The chemical and isotopic characteristics of the water and suspended particulate materials(SPM) in the Yangtze River were investigated on the samples collected from 25 hydrological monitoring stations in the mainste...The chemical and isotopic characteristics of the water and suspended particulate materials(SPM) in the Yangtze River were investigated on the samples collected from 25 hydrological monitoring stations in the mainsteam and 13 hydrological monitoring stations in the major tributaries during 2003 to 2007. The water samples show a large variation in both δD( 30‰ to 112‰) and δ18O( 3.8‰ to 15.4‰) values. Both δD and δ18O values show a decrease from the river head to the Jinsha Jiang section and then increase downstream to the river mouth. It is found that the oxygen and hydrogen isotopic compositions of the Yangtze water are controlled by meteoric precipitation, evaporation, ice(and snow) melting and dam building. The Yangtze SPM concentrations show a large variation and are well corresponded to the spatial and temporal changes of flow speed, runoff and SPM supply, which are affected by the slope of the river bed, local precipitation rate, weathering intensity, erosion condition and anthropogenic activity. The Yangtze SPM consists of clay minerals, clastic silicate and carbonate minerals, heavy minerals, iron hydroxide and organic compounds. From the upper to lower reaches, the clay and clastic silicate components in SPM increase gradually, but the carbonate components decrease gradually, which may reflect changes of climate and weathering intensity in the drainage area. Compared to those of the upper crust rocks, the Yangtze SPM has lower contents of SiO2, CaO, K2 O and Na2 O and higher contents of TFe2 O3 and trace metals of Co, Ni, Cu, Zn, Pb and Cd. The ΣREE in the Yangtze SPM is also slightly higher than that of the upper crust. From the upper to lower reaches, the CaO and MgO contents in SPM decrease gradually, but the SiO2 content increases gradually, corresponding to the increase of clay minerals and decrease of the carbonates. The δ30SiSPM values( 1.1‰ to 0.3‰) of the Yangtze SPM are similar to those of the average shale, but lower than those of the granite rocks( 0.3‰ to 0.3‰), reflecting the effect of silicon isotope fractionation in silicate weathering process. The δ30SiSPM values of the Yangtze SPM show a decreasing trend from the upper to the middle and lower reaches, responding to the variation of the clay content. The major anions of the river water are HCO 3, SO 4 2, Cl, NO 3, SiO 4 4 and F and the major cations include Ca2+, Na+, Mg2+, K+ and Sr2+. The good correlation between HCO3-content and the content of Ca2+may suggest that carbonate dissolution is the dominate contributor to the total dissolved solid(TDS) of the Yangtze River. Very good correlations are also found among contents of Cl, SO4 2, Na+, Mg2+, K+and Sr2+, indicating the important contribution of evaporite dissolution to the TDS of the Yangtze River. High TDS contents are generally found in the head water, reflecting a strong effect of evaporation in the Qinghai-Tibet Plateau. A small increase of the TDS is generally observed in the river mouth, indicating the influence of tidal intrusion. The F and NO3 contents show a clear increase trend from the upstream to downstream, reflecting the contribution of pesticides and fertilizers in the Chuan Jiang section and the middle and lower reaches. The DSi shows a decrease trend from the upstream to downstream, reflecting the effect of rice and grass growth along the Chuan Jiang section and the middle and lower reaches. The dissolved Cu, Zn and Cd in the Yangtze water are all higher than those in world large rivers, reflecting the effect of intensive mining activity along the Yangtze drainage area. The Yangtze water generally shows similar REE distribution pattern to the global shale. The δ30SiDiss values of the dissolved silicon vary from 0.5‰ to 3.7‰, which is the highest among those of the rivers studied. The δ30SiDiss values of the water in the Yangtze mainsteam show an increase trend from the upper stream to downstream. Its DSi and δ30SiDiss are influenced by multiple processes, such as weathering process, phytolith growth in plants, evaporation, phytolith dissolution, growth of fresh water diatom, adsorption and desorption of aqueous monosilicic acid on iron oxide, precipitation of silcretes and formation of clays coatings in aquifers, and human activity. The δ34SSO4 values of the Yangtze water range from 1.7‰ to 9.0‰. The SO4 in the Yangtze water are mainly from the SO4 in meteoric water, the dissolved sulfate from evaporite, and oxidation of sulfide in rocks, coal and ore deposits. The sulfate reduction and precipitation process can also affect the sulfur isotope composition of the Yangtze water. The87Sr/86Sr ratios of the Yangtze water range from 0.70823 to 0.71590, with an average value of 0.71084. The87Sr/86Sr ratio and Sr concentration are primary controlled by mixing of various sources with different87Sr/86Sr ratios and Sr contents, including the limestone, evaporite and the silicate rocks. The atmospheric precipitation and anthropogenic inputs can also contribute some Sr to the river. The δ11B values of the dissolved B in the Yangtze water range from 2.0‰ to 18.3‰, which is affected by multifactors, such as silicate weathering, carbonate weathering, evaporite dissolution, atmospheric deposition, and anthropogenic inputs.展开更多
In order to reduce the environmental and ecological problems induced by water resources development and utilization, this paper proposes a concept of environmental and ecological water requirement. It is defined as th...In order to reduce the environmental and ecological problems induced by water resources development and utilization, this paper proposes a concept of environmental and ecological water requirement. It is defined as the minimum water amount to be consumed by the natural water bodies to conserve its environmental and ecological functions. Based on the definition, the methods on calculating the amount of environmental and ecological water requirement are determined. In the case study on Haihe-Luanhe river system, the water requirement is divided into three parts, i.e., the basic in-stream flow, water requirement for sediment transfer and water consumption by evaporation of the lakes or everglades. The results of the calculation show that the environmental and ecological water requirement in the river system is about 124×108 m3, including 57×108 m3 for basic in-stream flow, 63×108 m3 for sediment transfer and 4×108 m3 for net evaporation loss of lakes. The total amount of environmental and ecological water requirement accounts for 54% of the amount of runoff (228×108 m3). However, it should be realized that the amount of environmental and ecological water requirement must be more than that we have calculated. According to this result, we consider that the rational utilization rate of the runoff in the river systems must not be more than 40%. Since the current utilization rate of the river system, which is over 80%, has been far beyond the limitation, the problems of environment and ecology are quite serious. It is imperative to control and adjust water development and utilization to eliminate the existing problems and to avoid the potential ecological or environmental crisis.展开更多
