Mn^(2+)doping has been adopted as an efficient approach to regulating the luminescence properties of halide perovskite nano-crystals(NCs).However,it is still difficult to understand the interplay of Mn^(2+)luminescenc...Mn^(2+)doping has been adopted as an efficient approach to regulating the luminescence properties of halide perovskite nano-crystals(NCs).However,it is still difficult to understand the interplay of Mn^(2+)luminescence and the matrix self-trapped exciton(STE)emission therein.In this study,Mn^(2+)-doped CsCdCl_(3) NCs are prepared by hot injection,in which CsCdCl_(3) is selected because of its unique crystal structure suitable for STE emission.The blue emission at 441 nm of undoped CsCdCl_(3) NCs originates from the defect states in the NCs.Mn^(2+)doping promotes lattice distortion of CsCdCl_(3) and generates bright orange-red light emission at 656 nm.The en-ergy transfer from the STEs of CsCdCl_(3) to the excited levels of the Mn^(2+)ion is confirmed to be a significant factor in achieving efficient luminescence in CsCdCl_(3):Mn^(2+)NCs.This work highlights the crucial role of energy transfer from STEs to Mn^(2+)dopants in Mn^(2+)-doped halide NCs and lays the groundwork for modifying the luminescence of other metal halide perovskite NCs.展开更多
We present a perturbation study of the ground-state energy of the beryllium atom by incorporating double parameters in the atom's Hamiltonian. The eigenvalue of the Hamiltonian is then solved with a double-fold pertu...We present a perturbation study of the ground-state energy of the beryllium atom by incorporating double parameters in the atom's Hamiltonian. The eigenvalue of the Hamiltonian is then solved with a double-fold perturbation scheme,where the spin-spin interaction of electrons from different shells of the atom is also considered. Calculations show that the obtained ground-state energy is in satisfactory agreement with experiment. It is found that the Coulomb repulsion of the inner-shell electrons enhances the effective nuclear charge seen by the outer-shell electrons, and the shielding effect of the outer-shell electrons to the nucleus is also notable compared with that of the inner-shell electrons.展开更多
The new method proposed recently by Friedberg,Lee and Zhao is applied to the derivation of the atomic ground-state energy with the inclusion of the screening effect.The present results are compared with those obtained...The new method proposed recently by Friedberg,Lee and Zhao is applied to the derivation of the atomic ground-state energy with the inclusion of the screening effect.The present results are compared with those obtained in the pure Coulomb potential and by the variational approach.The overall good results are obtained with this new method.展开更多
We study the ground-state information of one-dimensional Heisenberg chain with alternating D-term. Given the ground-state phase diagram, the ground-state energy and the entanglement entropy are obtained by tensor-net ...We study the ground-state information of one-dimensional Heisenberg chain with alternating D-term. Given the ground-state phase diagram, the ground-state energy and the entanglement entropy are obtained by tensor-net work algorithm. The phase transition points are shown in the entanglement entropy figure. The results are agreed with the phase diagram.展开更多
This paper studies the size dependence of biexciton binding energy in single quantum dots (QDs) by using atomic force microscopy and micro-photoluminescence measurements. It finds that the biexciton binding energies...This paper studies the size dependence of biexciton binding energy in single quantum dots (QDs) by using atomic force microscopy and micro-photoluminescence measurements. It finds that the biexciton binding energies in the QDs show "binding" and "antibinding" properties which correspond to the large and small sizes of QDs, respectively. The experimental results can be well interpreted by the biexciton potential curve, calculated from the exciton molecular model and the Heitler London method.展开更多
We consider a hybrid heterostructure containing an inorganic quantum well in close proximity with organic material as overlayer. The resonant optical pumping of Frenkel exciton can lead to an efficient indirect pumpin...We consider a hybrid heterostructure containing an inorganic quantum well in close proximity with organic material as overlayer. The resonant optical pumping of Frenkel exciton can lead to an efficient indirect pumping of Wannier excitons. As organic material in such a hybrid structure, we consider crystalline tetracene. In tetracene, the singlet exciton energy is close to twice the one of triplet exciton state and singlet exciton fission into two triplets can be efficient. This process in tetracene is thermally activated and we investigate here how the temperature-dependent exciton energy transfer affects the functional properties of hybrid organic-inorganic nanostructures. We have obtained the exact analytical solution of diffusion equation for organics at different temperatures defining different diffusion lengths of excitons. The effectiveness of energy transfer in hybrid with tetracene was calculated by definite method for two selected temperatures that open possibility to operate in full region of temperatures. Temperature dependence of energy transfer opens a new possibility to turn on and off the indirect pumping due to energy transfer from the organic subsystem to the inorganic subsystem.展开更多
This paper shows that the experimental results of quantum well energy transitions can be found numerically. The cases of several ZnO-ZnMgO wells are considered and their excitonic transition energies were calculated u...This paper shows that the experimental results of quantum well energy transitions can be found numerically. The cases of several ZnO-ZnMgO wells are considered and their excitonic transition energies were calculated using the finite difference method. In that way, the one-dimensional Schrödinger equation has been solved by using the BLAS and LAPACK libraries. The numerical results are in good agreement with the experimental ones.展开更多
