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The Equilibrium Moisture Content of Five Lesser Utilized Species of Ghana Contrasted with Three European Species
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作者 Gladys A. Quartey John Frank Eshun Emmanual Yaw Wereko 《Open Journal of Composite Materials》 2022年第2期73-81,共9页
Equilibrium moisture contents (EMC) of wood species are very necessary in the utilization of these in service. This study investigated the EMC of five lesser utilized species of Ghana and compared it with that of thre... Equilibrium moisture contents (EMC) of wood species are very necessary in the utilization of these in service. This study investigated the EMC of five lesser utilized species of Ghana and compared it with that of three European species. Sixteen randomly sampled specimens of each of the eight species (heartwood and sapwood) with dimensions 3 cm × 3 cm × 3 cm were exposed at various relative humidity conditions of 30%, 45%, 60%, 75% and 90% in a temperature and humidity-controlled climate chamber at a temperature of 25&deg;C in accordance to German standard DIN 52182. The species are Albies alba, Fagus sylvatica and Picea abies which are European species and Amphimas pterocarpoides, Antiaris toxicaria, Canarium schweinfurthii, Celtis zenkeri and Cola gigantea are wood species from Ghana. Internal wood temperature and humidity were measured with datalogger. Samples were considered to have reached equilibrium at any given humidity when the daily weight changes were less than 0.1 mg according to German standard DIN 52183. After the last measurements of the weight changes, the samples were dried at 103&deg;C until there was a constant weight. The five tropical hardwoods had low sorption values recorded and high sorption values for the European species and this could be attributed to differences in the microstructure of these woods. 展开更多
关键词 Albies alba Fagus sylvatica Picea abies equilibrium moisture content Amphimas pterocarpoides Antiaris toxicaria Canarium schweinfurthii Lesser Utilized Hardwood Species
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Determination of Moisture Sorption Isotherm Characteristics of Dehydrated Sorghum Flour ("Ogi")
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作者 Ajiboye Solomon Oyerinde 《Journal of Agricultural Science and Technology(B)》 2013年第2期86-91,共6页
Dehydrated sorghum flour ("ogi") is useful as additional ingredient in certain food and pharmaceutical formulation, this could be obtained by soaking sorghum in water for 3 to 4 days, wet milling the soaked materi... Dehydrated sorghum flour ("ogi") is useful as additional ingredient in certain food and pharmaceutical formulation, this could be obtained by soaking sorghum in water for 3 to 4 days, wet milling the soaked material, and fermentation for another 3 to 4 days. Typically, the fermented product is boiled into a pap or cooked into a stiff porridge. However, the fermented product can not be easily handled or stored and does not have a long shelf life (typically less than a week). Dehydrating the fermented product into flour is one of the ways that is being employed to overcome these problems. Equilibrium moisture content (EMC) of dehydrated sorghum flour (aka "ogi") was therefore determined at two temperatures of 25℃ and 40℃ and four salt solutions. Zinc chloride (ZnCl2), potassium acetate (KC2H3O2), calcium chloride (CaCl2) and sodium chloride (NaCl) salts were prepared to correspond to equilibrium relative humidities of 10.0% to 75.4%. The moisture sorption characteristics of the sorghum product showed the characteristics S-shaped sorption isotherm curve that is typically obtained for agricultural products. The equilibrium data and the monomolccular layer moisture content values were estimated using the Brunauer-Emmett-Teller (BET) equation. The moisture content range for optimum storage of the dehydrated sorghum flour lies between 2.84% to 3.69% at 25℃ and 6.84% and 7.67% at 40℃. The information obtained from this study will help in the design and selection of storage and packaging systems for dehydrated sorghum flour. 