The chemical and isotopic characteristics of the water and suspended particulate materials (SPM) in the Yellow River were investigated on the samples collected from 29 hydrological monitoring stations in the mainste...The chemical and isotopic characteristics of the water and suspended particulate materials (SPM) in the Yellow River were investigated on the samples collected from 29 hydrological monitoring stations in the mainstem and several major tributaries during 2004 to 2007. The JD and δ^18O values of the Yellow River water vary in large ranges from -32%0 to -91‰ and from -3.1‰ to -12.5‰, respectively. The characters of H and O isotope variations indicate that the major sources of the Yellow River water are meteoric water and snow melting water, and water cycle in the Yellow River basin is affected strongly by evaporation process and human activity. The average SPM content (9.635 g/L) of the Yellow River is the highest among the world large rivers. Compared with the Yangtze River, the Yellow River SPM has much lower clay content and significantly higher contents of clastic silicates and carbonates. In comparison to the upper crust rocks, the Yellow River SPM contains less SiO2, CaO, K2O and Na2O, but more TFe203, Co, Ni, Cu, Zn, Pb and Cd. The abnormal high Cd contents found in some sample may be related to local industrial activity. The REE contents and distribution pattern of the Yellow River SPM are very close to the average value of the global shale. The average δ^30Sisp in the Yellow River (-0.11‰) is slightly higher than the average value (-0.22‰) of the Yangtze River SPM. The major factors controlling the δ^30Si SPM of the Yellow River are the soil supply, the isotopic composition of the soil and the climate conditions. The TDS in the Yellow River are the highest among those of world large rivers. Fair correlations are observed among Cl, Na^+, K^+, and Mg^2+ contents of the Yellow River water, indicating the effect of evaporation. The Ca^2+ and Sr^2+ concentrations show good correlation to the SO42 concentration rather than HCO3-concentration, reflecting its origin from evaporates. The NO3-contents are affected by farmland fertilization. The Cu, Zn and Cd contents in dissolved load of the Yellow River water are all higher than those of average world large rivers, reflecting the effect of human activity. The dissolved load in the Yellow River water generally shows a REE distribution pattern parallel to those for the Yangtze River and the Xijiang River. The δ^30Si values of the dissolved silicon vary in a range from 0.4%0 to 2.9%0, averaging 1.34%o. The major processes controlling the Dsi weathering process of silicate rocks, growth of and δ^30SiDiss of the Yellow River water are the phytolith in plants, evaporation, dissolution of phytolith in soil, growth of fresh water diatom, adsorption and desorption of aqueous monosilicic acid on iron oxide and human activities. The average δ^30^SiDiss value of the Yellow River is significantly lower than that of the Nile River, Yangtze River and Siberia rivers, but higher than those of other rivers, reflecting their differences in chemical weathering and biological activity. The δ^34SSO4 values of the Yellow River water range from -3.8%0 to 14.1%o, averaging 7.97%0. There is some correlation between SO4^2- content and δ^34SSO4. The factors controlling the δ^34SSO4 of the Yellow River water are the SO4 in the meteoric water, the SO4 from gypsum or anhydrite in evaporite rocks, oxidation and dissolution of sulfides in the mineral deposits, magmatic rocks and sedimentary rocks, the sulfate reduction and precipitation process and the sulfate from fertilizer. The ^87Sr/^86Sr ratios of all samples range from 0.71041 to 0.71237, averaging 0.71128. The variations in the ^87Sr/^86Sr ratio and Sr concentration of river water are primarily caused by mixing of waters of various origins with different 87Sr/S6Sr ratios and Sr contents resulting from water-rock interaction with different rock types.展开更多
Water risk early warning systems based on the water environmental carrying capacity(WECC)are powerful and effective tools to guarantee the sustainability of rivers.Existing work on the early warning of WECC has mainly...Water risk early warning systems based on the water environmental carrying capacity(WECC)are powerful and effective tools to guarantee the sustainability of rivers.Existing work on the early warning of WECC has mainly concerned the comprehensive evaluation of the status quo and lacked a quantitative prejudgement and warning of future overload.In addition,existing quantitative methods for short-term early warning have rarely focused on the integrated change trends of the early warning indicators.Given the periodicity of the socioeconomic system,however,the water environmental system also follows a trend of cyclical fluctuations.Thus,it is meaningful to monitor and use this periodicity for the early warning of the WECC.In this study,we first adopted and improved the prosperity index method to develop an integrated water risk early warning framework.We also constructed a forecast model to qualitatively and quantitatively prejudge and warn about the development trends of the water environmental system.We selected the North Canal Basin(an essential connection among the Beijing-Tianjin-Hebei region)in China as a case study and predicted the WECC in 25 water environmental management units of the basin in 2018–2023.We found that the analysis of the prosperity index was helpful in predicting the WECC,to some extent.The result demonstrated that the early warning system provided reliable prediction(root mean square error of 0.0651 and mean absolute error of 0.1418),and the calculation results of the comprehensive early warning index(CEWI)conformed to the actual situation and related research in the river basin.From 2008 to 2023,the WECC of most water environmental management units in the basin had improved but with some spatial differences:the CEWI was generally poor in areas with many human disturbances,while it was relatively good in the upstream regions with higher forest and grass covers as well as in the downstream areas with larger water volume.Finally,through a sensitivity analysis of the indicators,we proposed specific management measures for the sustainability of the water environmental system in the North Canal Basin.Overall,the integrated water risk early warning framework could provide an appropriate method for the water environmental administration department to predict the WECC of the basin in the future.This framework could also assist in implementing corresponding management measures in advance,especially for the performance evaluation and the arrangement of key short-term tasks in the River Chief System in China.展开更多
Using the Xiangyang Reach of the Han River as an example, this paper evaluates the changes of water environmental capacity after the implementation of Cuijiaying Hydro-junction project. The allowable pollutant loads e...Using the Xiangyang Reach of the Han River as an example, this paper evaluates the changes of water environmental capacity after the implementation of Cuijiaying Hydro-junction project. The allowable pollutant loads entering the Xiangyang Reach were estimated using two-dimensional steady state water quality model with different data sets. The water environmental capacity has declined in the reservoir area of the Cuijiaying Hydro-junction project during the low-flow period;it is appearing to increase slightly in the upper and lower stream of this reservoir. However, the state of flow may turn into the state of reservoirs flow in the reservoir area, and the changes of hydrological regime may cause the water flow and the nutrient contents suitable for the occurrence of ecological environment problems.展开更多
