δ^34SSO4. The factors controlling the δ^34SSO4 of the Yellow River water are the SO4 in the meteoric water, the SO4 from gypsum or anhydrite in evaporite rocks, oxidation and dissolution of sulfides in the mineral deposits, magmatic rocks and sedimentary rocks, the sulfate reduction and precipitation process and the sulfate from fertilizer. The ^87Sr/^86Sr ratios of all samples range from 0.71041 to 0.71237, averaging 0.71128. The variations in the ^87Sr/^86Sr ratio and Sr concentration of river water are primarily caused by mixing of waters of various origins with different 87Sr/S6Sr ratios and Sr contents resulting from water-rock interaction with different rock types.
文摘The purpose of this paper is to present a brief concept of the ecological and environmental water demand of lake. The present situation and affecting factors of lake ecological system in the Haihe\|Luanhe Basin of North China was analyzed. The calculating method of the ecological and environmental water demand of the lake basis on the water body and the calculating method of the ecological and environmental water demand of the lake basis on the aquatic ecosystem, wetland and vegetation were compared and discussed. As the examples of Baiyangdian Lake and Beidagang Lake in Haihe\|Luanhe river basin, the ecological and environmental water demand of the two lakes was calculated to be 27×10\+8m\+3. It is 6.75 times to the water demand according to the calculating method of the ecological and environmental water demand of the lake basis on the water body. The research result indicated: (1) The calculating methods of the ecological and environmental water demand of the lake basis on the aquatic ecosystem should be better than only basis on the water body of lake. (2) The data, such as area of the vegetation kind around and in the lake, the vegetation coefficient, the evaporating amount of the vegetation and the vegetation water demand itself around and in the lake are lack and urgent need. Some suggestions for controlling and regulating the water resource of the lake in North China were proposed.
基金Supported by National Key Project of Water Pollution Control and Management (2008zx07526-008-03)International Science and Technology Cooperation Project (2006DFB91920)+2 种基金National Key Technology R & D Program in the 11th Five-year Plan of China (2007BAB23CO2)National Natural Science Foundation of China (40672159)Technical Assistance Project of China's Economic Reform Implementation (TCC5jxspyhzxh09-03)
文摘[Objective] The aim was to study the variation characteristics of water environmental capacity in Poyang Lake under the scheduling of Three Gorges Reservoir.[Method] Choosing chemical oxygen demand (COD),total nitrogen (TN) and total phosphorus (TP) as the control indexes of pollutants in Poyang Lake,the variation characteristics of water environmental capacity in Poyang Lake under the scheduling of Three Gorges Reservoir were analyzed based on the water environment mathematical models of organic compounds and nutrients.[Result] After the operation of Three Gorges Project,high water level in Poyang Lake lasted for a long time in flood season when Three Gorges Reservoir increased discharge volume,while water level went down obviously with the accelerating of recession flow when reservoir decreased discharge volume to store water,so Three Gorges Project had obvious effects on the hydrological regime of Poyang Lake.In 2009,when Three Gorges Reservoir stored water,the water environmental capacity of COD,TN and TP in Poyang Lake in October decreased by 14.0%,15.4% and 15.4% compared with those before operation,while they increased by 3.64%,4.88% and 4.88% in August when reservoir discharged water to prevent flood.[Conclusion] The study could provide scientific foundation for the water pollution control and water environment management of lakes.
文摘The Tai and Chao Lake basins are currently facing a serious water pollution crisis associated with the absence of an effective environmental governance system. The water pollution and the water governance system of the two basins will be compared. The reasons for water pollution in both basins are similar, namely the weak current water environmental governance system cannot deal with the consequences of the rapidly growing economy. China’s water governance system is a complicated combination of basin management with both departmental management and regional management. There is an absence of legal support and sound coordination mechanisms, resulting in fragmented management practices in the existing water environmental governance system. A comparison is made for the Tai and Chao Lake basins and Canada, France, the United Kingdom and the United States. Based on China’s present central-local governance structure and departmental system, an integrated reform of basin level and water environmental governance in China should learn from international experiences. The reforms could consist of improved governance structures, rebuilding authoritative and powerful agencies for basin management, strengthening the organizational structure of the basin administrations, improving legislation and regulatory systems for basin management and enhancing public participation mechanisms.
基金Project 2005003 supported by the Natural Science Foundation of Shaanxi Province
文摘There exists abundant thermal water recourses in Guanzhong basin, Shaanxi province (northwestern China). With the deepening of exploitation for thermal aquifer nowadays, the information about the origin and movement of thermal water is limited by using traditional methods. This paper applies environmental isotope techniques to offer direct constraints on the recharge and movement of thermal water and improve the geological and hydrogeological data- base in Guanzhong Basin. The research on the environmental isotopes shows that the geothermal water of the area is mainly recharged by meteoric water. The temperature of meteoric water which replenishes geothermal water in the study area is -16 ℃. The estimated age of recharging the geothermal water is 13.3-28.2 ka based on the isotope analysis, belonging to the last glacial period in Late Quaternary. The source of replenishment of the geothermal water is thought to have been derived from glacial snow-melt water with an elevation higher than 1 500 m (ASL) in the north side of Qinling Mountain. The isotopic analysis denotes that the geothermal water in the southern Guanzhong basin is the mixture of net thermal water and normal temperature groundwater. Based on calculating the percentage of the mixture, nearly half of cold groundwater had participated the circulating of the geothermal water. However, in the center part of the basin, some artificial factors such as mismanage of pumping are probably the reason for the mixturing. The temperature range of the geothermal reservoirs in the basin is estimated at about 80-121 ℃ based on calculation of both SiO2 geothermometer and thermal water saturation index, which are basically in accordance with the measured temperature of thermal water. Based on the replenishment time and mixture extent with cold water, the thermal water in the studied area can be classified into three parts: mixed thermal water replenished by modern meteoric water; mixed thermal water replenished by both modern and ancient meteoric water, and deep circulating thermal water replenished by ancient meteoric water without mixture.