展开更多
关键词 moisture adsorption sorghum flour equilibrium moisture content moisture isotherm storage stability
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Basic density, extractive content and moisture sorption properties of Pinus pinaster wood infected with the pinewood nematode, Bursaphelenchus xylophilus 被引量:1
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作者 Valeria Reva Luís Fonseca +3 位作者 José L.Lousada Isabel Abrantes António R.Figueiredo Domingos X.Viegas 《Journal of Forestry Research》 SCIE CAS CSCD 2015年第1期233-240,共8页
The pinewood nematode(PWN), Bursaphelenchus xylophilus, has become one of the most severe threats to pine forest worldwide. Nematodes, migrating through resin canals and feeding on the living cells, induce rapid met... The pinewood nematode(PWN), Bursaphelenchus xylophilus, has become one of the most severe threats to pine forest worldwide. Nematodes, migrating through resin canals and feeding on the living cells, induce rapid metabolic changes in ray parenchyma cells, create cavitation areas, decrease xylem water content and oleoresin exudation, and cause necrosis of parenchyma and cambial cells. This study focused on the impact of PWN infection on technological parameters of wood and evaluated the impact of anatomic and biochemical incidences of tree defense reactions on basic density, extractive content and moisture sorption properties of Pinus pinaster wood.Samples of infected and uninfected wood were studied.The presence of nematodes reduced wood basic density by2 % and decreased the total content of extractives in infected wood as compared with uninfected(5.98 and8.90 % of dry wood mass, respectively). Extractives in infected trees had inverse distribution along the trunk as compared with uninfected trees. The adsorption isotherms for infected and uninfected wood had similar positioning.We recorded differences(some statistically significant) in the equilibrium moisture content of infected and uninfected wood under varying environmental conditions. Despite the verified differences in wood basic density, extractive content and moisture sorption properties, the overall conclusion is that the PWN had a slight impact on these characteristics of wood. 展开更多
关键词 Pinewood nematode Wood density Extractives equilibrium moisture content Economic impact
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Experimental study of the isothermal sorption properties of late Qing and 1980s grey bricks in Wujiang, Suzhou, China 被引量:1
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作者 Yonghui Li Huarong Xie Jianguo Wang Xinjian Li 《Frontiers of Architectural Research》 CSCD 2013年第4期483-487,共5页
