A quantitative evaluation model that integrates kerogen adsorption and clay pore adsorption of shale oil was proposed,and the evaluation charts of adsorption-swelling capacity of kerogen(Mk)and adsorbed oil capacity o...A quantitative evaluation model that integrates kerogen adsorption and clay pore adsorption of shale oil was proposed,and the evaluation charts of adsorption-swelling capacity of kerogen(Mk)and adsorbed oil capacity of clay minerals(Mc)were established,taking the 1st member of Cretaceous Qingshankou Formation in the northern Songliao Basin as an example.The model and charts were derived from swelling oil experiments performed on naturally evolved kerogens and adsorbed oil experiments on clays(separated from shale core samples).They were constructed on the basis of clarifying the control law of kerogen maturity evolution on its adsorption-swelling capacity,and considering the effect of both the clay pore surface area that occupied by adsorbed oil and formation temperature.The results are obtained in four aspects:(1)For the Qing 1 Member shale,with the increase of maturity,Mk decreases.Given Ro of 0.83%–1.65%,Mk is about 50–250 mg/g.(2)The clay in shale adsorbs asphaltene.Mc is 0.63 mg/m^(2),and about 15%of the clay pore surface is occupied by adsorbed oil.(3)In the low to medium maturity stages,the shale oil adsorption is controlled by organic matter.When Ro>1.3%,the shale oil adsorption capacity is contributed by clay pores.(4)The oil adsorption capacity evaluated on the surface at room temperature is 8%–22%(avg.15%)higher than that is held in the formations.The proposed evaluation model reveals the occurrence mechanisms of shale oils with different maturities,and provides a new insight for estimating the reserves of shale oil under formation temperature conditions.展开更多
Based on faults surveying and research data in the Tianjin offshore areas,through studying tectonic structure,Quaternary activity,deep structure,stress and strain fields and seismicity in the Tianjin offshore areas,th...Based on faults surveying and research data in the Tianjin offshore areas,through studying tectonic structure,Quaternary activity,deep structure,stress and strain fields and seismicity in the Tianjin offshore areas,the activity and tectonic features of the faults are determined synthetically.Using seismo-geological data,and the historical and modern seismicity data,the frequency-magnitude relationship model normalized by 500a is established and based on the relationship between the upper limit of maximum magnitude M u and a t/b,the maximum magnitudes of the sea section of the Haihe river fault and the Haiyi fault are calculated.Then Poisson probability model is adopted and the quantitative parameters,such as the maximum magnitude,occurrence probability,recurrence cycle of the faults in the south Tianjin offshore areas in the coming 50～200a,are calculated.展开更多
The pyrolysis parameter S1,which indicates the amount of free hydrocarbons present in shale,is often underestimated due to hydrocarbon loss during sample handling and measurement processes.To remedy this issue,we stro...The pyrolysis parameter S1,which indicates the amount of free hydrocarbons present in shale,is often underestimated due to hydrocarbon loss during sample handling and measurement processes.To remedy this issue,we strongly recommend an immediate three-step hydrocarbon thermal desorption(HTD)approach to be conducted on oil shale at the drilling site.This approach measures S_(g),S_(O),and S_(1)^(*),which refer to gaseous,light,and free hydrocarbons,respectively.The new shale oil content value,calculated from the total of these three parameters,is far more precise and reliable than traditional pyrolysis S1.Moreover,we thoroughly investigated the components and microscopic occurrence features of hydrocarbons thermally desorbed at three temperature stages using gas chromatography(GC)and X-ray microcomputed tomography(CT).For example,we selected Chang 7_(3)mud shale.Our experimental results irrefutably indicate that the ultimate shale oil content of poor resource rocks is significantly impacted by evaporative loss,with this effect being greater when the total organic carbon(TOC)is lower.Additionally,C_(1-5)and C_(1-7)hydrocarbons constitute almost all of S_(g)and S_(O),respectively.S_(g)and S_(O)are predominantly composed of C_(1-3)gaseous hydrocarbons,with a maximum proportion of 42.93%.In contrast,S_(1)^(*)contains a substantial amount of C_(16-31)hydrocarbons.A three-dimensional reconstruction model of an X-ray micro-CT scan shows that while the amount of shale organic matter greatly decreases from the frozen state to 300℃,the pore volume significantly increases,particularly between 90 and 300℃.The increased pore volume is mainly due to macropores and fractures.It is imperative to note that the shale oil triple-division boundaries must be adjusted based on more accurate oil content,although this would not affect the resource zones to which the samples already belong(ineffective,low-efficient,and enriched resources).In conclusion,we strongly advise conducting an immediate well-site analysis or utilizing preservation procedures,such as deep freezing or plastic film wrapping followed by core waxing,to minimize volatile loss.展开更多
基金Supported by the National Natural Science Foundation of China(42102154,41922015,42072147)China Postdoctoral Science Foundation(2021M690168)Postdoctoral Innovation Talent Support Program of Shandong Province(SDBX2021004).
