Equilibrium moisture contents (EMC) of wood species are very necessary in the utilization of these in service. This study investigated the EMC of five lesser utilized species of Ghana and compared it with that of thre...Equilibrium moisture contents (EMC) of wood species are very necessary in the utilization of these in service. This study investigated the EMC of five lesser utilized species of Ghana and compared it with that of three European species. Sixteen randomly sampled specimens of each of the eight species (heartwood and sapwood) with dimensions 3 cm × 3 cm × 3 cm were exposed at various relative humidity conditions of 30%, 45%, 60%, 75% and 90% in a temperature and humidity-controlled climate chamber at a temperature of 25°C in accordance to German standard DIN 52182. The species are Albies alba, Fagus sylvatica and Picea abies which are European species and Amphimas pterocarpoides, Antiaris toxicaria, Canarium schweinfurthii, Celtis zenkeri and Cola gigantea are wood species from Ghana. Internal wood temperature and humidity were measured with datalogger. Samples were considered to have reached equilibrium at any given humidity when the daily weight changes were less than 0.1 mg according to German standard DIN 52183. After the last measurements of the weight changes, the samples were dried at 103°C until there was a constant weight. The five tropical hardwoods had low sorption values recorded and high sorption values for the European species and this could be attributed to differences in the microstructure of these woods.展开更多
Dehydrated sorghum flour ("ogi") is useful as additional ingredient in certain food and pharmaceutical formulation, this could be obtained by soaking sorghum in water for 3 to 4 days, wet milling the soaked materi...Dehydrated sorghum flour ("ogi") is useful as additional ingredient in certain food and pharmaceutical formulation, this could be obtained by soaking sorghum in water for 3 to 4 days, wet milling the soaked material, and fermentation for another 3 to 4 days. Typically, the fermented product is boiled into a pap or cooked into a stiff porridge. However, the fermented product can not be easily handled or stored and does not have a long shelf life (typically less than a week). Dehydrating the fermented product into flour is one of the ways that is being employed to overcome these problems. Equilibrium moisture content (EMC) of dehydrated sorghum flour (aka "ogi") was therefore determined at two temperatures of 25℃ and 40℃ and four salt solutions. Zinc chloride (ZnCl2), potassium acetate (KC2H3O2), calcium chloride (CaCl2) and sodium chloride (NaCl) salts were prepared to correspond to equilibrium relative humidities of 10.0% to 75.4%. The moisture sorption characteristics of the sorghum product showed the characteristics S-shaped sorption isotherm curve that is typically obtained for agricultural products. The equilibrium data and the monomolccular layer moisture content values were estimated using the Brunauer-Emmett-Teller (BET) equation. The moisture content range for optimum storage of the dehydrated sorghum flour lies between 2.84% to 3.69% at 25℃ and 6.84% and 7.67% at 40℃. The information obtained from this study will help in the design and selection of storage and packaging systems for dehydrated sorghum flour.展开更多
The pinewood nematode(PWN), Bursaphelenchus xylophilus, has become one of the most severe threats to pine forest worldwide. Nematodes, migrating through resin canals and feeding on the living cells, induce rapid met...The pinewood nematode(PWN), Bursaphelenchus xylophilus, has become one of the most severe threats to pine forest worldwide. Nematodes, migrating through resin canals and feeding on the living cells, induce rapid metabolic changes in ray parenchyma cells, create cavitation areas, decrease xylem water content and oleoresin exudation, and cause necrosis of parenchyma and cambial cells. This study focused on the impact of PWN infection on technological parameters of wood and evaluated the impact of anatomic and biochemical incidences of tree defense reactions on basic density, extractive content and moisture sorption properties of Pinus pinaster wood.Samples of infected and uninfected wood were studied.The presence of nematodes reduced wood basic density by2 % and decreased the total content of extractives in infected wood as compared with uninfected(5.98 and8.90 % of dry wood mass, respectively). Extractives in infected trees had inverse distribution along the trunk as compared with uninfected trees. The adsorption isotherms for infected and uninfected wood had similar positioning.We recorded differences(some statistically significant) in the equilibrium moisture content of infected and uninfected wood under varying environmental conditions. Despite the verified differences in wood basic density, extractive content and moisture sorption properties, the overall conclusion is that the PWN had a slight impact on these characteristics of wood.展开更多