Grey brick is a key material in Chinese traditional architecture. The isothermal sorption curve of grey bricks is one of the basic moisture characteristics for studying the heat transfer of brick building enclosure st... Grey brick is a key material in Chinese traditional architecture. The isothermal sorption curve of grey bricks is one of the basic moisture characteristics for studying the heat transfer of brick building enclosure structures and is also a fundamental parameter of research into the degradation mechanisms of Chinese traditional architecture. In this study, we measure the isothermal sorption curves of Wujiang (Suzhou, China) bricks from the 1980s and the late Qing period, by applying constant relative humidity controlled by saturated salt-water solutions under isothermal conditions. We then present their fitting formulas for humidity bound ranges of 5-92%. The results indicate that samples of the same-area traditional Suzhou grey bricks from different time periods show relatively large differences in their isothermal sorption properties, with the isothermal sorption property values of the late Qing grey bricks about three times those of the 1980s grey bricks. 展开更多
关键词 Grey brick Periods equilibrium moisture content isothermal sorption SUZHOU
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Hygroexpansion of Wood during Moisture Adsorption and Desorption Processes 被引量:3
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作者 Ma Er-ni Zhao Guang-jie Cao Jin-zhen 《Forestry Studies in China》 CAS 2005年第2期43-46,共4页
In order to investigate the shrinking and swelling behavior of wood at a non-equilibrium state, the moisture sorptlon processes of wood under constant and changing conditions were studied. For the static sorption expe... In order to investigate the shrinking and swelling behavior of wood at a non-equilibrium state, the moisture sorptlon processes of wood under constant and changing conditions were studied. For the static sorption experiment, Chinese fir (Cunninghamia lanceolata) specimens were subjected to the adsorption processes at 25℃, 10 different relative humidity environments and the moisture contents were measured at distinct time intervals of adsorption processes. For the dynamic sorption experiment, the specimens were exposed to periodically and linearly varying relative humidity between 45% and 75% at 25℃. Moisture content as well as radial and tangential dimensional changes in response to the changing relative humidity were measured. The main results from the experiments indicated that: the moisture sorption isotherms of Chinese fir at equilibrium state and different stages of adsorption processes could be characterized by S-shape curves. From the non-equilibrium state to the equilibrium state, the sigmoid moisture sorption isotherms changed from smooth, gradually increasing values to a steep rise at 100% humidity. Furthermore, under dynamic conditions with a constant temperature and a linearly and periodically varying relative humidity, the moisture content as well as radial and tangential dimensional changes of the specimens generally waved but lagged behind the relative humidity change. 展开更多
关键词 WOOD moisture content non-equilibrium state relative humidity hygroexpansion
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初烤烟叶主脉与叶片的吸附等温线及其热力学性质研究 被引量:1
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作者 陈卓 陈家鼎 +5 位作者 毛岚 白涛 李生栋 王涛 宋朝鹏 张豹林 《河南农业科学》 北大核心 2024年第4期143-151,共9页
为探究初烤烟叶主脉与叶片在吸湿过程中所表现出的水分吸附特性,测定初烤烟叶主脉与叶片在环境温度20、25、30、35、40℃以及环境相对湿度50%、60%、70%、80%、90%下的吸湿情况,绘制初烤烟叶主脉与叶片的吸附等温线,采用5种常用的农产... 为探究初烤烟叶主脉与叶片在吸湿过程中所表现出的水分吸附特性,测定初烤烟叶主脉与叶片在环境温度20、25、30、35、40℃以及环境相对湿度50%、60%、70%、80%、90%下的吸湿情况,绘制初烤烟叶主脉与叶片的吸附等温线,采用5种常用的农产品吸附等温线模型对试验数据进行拟合,并在此基础上探究初烤烟叶主脉与叶片的热力学性质。结果表明,初烤烟叶主脉与叶片的吸附等温线属于Ⅲ型等温线,在环境相对湿度相同的条件下,初烤烟叶主脉与叶片的平衡含水率随环境温度的升高而降低。MHAE模型是描述初烤烟叶主脉与叶片吸附等温线的最佳模型,决定系数(R^(2))为0.99877~0.99905,平均相对百分率误差(MRE)为1.45515%~2.94968%。热力学性质研究结果表明,在平衡含水率发生变化时,初烤烟叶主脉与叶片的净等量吸附热(Q_(st))与微分吸附熵(ΔS)有相似的变化趋势,均随平衡含水率的升高而下降,且两者与温度之间都没有明显关系。在初烤烟叶主脉与叶片的水分吸附过程中,熵-焓补偿理论也同样存在并适用,并且水分吸附过程是自发的由焓所驱动的反应。综上,初烤烟叶主脉与叶片在水分吸附过程中的热力学性质较为相似,MHAE模型适合用来描述初烤烟叶主脉与叶片在温度20~40℃的吸附等温线。 展开更多