We investigate the transfer of phosphorescent energy between co-assembled metallophosphors in crystalline nanostructures [Angew. Chem. Int. Ed. 57 7820(2018) and J. Am. Chem. Soc. 140 4269(2018)]. Neither Dexter's...We investigate the transfer of phosphorescent energy between co-assembled metallophosphors in crystalline nanostructures [Angew. Chem. Int. Ed. 57 7820(2018) and J. Am. Chem. Soc. 140 4269(2018)]. Neither Dexter's nor Forster's mechanism of resonance energy transfer(RET) could account fully for the observed rates, which exceed 85% with significant temperature dependence. But there exists an alternative pathway on RET mediated by intermediate states of resonantly confined exciton–polaritons. Such a mechanism was used to analyze artificial photosynthesis in organic fluorescents [Phys.Rev. Lett. 122 257402(2019)]. For metallophosphors, the confined modes act as extended states lying between the molecular S_(1) and T_(1) states, offering a bridge for the long-lived T_(1) excitons to migrate from donors to acceptors. Population dynamics with parameters taken entirely based on experiments fits the observed lifetimes of phosphorescence across a broad range of doping and temperature.展开更多
Owing to the large exciton binding energy(>100 meV)of most organic materials,the process of exciton dissociation into free electrons and holes is seriously hindered,which plays a key role in the photocatalytic syst...Owing to the large exciton binding energy(>100 meV)of most organic materials,the process of exciton dissociation into free electrons and holes is seriously hindered,which plays a key role in the photocatalytic system.In this study,a series of chalcogen(S,Se)-substituted mesoporous covalent organic frameworks(COFs)have been synthesized for enhanced photocatalytic organic transformations.Photoelectrochemical measurements indicate that the introduction of semi-metallic Se atom and the enlargement of conjugation degree can not only reduce the exciton binding energy accelerating the charge separation,but also reduce the band gap of COFs.As a result,the COF-NUST-36 with the lowest exciton binding energy(39.5 meV)shows the highest photocatalytic performance for selective oxidation of amines(up to 98%Conv.and 97.5%Sel.).This work provides a feasible method for designing COFs with high photocatalytic activity by adjusting exciton binding energy.展开更多
Exciton energies as a function of radii of quantum dots in the range of 5-35 A are calculated based on effective mass approximation model with the B-spline technique and compared with experimental and other theoretica...Exciton energies as a function of radii of quantum dots in the range of 5-35 A are calculated based on effective mass approximation model with the B-spline technique and compared with experimental and other theoretical data for the CdS dots. This method leads to accurate and fast convergent exciton energy, which are in good agreement with experimental data in the whole confinement regime. The effect of penetration of wave function from the inside to the outside of the dots and the effect of dielectric constants are taken into account. The magnitudes of dynamical parameters are discussed. It is found that the different materials surrounding the CdS quantum dot affect not only the potential energy and Coulomb interaction energy of the system, but also the effective masses. The comparison shows that the effective mass approximation model can describe very well the quantum size effects observed experimentally on the exciton ground state energy.展开更多
The effects of exciton-optical phonon interaction on the binding energy and the total and reduced effective masses of an exciton in a cylindrical quantum wire have been investigated. We adopt a perturbative-PLL [T.D. ...The effects of exciton-optical phonon interaction on the binding energy and the total and reduced effective masses of an exciton in a cylindrical quantum wire have been investigated. We adopt a perturbative-PLL [T.D. Lee,F. Low, and D. Pines, Phys. Rev. B90 (1953) 297] technique to construct an effective Hamiltonian and then use a variational solution to deal with the exciton-phonon system. The interactions of exciton with the longitudinal-optical phonon and the surface-optical phonon have been taken into consideration. The numerical calculations for GaAs show that the influences of phonon modes on the exciton in a quasi-one-dimensional quantum wire are considerable and should not be neglected. Moreover the numerical results for heavy- and light-hole exciton are obtained, which show that the polaronic effects on two types of excitons are very different but both depend heavily on the sizes of the wire.展开更多
Binding energies of excitons in GaAs films on AlxGal-xAs substrates are studied theoretically with the fractional- dimensional approach. In this approach, the real anisotropic "exciton + film" semiconductor system ...Binding energies of excitons in GaAs films on AlxGal-xAs substrates are studied theoretically with the fractional- dimensional approach. In this approach, the real anisotropic "exciton + film" semiconductor system is mapped into an effective fractional-dimensional isotropic space. For different aluminum concentrations and substrate thicknesses, the exci- ton binding energies are obtained as a function of the film thickness. The numerical results show that, for different aluminum concentrations and substrate thicknesses, the exciton binding energies in GaAs films on AlxGal_xAs substrates all exhibit their maxima with increasing film thickness. It is also shown that the binding energies of heavy-hole and light-hole excitons both have their maxima with increasing film thickness.展开更多