Grey brick is a key material in Chinese traditional architecture. The isothermal sorption curve of grey bricks is one of the basic moisture characteristics for studying the heat transfer of brick building enclosure st...Grey brick is a key material in Chinese traditional architecture. The isothermal sorption curve of grey bricks is one of the basic moisture characteristics for studying the heat transfer of brick building enclosure structures and is also a fundamental parameter of research into the degradation mechanisms of Chinese traditional architecture. In this study, we measure the isothermal sorption curves of Wujiang (Suzhou, China) bricks from the 1980s and the late Qing period, by applying constant relative humidity controlled by saturated salt-water solutions under isothermal conditions. We then present their fitting formulas for humidity bound ranges of 5-92%. The results indicate that samples of the same-area traditional Suzhou grey bricks from different time periods show relatively large differences in their isothermal sorption properties, with the isothermal sorption property values of the late Qing grey bricks about three times those of the 1980s grey bricks.展开更多
In order to investigate the shrinking and swelling behavior of wood at a non-equilibrium state, the moisture sorptlon processes of wood under constant and changing conditions were studied. For the static sorption expe...In order to investigate the shrinking and swelling behavior of wood at a non-equilibrium state, the moisture sorptlon processes of wood under constant and changing conditions were studied. For the static sorption experiment, Chinese fir (Cunninghamia lanceolata) specimens were subjected to the adsorption processes at 25℃, 10 different relative humidity environments and the moisture contents were measured at distinct time intervals of adsorption processes. For the dynamic sorption experiment, the specimens were exposed to periodically and linearly varying relative humidity between 45% and 75% at 25℃. Moisture content as well as radial and tangential dimensional changes in response to the changing relative humidity were measured. The main results from the experiments indicated that: the moisture sorption isotherms of Chinese fir at equilibrium state and different stages of adsorption processes could be characterized by S-shape curves. From the non-equilibrium state to the equilibrium state, the sigmoid moisture sorption isotherms changed from smooth, gradually increasing values to a steep rise at 100% humidity. Furthermore, under dynamic conditions with a constant temperature and a linearly and periodically varying relative humidity, the moisture content as well as radial and tangential dimensional changes of the specimens generally waved but lagged behind the relative humidity change.展开更多
Moisture sorption isotherms and thermodynamic properties of Camellia oleifera seeds as influenced by oil content were investigated.Moisture desorption and adsorption isotherms of Camellia oleifera seeds,kernels and sh...Moisture sorption isotherms and thermodynamic properties of Camellia oleifera seeds as influenced by oil content were investigated.Moisture desorption and adsorption isotherms of Camellia oleifera seeds,kernels and shells from three varieties were determined using constant temperature and humidity chamber method at different temperatures(10°C,25°C,and 40°C)with water activity ranging from 0.20 to 0.90.Six selected mathematic models were employed to fit the experimental data.The Peleg model gave the best results for both seeds and kernels and Langmuir model was the best for shells.The difference of equilibrium moisture contents at the same water activities during desorption and adsorption indicated the occurrence of hysteresis of adsorption processes and the equilibrium moisture contents tended to decrease with the increasing oil content and temperature.The binding energy and average capacity per unit mass decreased with increasing temperature and oil content.The relationships between water activity and the logarithm of sorption activity showed the capillary porous body characteristics of the seeds.展开更多
In our context, and in the goal to valorize the Pistacia atlantica species Desfthat grows spontaneously in Algeria occidental except the coastline, and that is used by the nomadic populations in their daily consumptio...In our context, and in the goal to valorize the Pistacia atlantica species Desfthat grows spontaneously in Algeria occidental except the coastline, and that is used by the nomadic populations in their daily consumptions, we are thinking about drying its leaves. Here, the biochemical analysis of dried leaves ofPistacia atlantica is determined, the sorption is other ms are of great importance in the food industry, especially in the drying; the sorption isotherms of pistachio leaves were measured by the gravimetric method at three temperatures 40, 50 and 60 ℃. The equilibrium was achieved after eight days for desorption and seven days for adsorption with water activity ranging from 5% to 90%. Only the GAB and Peleg models were found to be the most suitable for describing the sorption curves. The isosteric heat of sorption of Pistacia atlantica leaves decreases with an increase in moisture content and was found to be an exponential function of moisture content for adsorption and desorption. The pistachio leaves could be considered as a rich natural source of valuable nutriments (carbohydrates, proteins and lipids); lipid fraction is equal to 2.25%; proteins are the second macronutriment that predominates in these sheets: 4.35%; accordingly carbohydrates content was about 25.77%.展开更多
