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Measurements of Hydrate Equilibrium Conditions for CH4, CO2, and CH4+C2H6+C3H8 in Various Systems by Step-heating Method 被引量:8
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作者 陈立涛 孙长宇 +3 位作者 陈光进 聂运强 孙占松 刘延涛 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第4期635-641,共7页
Phase equilibrium conditions of gas hydrate in several systems were measured by the step-heating method using the cylindrical transparent sapphire cell device.The experimental data for pure CH4 or CO2+deionized water ... Phase equilibrium conditions of gas hydrate in several systems were measured by the step-heating method using the cylindrical transparent sapphire cell device.The experimental data for pure CH4 or CO2+deionized water systems showed good agreement with those in the literatures.This kind of method was then applied to CH4/CO2+sodium dodecyl sulfate(SDS)aqueous solution,CH4/CO2+SDS aqueous solution+silica sand,and(CH4+C2H6+C3H8)gas mixture+SDS aqueous solution systems,where SDS was added to increase the hydrate formation rate without evident influence on the equilibrium conditions.The feasibility and reliability of the step-heating method,especially for porous media systems and gas mixtures systems were determined.The experimental data for CO2+silica sand data shows that the equilibrium pressure will change significantly when the particle size of silica sand is less than 96μm.The formation equilibrium pressure was also measured by the reformation of hydrate. 展开更多
关键词 equilibrium condition HYDRATE step-heating sodium dodecyl sullate silica sand
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Shear strength degradation of gas hydrate-bearing sediment due to partial hydrate dissociation
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作者 Yuan Zhou Jiazuo Zhou +1 位作者 Pan Chen Changfu Wei 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第7期2749-2763,共15页
Extraction of methane hydrate from subseafloor reservoir may potentially trigger seabed slides and induce subsidence.To address the problems,it is crucial to properly characterize the phase equilibrium condition of po... Extraction of methane hydrate from subseafloor reservoir may potentially trigger seabed slides and induce subsidence.To address the problems,it is crucial to properly characterize the phase equilibrium condition of pore hydrate and the shear strength of the soil.As one of the key constitutive components,the phase equilibrium condition enforces a constraint over pore gas pressure,temperature and unhydrated water content.Such a constraint,however,has been traditionally ignored in analyzing the mechanical behavior of hydrate-bearing soil.In this paper,a series of stepwise hydrate dissociation tests was performed,and the phase equilibrium condition of pore hydrate was determined,providing an effective way to evaluate the unhydrated water content during hydrate dissociation.Meanwhile,a series of direct shear tests was also conducted to explore the shear strength characteristics of the soil.It is shown that the shear strength of the hydrate-bearing soil can be significantly influenced by pore gas pressure,unhydrated water content,hydrate saturation and several other factors.In particular,the measured shear strength depends upon the initial water content of the sample,pointing to a potential problem that the shear strength could be wrongly determined if not properly interpreted.A shear strength criterion,which enforces the equilibrium condition of pore hydrate,is developed for hydrate-bearing soil,establishing a link between the equilibrium condition and the shear strength.The proposed equation describes well the shear strength characteristics of hydrate-bearing soils,remarkably unifying the effects of pore pressure,temperature,water content and hydrate saturation. 展开更多
关键词 Hydrate-bearing soil Phase equilibrium condition Shear strength Unhydrated water content Mechanical behavior
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二人博弈问题中单一纳什均衡的搜索算法 被引量:1
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作者 孙舒杨 刘大有 孙成敏 《吉林大学学报(理学版)》 CAS CSCD 北大核心 2006年第3期418-420,共3页
给出计算二人博弈问题中单一纳什均衡的一种搜索算法,用支付矩阵的秩数和条件占优行的个数限定待搜索策略对空间,将该空间按一定规则排序,通过对有序有限策略对空间进行搜索得到一个简单的纳什均衡.
