Considering the economic and environmental benefits associated with the recycling of polyester(PET)fibres,it is vital to study the application of fibre-reinforced cement composites.According to the characteristics of ...Considering the economic and environmental benefits associated with the recycling of polyester(PET)fibres,it is vital to study the application of fibre-reinforced cement composites.According to the characteristics of the wind-blown sand environment in Inner Mongolia,the erosion resistance of the polyester fibre-reinforced cement composites(PETFRCC)with different PET fibre contents to various erosion angles,velocities and sand particle flows was investigated by the gas-blast method.Based on the actual conditions of sandstorms in Inner Mongolia,the sand erosion parameters required for testing were calculated by the similarity theory.The elastic-plastic model and rigid plastic model of PETFRCC and cement mortar were established,and the energy consumption mechanism of the model under particle impact was analyzed.The experimental results indicate that the microstructure of PETFRCC rafter hydration causes a spring-like buffering effect,and the deformation of PETFRCC under the same impact load is slightly smaller than that of cement mortar,and the damage mechanism of PETFRCC is mainly characterized by fiber deformation and slight brittle spalling of matrix.And under the most unfavorable conditions of the erosion,the erosion rate of 0.5PETFRCC is about 57.69%lower than that of cement mortar,showing better erosion resistance.展开更多
Al_(2)O_(3)-SiC castables,for the relining of BF hearths in mid-campaign repair,were sampled and investigated after two years’service.The chemical and mineralogical characteristics of the residual castables were anal...Al_(2)O_(3)-SiC castables,for the relining of BF hearths in mid-campaign repair,were sampled and investigated after two years’service.The chemical and mineralogical characteristics of the residual castables were analyzed by X-ray diffraction,scanning electron microscopy,and energy dispersive X-ray spectrometry to study the erosion mechanism.The results show that as gaseous K diffuses in the castables,leucite(KAlSi_(2)O_(8))and multiple cracks are formed.Molten iron and slag penetrate through the cracks to form anorthite([Ca,Na][Al,Si]_(4)O_(8))and iron,which will not form an embrittlement layer similar to carbon bricks.The entire repair of the hearth with Al_(2)O_(3)-SiC castables combined with the design of thin-wall lining hearth eliminates“elephant foot shaped”erosion,greatly prolonging the service life of the hearth lining.展开更多
The comparison results of three beach profile data repeatedly measured before and after the typhoon in Shuidong Bay,west Guangdong province which show that there are significant differences in beach profile erosion an...The comparison results of three beach profile data repeatedly measured before and after the typhoon in Shuidong Bay,west Guangdong province which show that there are significant differences in beach profile erosion and response process.And the changes of beach profile can be divided into:strong downward overall low shoreline regressive type and overall slight erosion shoreline regressive type.Application of the modified mildslope equation along three beach profile are simulated wave high reflection to the sea side,to the section vertical shore pressure gradient and including water roll force and radiation stress,the vertical shore forces one dimensional profile along the momentum conservation equation(radiation stress and water roll force)bottom friction and lateral mixing reaction between numerical solution,the momentum conservation equations of the wave increases the water flow velocity and section along the profile distribution of wave height and related forces.The analysis shows that the extent and difference of coastal erosion depend on the shoreline erosion mode stimulated by the maximum surge water of the coastal current and the maximum velocity of the coastal current and the dynamic state of the profile topography under the action of the profile location,morphology and incident wave elements.展开更多