文摘Equilibrium moisture contents (EMC) of wood species are very necessary in the utilization of these in service. This study investigated the EMC of five lesser utilized species of Ghana and compared it with that of three European species. Sixteen randomly sampled specimens of each of the eight species (heartwood and sapwood) with dimensions 3 cm × 3 cm × 3 cm were exposed at various relative humidity conditions of 30%, 45%, 60%, 75% and 90% in a temperature and humidity-controlled climate chamber at a temperature of 25°C in accordance to German standard DIN 52182. The species are Albies alba, Fagus sylvatica and Picea abies which are European species and Amphimas pterocarpoides, Antiaris toxicaria, Canarium schweinfurthii, Celtis zenkeri and Cola gigantea are wood species from Ghana. Internal wood temperature and humidity were measured with datalogger. Samples were considered to have reached equilibrium at any given humidity when the daily weight changes were less than 0.1 mg according to German standard DIN 52183. After the last measurements of the weight changes, the samples were dried at 103°C until there was a constant weight. The five tropical hardwoods had low sorption values recorded and high sorption values for the European species and this could be attributed to differences in the microstructure of these woods.
文摘Dehydrated sorghum flour ("ogi") is useful as additional ingredient in certain food and pharmaceutical formulation, this could be obtained by soaking sorghum in water for 3 to 4 days, wet milling the soaked material, and fermentation for another 3 to 4 days. Typically, the fermented product is boiled into a pap or cooked into a stiff porridge. However, the fermented product can not be easily handled or stored and does not have a long shelf life (typically less than a week). Dehydrating the fermented product into flour is one of the ways that is being employed to overcome these problems. Equilibrium moisture content (EMC) of dehydrated sorghum flour (aka "ogi") was therefore determined at two temperatures of 25℃ and 40℃ and four salt solutions. Zinc chloride (ZnCl2), potassium acetate (KC2H3O2), calcium chloride (CaCl2) and sodium chloride (NaCl) salts were prepared to correspond to equilibrium relative humidities of 10.0% to 75.4%. The moisture sorption characteristics of the sorghum product showed the characteristics S-shaped sorption isotherm curve that is typically obtained for agricultural products. The equilibrium data and the monomolccular layer moisture content values were estimated using the Brunauer-Emmett-Teller (BET) equation. The moisture content range for optimum storage of the dehydrated sorghum flour lies between 2.84% to 3.69% at 25℃ and 6.84% and 7.67% at 40℃. The information obtained from this study will help in the design and selection of storage and packaging systems for dehydrated sorghum flour.
基金supported by Grant No.SFRH/BPD/40135/2008 Funded by FCT(POPH-QREN-Typology 4.1,FCI and MEC)
文摘The pinewood nematode(PWN), Bursaphelenchus xylophilus, has become one of the most severe threats to pine forest worldwide. Nematodes, migrating through resin canals and feeding on the living cells, induce rapid metabolic changes in ray parenchyma cells, create cavitation areas, decrease xylem water content and oleoresin exudation, and cause necrosis of parenchyma and cambial cells. This study focused on the impact of PWN infection on technological parameters of wood and evaluated the impact of anatomic and biochemical incidences of tree defense reactions on basic density, extractive content and moisture sorption properties of Pinus pinaster wood.Samples of infected and uninfected wood were studied.The presence of nematodes reduced wood basic density by2 % and decreased the total content of extractives in infected wood as compared with uninfected(5.98 and8.90 % of dry wood mass, respectively). Extractives in infected trees had inverse distribution along the trunk as compared with uninfected trees. The adsorption isotherms for infected and uninfected wood had similar positioning.We recorded differences(some statistically significant) in the equilibrium moisture content of infected and uninfected wood under varying environmental conditions. Despite the verified differences in wood basic density, extractive content and moisture sorption properties, the overall conclusion is that the PWN had a slight impact on these characteristics of wood.