关键词 初烤烟叶 含水率 吸附等温线 数学模型 热力学性质
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高压注入条件下N_(2)对含水煤中CH_(4)置换效应的影响
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作者 陈立伟 严越涵 +2 位作者 赵明振 杨宏民 刘媛 《煤矿现代化》 2024年第1期43-47,51,共6页
为了揭示高压注入条件下N_(2)对不同含水率煤中CH_(4)置换效应影响,基于含水率为0.75%、1.5%和3%的3种煤样,开展了高压注N_(2)置换CH_(4)实验。实验结果表明:随着煤含水率的增加,煤吸附CH_(4)和N_(2)的能力表现出逐渐减弱的趋势,N_(2)... 为了揭示高压注入条件下N_(2)对不同含水率煤中CH_(4)置换效应影响,基于含水率为0.75%、1.5%和3%的3种煤样,开展了高压注N_(2)置换CH_(4)实验。实验结果表明:随着煤含水率的增加,煤吸附CH_(4)和N_(2)的能力表现出逐渐减弱的趋势,N_(2)的吸附量始终小于CH_(4)的吸附量,且N_(2)置换CH_(4)的能力逐步下降;在本实验压力条件下,CH_(4)预吸附平衡压力超出0.75 MPa越大,其N_(2)利用率越低。同时随煤含水量的增加,CH_(4)置换率、N_(2)注置比均出现逐步减小的趋势,因此可得CH_(4)置换率、N_(2)注置比均与煤的含水量呈负相关关系。实验含水煤样更好的还原井下处于潮湿环境中的原煤,通过CH_(4)置换率和N_(2)注置比的反馈得出,过大的注气压力并不能得到良好的注气效果,反而会降低该置换源气体的利用率,因此对井下注N_(2)置换煤层CH_(4)的工程技术来说,为避免盲目提高注气压力而造成N_(2)的置换效率下降的现象,建议井下煤层注N_(2)置换CH_(4)时,CH_(4)吸附平衡压力控制在0.75 MPa最佳。 展开更多
关键词 高压注入 煤的含水率 CH_(4)预吸附平衡压力 CH_(4)置换率 N_(2)注置比
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温度影响下不同级配生土材料吸湿性能的研究
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作者 冯梅瑾 穆钧 于沈尉 《建筑节能(中英文)》 CAS 2024年第9期30-37,共8页
采用饱和盐溶液法,研究了9种级配生土材料在不同温湿度环境下的吸湿性能。研究结果表明,当环境温度在10~30℃之间时,生土材料的平衡含湿量随着温度的升高呈现出先增大后降低的趋势,在20~25℃区间内平衡含湿量达到最大。低温环境下,级配... 采用饱和盐溶液法,研究了9种级配生土材料在不同温湿度环境下的吸湿性能。研究结果表明,当环境温度在10~30℃之间时,生土材料的平衡含湿量随着温度的升高呈现出先增大后降低的趋势,在20~25℃区间内平衡含湿量达到最大。低温环境下,级配对生土材料吸湿量的影响相对较小,吸湿速率相对较慢。当土、沙、石比例为28∶67∶6时,生土材料吸湿性能相对较差(最大平衡含湿量约为2.66%);而当土、沙、石比例为45∶13∶42时,生土材料吸湿性能相对较好(最大平衡含湿量约为3.95%)。由此可见,小粒径成分含量高的生土材料展现出更好的吸湿性能。此外,采用数据拟合的方法对不同吸湿性能预测模型进行分析,最终修正了温度因子对预估数值的影响,且修正系数与温度之间符合二次函数关系α=-0.0656t2+0.4185t+0.3033,相关性系数高达0.9354。上述结论为生土材料平衡环境温湿度性能的量化计算提供了科学便捷的方法。 展开更多
关键词 生土材料 粒径构成 平衡含湿量 吸湿速率
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公路膨胀土路堤膨胀变形预测方法
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作者 陈亮胜 《内蒙古公路与运输》 2024年第5期23-27,62,共6页
为保证运营期包边膨胀土路基的长期稳定,对膨胀土路堤填筑后产生的膨胀变形进行预估。利用非饱和土的湿热耦合理论,构建了膨胀土路堤湿度变化的计算方法;根据膨胀土的侧限膨胀试验,推导出了考虑现在应力状态和将来应力状态的膨胀变形的... 为保证运营期包边膨胀土路基的长期稳定,对膨胀土路堤填筑后产生的膨胀变形进行预估。利用非饱和土的湿热耦合理论,构建了膨胀土路堤湿度变化的计算方法;根据膨胀土的侧限膨胀试验,推导出了考虑现在应力状态和将来应力状态的膨胀变形的预估模型;依托实际工程研究了大气作用下公路膨胀土路基湿度的变化规律,对膨胀土填料的平衡含水率和膨胀变形进行了计算。结果表明:膨胀土路基的平衡含水率仅与当地的气候条件以及地下水位有关,与初始压实控制含水率无关;在初始干密度不变的情况下,膨胀土的膨胀系数随初始含水率的增大而增大;填筑膨胀土路基时,应尽量采用路基平衡含水率作为路基的填筑控制含水率。研究成果可为膨胀土路堤填筑技术提供理论参考。 展开更多
关键词 膨胀土路基 膨胀变形 湿热耦合理论 平衡含水率
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Moisture sorption and thermodynamic properties of Camellia oleifera seeds as influenced by oil content 被引量:1
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作者 Guangfei Zhu Qi Jin +3 位作者 Yanhong Liu Yawen Lin Jun Wang Xingyi Li 《International Journal of Agricultural and Biological Engineering》 SCIE EI CAS 2021年第1期251-258,共8页
Moisture sorption isotherms and thermodynamic properties of Camellia oleifera seeds as influenced by oil content were investigated.Moisture desorption and adsorption isotherms of Camellia oleifera seeds,kernels and sh... Moisture sorption isotherms and thermodynamic properties of Camellia oleifera seeds as influenced by oil content were investigated.Moisture desorption and adsorption isotherms of Camellia oleifera seeds,kernels and shells from three varieties were determined using constant temperature and humidity chamber method at different temperatures(10°C,25°C,and 40°C)with water activity ranging from 0.20 to 0.90.Six selected mathematic models were employed to fit the experimental data.The Peleg model gave the best results for both seeds and kernels and Langmuir model was the best for shells.The difference of equilibrium moisture contents at the same water activities during desorption and adsorption indicated the occurrence of hysteresis of adsorption processes and the equilibrium moisture contents tended to decrease with the increasing oil content and temperature.The binding energy and average capacity per unit mass decreased with increasing temperature and oil content.The relationships between water activity and the logarithm of sorption activity showed the capillary porous body characteristics of the seeds. 展开更多