文摘A quantitative evaluation model that integrates kerogen adsorption and clay pore adsorption of shale oil was proposed,and the evaluation charts of adsorption-swelling capacity of kerogen(Mk)and adsorbed oil capacity of clay minerals(Mc)were established,taking the 1st member of Cretaceous Qingshankou Formation in the northern Songliao Basin as an example.The model and charts were derived from swelling oil experiments performed on naturally evolved kerogens and adsorbed oil experiments on clays(separated from shale core samples).They were constructed on the basis of clarifying the control law of kerogen maturity evolution on its adsorption-swelling capacity,and considering the effect of both the clay pore surface area that occupied by adsorbed oil and formation temperature.The results are obtained in four aspects:(1)For the Qing 1 Member shale,with the increase of maturity,Mk decreases.Given Ro of 0.83%–1.65%,Mk is about 50–250 mg/g.(2)The clay in shale adsorbs asphaltene.Mc is 0.63 mg/m^(2),and about 15%of the clay pore surface is occupied by adsorbed oil.(3)In the low to medium maturity stages,the shale oil adsorption is controlled by organic matter.When Ro>1.3%,the shale oil adsorption capacity is contributed by clay pores.(4)The oil adsorption capacity evaluated on the surface at room temperature is 8%–22%(avg.15%)higher than that is held in the formations.The proposed evaluation model reveals the occurrence mechanisms of shale oils with different maturities,and provides a new insight for estimating the reserves of shale oil under formation temperature conditions.
基金funded by earthquake security infrastructure of Tianjin 11th "Five-year Plan" (Tianjin Development and Reforming Office[2009]-1230),the Spark Program of Earthquake Sciences(Grant No.XH13002)
文摘Based on faults surveying and research data in the Tianjin offshore areas,through studying tectonic structure,Quaternary activity,deep structure,stress and strain fields and seismicity in the Tianjin offshore areas,the activity and tectonic features of the faults are determined synthetically.Using seismo-geological data,and the historical and modern seismicity data,the frequency-magnitude relationship model normalized by 500a is established and based on the relationship between the upper limit of maximum magnitude M u and a t/b,the maximum magnitudes of the sea section of the Haihe river fault and the Haiyi fault are calculated.Then Poisson probability model is adopted and the quantitative parameters,such as the maximum magnitude,occurrence probability,recurrence cycle of the faults in the south Tianjin offshore areas in the coming 50～200a,are calculated.
基金This study is financially supported by the National Natural Science Foundation of China(Grant Number 41972122,42172139 and 42072186)the China Scholarship Council(CSC),the Open Foundation of Cooperative Innovation Center of Uncon-ventional Oil and Gas,Yangtze University(Ministry of Education&Hubei Province)(Grant Number UOGBX 2022-03)Petro-China Innovation Found(No.2020D-5007-0101)。
文摘The pyrolysis parameter S1,which indicates the amount of free hydrocarbons present in shale,is often underestimated due to hydrocarbon loss during sample handling and measurement processes.To remedy this issue,we strongly recommend an immediate three-step hydrocarbon thermal desorption(HTD)approach to be conducted on oil shale at the drilling site.This approach measures S_(g),S_(O),and S_(1)^(*),which refer to gaseous,light,and free hydrocarbons,respectively.The new shale oil content value,calculated from the total of these three parameters,is far more precise and reliable than traditional pyrolysis S1.Moreover,we thoroughly investigated the components and microscopic occurrence features of hydrocarbons thermally desorbed at three temperature stages using gas chromatography(GC)and X-ray microcomputed tomography(CT).For example,we selected Chang 7_(3)mud shale.Our experimental results irrefutably indicate that the ultimate shale oil content of poor resource rocks is significantly impacted by evaporative loss,with this effect being greater when the total organic carbon(TOC)is lower.Additionally,C_(1-5)and C_(1-7)hydrocarbons constitute almost all of S_(g)and S_(O),respectively.S_(g)and S_(O)are predominantly composed of C_(1-3)gaseous hydrocarbons,with a maximum proportion of 42.93%.In contrast,S_(1)^(*)contains a substantial amount of C_(16-31)hydrocarbons.A three-dimensional reconstruction model of an X-ray micro-CT scan shows that while the amount of shale organic matter greatly decreases from the frozen state to 300℃,the pore volume significantly increases,particularly between 90 and 300℃.The increased pore volume is mainly due to macropores and fractures.It is imperative to note that the shale oil triple-division boundaries must be adjusted based on more accurate oil content,although this would not affect the resource zones to which the samples already belong(ineffective,low-efficient,and enriched resources).In conclusion,we strongly advise conducting an immediate well-site analysis or utilizing preservation procedures,such as deep freezing or plastic film wrapping followed by core waxing,to minimize volatile loss.