Extensive land use will cause many environmental problems.It is an urgent task to improve land use efficiency and optimize land use patterns.In recent years,due to the flow decrease,the Guanzhong Basin in Shaanxi Prov...Extensive land use will cause many environmental problems.It is an urgent task to improve land use efficiency and optimize land use patterns.In recent years,due to the flow decrease,the Guanzhong Basin in Shaanxi Province is confronted with the problem of insufficient water resources reserve.Based on the Coupled Ground-Water and Surface-Water Flow Model(GSFLOW),this paper evaluates the response of water resources in the basin to changes in land use patterns,optimizes the land use pattern,improves the ecological and economic benefits,and the efficiency of various spatial development,providing a reference for ecological protection and high-quality development of the Yellow River Basin.The research shows that the land use pattern in the Guanzhong Basin should be further optimized.Under the condition of considering ecological and economic development,the percentage change of the optimum area of farmland,forest,grassland,water area,and urban area compared with the current land use area ratio is+2.3,+2.4,-6.1,+0.2,and+1.6,respectively.The economic and ecological value of land increases by14.1%and 3.1%,respectively,and the number of water resources can increase by 2.5%.展开更多
Based on the monitoring results of environmental quality of the waters near the Oujiang River estuary from 2010 to 2017,the present situation of environmental quality of the waters was analyzed and evaluated.The resul...Based on the monitoring results of environmental quality of the waters near the Oujiang River estuary from 2010 to 2017,the present situation of environmental quality of the waters was analyzed and evaluated.The results showed that pH,DO,COD Mn ,petroleum,and heavy metal (Cu,Pb,Zn,Cd,Hg,As and Cr) content in the waters near the Oujiang River estuary did not exceed the second-class standard of Seawater Quality Standard (GB 3097-1997),while both inorganic nitrogen and reactive phosphate in the waters greatly exceeded the second-class standard.The water quality near the Oujiang River estuary was in an eutrophic state.In terms of sediment quality,the standard index of most evaluation factors except for Cu was smaller than 1,meeting the demands of sediment quality for environmental protection.展开更多
Based on the monitoring results of environmental quality of the waters near the Feiyun River estuary during 2011-2016, the current situation of environmental quality of the waters was analyzed and evaluated. The resul...Based on the monitoring results of environmental quality of the waters near the Feiyun River estuary during 2011-2016, the current situation of environmental quality of the waters was analyzed and evaluated. The results showed that pH, DO, COD Mn , petroleum, and heavy metals (Cu, Pb, Zn, Cd, Hg, As and Cr) in the waters near the Feiyun River estuary did not exceed the second-class standard of Seawater Quality Standard (GB 3097-1997), while both inorganic nitrogen and reactive phosphate in the waters exceeded the second-class standard obviously. The water quality of the waters near the Feiyun River estuary was in an eutrophic state. In terms of sediment quality, the standard index of most evaluation factors except for Cu was smaller than 1, meeting the demands of sediment quality for environmental protection.展开更多
The issue on water environmental degradation in the source area of the Yellow River has been one of very serious ecological and socially economic problems. The temporal-spatial changes of water environment led to the ...The issue on water environmental degradation in the source area of the Yellow River has been one of very serious ecological and socially economic problems. The temporal-spatial changes of water environment led to the decreasing of land capacity and river disconnecting. The status of water environmental degradation in this paper was analyzed based on the data and field investigation. The results indicated that the surface water area in the region has obviously decreased owing to the climate changes and human irrational use of water resources and the continuous lowering of the regional groundwater table and the steadily decreasing tendency of the flow rate in the source areas of the Yellow River.展开更多
Environmental issue has been considered more significant in many aspects of engineering decision-making process particularly in river management. There is an increasing effort to conserve functioning of rivers for hum...Environmental issue has been considered more significant in many aspects of engineering decision-making process particularly in river management. There is an increasing effort to conserve functioning of rivers for human use as well as nature, therefore environmental flow assessment has been widely developed. This paper discusses on environmental flow assessment of the Sekampung River, particularly on its middle reach. A new analytical approach based on water-sediment equations was introduced in order to determine a minimum environmental flow at the certain cross section of a river. The result of the new method was then compared with a minimum environmental flow provided by using two hydrological based methods, namely, Tennant and Flow Duration Curve Analysis (FDCA) method. The result shows that the concerned discharge provided by the water-sediment method (3.5 m3/s) is the smallest compare with a minimum environmental flow that is provided by both Tennant (5.7 m3/s) and FDCA method (4.5 m3/s). It is promising that the water-sediment method can be used as a simple approach on preliminary state of environmental flow assessment. The method involves not only water discharge but also its related sediment flow of the river in order to mitigate further ecological and morphological risks.展开更多
In order to realistically reflect the difference between regional water demand for instream flow and river ecological water demand as well as to resolve the problem that water demand may be counted repeatedly, a conce...In order to realistically reflect the difference between regional water demand for instream flow and river ecological water demand as well as to resolve the problem that water demand may be counted repeatedly, a concept of regional water demand for minimum instream flow have been developed. The concept was used in the process of determining river functions and calculating ecological water demand for a river. The Yellow River watershed was used to validate the calculation methodology for regional water demand. CaIculation results indicate that there are significant differences in water demands among the different regions. The regional water demand at the downstream of the Yellow River is the largest about 14.893 × 10^9 m^3/a. The regional water demand of upstream, Lanzhou-Hekou section is the smallest about -5.012 × 10^9 m^3/a. The total ecological water demand of the Yellow River Basin is 23.06 × 10^9 m^3/a, about the 39% of surface water resources of the water resources should not exceed 61% in the Yellow River Basin. Yellow River Basin. That means the maximum available surface The regional river ecological water demands at the Lower Section of the Yellow River and Longyangxia-Lanzhou Section exceed the surface water resources produced in its region and need to be supplemented from other regions through the water rational planning of watershed water resources. These results provides technical basis for rational plan of water resources of the Yellow River Basin.展开更多
