A quantitative evaluation model that integrates kerogen adsorption and clay pore adsorption of shale oil was proposed,and the evaluation charts of adsorption-swelling capacity of kerogen(Mk)and adsorbed oil capacity o...A quantitative evaluation model that integrates kerogen adsorption and clay pore adsorption of shale oil was proposed,and the evaluation charts of adsorption-swelling capacity of kerogen(Mk)and adsorbed oil capacity of clay minerals(Mc)were established,taking the 1st member of Cretaceous Qingshankou Formation in the northern Songliao Basin as an example.The model and charts were derived from swelling oil experiments performed on naturally evolved kerogens and adsorbed oil experiments on clays(separated from shale core samples).They were constructed on the basis of clarifying the control law of kerogen maturity evolution on its adsorption-swelling capacity,and considering the effect of both the clay pore surface area that occupied by adsorbed oil and formation temperature.The results are obtained in four aspects:(1)For the Qing 1 Member shale,with the increase of maturity,Mk decreases.Given Ro of 0.83%–1.65%,Mk is about 50–250 mg/g.(2)The clay in shale adsorbs asphaltene.Mc is 0.63 mg/m^(2),and about 15%of the clay pore surface is occupied by adsorbed oil.(3)In the low to medium maturity stages,the shale oil adsorption is controlled by organic matter.When Ro>1.3%,the shale oil adsorption capacity is contributed by clay pores.(4)The oil adsorption capacity evaluated on the surface at room temperature is 8%–22%(avg.15%)higher than that is held in the formations.The proposed evaluation model reveals the occurrence mechanisms of shale oils with different maturities,and provides a new insight for estimating the reserves of shale oil under formation temperature conditions.展开更多
Based on faults surveying and research data in the Tianjin offshore areas,through studying tectonic structure,Quaternary activity,deep structure,stress and strain fields and seismicity in the Tianjin offshore areas,th...Based on faults surveying and research data in the Tianjin offshore areas,through studying tectonic structure,Quaternary activity,deep structure,stress and strain fields and seismicity in the Tianjin offshore areas,the activity and tectonic features of the faults are determined synthetically.Using seismo-geological data,and the historical and modern seismicity data,the frequency-magnitude relationship model normalized by 500a is established and based on the relationship between the upper limit of maximum magnitude M u and a t/b,the maximum magnitudes of the sea section of the Haihe river fault and the Haiyi fault are calculated.Then Poisson probability model is adopted and the quantitative parameters,such as the maximum magnitude,occurrence probability,recurrence cycle of the faults in the south Tianjin offshore areas in the coming 50～200a,are calculated.展开更多
针对陆东凹陷交力格洼陷中低成熟度页岩油储层分布特征与富集控制因素不明等问题,通过开展二维核磁共振分析、纳米CT扫描、干酪根显微组分鉴定等方法,对页岩油储层含油性特征进行研究,综合页岩岩相、储集性、含油性及可动性等因素,基于...针对陆东凹陷交力格洼陷中低成熟度页岩油储层分布特征与富集控制因素不明等问题,通过开展二维核磁共振分析、纳米CT扫描、干酪根显微组分鉴定等方法,对页岩油储层含油性特征进行研究,综合页岩岩相、储集性、含油性及可动性等因素,基于储层及含油性分级参数建立了页岩油“甜点”综合评价标准。结果表明:页岩纹层与层理的发育程度、密度、岩性等结构特征是含油性特征及分布的主要影响因素。层状含粗粒岩屑粉砂岩与纹层状长英质页岩岩相微观孔隙结构及连通性较好,比表面积小于15 m 2/g,氮气吸附平均孔径大于8 nm,为优质储层。Ⅰ+Ⅱ类“甜点”TOC大于1%,储层发育中、大孔,占比大于25%,储集空间孔径大于8 nm,含油性和可动性为中等—好,油气相对富集。该成果可为研究区页岩油有利目标优选及试验区部署评价提供技术支撑。展开更多
基金Supported by the National Natural Science Foundation of China(42102154,41922015,42072147)China Postdoctoral Science Foundation(2021M690168)Postdoctoral Innovation Talent Support Program of Shandong Province(SDBX2021004).
文摘A quantitative evaluation model that integrates kerogen adsorption and clay pore adsorption of shale oil was proposed,and the evaluation charts of adsorption-swelling capacity of kerogen(Mk)and adsorbed oil capacity of clay minerals(Mc)were established,taking the 1st member of Cretaceous Qingshankou Formation in the northern Songliao Basin as an example.The model and charts were derived from swelling oil experiments performed on naturally evolved kerogens and adsorbed oil experiments on clays(separated from shale core samples).They were constructed on the basis of clarifying the control law of kerogen maturity evolution on its adsorption-swelling capacity,and considering the effect of both the clay pore surface area that occupied by adsorbed oil and formation temperature.The results are obtained in four aspects:(1)For the Qing 1 Member shale,with the increase of maturity,Mk decreases.Given Ro of 0.83%–1.65%,Mk is about 50–250 mg/g.(2)The clay in shale adsorbs asphaltene.Mc is 0.63 mg/m^(2),and about 15%of the clay pore surface is occupied by adsorbed oil.(3)In the low to medium maturity stages,the shale oil adsorption is controlled by organic matter.When Ro>1.3%,the shale oil adsorption capacity is contributed by clay pores.(4)The oil adsorption capacity evaluated on the surface at room temperature is 8%–22%(avg.15%)higher than that is held in the formations.The proposed evaluation model reveals the occurrence mechanisms of shale oils with different maturities,and provides a new insight for estimating the reserves of shale oil under formation temperature conditions.
基金funded by earthquake security infrastructure of Tianjin 11th "Five-year Plan" (Tianjin Development and Reforming Office[2009]-1230),the Spark Program of Earthquake Sciences(Grant No.XH13002)
文摘Based on faults surveying and research data in the Tianjin offshore areas,through studying tectonic structure,Quaternary activity,deep structure,stress and strain fields and seismicity in the Tianjin offshore areas,the activity and tectonic features of the faults are determined synthetically.Using seismo-geological data,and the historical and modern seismicity data,the frequency-magnitude relationship model normalized by 500a is established and based on the relationship between the upper limit of maximum magnitude M u and a t/b,the maximum magnitudes of the sea section of the Haihe river fault and the Haiyi fault are calculated.Then Poisson probability model is adopted and the quantitative parameters,such as the maximum magnitude,occurrence probability,recurrence cycle of the faults in the south Tianjin offshore areas in the coming 50～200a,are calculated.
文摘针对陆东凹陷交力格洼陷中低成熟度页岩油储层分布特征与富集控制因素不明等问题,通过开展二维核磁共振分析、纳米CT扫描、干酪根显微组分鉴定等方法,对页岩油储层含油性特征进行研究,综合页岩岩相、储集性、含油性及可动性等因素,基于储层及含油性分级参数建立了页岩油“甜点”综合评价标准。结果表明:页岩纹层与层理的发育程度、密度、岩性等结构特征是含油性特征及分布的主要影响因素。层状含粗粒岩屑粉砂岩与纹层状长英质页岩岩相微观孔隙结构及连通性较好,比表面积小于15 m 2/g,氮气吸附平均孔径大于8 nm,为优质储层。Ⅰ+Ⅱ类“甜点”TOC大于1%,储层发育中、大孔,占比大于25%,储集空间孔径大于8 nm,含油性和可动性为中等—好,油气相对富集。该成果可为研究区页岩油有利目标优选及试验区部署评价提供技术支撑。