关键词 二人博弈 纳什均衡 支撑集 条件占优策略
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Bearing capacity of concrete filled bidirectional FRP tube subjected to axial compression
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作者 于峰 牛荻涛 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2010年第1期145-148,共4页
External confinement by fiber reinforced polymer (FRP) is an efficient technique to increase the bearing capacity and ductility of concrete. To better study the mechanical behavior of bidirectional FRP confined concre... External confinement by fiber reinforced polymer (FRP) is an efficient technique to increase the bearing capacity and ductility of concrete. To better study the mechanical behavior of bidirectional FRP confined concrete, the yield criterion of bidirectional FRP is presented based on the static equilibrium condition in this paper, and a model for calculating the bearing capacity of bidirectional FRP confined concrete is established. The model can capture the character of bidirectional FRP confined concrete. Effects of the confinement effect coefficient, the unconfined concrete strength and the material properties of FRP on bearing capacity are analyzed. Results show that each parameter has different effects on the bearing capacity of bidirectional FRP confined concrete. 展开更多
关键词 fiber reinforced polymer confined concrete bearing capacity column ultimate equilibrium condition
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燃气空调的发展及前景 被引量:1
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作者 徐永生 《天津城市建设学院学报》 CAS 2002年第3期151-155,共5页
介绍了国内外燃气空调开发与利用的概况 ,提出了燃气空调在我国的适用条件 。
关键词 燃气空调 环境保护 节能 平衡 建筑面积
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APPLICATION OF PENALTY FUNCTION METHOD IN ISOPARANIETRIC HYBRID FINITE ELEMENT ANALYSIS 被引量:1
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作者 CHEN Dao-zheng(陈道政) JIAO Zhao-ping(焦兆平) 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2005年第8期1017-1025,共9页
By the aid of the penalty function method, the equilibrium restriction conditions were introduced to the isoparametric hybrid finite element analysis, and the concrete application course of the penalty function method... By the aid of the penalty function method, the equilibrium restriction conditions were introduced to the isoparametric hybrid finite element analysis, and the concrete application course of the penalty function method in three-dimensional isoparametdc hybrid finite element was discussed. The separated penalty parameters method and the optimal hybrid element model with penalty balance were also presented. The penalty balance method can effectively refrain the parasitical stress on the premise of no additional degrees of freedom. The numeric experiment shows that the presented element not only is effective in improving greatly the numeric calculation precision of distorted grids but also has the universality. 展开更多
关键词 hybrid element equilibrium restriction condition penalty function method
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First fundamental problems of anisotropic elastic plane weakened by periodic collinear cracks
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作者 蔡海涛 路见可 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2009年第11期1429-1436,共8页
Using the method of complex functions, we discuss the first fundamental problems of an anisotropic infinite elastic plane weakened by periodic collinear cracks and with periodic boundary loads on both sides of the cra... Using the method of complex functions, we discuss the first fundamental problems of an anisotropic infinite elastic plane weakened by periodic collinear cracks and with periodic boundary loads on both sides of the cracks. This problem was considered by Cai [Engineering Fracture Mechanics 46(1), 133-142 (1993)]. However, the previous method is imperfect. Therefore, the results are incorrect. Here, we revise the method and give a correct solution. 展开更多
