Detailed Description of Pulse Isotopic Exchange Method for Analyzing Oxygen Surface Exchange Behavior on Oxide Ion Conductors

A novel pulse 18O-16O isotopic exchange (PIE) technique for measurement of the rate of oxygen surface exchange of oxide ion conductors was presented. The technique employs a continuous flow packed-bed micro-reactor loaded with the oxide powder. The isothermal response to an 18O-enriched pulse passing through the reactor, thereby maintaining chemical equilibrium, is measured by on-line mass spectrometry. Evaluation of the apparent exchange rate follows from the uptake of 18O by the oxide at given reactor residence time and surface area available for exchange. The developed PIE technique is rapid, simple and highly suitable for screening and systematic studies. No rapid heating/quenching steps are required to facilitate 18O tracer anneal or analysis, as in other commonly used techniques based upon oxygen isotopic exchange. Moreover, the relative distribution of the oxygen isotopologues 18O2, 16O18O, and 16O2 in the effluent pulse provides insight into the mechanism of the oxygen exchange reaction. The PIE technique has been demonstrated by measuring the exchange rate of selected oxides with enhanced oxide ionic conductivity in the range of 350?900 oC. Analysis of the experimental data in terms of a model with two consecutive, lumped steps for the isotopic exchange reaction shows that for mixed conductors Ba0.5Sr0.5Co0.8Fe0.2O3-δ(BSCF) and La2NiO4+δ the reaction is limited by the apparent rate of dissociative adsorption of O2 molecules at the oxide surface. For yttria-stabilized zirconia (YSZ), a change-over takes place, from rate-limitations by oxygen incorporation below ∽800 oC to rate-limitations by O2 dissociative adsorption above this temperature. Good agreement is obtained with exchange rates reported for these materials in literature.

Molecular dynamics simulation of nanoscale surface diffusion of heterogeneous adatoms clusters

Molecular dynamics simulation employing the embedded atom method potential is utilized to investigate nanoscale surface diffusion mechanisms of binary heterogeneous adatoms clusters at 300 K, 500 K, and 700 K. Surface diffusion of heterogeneous adatoms clusters can be vital for the binary island growth on the surface and can be useful for the formation of alloy-based thin film surface through atomic exchange process. The results of the diffusion process show that at 300 K, the diffusion of small adatoms clusters shows hopping, sliding, and shear motion; whereas for large adatoms clusters（hexamer and above）, the diffusion is negligible. At 500 K, small adatoms clusters, i.e., dimer, show almost all possible diffusion mechanisms including the atomic exchange process; however no such exchange is observed for adatoms clusters greater than dimer. At 700 K, the exchange mechanism dominates for all types of clusters, where Zr adatoms show maximum tendency and Ag adatoms show minimum or no tendency toward the exchange process. Separation and recombination of one or more adatoms are also observed at 500 K and 700 K. The Ag adatoms also occupy pop-up positions over the adatoms clusters for short intervals. At 700 K, the vacancies are also generated in the vicinity of the adatoms cluster,vacancy formation, filling, and shifting can be observed from the results.

Effect of Initial Size and Shape Importance on Masse Transfer during Convective Drying

In this paper the influence of sample initial size on their convective drying at 80°C using convective dryer is determined. Results prove that initial size must be taken into account when drying process was estimated. This influence is limited by its form of cut. Comparing cubic form and parallelepiped (slice) one;results seem to show that thickness is the most important parameter governing the transfer phenomena during foodstuff convective drying. Three slices with thickness of 0.5 cm and surface area of 17, 82 and 112 cm2 respectively, dry better than cubic sample with a = 1 cm or a = 2 cm of arrest and having respectively 6 and 24 cm2 of surface area. All things seem to show that initial surface is not only the essential parameter;but also the thickness of the sample must be taken into account. Indeed, all of the samples with equal thickness (0.5 cm) and different exchange surfaces dry at the same time, about 210 min, comparing with cubic form 1 cm of arrest and 6 cm2 of surface and drying time of 230 min. A new parameter noted Dc called characteristic diameter is so considered to bridge the gaps. It is defined to be the diameter of the biggest sphere we can cut into a sample. This parameter is independent of form of the sample, and time increase with characteristic diameter increasing.

STUDY ON CLIMATIC FEATURES OF SURFACE TURBULENT HEAT EXCHANGE COEFFICIENTS AND SURFACE THERMAL SOURCES OVER THE QINGHAI-XIZANG PLATEAU