A simple, rapid, and reproducible method is described employing solid phase extraction(SPE) using dichloromethane followed by gas chromatography(GC) with flame ionization detection(FID) for determination of volatile ...A simple, rapid, and reproducible method is described employing solid phase extraction(SPE) using dichloromethane followed by gas chromatography(GC) with flame ionization detection(FID) for determination of volatile organic compound(VOC) from the Buriganga River water of Bangladesh. The method was applied to detect the benzene, toluene, ethylbenzene, xylene and cumene(BTEXC) in the sample collected from the surface or 15 cm depth of water. Two hundred ml of n hexane pretreated and filtered water samples were applied directly to a C 18 SPE column. BTEXC were extracted with dichloromethane and average concentrations were obtained as 0 104 to 0 372 μg/ml. The highest concentration of benzene was found as 0 372 μg/ml with a relative standard deviation(RSD) of 6 2%, and cumene was not detected. Factors influencing SPE e.g., adsorbent types, sample load volume, eluting solvent, headspace and temperatures, were investigated. A cartridge containing a C 18 adsorbent and using dichloromethane gave better performance for extraction of BTEXC from water. Average recoveries exceeding 90% could be achieved for cumene at 4℃ with a 2 7% RSD.展开更多
In this article the meaning of the quantity and quality of environmental flows of river in dualistic water cycle is discussed, and compared with the meaning of unitary water cycle. Based on the analysis of the relatio...In this article the meaning of the quantity and quality of environmental flows of river in dualistic water cycle is discussed, and compared with the meaning of unitary water cycle. Based on the analysis of the relationship between environmental flows of river requirements, the efficiency of water resource usage, the consumption coefficient, and the concentration of waste water elimination, the water quantity and water quality calculation method of the environmental flows of river requirements in dualistic water cycle is developed, and the criteria for environmental flows of river requirements are established, and therefore the water quantity-quality combined evaluation of natural river flows requirements are realized Taking the Liaohe River as a model, the environmental flows of river requirements for Xiliao River, Dongliao River, mainstream Liaohe River, Huntai River and northeast rivers along the coasts of the Yellow and Bohai seas in unitary water cycle are calculated, each taking up 39.3%, 63.0%, 43.9%, 43.3% and 43.5% of runoff respectively. Evaluated according to Tennant recommended flow, the results show that: except Xiliao River is "median", the rest are all upon "good", the Dongliao River is even "very good". The corresponding results in dualistic water cycle are that, the proportion of natural flows for each river is 57.5%, 74.1%, 60.8%, 60.3% and 60.4%; while the combined evaluation results show that: considering "quantity", except Xiliao River, the rest rivers can all achieve the "quantity" criteria of the en- vironmental flows of river requirements, but if considering the aspect of "quality", only Dongliao River can reach the "quality" standard. By water quantity-quality combined evaluation method, only Dongliao River can achieve the criteria. So the water quality is the main factor that determines whether the environmental flows can meet the river ecosystem demands.展开更多
Microplastic pollution is widely distributed from surface water to sediments to groundwater vertically and from land to the ocean horizontally.This study collected samples from surface water,groundwater,and sediments ...Microplastic pollution is widely distributed from surface water to sediments to groundwater vertically and from land to the ocean horizontally.This study collected samples from surface water,groundwater,and sediments from upper to lower reaches and then to the estuary in 16 typical areas in the Jinjiang River Basin,Fujian Province,China.Afterward,it determined the components and abundance of the microplastics and analyzed the possible microplastic sources through principal component analysis(PCA).As a result,seven main components of microplastics were detected,i.e.,polyethylene(PE),polypropylene(PP),polyvinyl chloride(PVC),polyethylene terephthalate(PET),polyformaldehyde(POM),nylon 6(PA6),and polystyrene(PS).Among them,PE and PP were found to have the highest proportion in the surface water and sediments and in the groundwater,respectively.The surface water,groundwater,and sediments had average microplastic abundance of 1.6 n/L,2.7 n/L and 33.8 n/kg,respectively.The microplastics in the sediments had the largest particle size,while those in the groundwater had the smallest particle size.Compared with water bodies and sediments in other areas,those in the study area generally have medium-low-level microplastic abundance.Three pollution sources were determined according to PCA,i.e.,the dominant agriculture-forestry-fishery source,domestic wastewater,and industrial production.This study can provide a scientific basis for the control of microplastics in rivers.展开更多
Authors have conducted an experiment of irradiation using sound waves (frequency) including ultrasonic waves into water such as drinking water, sea water and forest water and wastewater so far. As a result, almost the...Authors have conducted an experiment of irradiation using sound waves (frequency) including ultrasonic waves into water such as drinking water, sea water and forest water and wastewater so far. As a result, almost the same effect of improvement of water quality was confirmed for each sound wave. Then, an environmental anthropological study of watershed management based on the sound was carried out assuming that a water quality management using the sound could be possible. The Goulburn River basin in the southern part of Australia in which indigenous peoples (Yorta Yorta) have been concerned with the management for a long time so far was selected as an objective drainage basin this time. As a result, a couple of environmental anthropological perspectives on watershed management were proposed.展开更多
Through high-resolution research of sedimental chronology and the sediment environmental indexes, such as graininess, minerals, magnetic parameters, pigment content, organic carbon and chronology in Ds-co...Through high-resolution research of sedimental chronology and the sediment environmental indexes, such as graininess, minerals, magnetic parameters, pigment content, organic carbon and chronology in Ds-core and Ws-core in Nansihu Lake, the authors analyze the formation cause of the Nansihu Lake and its water environmental changes. Historical documents are also analyzed here in order to reach the conclusion. Researches indicate that the Nansihu Lake came into being about 2500 aBP and its evolution succession can be divided into four stages. In this evolution process, several scattered lakes merge into one large lake in the east of China. This process is distinctively affected by the overflow of the Yellow River, the excavation of the Grand Canal and other human activities.展开更多