The Pelton turbine has been widely used to develop high-head water resources with sediments because of its advantages in life cycle costs.When a flood or monsoon season occurs,the sediment concentration in the river i...The Pelton turbine has been widely used to develop high-head water resources with sediments because of its advantages in life cycle costs.When a flood or monsoon season occurs,the sediment concentration in the river increases suddenly,causing severe erosion to the nozzle,needle,and runner of Pelton turbines.After decades of development,researchers have developed practical engineering experience to reduce the sediment concentration of the flow through the turbine and ensure the safety and efficiency of power generation.Research on the mechanism of sediment erosion,development of anti-erosion materials,and establishment of erosion prediction models have attracted scholarly interest in recent years.Extensive research has been conducted to determine a complete and valuable syndication erosion model.However,owing to the complexity of the flow and wear mechanisms,the influence of specific parameters of erosion and the syndication effect is still difficult to determine.Computational fluid dynamics and erosion monitoring technology have also been evaluated and applied.This paper presents a comprehensive review of the erosion of Pelton turbines,some of the latest technical methods,and possible future development directions.展开更多
Jade ware Jue is one of the most fashionable ornament in ancient China from the Neolithic Age to the Han Dynasty.In this study,the remnants of jade ware Jue,from Lijiashan ancient tomb group have been tested and analy...Jade ware Jue is one of the most fashionable ornament in ancient China from the Neolithic Age to the Han Dynasty.In this study,the remnants of jade ware Jue,from Lijiashan ancient tomb group have been tested and analyzed respectively.The samples through a light etch surface showing glass luster and those with a severe etch surface showing earthen luster.With the aid of X-ray fluorescence Spectrometer(X-ray Fluorescence)test and X-ray diffraction(XRD)detection,the results show that tremolite is not the main mineral of the sample.The main components of the tested samples with light erosion are antigorite and talc,although the main components of the samples with severe erosion are calcite containing calcium carbonate barium.Furthermore,the research on jade ware Jue in Yunnan culture has not only contributed to our further understanding of the jade objects from Yunnan culture and the variety of jade material located in the Yunnan Province.It also provides a basis for the trace of the history and culture through the distribution and evolution of burial hierarchy laws.At the same time,the microscopic observation of the tested samples manifested a residual trace of“string”at the perforation,which has played a critical role in restoring the wearing of jade ware Jue from the tombs of the ancient Yunnan State and the handicraft skills at that time.展开更多
Al-containing MAX phase ceramic has demonstrated great potential in the field of high-performance low-voltage electrical contact material.Elucidating the anti-arc erosion mechanism of the MAX phase is crucial for furt...Al-containing MAX phase ceramic has demonstrated great potential in the field of high-performance low-voltage electrical contact material.Elucidating the anti-arc erosion mechanism of the MAX phase is crucial for further improving performance,but it is not well-understood.In this study,Ag/Ti_(3)AlC_(2) electrical contact material was synthesized by powder metallurgy and examined by nanoindentation techniques such as constant loading rate indentation,creep testing,and continuous stiffness measurements.Our results indicated a gradual degradation in the nano-mechanical properties of the Ti_(3)AlC_(2) reinforcing phase with increasing arc erosion times,although the rate of this degradation appeared to decelerate over arc erosion times.Specifically,continuous stiffness measurements highlighted the uneven mechanical properties within Ti_(3)AlC_(2),attributing this heterogeneity to the phase’s decomposition.During the early(1-100 times)and intermediate(100-1000 times)stages of arc erosion,the decline in the nano-mechanical properties of Ti_(3)AlC_(2) was primarily ascribed to the decomposition of Ti_(3)AlC_(2) and limited surface oxidation.During the later stage of arc erosion(1000-6200 times),the inner region of Ti_(3)AlC_(2) also sustained arc damage,but a thick oxide layer formed on its surface,enhancing the mechanical properties and overall arc erosion resistance of the Ag/Ti_(3)AlC_(2).展开更多