关键词 Camellia oleifera seeds moisture desorption and adsorption isotherms equilibrium moisture content oil content thermodynamic property
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Conservation of Leaves of a Medicinal Plant of Western Algeria (Pistacia atlantica)
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作者 Abdenbi Asma Touati Boumediene +2 位作者 Bouaaza Mohammed Dennai Brahim Saad Amel 《Journal of Food Science and Engineering》 2014年第2期96-106,共11页
In our context, and in the goal to valorize the Pistacia atlantica species Desfthat grows spontaneously in Algeria occidental except the coastline, and that is used by the nomadic populations in their daily consumptio... In our context, and in the goal to valorize the Pistacia atlantica species Desfthat grows spontaneously in Algeria occidental except the coastline, and that is used by the nomadic populations in their daily consumptions, we are thinking about drying its leaves. Here, the biochemical analysis of dried leaves ofPistacia atlantica is determined, the sorption is other ms are of great importance in the food industry, especially in the drying; the sorption isotherms of pistachio leaves were measured by the gravimetric method at three temperatures 40, 50 and 60 ℃. The equilibrium was achieved after eight days for desorption and seven days for adsorption with water activity ranging from 5% to 90%. Only the GAB and Peleg models were found to be the most suitable for describing the sorption curves. The isosteric heat of sorption of Pistacia atlantica leaves decreases with an increase in moisture content and was found to be an exponential function of moisture content for adsorption and desorption. The pistachio leaves could be considered as a rich natural source of valuable nutriments (carbohydrates, proteins and lipids); lipid fraction is equal to 2.25%; proteins are the second macronutriment that predominates in these sheets: 4.35%; accordingly carbohydrates content was about 25.77%. 展开更多
关键词 Pistacia atlantica leaves equilibrium moisture content sorption isotherms MODELING isosteric heat of sorption biochemical analysis.
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干制荔枝果肉吸附等温线及热力学性质 被引量:18
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作者 李辉 林河通 +2 位作者 林毅雄 袁芳 林福兴 《农业工程学报》 EI CAS CSCD 北大核心 2014年第22期309-315,共7页
为了解干制“乌叶”荔枝果肉含水率与水分活度、贮藏温度之间的复杂关系,并为干制“乌叶”荔枝果肉贮藏条件的确定提供技术依据,运用吸附原理,在水分活度为0.112~0.976范围内,研究了干制“乌叶”荔枝果肉在20、30和40℃时的水分吸... 为了解干制“乌叶”荔枝果肉含水率与水分活度、贮藏温度之间的复杂关系,并为干制“乌叶”荔枝果肉贮藏条件的确定提供技术依据,运用吸附原理,在水分活度为0.112~0.976范围内,研究了干制“乌叶”荔枝果肉在20、30和40℃时的水分吸附等温线;采用8种模型对试验数据进行拟合,通过比较模型决定系数(R2)和均方根误差确定用于描述干制“乌叶”荔枝果肉吸附等温线的最适模型;通过不同温度下干制“乌叶”荔枝果肉的吸附等温线数据获得净等量吸附热、焓变、熵变和自由能等热力学性质。结果表明,干制“乌叶”荔枝果肉的水分吸附呈Ⅲ型等温线,在相同水分活度时,平衡含水率随温度的升高而下降。Peleg模型用于描述吸附等温线是较适合的,决定系数为R2为0.9950~0.9979,均方根误差为1.9431~2.7102。热力学性质显示,净等量吸附热随含水率的增加而降低,在较高含水率时趋近于0。焓变与净等量吸附热有相同的值,其范围为0.95~186.98 kJ/mol。熵变随含水率的增加而降低,并没有表现出对温度的依赖性。自由能随含水率和温度的增加而减小。焓-熵补偿理论适用于干制“乌叶”荔枝果肉中的水分吸附过程,此水分吸附过程是焓驱动的。研究结果为干制“乌叶”荔枝果肉的加工和贮藏稳定性提供理论依据。 展开更多
关键词 贮藏 吸附 热力学性质 荔枝 果肉 等温线 平衡含水率 LITCHI (Litchi CHINENSIS Sonn.)