In this paper, according to the rule of unbalanced sediment transport and the analysis of field data, different water diversion schemes were theoretically studied, including the erosion and sedimentation trend as well...In this paper, according to the rule of unbalanced sediment transport and the analysis of field data, different water diversion schemes were theoretically studied, including the erosion and sedimentation trend as well as their impacts on the environment of the middle and lower reaches of the Hanjiang River. The results showed that the 95×10 8m 3 water diversion scheme will cause less erosion and water level decrease than the 15×10 8m 3 water diversion scheme. Using a water diversion scheme of 95×10 8m 3, the decrease of water quantity can impact the river hydrodynamic regime substantially and the environments of the middle and lower reaches of the Hanjiang River will be greatly affected. It is therefore necessary to develop new water resources or build projects to meet the need of the environment and the needs for navigation.展开更多
The paper describes the water resources in the irrigated area of Ningxia, China, andthe methods for improving the utilization of the water resources, and puts forward somesuggestions so as to utilize the water resourc...The paper describes the water resources in the irrigated area of Ningxia, China, andthe methods for improving the utilization of the water resources, and puts forward somesuggestions so as to utilize the water resources rationally. The history of irrigation farming in Ningxia can be traced back to more than two thou-展开更多
基金supported by the National Natural Science Foundation of China (Item No. 40673005)the Ministry of Science and Technology (2004DIB3J081)the Geological Survey of China (200320130-006)
文摘The chemical and isotopic characteristics of the water and suspended particulate materials(SPM) in the Yangtze River were investigated on the samples collected from 25 hydrological monitoring stations in the mainsteam and 13 hydrological monitoring stations in the major tributaries during 2003 to 2007. The water samples show a large variation in both δD( 30‰ to 112‰) and δ18O( 3.8‰ to 15.4‰) values. Both δD and δ18O values show a decrease from the river head to the Jinsha Jiang section and then increase downstream to the river mouth. It is found that the oxygen and hydrogen isotopic compositions of the Yangtze water are controlled by meteoric precipitation, evaporation, ice(and snow) melting and dam building. The Yangtze SPM concentrations show a large variation and are well corresponded to the spatial and temporal changes of flow speed, runoff and SPM supply, which are affected by the slope of the river bed, local precipitation rate, weathering intensity, erosion condition and anthropogenic activity. The Yangtze SPM consists of clay minerals, clastic silicate and carbonate minerals, heavy minerals, iron hydroxide and organic compounds. From the upper to lower reaches, the clay and clastic silicate components in SPM increase gradually, but the carbonate components decrease gradually, which may reflect changes of climate and weathering intensity in the drainage area. Compared to those of the upper crust rocks, the Yangtze SPM has lower contents of SiO2, CaO, K2 O and Na2 O and higher contents of TFe2 O3 and trace metals of Co, Ni, Cu, Zn, Pb and Cd. The ΣREE in the Yangtze SPM is also slightly higher than that of the upper crust. From the upper to lower reaches, the CaO and MgO contents in SPM decrease gradually, but the SiO2 content increases gradually, corresponding to the increase of clay minerals and decrease of the carbonates. The δ30SiSPM values( 1.1‰ to 0.3‰) of the Yangtze SPM are similar to those of the average shale, but lower than those of the granite rocks( 0.3‰ to 0.3‰), reflecting the effect of silicon isotope fractionation in silicate weathering process. The δ30SiSPM values of the Yangtze SPM show a decreasing trend from the upper to the middle and lower reaches, responding to the variation of the clay content. The major anions of the river water are HCO 3, SO 4 2, Cl, NO 3, SiO 4 4 and F and the major cations include Ca2+, Na+, Mg2+, K+ and Sr2+. The good correlation between HCO3-content and the content of Ca2+may suggest that carbonate dissolution is the dominate contributor to the total dissolved solid(TDS) of the Yangtze River. Very good correlations are also found among contents of Cl, SO4 2, Na+, Mg2+, K+and Sr2+, indicating the important contribution of evaporite dissolution to the TDS of the Yangtze River. High TDS contents are generally found in the head water, reflecting a strong effect of evaporation in the Qinghai-Tibet Plateau. A small increase of the TDS is generally observed in the river mouth, indicating the influence of tidal intrusion. The F and NO3 contents show a clear increase trend from the upstream to downstream, reflecting the contribution of pesticides and fertilizers in the Chuan Jiang section and the middle and lower reaches. The DSi shows a decrease trend from the upstream to downstream, reflecting the effect of rice and grass growth along the Chuan Jiang section and the middle and lower reaches. The dissolved Cu, Zn and Cd in the Yangtze water are all higher than those in world large rivers, reflecting the effect of intensive mining activity along the Yangtze drainage area. The Yangtze water generally shows similar REE distribution pattern to the global shale. The δ30SiDiss values of the dissolved silicon vary from 0.5‰ to 3.7‰, which is the highest among those of the rivers studied. The δ30SiDiss values of the water in the Yangtze mainsteam show an increase trend from the upper stream to downstream. Its DSi and δ30SiDiss are influenced by multiple processes, such as weathering process, phytolith growth in plants, evaporation, phytolith dissolution, growth of fresh water diatom, adsorption and desorption of aqueous monosilicic acid on iron oxide, precipitation of silcretes and formation of clays coatings in aquifers, and human activity. The δ34SSO4 values of the Yangtze water range from 1.7‰ to 9.0‰. The SO4 in the Yangtze water are mainly from the SO4 in meteoric water, the dissolved sulfate from evaporite, and oxidation of sulfide in rocks, coal and ore deposits. The sulfate reduction and precipitation process can also affect the sulfur isotope composition of the Yangtze water. The87Sr/86Sr ratios of the Yangtze water range from 0.70823 to 0.71590, with an average value of 0.71084. The87Sr/86Sr ratio and Sr concentration are primary controlled by mixing of various sources with different87Sr/86Sr ratios and Sr contents, including the limestone, evaporite and the silicate rocks. The atmospheric precipitation and anthropogenic inputs can also contribute some Sr to the river. The δ11B values of the dissolved B in the Yangtze water range from 2.0‰ to 18.3‰, which is affected by multifactors, such as silicate weathering, carbonate weathering, evaporite dissolution, atmospheric deposition, and anthropogenic inputs.