La_(2)Sn_(2)O_(7)/SnO_(2)powder was synthesized by chemical co-precipitation method,and Ag-La_(2)Sn_(2)O_(7)/SnO_(2)composites were prepared by hot-pressing sintering.The electrical resistivity,density,Brinell hardnes...La_(2)Sn_(2)O_(7)/SnO_(2)powder was synthesized by chemical co-precipitation method,and Ag-La_(2)Sn_(2)O_(7)/SnO_(2)composites were prepared by hot-pressing sintering.The electrical resistivity,density,Brinell hardness and flexural strength of Ag-La_(2)Sn_(2)O_(7)/SnO_(2)composites were measured.Moreover,the effect of La_(2)Sn_(2)O_(7)content on the arc erosion behavior of Ag-La_(2)Sn_(2)O_(7)/SnO_(2)composites at 7 kV voltage was studied.With the increase of La_(2)Sn_(2)O_(7)content,the arc duration and arc energy decrease,and the breakdown strength increases.The surface morphology of Ag-La_(2)Sn_(2)O_(2)/SnO_(2)composites after arc erosion was investigated using scanning electron microscopy and three-dimensio nal laser confocal scanning microscopy.With the increase of La_(2)Sn_(2)O_(7)content,the smaller the erosion damage,the better the anti-arc erosion performance.However,too much La_(2)Sn_(2)O_(7)results in the decrease of Ag-La_(2)Sn_(2)O_(7)/SnO_(2)properties and severe arc erosion.X-ray photoelectron spectroscopy was used to determine the composition of the erosion region.The effect of La_(2)Sn_(2)O_(7)on wettability between Ag and SnO_(2)was investigated,and the erosion mechanism of Ag-La_(2)Sn_(2)O_(7)/SnO_(2)composites was discussed systematically.This study can provide a reference for the application of Ag matrix electrical contact materials in high-voltage electrical appliances.展开更多
The glacial history of Pico de Orizaba indicates that during the Last Glacial Maximum,its icecap covered up to~3000 m asl;due to the air temperature increasing,its main glacier has retreated to 5050 m asl.The retracti...The glacial history of Pico de Orizaba indicates that during the Last Glacial Maximum,its icecap covered up to~3000 m asl;due to the air temperature increasing,its main glacier has retreated to 5050 m asl.The retraction of the glacier has left behind an intense climatic instability that causes a high frequency of freeze-thaw cycles of great intensity;the resulting geomorphological processes are represented by the fragmentation of the bedrock that occupies the upper parts of the mountain.There is a notable lack of studies regarding the fragmentation and erosion occurring in tropical high mountains,and the associated geomorphological risks;for this reason,as a first stage of future continuous research,this study analyzes the freezing and thawing cycles that occur above 4000 m asl,through continuous monitoring of surface ground temperature.The results allow us to identify and characterize four zones:glacial,paraglacial,periglacial and proglacial.It was found that the paraglacial zone presents an intense drop of temperature,of up to~9℃ in only sixty minutes.The rock fatigue and intense freeze-thaw cycles that occur in this area are responsible for the high rate of rock disintegration and represent the main factor of the constant slope dynamics that occur at the site.This activity decreases,both in frequency and intensity,according to the distance to the glacier,which is where the temperature presents a certain degree of stability,until reaching the proglacial zone,where cycles are almost non-existent,and therefore there is no gelifraction activity.The geomorphological processes have resulted in significant alterations to the mountain slopes,which can have severe consequences in terms of risk and water.展开更多
Environmental economics is accelerating the urgency to develop recycling technologies for the ever-growing quantity of discarded thermoset polymers.Herein,we developed a mild and energy-saving pro-cess for high-eficie...Environmental economics is accelerating the urgency to develop recycling technologies for the ever-growing quantity of discarded thermoset polymers.Herein,we developed a mild and energy-saving pro-cess for high-eficiency degradation and reuse of anhydride-cured epoxy thermoset with the aid of hy-drazine hydrate.The degradation degree of the epoxy resin reached 99.6%at 120℃ within a short time of 60min.During the reaction,the ester bonds in the cross-linked network were selectively cleaved by the amination of hydrazine hydrate,and the epoxy resin was fully converted to new monomers that con-tained hydrazide and hydroxyl groups,respectively.Moreover,the degradation mechanism of the epoxy resin in hydrazine hydrate was studied and a nucleation model was utilized to predict the actual degra-dation behavior of the system.Finally,the degradation products can be directly mixed with epoxy precur-sor to prepare a new waterborne epoxy coating with good comprehensive properties.This work not only demonstrates a new way to realize the efficient degradation of epoxy resins,but also provides a facile and efficient recycling protocol for thermosets.展开更多