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特高煤级煤平衡水条件下的吸附实验 被引量:30
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作者 傅雪海 秦勇 +2 位作者 李贵中 徐磊 胡超 《石油实验地质》 CAS CSCD 2002年第2期177-180,共4页
鉴于国内外对镜质组最大反射率Ro(max)大于4.0%的特高煤级煤的吸附特性研究的空白,作者系统地采集了12个Ro(max)>4.0%的煤样进行了平衡水条件下的高压等温吸附实验,分析了特高煤级煤样的朗格缪尔常数与Ro(max)、显微煤岩组分、比孔... 鉴于国内外对镜质组最大反射率Ro(max)大于4.0%的特高煤级煤的吸附特性研究的空白,作者系统地采集了12个Ro(max)>4.0%的煤样进行了平衡水条件下的高压等温吸附实验,分析了特高煤级煤样的朗格缪尔常数与Ro(max)、显微煤岩组分、比孔容和比表面积的关系,发现了煤的朗格缪尔体积随煤级变化的拐点是在Ro(max)为4.5%左右。在上述研究的基础上,文中探讨了煤的吸附特征及机理。 展开更多
关键词 特高煤级煤 平衡水条件 吸附实验 显微组分 等温吸附 镜质 两淮煤田 沁水煤田
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小麦的平衡水分与吸着热研究 被引量:19
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作者 李兴军 王双林 +2 位作者 王金水 韦志彦 曹志洋 《河南工业大学学报(自然科学版)》 CAS 北大核心 2009年第3期1-6,共6页
在10-35℃、RH11.3%-96%的温湿度范围内,采用静态平衡称重法对软麦和硬麦的吸附与解吸平衡水分进行了测定.小麦的平衡水分在一定相对湿度下随温度的增加而减少,解吸与吸附等温线之间存在滞后现象.采用6个非线性回归方程描述吸着... 在10-35℃、RH11.3%-96%的温湿度范围内,采用静态平衡称重法对软麦和硬麦的吸附与解吸平衡水分进行了测定.小麦的平衡水分在一定相对湿度下随温度的增加而减少,解吸与吸附等温线之间存在滞后现象.采用6个非线性回归方程描述吸着(吸附/解吸)等温线,其中MOE、MCPE及修正BET方程分别在ERH11.3%-96%、11.3%-96%及11.3%-49.9%范围内适合描述小麦等温线.硬麦(陇塬2号、南段1号)的吸湿特性与软麦(赵庄2号、鲁麦1号)的差异很小.从不同温度下的ERH/EMC数据所计算的水分吸附等热和解吸等热,均随着EMC增加而减少. 展开更多
关键词 平衡水分含量 小麦 吸着等温线 数学模型 吸着等热 干燥
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玉米平衡水分测定及等温线方程确定 被引量:10
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作者 王双林 郭道林 +2 位作者 李兴军 陈兰 栾霞 《中国粮油学报》 EI CAS CSCD 北大核心 2010年第11期33-36,47,共5页
采用静态称重法对6个玉米品种的吸附/解吸等温线进行测定,并用6个非线性回归方程描述吸附/解吸等温线,修正Chung-Pfost方程(MCPE)、修正Henderson方程(MHE)、修正Oswin方程(MOE)及Strohman-Yoerger方程(STYE)均在ERH 11.3%~96%范围内... 采用静态称重法对6个玉米品种的吸附/解吸等温线进行测定,并用6个非线性回归方程描述吸附/解吸等温线,修正Chung-Pfost方程(MCPE)、修正Henderson方程(MHE)、修正Oswin方程(MOE)及Strohman-Yoerger方程(STYE)均在ERH 11.3%~96%范围内适合描述玉米等温线,其中最佳数学模型是MCPE,以M=f(ERH,t)形式表达的M=-1/C3×ln[-1/C1×(t+C2)ln(ERH)],C1、C2及C3参数对吸附数据分别是863.159、108.443及0.216,对解吸数据分别是581.393、35.840、0.235,平均数据是655.792、59.035、0.225。分析MCPE方程预测的6个玉米品种解吸或吸附等温线之间的差异,6个品种解吸等温线之间有差异,但是6个品种吸附等温线之间没有差异。解吸与吸附等温线之间存在滞后现象。 展开更多