基金Key Project of Chinese Academy of Sciences, KZ951-A1-203 Knowledge Innovation Project of Institute of Geographic Sciences and N
文摘In order to reduce the environmental and ecological problems induced by water resources development and utilization, this paper proposes a concept of environmental and ecological water requirement. It is defined as the minimum water amount to be consumed by the natural water bodies to conserve its environmental and ecological functions. Based on the definition, the methods on calculating the amount of environmental and ecological water requirement are determined. In the case study on Haihe-Luanhe river system, the water requirement is divided into three parts, i.e., the basic in-stream flow, water requirement for sediment transfer and water consumption by evaporation of the lakes or everglades. The results of the calculation show that the environmental and ecological water requirement in the river system is about 124×108 m3, including 57×108 m3 for basic in-stream flow, 63×108 m3 for sediment transfer and 4×108 m3 for net evaporation loss of lakes. The total amount of environmental and ecological water requirement accounts for 54% of the amount of runoff (228×108 m3). However, it should be realized that the amount of environmental and ecological water requirement must be more than that we have calculated. According to this result, we consider that the rational utilization rate of the runoff in the river systems must not be more than 40%. Since the current utilization rate of the river system, which is over 80%, has been far beyond the limitation, the problems of environment and ecology are quite serious. It is imperative to control and adjust water development and utilization to eliminate the existing problems and to avoid the potential ecological or environmental crisis.
基金supported by the National Natural Science Foundation of China(Item No.40673005)the Ministry of Science and Technology(Item No. 2004DIB3J081)the Geological Survey of China(Item No.200320130-006)
文摘The chemical and isotopic characteristics of the water and suspended particulate materials (SPM) in the Yellow River were investigated on the samples collected from 29 hydrological monitoring stations in the mainstem and several major tributaries during 2004 to 2007. The JD and δ^18O values of the Yellow River water vary in large ranges from -32%0 to -91‰ and from -3.1‰ to -12.5‰, respectively. The characters of H and O isotope variations indicate that the major sources of the Yellow River water are meteoric water and snow melting water, and water cycle in the Yellow River basin is affected strongly by evaporation process and human activity. The average SPM content (9.635 g/L) of the Yellow River is the highest among the world large rivers. Compared with the Yangtze River, the Yellow River SPM has much lower clay content and significantly higher contents of clastic silicates and carbonates. In comparison to the upper crust rocks, the Yellow River SPM contains less SiO2, CaO, K2O and Na2O, but more TFe203, Co, Ni, Cu, Zn, Pb and Cd. The abnormal high Cd contents found in some sample may be related to local industrial activity. The REE contents and distribution pattern of the Yellow River SPM are very close to the average value of the global shale. The average δ^30Sisp in the Yellow River (-0.11‰) is slightly higher than the average value (-0.22‰) of the Yangtze River SPM. The major factors controlling the δ^30Si SPM of the Yellow River are the soil supply, the isotopic composition of the soil and the climate conditions. The TDS in the Yellow River are the highest among those of world large rivers. Fair correlations are observed among Cl, Na^+, K^+, and Mg^2+ contents of the Yellow River water, indicating the effect of evaporation. The Ca^2+ and Sr^2+ concentrations show good correlation to the SO42 concentration rather than HCO3-concentration, reflecting its origin from evaporates. The NO3-contents are affected by farmland fertilization. The Cu, Zn and Cd contents in dissolved load of the Yellow River water are all higher than those of average world large rivers, reflecting the effect of human activity. The dissolved load in the Yellow River water generally shows a REE distribution pattern parallel to those for the Yangtze River and the Xijiang River. The δ^30Si values of the dissolved silicon vary in a range from 0.4%0 to 2.9%0, averaging 1.34%o. The major processes controlling the Dsi weathering process of silicate rocks, growth of and δ^30SiDiss of the Yellow River water are the phytolith in plants, evaporation, dissolution of phytolith in soil, growth of fresh water diatom, adsorption and desorption of aqueous monosilicic acid on iron oxide and human activities. The average δ^30^SiDiss value of the Yellow River is significantly lower than that of the Nile River, Yangtze River and Siberia rivers, but higher than those of other rivers, reflecting their differences in chemical weathering and biological activity. The δ^34SSO4 values of the Yellow River water range from -3.8%0 to 14.1%o, averaging 7.97%0. There is some correlation between SO4^2- content and δ^34SSO4. The factors controlling the δ^34SSO4 of the Yellow River water are the SO4 in the meteoric water, the SO4 from gypsum or anhydrite in evaporite rocks, oxidation and dissolution of sulfides in the mineral deposits, magmatic rocks and sedimentary rocks, the sulfate reduction and precipitation process and the sulfate from fertilizer. The ^87Sr/^86Sr ratios of all samples range from 0.71041 to 0.71237, averaging 0.71128. The variations in the ^87Sr/^86Sr ratio and Sr concentration of river water are primarily caused by mixing of waters of various origins with different 87Sr/S6Sr ratios and Sr contents resulting from water-rock interaction with different rock types.
基金supported by the National Key R&D Program of China(2021YFB3901104).
文摘Water risk early warning systems based on the water environmental carrying capacity(WECC)are powerful and effective tools to guarantee the sustainability of rivers.Existing work on the early warning of WECC has mainly concerned the comprehensive evaluation of the status quo and lacked a quantitative prejudgement and warning of future overload.In addition,existing quantitative methods for short-term early warning have rarely focused on the integrated change trends of the early warning indicators.Given the periodicity of the socioeconomic system,however,the water environmental system also follows a trend of cyclical fluctuations.Thus,it is meaningful to monitor and use this periodicity for the early warning of the WECC.In this study,we first adopted and improved the prosperity index method to develop an integrated water risk early warning framework.We also constructed a forecast model to qualitatively and quantitatively prejudge and warn about the development trends of the water environmental system.We selected the North Canal Basin(an essential connection among the Beijing-Tianjin-Hebei region)in China as a case study and predicted the WECC in 25 water environmental management units of the basin in 2018–2023.We found that the analysis of the prosperity index was helpful in predicting the WECC,to some extent.The result demonstrated that the early warning system provided reliable prediction(root mean square error of 0.0651 and mean absolute error of 0.1418),and the calculation results of the comprehensive early warning index(CEWI)conformed to the actual situation and related research in the river basin.From 2008 to 2023,the WECC of most water environmental management units in the basin had improved but with some spatial differences:the CEWI was generally poor in areas with many human disturbances,while it was relatively good in the upstream regions with higher forest and grass covers as well as in the downstream areas with larger water volume.Finally,through a sensitivity analysis of the indicators,we proposed specific management measures for the sustainability of the water environmental system in the North Canal Basin.Overall,the integrated water risk early warning framework could provide an appropriate method for the water environmental administration department to predict the WECC of the basin in the future.This framework could also assist in implementing corresponding management measures in advance,especially for the performance evaluation and the arrangement of key short-term tasks in the River Chief System in China.