基金Funded by the National Natural Science Foundation of China(Nos.11162011,51468049 and 11862022)the Open Project Program of Fujian Key Laboratory of Novel Functional Textile Fibers and Materials+1 种基金Minjiang University(China)(No.FKLT FM1907)the Inner Mongolia Colleges and Universities Youth Science and Technology Talents Support Program(No.NJYT-17-A09)。
文摘Considering the economic and environmental benefits associated with the recycling of polyester(PET)fibres,it is vital to study the application of fibre-reinforced cement composites.According to the characteristics of the wind-blown sand environment in Inner Mongolia,the erosion resistance of the polyester fibre-reinforced cement composites(PETFRCC)with different PET fibre contents to various erosion angles,velocities and sand particle flows was investigated by the gas-blast method.Based on the actual conditions of sandstorms in Inner Mongolia,the sand erosion parameters required for testing were calculated by the similarity theory.The elastic-plastic model and rigid plastic model of PETFRCC and cement mortar were established,and the energy consumption mechanism of the model under particle impact was analyzed.The experimental results indicate that the microstructure of PETFRCC rafter hydration causes a spring-like buffering effect,and the deformation of PETFRCC under the same impact load is slightly smaller than that of cement mortar,and the damage mechanism of PETFRCC is mainly characterized by fiber deformation and slight brittle spalling of matrix.And under the most unfavorable conditions of the erosion,the erosion rate of 0.5PETFRCC is about 57.69%lower than that of cement mortar,showing better erosion resistance.
文摘Al_(2)O_(3)-SiC castables,for the relining of BF hearths in mid-campaign repair,were sampled and investigated after two years’service.The chemical and mineralogical characteristics of the residual castables were analyzed by X-ray diffraction,scanning electron microscopy,and energy dispersive X-ray spectrometry to study the erosion mechanism.The results show that as gaseous K diffuses in the castables,leucite(KAlSi_(2)O_(8))and multiple cracks are formed.Molten iron and slag penetrate through the cracks to form anorthite([Ca,Na][Al,Si]_(4)O_(8))and iron,which will not form an embrittlement layer similar to carbon bricks.The entire repair of the hearth with Al_(2)O_(3)-SiC castables combined with the design of thin-wall lining hearth eliminates“elephant foot shaped”erosion,greatly prolonging the service life of the hearth lining.
基金Project funded by the National Nature Fund(41371498,42071007)。
文摘The comparison results of three beach profile data repeatedly measured before and after the typhoon in Shuidong Bay,west Guangdong province which show that there are significant differences in beach profile erosion and response process.And the changes of beach profile can be divided into:strong downward overall low shoreline regressive type and overall slight erosion shoreline regressive type.Application of the modified mildslope equation along three beach profile are simulated wave high reflection to the sea side,to the section vertical shore pressure gradient and including water roll force and radiation stress,the vertical shore forces one dimensional profile along the momentum conservation equation(radiation stress and water roll force)bottom friction and lateral mixing reaction between numerical solution,the momentum conservation equations of the wave increases the water flow velocity and section along the profile distribution of wave height and related forces.The analysis shows that the extent and difference of coastal erosion depend on the shoreline erosion mode stimulated by the maximum surge water of the coastal current and the maximum velocity of the coastal current and the dynamic state of the profile topography under the action of the profile location,morphology and incident wave elements.
基金Supported by National Natural Science Foundation of China(Grant No.52279083).