Using monthly mean of surface turbulent heat exchange coefficients calculated based on data from four automatic weather stations(AWS)for thermal equilibrium observation in July 1993— September 1996 and of surface conventional measurements,an empirical expression is established for such coefficients.With the expression,the heat exchange coefficients and the components of surface thermal source are computed in terms of 1961—1990 monthly mean conventional data from 148 stations over the Qinghai-Xizang(Tibetan)Plateau(QXP)and its adjoining areas,and the 1961—1990 climatic means are examined. Evidence suggests that the empirical expression is capable of showing the variation of the heat exchange coefficient in a climatic context.The monthly variation of the coefficients averaged over the QXP is in a range of 4×10^(-3)-5×10^(-3).The wintertime values are bigger in the mountains than in the valleys and reversal in summer.Surface effective radiation and sensible heat are the dominant factors of surface total heat.In spring surface sensible heat is enhanced quickly, resulting in two innegligible regions of sensible heat,one in the west QXP and the other in northern Tibet.with their maximums emerging in different months.In spring and summer sensible heat and surface effective radiation are higher in the west than in the east.The effective radiation peaks for the east in October—December and the whole QXP and in June and October for the west.The surface total heat of the plateau maximizes in May.minimizes in December and January,and shows seasonal variation more remarkable in the SW compared to the eastern part.In the SW plateau the total heat is much more intense than the eastern counterpart in all the seasons except winter.Under the effect of the sensible heat,the total heat on the SW plateau starts to considerably intensify in February,which leads to a predominant heating region in the west,with its center experiencing a noticeable westward migration early in summer and twice pronounced weakening in July and after October.However,the weakening courses are owing to different causes.The total heat over the north of QXP is greatly strengthened in March.thus generating another significant thermal region in the plateau.

Heterogeneity of Surface Heat Exchange of Slopes and Potential Drivers of the Initiation of Thaw Slump,Qinghai‑Tibet Plateau

In the mountainous permafrost area,most thaw slumps are distributed in north or northeast-facing shady slope areas.It is commonly known that there is a heterogeneity in permafrost between diferent slope aspects,but there has been a lack of detailed measured data to quantitatively evaluate their relationships,and in-depth understandings on how the slope aspects are linked to the distribution of thaw slumps.This study examined the heterogenous thermal regime,soil moisture content,and surface radiation at two slope sites with opposing aspects in a warming permafrost region on the Qinghai-Tibet Plateau(QTP).The results indicate that similar air temperatures(T_(a))were monitored on the two slopes,but there were signifcant diferences in ground temperature and moisture content in the active layer from 2016 to 2021.The sunny slope exhibited a higher mean annual ground surface temperature(T_(s)),and over the fve years the mean annual temperature at the top of permafrost was 1.3–1.4℃warmer on the sunny slope than the shady slope.On the contrary,the near-surface soil moisture content was about 10–13%lower on the sunny slope(~22–27%)than the shady slope(~35–38%)during the thawing season(June–September).Radiation data indicate that signifcantly higher shortwave downward radiation(DR)appeared at the sunny slope site.However,due to the greater surface albedo,the net radiation(Rn)was lower on the sunny slope.Slope aspect also afects the ground ice content due to its infuence on ground temperature,freeze-thaw cycles,and soil moisture.Shady slopes have a shallower burial of ice-rich permafrost compared to sunny slopes.The results highlight greatly diferent near-surface ground thermal conditions at the two slope sites with diferent aspects in a mountainous permafrost region.This helps identify the slope-related causes of increasing thaw slumps and provides a basis for predicting their future development.

Uncertainty in TC Maximum Intensity with Fixed Ratio of Surface Exchange Coefficients for Enthalpy and Momentum

The classical tropical cyclone(TC)maximum intensity theory of Emanuel suggests that the maximum azimuthal wind of TC depends linearly on the ratio of surface exchange coefficients for enthalpy and momentum(C_(k)and C_(d)).In this study,a series of sensitivity experiments are conducted with the three-dimensional Cloud Model 1(CM1),by fixing the ratio of C_(k)/C_(d)but varying the specific values of C_(k)and C_(d)simultaneously.The results show significant variations in the simulated TC maximum intensity by varying C_(k)and C_(d),even if their ratio is fixed.Overall,the maximum intensity increases steadily with increasing C_(k)and C_(d)when their value is smaller than 1.00×10^(-3),and then this increasing trend slows down with further increases in the coefficients.Two previous theoretical frameworks—one based on gradient wind balance and the other incorporating the unbalanced terms-are applied to calculate the maximum potential intensity(PI).The calculated value of the former shows little variation when varying the specific values of C_(k)and C_(d),while the latter shows larger values with increases in both C_(k)and C_(d).Further examination suggests that the unbalanced effect plays a key role in contributing to the increasing intensity with increasing C_(k)and C_(d).

Chemical diffusion and oxygen exchange of LaNi_(0.4)Fe_(0.6)O_(3-δ)ceramics

Oxygen surface exchange and oxygen chemical diffusion coefficients of LaNi_(0.4)Fe_(0.6)O_(3-δ)ceramics are determined via conductivity relaxation method after stepwise change of temperature in the range of 700-950℃in air and Ar/O2 gas flow at oxygen partial pressures(p_(o2))of 4 Pa,18 Pa,37 Pa,47 Pa and 59 Pa.The highest conductivity(about 160 S·cm^(-1))is found at 950℃in air.No oxygen exchange(δ=0)below 700℃is observed in the investigated p_(o2) range.The oxygen exchange coefficients determined in reduction mode are higher than those determined in oxidation mode.This is explained by clusterization of oxygen vacancies on the surface of the sample investigated in oxidation mode.The opposite tendency is found for chemical diffusion coefficients.Unlike surface,the oxygen vacancies of the volume region are probably not clustered and have predetermined the higher oxygen diffusion mobility of the sample treated in oxidation mode.