Interannual variations of the air-sea CO2 exchange from 1965 to 2000 in the Pacific Ocean are studied with a Pacific Ocean model. Two numerical experiments are performed, including the control run that is forced by cl...Interannual variations of the air-sea CO2 exchange from 1965 to 2000 in the Pacific Ocean are studied with a Pacific Ocean model. Two numerical experiments are performed, including the control run that is forced by climatological monthly mean physical data and the climate-change run that is forced by interannually varying monthly mean physical data. Climatological monthly winds are used in both runs to calculate the coefficient of air-sea CO2 exchange. The analysis through the differences between the two runs shows that in the tropical Pacific the variation of export production induced by interannual variations of the physical fields is negatively correlated with that of the air-sea CO2 flux, while there is no correlation or a weak positive correlation in the subtropical North and South Pacific. It indicates that the variation of the physical fields can modulate the variation of the air-sea CO2 flux in converse ways in the tropical Pacific by changing the direct transport and biochemical process. Under the interannually varying monthly mean forcing, the simulated EOF 1 of the air-sea CO2 flux is basically consistent with that of sea surface temperature （SST） in the tropical Pacific, but contrary in the two subtropical Pacific Ocean. The correlation coefficient between the regionally integrated air-sea CO2 flux and area-mean SST shows that when the air-sea CO2 flux lags SST by about 5 months, the positive coefficient in the three regions is largest, indicating that in the tropical Pacific or on the longer time scale in the three regions, physical processes control the fiux-SST relationship.展开更多
The hybrid metal-organic framework [（CH3）2NH2]Fe（HCOO）3 with a perovskite-like structure exhibits a variety of unusual magnetic behaviors at low temperatures. While the long-distance super-exchange through the Fe-...The hybrid metal-organic framework [（CH3）2NH2]Fe（HCOO）3 with a perovskite-like structure exhibits a variety of unusual magnetic behaviors at low temperatures. While the long-distance super-exchange through the Fe-（Y-CH-O- Fe exchange path leads to a canted antiferromagnetic ordering at TN - 19 K, a second transition of magnetic blocking develops at TB- 9 K. The stair-shaped magnetization hysteresis loops below TB resemble the behaviors of resonant quantum tunneling of magnetization in single-molecular quantum magnets. Moreover, the magnetic relaxation also exhibits several features of resonant quantum relaxation, such as the exponential law with a single characteristic relaxation time, and the nonmonotonic dependence of relaxation rate on the applied magnetic field with a much faster relaxation around the resonant fields. The origin of quantum tunneling behaviors in the [（CH3）2NH2]Fe（HCOO）3 metal-organic framework is discussed in terms of magnetic phase separation due to the modification of hydrogen bonding on the long-distance super-exchange interaction.展开更多
基金The Research and Development Special Fund for Public Welfare Industry (meteorology) of the China Meteorological Adminstration under contract No.2008416022the Ocean Public Welfare Scientific Research Project of State Oceanic Administration of China under contract No.200905012-4+1 种基金the National Natural Science Foundation of China under contract Nos 40730106,41075091 and 41105087the National Basic Research Program (973 Program) of China under contract No. 2010CB951802
文摘Interannual variations of the air-sea CO2 exchange from 1965 to 2000 in the Pacific Ocean are studied with a Pacific Ocean model. Two numerical experiments are performed, including the control run that is forced by climatological monthly mean physical data and the climate-change run that is forced by interannually varying monthly mean physical data. Climatological monthly winds are used in both runs to calculate the coefficient of air-sea CO2 exchange. The analysis through the differences between the two runs shows that in the tropical Pacific the variation of export production induced by interannual variations of the physical fields is negatively correlated with that of the air-sea CO2 flux, while there is no correlation or a weak positive correlation in the subtropical North and South Pacific. It indicates that the variation of the physical fields can modulate the variation of the air-sea CO2 flux in converse ways in the tropical Pacific by changing the direct transport and biochemical process. Under the interannually varying monthly mean forcing, the simulated EOF 1 of the air-sea CO2 flux is basically consistent with that of sea surface temperature （SST） in the tropical Pacific, but contrary in the two subtropical Pacific Ocean. The correlation coefficient between the regionally integrated air-sea CO2 flux and area-mean SST shows that when the air-sea CO2 flux lags SST by about 5 months, the positive coefficient in the three regions is largest, indicating that in the tropical Pacific or on the longer time scale in the three regions, physical processes control the fiux-SST relationship.
基金supported by the National Natural Science Foundation of China(Grant Nos.11227405,51371192,and 51371193)the Chinese Academy of Sciences(Grant No.XDB07030200)
文摘The hybrid metal-organic framework [（CH3）2NH2]Fe（HCOO）3 with a perovskite-like structure exhibits a variety of unusual magnetic behaviors at low temperatures. While the long-distance super-exchange through the Fe-（Y-CH-O- Fe exchange path leads to a canted antiferromagnetic ordering at TN - 19 K, a second transition of magnetic blocking develops at TB- 9 K. The stair-shaped magnetization hysteresis loops below TB resemble the behaviors of resonant quantum tunneling of magnetization in single-molecular quantum magnets. Moreover, the magnetic relaxation also exhibits several features of resonant quantum relaxation, such as the exponential law with a single characteristic relaxation time, and the nonmonotonic dependence of relaxation rate on the applied magnetic field with a much faster relaxation around the resonant fields. The origin of quantum tunneling behaviors in the [（CH3）2NH2]Fe（HCOO）3 metal-organic framework is discussed in terms of magnetic phase separation due to the modification of hydrogen bonding on the long-distance super-exchange interaction.