关键词 平衡水分 玉米 吸附 解吸 等温线
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采用水分解吸方程估算我国稻谷安全水分 被引量:8
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作者 李兴军 刘丁 +2 位作者 王双林 秦文 李爱科 《中国粮油学报》 EI CAS CSCD 北大核心 2011年第4期81-84,共4页
对静态称重法测定的我国稻谷主产区15个品种(包括3个粳稻、10个籼稻、2个糯稻)的解吸等温线数据,分别采用Brunauer-Emmett-Teller(BET)、Guggenhein-Anderson-de Boer(GAB)、修正Chung-Pfost(MCPE)、修正Henderson(MHE)、修正... 对静态称重法测定的我国稻谷主产区15个品种(包括3个粳稻、10个籼稻、2个糯稻)的解吸等温线数据,分别采用Brunauer-Emmett-Teller(BET)、Guggenhein-Anderson-de Boer(GAB)、修正Chung-Pfost(MCPE)、修正Henderson(MHE)、修正Oswin(MOE)及Strohman-Yoerger(STYE)6个数学模型进行拟合,MCPE被判定为稻谷最佳解吸等温线模型。稻谷的解吸特性受产地影响较小。以M=f(hr,t)形式表达的平均解吸等温线方程MCPE的3个参数C1、C2及C3各是502.485、45.276及0.186。在70%相对湿度下,推导10、15、20、25、30及35℃条件下15个稻谷品种平均解吸值,分别是14.83%、14.49%、14.13%、13.88%、13.61%及13.35%。尤其是在RH 70%、30~35℃条件下,稻谷解吸水分范围是13.61%~13.35%,与规定的稻谷安全储藏水分13.5%近似。 展开更多
关键词 平衡水分 稻谷 解吸 等温线 数学模型 安全储藏水分
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玉米吸湿特性及其等温线类型研究 被引量:14
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作者 李兴军 王双林 +1 位作者 张元娣 秦文 《中国粮油学报》 EI CAS CSCD 北大核心 2012年第1期80-86,96,共8页
对测定的我国16个玉米品种的水分吸着等温线数据,采用9个水分吸着方程进行拟合,并根据修正4-参数Guggenheim-Anderson-de Boer方程(4-MGAB)派生的指标划分等温线类型。结果表明,CAE、修正Chung-Pfost(MCPE)、Strohman-Yoerger(STYE)、Br... 对测定的我国16个玉米品种的水分吸着等温线数据,采用9个水分吸着方程进行拟合,并根据修正4-参数Guggenheim-Anderson-de Boer方程(4-MGAB)派生的指标划分等温线类型。结果表明,CAE、修正Chung-Pfost(MCPE)、Strohman-Yoerger(STYE)、Brunauer-Emmett-Teller(BET)、3-MGAB、4-MGAB、修正Henderson(MHE)及修正的Oswin(MOE)方程均适合拟合测定的玉米水分吸着等温线,而Modi-fied Halsey(MHAE)不适合。MCPE和CAE被认为是玉米较佳水分吸着方程,方程参数MCPE的C1和C2、CAE的b1在不同玉米品种之间、黄玉米和白玉米之间差异不明显。但是,同一玉米品种吸附等温线的方程参数不同于解吸等温线的对应方程参数。另外,根据D10、Rfi、awn、X4指标判断玉米水分吸着等温线类型,16个玉米品种的吸附和解吸等温线均属于S型等温线(Ⅱ)。结果表明玉米水分吸附与解吸的MCPE和CAE方程参数可用于玉米收获后干燥及储藏通风操作。 展开更多