文摘Using the Xiangyang Reach of the Han River as an example, this paper evaluates the changes of water environmental capacity after the implementation of Cuijiaying Hydro-junction project. The allowable pollutant loads entering the Xiangyang Reach were estimated using two-dimensional steady state water quality model with different data sets. The water environmental capacity has declined in the reservoir area of the Cuijiaying Hydro-junction project during the low-flow period;it is appearing to increase slightly in the upper and lower stream of this reservoir. However, the state of flow may turn into the state of reservoirs flow in the reservoir area, and the changes of hydrological regime may cause the water flow and the nutrient contents suitable for the occurrence of ecological environment problems.
基金jointly supported by the National Natural Science Foundation of China(41702280)the projects of the China Geology Survey(DD20221754 and DD20190333)。
文摘Extensive land use will cause many environmental problems.It is an urgent task to improve land use efficiency and optimize land use patterns.In recent years,due to the flow decrease,the Guanzhong Basin in Shaanxi Province is confronted with the problem of insufficient water resources reserve.Based on the Coupled Ground-Water and Surface-Water Flow Model(GSFLOW),this paper evaluates the response of water resources in the basin to changes in land use patterns,optimizes the land use pattern,improves the ecological and economic benefits,and the efficiency of various spatial development,providing a reference for ecological protection and high-quality development of the Yellow River Basin.The research shows that the land use pattern in the Guanzhong Basin should be further optimized.Under the condition of considering ecological and economic development,the percentage change of the optimum area of farmland,forest,grassland,water area,and urban area compared with the current land use area ratio is+2.3,+2.4,-6.1,+0.2,and+1.6,respectively.The economic and ecological value of land increases by14.1%and 3.1%,respectively,and the number of water resources can increase by 2.5%.
文摘Based on the monitoring results of environmental quality of the waters near the Oujiang River estuary from 2010 to 2017,the present situation of environmental quality of the waters was analyzed and evaluated.The results showed that pH,DO,COD Mn ,petroleum,and heavy metal (Cu,Pb,Zn,Cd,Hg,As and Cr) content in the waters near the Oujiang River estuary did not exceed the second-class standard of Seawater Quality Standard (GB 3097-1997),while both inorganic nitrogen and reactive phosphate in the waters greatly exceeded the second-class standard.The water quality near the Oujiang River estuary was in an eutrophic state.In terms of sediment quality,the standard index of most evaluation factors except for Cu was smaller than 1,meeting the demands of sediment quality for environmental protection.
文摘Based on the monitoring results of environmental quality of the waters near the Feiyun River estuary during 2011-2016, the current situation of environmental quality of the waters was analyzed and evaluated. The results showed that pH, DO, COD Mn , petroleum, and heavy metals (Cu, Pb, Zn, Cd, Hg, As and Cr) in the waters near the Feiyun River estuary did not exceed the second-class standard of Seawater Quality Standard (GB 3097-1997), while both inorganic nitrogen and reactive phosphate in the waters exceeded the second-class standard obviously. The water quality of the waters near the Feiyun River estuary was in an eutrophic state. In terms of sediment quality, the standard index of most evaluation factors except for Cu was smaller than 1, meeting the demands of sediment quality for environmental protection.
文摘The issue on water environmental degradation in the source area of the Yellow River has been one of very serious ecological and socially economic problems. The temporal-spatial changes of water environment led to the decreasing of land capacity and river disconnecting. The status of water environmental degradation in this paper was analyzed based on the data and field investigation. The results indicated that the surface water area in the region has obviously decreased owing to the climate changes and human irrational use of water resources and the continuous lowering of the regional groundwater table and the steadily decreasing tendency of the flow rate in the source areas of the Yellow River.
文摘Environmental issue has been considered more significant in many aspects of engineering decision-making process particularly in river management. There is an increasing effort to conserve functioning of rivers for human use as well as nature, therefore environmental flow assessment has been widely developed. This paper discusses on environmental flow assessment of the Sekampung River, particularly on its middle reach. A new analytical approach based on water-sediment equations was introduced in order to determine a minimum environmental flow at the certain cross section of a river. The result of the new method was then compared with a minimum environmental flow provided by using two hydrological based methods, namely, Tennant and Flow Duration Curve Analysis (FDCA) method. The result shows that the concerned discharge provided by the water-sediment method (3.5 m3/s) is the smallest compare with a minimum environmental flow that is provided by both Tennant (5.7 m3/s) and FDCA method (4.5 m3/s). It is promising that the water-sediment method can be used as a simple approach on preliminary state of environmental flow assessment. The method involves not only water discharge but also its related sediment flow of the river in order to mitigate further ecological and morphological risks.
基金The National Natural Sciences Foundation of China (No. 50239020)
文摘In order to realistically reflect the difference between regional water demand for instream flow and river ecological water demand as well as to resolve the problem that water demand may be counted repeatedly, a concept of regional water demand for minimum instream flow have been developed. The concept was used in the process of determining river functions and calculating ecological water demand for a river. The Yellow River watershed was used to validate the calculation methodology for regional water demand. CaIculation results indicate that there are significant differences in water demands among the different regions. The regional water demand at the downstream of the Yellow River is the largest about 14.893 × 10^9 m^3/a. The regional water demand of upstream, Lanzhou-Hekou section is the smallest about -5.012 × 10^9 m^3/a. The total ecological water demand of the Yellow River Basin is 23.06 × 10^9 m^3/a, about the 39% of surface water resources of the water resources should not exceed 61% in the Yellow River Basin. Yellow River Basin. That means the maximum available surface The regional river ecological water demands at the Lower Section of the Yellow River and Longyangxia-Lanzhou Section exceed the surface water resources produced in its region and need to be supplemented from other regions through the water rational planning of watershed water resources. These results provides technical basis for rational plan of water resources of the Yellow River Basin.
