Equilibrium concentration of lithium ion in sodium aluminate solution

Excess lithium in alumina is significantly bad for aluminum reduction.In this study,the concentration variation of lithium ion in sodium aluminate solution with addition of synthetic lithium aluminate was investigated.Elevating temperature,increasing caustic soda concentration,reducing alumina concentration or raising molar ratioαk improved equilibrium concentration of lithium ion in sodium aluminate solution.Agitation speed had a minimal effect on lithium ion concentration.Over 0.65 g/L lithium ion equilibrium concentration was observed in digestion process,whereas 35 mg/L lithium ion concentration remained in solution after precipitation time of 9 h.Moreover,equilibrium concentration decreased sharply from digestion of boehmite or diaspore to seed precipitation,about 95%lithium was precipitated into red mud(bauxite residue)and aluminum hydroxide.This study provides a valuable perspective in removal or extraction of lithium from sodium aluminate solution in alumina refineries.

Experimental Determination of Calcite Dissolution Rates and Equilibrium Concentrations in Deionized Water Approaching Calcite Equilibrium

The calcite dissolution rates at 50-250 ℃ and 20 MPa in deionized water with flow rate varying from 0.2 to 5 mL/min were experimentally measured in a continuous flow column pressure vessel reactor. Equilibrium concentration （Ceq） of calcite dissolution in deionized water at 20 MPa was determined using dissolution data according to the iterative method presented by Jeschke and Dreybrodt. The equilibrium concentrations at 50, 100, 150, 200 and 250 ℃ are 1.84×10^-4, 2.23×10^-4, 2.25×10^-4, 2.31×10^-4 and 2.24×10^-4 mol/L, respectively. The Ceq increases first and then decreases with temperature varying from 50 to 250 ℃ at 20 MPa, and the same variation trend occurs at 10 MPa with lower values. The maximum value （or extremum） of Ceq would increase with temperature at constant pressures. The dissolution reaction of calcite in this experiment is approaching the calcite equilibrium, and the reaction order doesn＇t keep a constant at different temperatures, which could imply that a change of the reac- tion mechanism was occurring. The Arrhenius equation shouldn＇t be used to calculate apparent activation energy using rate constant data at different temperatures when the reaction order or reaction mechanism changed.

Equilibrium bed—concentration of nonuniform sediment

Knowledge of the equilibrium bed-concentration is vital to mathematic a l modeling of the river-bed deformation associated with suspended load but prev i ous investigations only dealt with the reference concentration of uniform sedime nt because of difficulties in observation of the bed-concentration. This work i s a first attempt to develop a theoretical formula for the equilibrium bed-conce n tration of any fraction of nonuniform sediment defined at the bed-surface. The f ormula is based on a stochastic-mechanistic model for the exchange of nonunifor m sediment near the bed, and described as a function of incipient motion probabil ity, non-ceasing probability, pick-up probability, and the ratio of the averag e single-step continuous motion time to static time. Comparison of bed-concentra ti on calculated from the proposed formula with the measured data showed satisfacto ry agreement, indicating the present formula can be used for solving the differe ntial equation governing the motion of suspended load.

Prediction of the P-leaching potential of arable soils in areas with high livestock densities

Due to long-term positive P-balances many surface soils in areas with high livestock density in Germany are over-supplied with available P, creating a potential for vertical P losses by leaching. In extensive studies to characterize the endangering of ground water to P pollution by chemical soil parameters it is shown that the available P content and the P concentration of the soil solution in the deeper soil layers, as indicators of the P-leaching potential, cannot be satisfactorily predicted from the available P content of the topsoils. The P equilibrium concentration in the soil solution directly above ground water table or the pipe drainage system highly depends on the relative saturation of the P-sorption capacity in this layer. A saturation index of <20% normally corresponds with P equilibrium concentrations of <0.2 mg P/L. Phytoremediation may reduce the P leaching potential of P-enriched soils only over a very long period.

Sediment movement characteristics of coast and analysis of seabed evolution

The rotary ring flume is used to study the silty sand movement in a periodic alternating current.Characteristics of sediment movement of different coasts in the tidal current are summarized.More detailed analysis of erosion-sedimentation function in a numerical simulation is made.The equilibrium sediment concentration is advanced.Based on the equilibrium sediment concentration,the seabed erosion-sedimentation index is derived and the seabed erosion-sedimentation calculation is analyzed.The seabed erosion-sedimentation index is used to calculate the seabed evolution of Yangshan sea area and a good agreement with field measurements is obtained.

Comparison of Phosphorus Sorption by Light-Weight Aggregates Produced in the United States

In this study, phosphorus(P) sorption of thirteen light-weight aggregates(LWAs) from USA was compared during batch equilibrium experiments in order to identify those materials which had the highest P sorption capacity for further study. Seven different levels of sorption activity were observed, which were broadly grouped into three categories—high performing, middle performing, and low performing aggregates. Chemical analysis of Ca, Al, Fe, and Mg was used to describe the differences between LWAs. There was a significant correlation between cation(especially Al, Ca, Fe, and Mg) content and P sorbed. Langmuir isotherms were used to describe P sorption maximum and binding affinity for four of the top five performing LWAs, Universal, Stalite "D", Stalite "Mix", and TXI.The fifth aggregate, Lehigh, exhibited more complex sorption, and was better described by the Freundlich isotherm. Universal had a mean P sorption at the highest concentration of 824 mg kg-1, well above its calculated sorption maximum(702 mg kg-1), and also had the highest binding affinity(1.1 L mg-1). This experiment suggests that the top performing LWA(Universal) may perform poorly in column and field studies due to observed precipitates, which could degrade constructed wetland performance. Other LWAs may exhibit superior field performance due to their high calculated sorption maxima. In general, these results highlight the importance of batch experiments as a first step in identifying materials suitable for column and field experiments.