文摘The Pelton turbine has been widely used to develop high-head water resources with sediments because of its advantages in life cycle costs.When a flood or monsoon season occurs,the sediment concentration in the river increases suddenly,causing severe erosion to the nozzle,needle,and runner of Pelton turbines.After decades of development,researchers have developed practical engineering experience to reduce the sediment concentration of the flow through the turbine and ensure the safety and efficiency of power generation.Research on the mechanism of sediment erosion,development of anti-erosion materials,and establishment of erosion prediction models have attracted scholarly interest in recent years.Extensive research has been conducted to determine a complete and valuable syndication erosion model.However,owing to the complexity of the flow and wear mechanisms,the influence of specific parameters of erosion and the syndication effect is still difficult to determine.Computational fluid dynamics and erosion monitoring technology have also been evaluated and applied.This paper presents a comprehensive review of the erosion of Pelton turbines,some of the latest technical methods,and possible future development directions.
基金supported by the major project of“Archaeological China”(Cultural Relics Guarantee[2020]No.444)China University of Geosciences(Wuhan)Gemmological Institute research project CIGTXM-04-S202145.
文摘Jade ware Jue is one of the most fashionable ornament in ancient China from the Neolithic Age to the Han Dynasty.In this study,the remnants of jade ware Jue,from Lijiashan ancient tomb group have been tested and analyzed respectively.The samples through a light etch surface showing glass luster and those with a severe etch surface showing earthen luster.With the aid of X-ray fluorescence Spectrometer(X-ray Fluorescence)test and X-ray diffraction(XRD)detection,the results show that tremolite is not the main mineral of the sample.The main components of the tested samples with light erosion are antigorite and talc,although the main components of the samples with severe erosion are calcite containing calcium carbonate barium.Furthermore,the research on jade ware Jue in Yunnan culture has not only contributed to our further understanding of the jade objects from Yunnan culture and the variety of jade material located in the Yunnan Province.It also provides a basis for the trace of the history and culture through the distribution and evolution of burial hierarchy laws.At the same time,the microscopic observation of the tested samples manifested a residual trace of“string”at the perforation,which has played a critical role in restoring the wearing of jade ware Jue from the tombs of the ancient Yunnan State and the handicraft skills at that time.
基金supported by the National Natural Science Foundation of China(52101064,52171033)Jiangsu Planned Projects for Postdoctoral Research Funds(2020Z158)Natural Science Foundation of Jiangsu Province(BK20220627).
文摘Al-containing MAX phase ceramic has demonstrated great potential in the field of high-performance low-voltage electrical contact material.Elucidating the anti-arc erosion mechanism of the MAX phase is crucial for further improving performance,but it is not well-understood.In this study,Ag/Ti_(3)AlC_(2) electrical contact material was synthesized by powder metallurgy and examined by nanoindentation techniques such as constant loading rate indentation,creep testing,and continuous stiffness measurements.Our results indicated a gradual degradation in the nano-mechanical properties of the Ti_(3)AlC_(2) reinforcing phase with increasing arc erosion times,although the rate of this degradation appeared to decelerate over arc erosion times.Specifically,continuous stiffness measurements highlighted the uneven mechanical properties within Ti_(3)AlC_(2),attributing this heterogeneity to the phase’s decomposition.During the early(1-100 times)and intermediate(100-1000 times)stages of arc erosion,the decline in the nano-mechanical properties of Ti_(3)AlC_(2) was primarily ascribed to the decomposition of Ti_(3)AlC_(2) and limited surface oxidation.During the later stage of arc erosion(1000-6200 times),the inner region of Ti_(3)AlC_(2) also sustained arc damage,but a thick oxide layer formed on its surface,enhancing the mechanical properties and overall arc erosion resistance of the Ag/Ti_(3)AlC_(2).