文摘A simple, rapid, and reproducible method is described employing solid phase extraction(SPE) using dichloromethane followed by gas chromatography(GC) with flame ionization detection(FID) for determination of volatile organic compound(VOC) from the Buriganga River water of Bangladesh. The method was applied to detect the benzene, toluene, ethylbenzene, xylene and cumene(BTEXC) in the sample collected from the surface or 15 cm depth of water. Two hundred ml of n hexane pretreated and filtered water samples were applied directly to a C 18 SPE column. BTEXC were extracted with dichloromethane and average concentrations were obtained as 0 104 to 0 372 μg/ml. The highest concentration of benzene was found as 0 372 μg/ml with a relative standard deviation(RSD) of 6 2%, and cumene was not detected. Factors influencing SPE e.g., adsorbent types, sample load volume, eluting solvent, headspace and temperatures, were investigated. A cartridge containing a C 18 adsorbent and using dichloromethane gave better performance for extraction of BTEXC from water. Average recoveries exceeding 90% could be achieved for cumene at 4℃ with a 2 7% RSD.
基金Major consultation programs of Chinese Academy of EngineeringKey Scientific and Technological Pro-grams of the Ministry of Education, No.105042"973" Project,No.G1999043601
文摘In this article the meaning of the quantity and quality of environmental flows of river in dualistic water cycle is discussed, and compared with the meaning of unitary water cycle. Based on the analysis of the relationship between environmental flows of river requirements, the efficiency of water resource usage, the consumption coefficient, and the concentration of waste water elimination, the water quantity and water quality calculation method of the environmental flows of river requirements in dualistic water cycle is developed, and the criteria for environmental flows of river requirements are established, and therefore the water quantity-quality combined evaluation of natural river flows requirements are realized Taking the Liaohe River as a model, the environmental flows of river requirements for Xiliao River, Dongliao River, mainstream Liaohe River, Huntai River and northeast rivers along the coasts of the Yellow and Bohai seas in unitary water cycle are calculated, each taking up 39.3%, 63.0%, 43.9%, 43.3% and 43.5% of runoff respectively. Evaluated according to Tennant recommended flow, the results show that: except Xiliao River is "median", the rest are all upon "good", the Dongliao River is even "very good". The corresponding results in dualistic water cycle are that, the proportion of natural flows for each river is 57.5%, 74.1%, 60.8%, 60.3% and 60.4%; while the combined evaluation results show that: considering "quantity", except Xiliao River, the rest rivers can all achieve the "quantity" criteria of the en- vironmental flows of river requirements, but if considering the aspect of "quality", only Dongliao River can reach the "quality" standard. By water quantity-quality combined evaluation method, only Dongliao River can achieve the criteria. So the water quality is the main factor that determines whether the environmental flows can meet the river ecosystem demands.
基金funded by National Natural Science Foundation of China(41907175 and 41902259)China Geological Survey project(DD20190303).
文摘Microplastic pollution is widely distributed from surface water to sediments to groundwater vertically and from land to the ocean horizontally.This study collected samples from surface water,groundwater,and sediments from upper to lower reaches and then to the estuary in 16 typical areas in the Jinjiang River Basin,Fujian Province,China.Afterward,it determined the components and abundance of the microplastics and analyzed the possible microplastic sources through principal component analysis(PCA).As a result,seven main components of microplastics were detected,i.e.,polyethylene(PE),polypropylene(PP),polyvinyl chloride(PVC),polyethylene terephthalate(PET),polyformaldehyde(POM),nylon 6(PA6),and polystyrene(PS).Among them,PE and PP were found to have the highest proportion in the surface water and sediments and in the groundwater,respectively.The surface water,groundwater,and sediments had average microplastic abundance of 1.6 n/L,2.7 n/L and 33.8 n/kg,respectively.The microplastics in the sediments had the largest particle size,while those in the groundwater had the smallest particle size.Compared with water bodies and sediments in other areas,those in the study area generally have medium-low-level microplastic abundance.Three pollution sources were determined according to PCA,i.e.,the dominant agriculture-forestry-fishery source,domestic wastewater,and industrial production.This study can provide a scientific basis for the control of microplastics in rivers.
文摘Authors have conducted an experiment of irradiation using sound waves (frequency) including ultrasonic waves into water such as drinking water, sea water and forest water and wastewater so far. As a result, almost the same effect of improvement of water quality was confirmed for each sound wave. Then, an environmental anthropological study of watershed management based on the sound was carried out assuming that a water quality management using the sound could be possible. The Goulburn River basin in the southern part of Australia in which indigenous peoples (Yorta Yorta) have been concerned with the management for a long time so far was selected as an objective drainage basin this time. As a result, a couple of environmental anthropological perspectives on watershed management were proposed.
基金Natural Science Foundation of Shandong Province No.Z2000E01
文摘Through high-resolution research of sedimental chronology and the sediment environmental indexes, such as graininess, minerals, magnetic parameters, pigment content, organic carbon and chronology in Ds-core and Ws-core in Nansihu Lake, the authors analyze the formation cause of the Nansihu Lake and its water environmental changes. Historical documents are also analyzed here in order to reach the conclusion. Researches indicate that the Nansihu Lake came into being about 2500 aBP and its evolution succession can be divided into four stages. In this evolution process, several scattered lakes merge into one large lake in the east of China. This process is distinctively affected by the overflow of the Yellow River, the excavation of the Grand Canal and other human activities.
文摘In this paper, according to the rule of unbalanced sediment transport and the analysis of field data, different water diversion schemes were theoretically studied, including the erosion and sedimentation trend as well as their impacts on the environment of the middle and lower reaches of the Hanjiang River. The results showed that the 95×10 8m 3 water diversion scheme will cause less erosion and water level decrease than the 15×10 8m 3 water diversion scheme. Using a water diversion scheme of 95×10 8m 3, the decrease of water quantity can impact the river hydrodynamic regime substantially and the environments of the middle and lower reaches of the Hanjiang River will be greatly affected. It is therefore necessary to develop new water resources or build projects to meet the need of the environment and the needs for navigation.
文摘The paper describes the water resources in the irrigated area of Ningxia, China, andthe methods for improving the utilization of the water resources, and puts forward somesuggestions so as to utilize the water resources rationally. The history of irrigation farming in Ningxia can be traced back to more than two thou-