基金Acknowledgement This study was supported by the National Science Foundation of China (Grant nos. 51108072, 51138002). This work was also supported by the Specialized Research Fund for Overseas Returned People Programme of the Ministry of Personnel of the People's Republic of China (No.6701000016).
文摘Grey brick is a key material in Chinese traditional architecture. The isothermal sorption curve of grey bricks is one of the basic moisture characteristics for studying the heat transfer of brick building enclosure structures and is also a fundamental parameter of research into the degradation mechanisms of Chinese traditional architecture. In this study, we measure the isothermal sorption curves of Wujiang (Suzhou, China) bricks from the 1980s and the late Qing period, by applying constant relative humidity controlled by saturated salt-water solutions under isothermal conditions. We then present their fitting formulas for humidity bound ranges of 5-92%. The results indicate that samples of the same-area traditional Suzhou grey bricks from different time periods show relatively large differences in their isothermal sorption properties, with the isothermal sorption property values of the late Qing grey bricks about three times those of the 1980s grey bricks.
文摘In order to investigate the shrinking and swelling behavior of wood at a non-equilibrium state, the moisture sorptlon processes of wood under constant and changing conditions were studied. For the static sorption experiment, Chinese fir (Cunninghamia lanceolata) specimens were subjected to the adsorption processes at 25℃, 10 different relative humidity environments and the moisture contents were measured at distinct time intervals of adsorption processes. For the dynamic sorption experiment, the specimens were exposed to periodically and linearly varying relative humidity between 45% and 75% at 25℃. Moisture content as well as radial and tangential dimensional changes in response to the changing relative humidity were measured. The main results from the experiments indicated that: the moisture sorption isotherms of Chinese fir at equilibrium state and different stages of adsorption processes could be characterized by S-shape curves. From the non-equilibrium state to the equilibrium state, the sigmoid moisture sorption isotherms changed from smooth, gradually increasing values to a steep rise at 100% humidity. Furthermore, under dynamic conditions with a constant temperature and a linearly and periodically varying relative humidity, the moisture content as well as radial and tangential dimensional changes of the specimens generally waved but lagged behind the relative humidity change.
基金The authors acknowledge that this work was financially supported by the Gannan Oil Tea Camellia Industry Collaborative Innovation Center(Grant No.YP201610).
文摘Moisture sorption isotherms and thermodynamic properties of Camellia oleifera seeds as influenced by oil content were investigated.Moisture desorption and adsorption isotherms of Camellia oleifera seeds,kernels and shells from three varieties were determined using constant temperature and humidity chamber method at different temperatures(10°C,25°C,and 40°C)with water activity ranging from 0.20 to 0.90.Six selected mathematic models were employed to fit the experimental data.The Peleg model gave the best results for both seeds and kernels and Langmuir model was the best for shells.The difference of equilibrium moisture contents at the same water activities during desorption and adsorption indicated the occurrence of hysteresis of adsorption processes and the equilibrium moisture contents tended to decrease with the increasing oil content and temperature.The binding energy and average capacity per unit mass decreased with increasing temperature and oil content.The relationships between water activity and the logarithm of sorption activity showed the capillary porous body characteristics of the seeds.
文摘In our context, and in the goal to valorize the Pistacia atlantica species Desfthat grows spontaneously in Algeria occidental except the coastline, and that is used by the nomadic populations in their daily consumptions, we are thinking about drying its leaves. Here, the biochemical analysis of dried leaves ofPistacia atlantica is determined, the sorption is other ms are of great importance in the food industry, especially in the drying; the sorption isotherms of pistachio leaves were measured by the gravimetric method at three temperatures 40, 50 and 60 ℃. The equilibrium was achieved after eight days for desorption and seven days for adsorption with water activity ranging from 5% to 90%. Only the GAB and Peleg models were found to be the most suitable for describing the sorption curves. The isosteric heat of sorption of Pistacia atlantica leaves decreases with an increase in moisture content and was found to be an exponential function of moisture content for adsorption and desorption. The pistachio leaves could be considered as a rich natural source of valuable nutriments (carbohydrates, proteins and lipids); lipid fraction is equal to 2.25%; proteins are the second macronutriment that predominates in these sheets: 4.35%; accordingly carbohydrates content was about 25.77%.