基金Project supported by the National Natural Science Foundation of China(51871085)。
文摘La_(2)Sn_(2)O_(7)/SnO_(2)powder was synthesized by chemical co-precipitation method,and Ag-La_(2)Sn_(2)O_(7)/SnO_(2)composites were prepared by hot-pressing sintering.The electrical resistivity,density,Brinell hardness and flexural strength of Ag-La_(2)Sn_(2)O_(7)/SnO_(2)composites were measured.Moreover,the effect of La_(2)Sn_(2)O_(7)content on the arc erosion behavior of Ag-La_(2)Sn_(2)O_(7)/SnO_(2)composites at 7 kV voltage was studied.With the increase of La_(2)Sn_(2)O_(7)content,the arc duration and arc energy decrease,and the breakdown strength increases.The surface morphology of Ag-La_(2)Sn_(2)O_(2)/SnO_(2)composites after arc erosion was investigated using scanning electron microscopy and three-dimensio nal laser confocal scanning microscopy.With the increase of La_(2)Sn_(2)O_(7)content,the smaller the erosion damage,the better the anti-arc erosion performance.However,too much La_(2)Sn_(2)O_(7)results in the decrease of Ag-La_(2)Sn_(2)O_(7)/SnO_(2)properties and severe arc erosion.X-ray photoelectron spectroscopy was used to determine the composition of the erosion region.The effect of La_(2)Sn_(2)O_(7)on wettability between Ag and SnO_(2)was investigated,and the erosion mechanism of Ag-La_(2)Sn_(2)O_(7)/SnO_(2)composites was discussed systematically.This study can provide a reference for the application of Ag matrix electrical contact materials in high-voltage electrical appliances.
基金part of the SIREI project num 531062023178 developed at CCT-UV.
文摘The glacial history of Pico de Orizaba indicates that during the Last Glacial Maximum,its icecap covered up to~3000 m asl;due to the air temperature increasing,its main glacier has retreated to 5050 m asl.The retraction of the glacier has left behind an intense climatic instability that causes a high frequency of freeze-thaw cycles of great intensity;the resulting geomorphological processes are represented by the fragmentation of the bedrock that occupies the upper parts of the mountain.There is a notable lack of studies regarding the fragmentation and erosion occurring in tropical high mountains,and the associated geomorphological risks;for this reason,as a first stage of future continuous research,this study analyzes the freezing and thawing cycles that occur above 4000 m asl,through continuous monitoring of surface ground temperature.The results allow us to identify and characterize four zones:glacial,paraglacial,periglacial and proglacial.It was found that the paraglacial zone presents an intense drop of temperature,of up to~9℃ in only sixty minutes.The rock fatigue and intense freeze-thaw cycles that occur in this area are responsible for the high rate of rock disintegration and represent the main factor of the constant slope dynamics that occur at the site.This activity decreases,both in frequency and intensity,according to the distance to the glacier,which is where the temperature presents a certain degree of stability,until reaching the proglacial zone,where cycles are almost non-existent,and therefore there is no gelifraction activity.The geomorphological processes have resulted in significant alterations to the mountain slopes,which can have severe consequences in terms of risk and water.
基金supported by the National Natural Science Foundation of China(Nos.52073038 and 51873027)the Fundamental Research Funds for the Central Universities(Nos.DUT20TD114 and DUT22LAB605).
文摘Environmental economics is accelerating the urgency to develop recycling technologies for the ever-growing quantity of discarded thermoset polymers.Herein,we developed a mild and energy-saving pro-cess for high-eficiency degradation and reuse of anhydride-cured epoxy thermoset with the aid of hy-drazine hydrate.The degradation degree of the epoxy resin reached 99.6%at 120℃ within a short time of 60min.During the reaction,the ester bonds in the cross-linked network were selectively cleaved by the amination of hydrazine hydrate,and the epoxy resin was fully converted to new monomers that con-tained hydrazide and hydroxyl groups,respectively.Moreover,the degradation mechanism of the epoxy resin in hydrazine hydrate was studied and a nucleation model was utilized to predict the actual degra-dation behavior of the system.Finally,the degradation products can be directly mixed with epoxy precur-sor to prepare a new waterborne epoxy coating with good comprehensive properties.This work not only demonstrates a new way to realize the efficient degradation of epoxy resins,but also provides a facile and efficient recycling protocol for thermosets.