关键词 anisotropic elastic plane collinear cracks condition of elastic equilibrium
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GROUNDWATER MASS TRANSPORT AND HOMOGENEOUS EQUILIBRIUM CHEMISTRY IN THE PRESENCE OF FLUX BOUNDARY CONDITIONS
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作者 管志成 《Acta Mathematicae Applicatae Sinica》 SCIE CSCD 1991年第2期165-172,共8页
Considering a solute transport problem deseribed by some algebraic and partial differentialequations with the presence of flux boundary conditions, we reduce the problem to a fixed point oneand use a priori estimates ... Considering a solute transport problem deseribed by some algebraic and partial differentialequations with the presence of flux boundary conditions, we reduce the problem to a fixed point oneand use a priori estimates to prove the existence and uniqueness of the global solutions. 展开更多
关键词 GROUNDWATER MASS TRANSPORT AND HOMOGENEOUS equilibrium CHEMISTRY IN THE PRESENCE OF FLUX BOUNDARY conditionS
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Compact stars admitting Finch-Skea symmetry in the presence of various matter fields
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作者 Oleksii Sokoliuk Alexander Baransky P.K.Sahoo 《Chinese Physics C》 SCIE CAS CSCD 2023年第1期234-251,共18页
In the present study,we investigate the anisotropic stellar solutions admitting Finch-Skea symmetry(viable and non-singular metric potentials)in the presence of some exotic matter fields,such as Bose-Einstein Condensa... In the present study,we investigate the anisotropic stellar solutions admitting Finch-Skea symmetry(viable and non-singular metric potentials)in the presence of some exotic matter fields,such as Bose-Einstein Condensate(BEC)dark matter,the Kalb-Ramond fully anisotropic rank-2 tensor field from the low-energy string theory effective action,and the gauge field imposing U(1)symmetry.Interior spacetime is matched with both Schwarzchild and Reissner-N?rdstrom vacuum spacetimes for BEC,KB,and gauge fields.In addition,we study the energy conditions,Equation of State(EoS),radial derivatives of energy density and anisotropic pressures,Tolman-OppenheimerVolkoff equilibrium condition,relativistic adiabatic index,sound speed,and surface redshift.Most of the aforementioned conditions are satisfied.Therefore,the solutions derived in the current study lie in the physically acceptable regime. 展开更多
关键词 compact stars Finch-Skea symmetry energy conditions Tolman-Oppenheimer-Volkoff equilibrium condition sound speed
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深度脱水污泥焚烧过程中调理剂的热转化行为及其对重金属挥发的影响 被引量:3
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作者 刘敬勇 傅杰文 +4 位作者 党晓娥 孙健 孙水裕 郭家宏 王玉洁 《环境科学学报》 CAS CSCD 北大核心 2016年第7期2540-2556,共17页
采用化学热力学平衡分析方法,应用污泥实测数据模拟计算了深度脱水后污泥焚烧过程中调理剂的热转化过程及逸出产物,并预测了含Cl调理剂与CaO耦合作用对重金属迁移转化及排放的影响.研究结果表明,污泥添加单一调理剂Al_2(SO_4)_3、Fe_2(S... 采用化学热力学平衡分析方法,应用污泥实测数据模拟计算了深度脱水后污泥焚烧过程中调理剂的热转化过程及逸出产物,并预测了含Cl调理剂与CaO耦合作用对重金属迁移转化及排放的影响.研究结果表明,污泥添加单一调理剂Al_2(SO_4)_3、Fe_2(SO_4)_3、FeSO_4、AlCl_3及FeCl_3后,Fe和Al在高温下主要以Al_2O_3(s)和Fe_2O_3(s)存在,主要气态产物是HCl和SO_2.调理剂CaO和FeCl_3共存且含量增加时,焚烧过程中HCl(g)逸出过程变慢,并且Fe_2O_3(s)易于和CaO(s)作用导致Fe_2O_3(s)存在温度区间变窄.污泥未添加调理剂焚烧过程中,重金属Cd、Pb、Cr、Tl、Hg、As易于以Cd(OH)_2(g)、PbO(g)、CrO_2(OH)_2(g)、AsO(g)、Hg(g)、Tl(g)形式挥发,而Cu、Zn、Ni以其氧化物形式存在而难挥发.调理剂FeCl_3及CaO添加到污泥后,重金属(Cd、Pb、Cu、Zn、Ni、Hg、Tl)的分布受FeCl3的影响大于CaO,导致其形成重金属氯化物而挥发,而Cr和As与CaO作用生成CaCr_2O_4(s)、Ca_3(AsO_4)_2(s)热稳定化学物,抑制了Cr、As的挥发.当脱水污泥与含硫化物掺烧时,重金属(Pb、Cu、Zn、Ni)挥发受到Cl的影响大于S,在低温区间其主要以硫酸盐为主,在中高温区间以氯化物存在,而Hg和Tl不受硫化物影响. 展开更多
关键词 污泥焚烧 调理剂 重金属 深度脱水 热力学平衡分析
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