关键词 平衡水分 玉米 吸着等温线 数学模型 通风 水分活度
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低煤级煤平衡水条件下的吸附实验 被引量:33
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作者 傅雪海 焦宗福 +2 位作者 秦勇 张万红 韩训晓 《辽宁工程技术大学学报(自然科学版)》 EI CAS 北大核心 2005年第2期161-164,共4页
基于13个镜质组最大反射率小于0.65%的低煤级煤样平衡水条件下的高压等温吸附实验,分析了低煤级煤的朗格缪尔常数与平衡水分、煤级、显微煤岩组分、比孔容和比表面积之间的关系,揭示了低煤级煤的吸附特征与中、高煤级煤之间的差异,探讨... 基于13个镜质组最大反射率小于0.65%的低煤级煤样平衡水条件下的高压等温吸附实验,分析了低煤级煤的朗格缪尔常数与平衡水分、煤级、显微煤岩组分、比孔容和比表面积之间的关系,揭示了低煤级煤的吸附特征与中、高煤级煤之间的差异,探讨了低煤级煤的吸附机理。 展开更多
关键词 低煤级煤 平衡水分 显微组分 等温吸附
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谷物平衡水分研究概况 被引量:37
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作者 李兴军 王双林 王金水 《中国粮油学报》 EI CAS CSCD 北大核心 2009年第11期137-145,共9页
控制吸湿是谷物安全贮藏的基本原则之一,平衡水分测定可用来判断谷物水分变化的趋向。概述了谷物平衡水分测定的原理及数学模型分析,并归纳,发生纳滞后效应的可能理论、影响谷物吸着(包括吸附与解吸)等温线测定的因子,还重点介绍了近年... 控制吸湿是谷物安全贮藏的基本原则之一,平衡水分测定可用来判断谷物水分变化的趋向。概述了谷物平衡水分测定的原理及数学模型分析,并归纳,发生纳滞后效应的可能理论、影响谷物吸着(包括吸附与解吸)等温线测定的因子,还重点介绍了近年发展起来的、利用平衡水分吸附/解吸数据分析谷物及食品的热动力学函数——水分吸着等热。这些研究进展对完善我国储粮生态区域划分、谷物主产区低温干燥、设计干燥程序和设备、谷物及加工产品的包装及货架期皆有意义。 展开更多
关键词 平衡水分 谷物 等温线 滞后效应 干燥 通风 吸着等热
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青豆种子等温线及平衡含水率模型 被引量:7
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作者 朱恩龙 杨昭 +2 位作者 尹海蛟 朱宗升 陈爱强 《天津大学学报》 EI CAS CSCD 北大核心 2012年第5期400-404,共5页
为研究青豆种子的热动力学特性,深入理解青豆吸附过程的水分特性和所需能量变化,利用饱和盐溶液,采用静态称重法测定了青豆种子在20~40,℃和水分活度在0.112~0.946范围的等温线;采用非线性回归方法确定了BET多分子层吸附理论模型的系... 为研究青豆种子的热动力学特性,深入理解青豆吸附过程的水分特性和所需能量变化,利用饱和盐溶液,采用静态称重法测定了青豆种子在20~40,℃和水分活度在0.112~0.946范围的等温线;采用非线性回归方法确定了BET多分子层吸附理论模型的系数,并判定了青豆的吸附与解吸模型的拟合优度;应用Clausius-Clapeyron方程计算了青豆的净等量吸附热.结果表明:吸附与解吸相比存在明显的滞后现象;解吸时单分子层饱和吸附量大于吸附时的数值,随着温度升高青豆的单分子层饱和吸附量下降;吸附层数的变化趋势与单分子层饱和吸附量的相反;在Henderson、修正的Henderson、修正的Chung-Pfost、Halsey、修正的Halsey、修正的Oswin、修正的GAB模型中,Halsey模型拟合优度最佳;净等量吸附热随平衡含水率的增加而减少. 展开更多
关键词 青豆 等温线 平衡含水率 拟合优度 净等量吸附热
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