DFT and TD-DFT calculations of HOMO and LUMO energies and photovoltaic properties are carried out on four selected pentathiophene donor and one IDIC-4F acceptor molecules using B3LYP and PBE0 functionals for the groun...DFT and TD-DFT calculations of HOMO and LUMO energies and photovoltaic properties are carried out on four selected pentathiophene donor and one IDIC-4F acceptor molecules using B3LYP and PBE0 functionals for the ground state energy calculations and CAM-B3LYP functional for the excited state calculations.The discrepancy between the calculated and experimental energies is reduced by correlating them with a linear fit.The fitted energies of HOMO and LUMO are used to calculate the Voc of an OSC based on these donors and acceptor blend and compared with experimental values.Using the Scharber model the calculated PCE of the donor-acceptor molecules agree with the experiment.It has been found that fluorine substitution can be used to improve charge transport by reducing the electron and hole reorganization energies of the molecules.It is also found that the introduction of fluorine onto the donor pentathiophene unit of the donor molecule results in a change of polarity of the distributed charges in the molecule due to the high electronegativity of the fluorine atom.The quantum chemical potential(μ),chemical hardness(η)and electronegativity(χ),and electrostatic potential maps(EPMs)are also calculated to identify different charge distribution regions in all five molecules.展开更多
This paper investigates the effects of quantum well size changes on center frequency and slow down factor of an slow light device. In this way, we consider the quantum well size alteration effects on oscillator streng...This paper investigates the effects of quantum well size changes on center frequency and slow down factor of an slow light device. In this way, we consider the quantum well size alteration effects on oscillator strength and binding energy of exciton. First, we investigate the variations in oscillator strength of exciton due to different quantum well size. Second, exciton binding energy level shift due to size of quantum well is investigated. According to this analysis, we have developed a new method for tuning slow light device bandwidth center frequency and slow down factor. Analysis and simulation of a basic GaAs/AlGaAs quantum wells optical slow light device based on excitonic population oscillation shows that size of quantum wells could tune both of the frequency properties and slow down factor of an optical slow light device. In our simulation with 34 quantum wells each with the width of 60?, we have received the slow down factor of more than 60,000. These achievements are useful in optical nonlinearity enhancements, all-optical signal processing applications and optical communications.展开更多
The outstanding difference between high temperature superconductors and low temperature superconductors is the sign of the Hall coefficient, properly understood. Since the Lorentz force acts on particles, not voids no...The outstanding difference between high temperature superconductors and low temperature superconductors is the sign of the Hall coefficient, properly understood. Since the Lorentz force acts on particles, not voids nor immobile ions, we propose that the experimental positive coefficient is due to dispersion dynamics in valence bands, i.e. on electrons with positive charge/mass ratio, but with negative charge and negative effective mass. In HiT ccompounds, anionic and cationic doping creates holes that substitute for the lattice distortions that bind Cooper pairs in metallic superconductors such as Nb. In both types of superconductor, the conventional notion of antiparallel spins S = 0, with paired wave vectors k and -k, is maintained;but in the ceramics “holes” h, produced by chemical doping and measured in the normal state, are available to bond super-conducting Boson pairs via h−or h02?excitons.展开更多
Based on the framework of the effective-mass approximation,the ionized acceptor bound exciton(A-,X) binding energy and the emission wavelength are investigated for a cylindrical wurtzite(WZ) GaN/Al x Ga1-x N quantum d...Based on the framework of the effective-mass approximation,the ionized acceptor bound exciton(A-,X) binding energy and the emission wavelength are investigated for a cylindrical wurtzite(WZ) GaN/Al x Ga1-x N quantum dot(QD) with finite potential barriers by means of a variational method.Numerical results show that the binding energy and the emission wavelength highly depend on the QD size,the position of the ionized acceptor and the Al composition x of the barrier material Al x Ga1-x N.The binding energy and the emission wavelength are larger when the acceptor is located in the vicinity of the left interface of the QD.In particular,the binding energy of(A-,X) complex is insensitive to the dot height when the acceptor is located at the left boundary of the QD.The ionized acceptor bound exciton binding energy and the emission wavelength are both increased if Al composition x is increased.展开更多
Laser pulse nonlinear transmission measurements through saturable absorbers of known absorption parameters allow the measurement of their energy density. On the other hand, nonlinear transmission measurements of laser...Laser pulse nonlinear transmission measurements through saturable absorbers of known absorption parameters allow the measurement of their energy density. On the other hand, nonlinear transmission measurements of laser pulses of known energy density through absorbing media allow their absorption parameter determination. The peak energy density w0P of second harmonic pulses of a mode-locked titanium sapphire laser at wavelength λP = 400 nm is determined by nonlinear energy transmission measurement TE through the dye ADS084BE (1,4-bis(9-ethyl-3-car-bazovinylene)-2-methoxy-5-(2’-ethyl-hexyloxy)-benzene) in tetrahydrofuran. TE(w0P) calibration curves are calculated for laser pulse peak energy density reading w0P from measured pulse energy transmissions TE. The ground-state absorption cross-section σP and the excited-state absorption cross-section σex at λP, and the number density N0 of the retinal Schiff base isoform RetA in pH 7.4 buffer of the blue-light adapted recombinant rhodopsin fragment of the histidine kinase rhodopsin HKR1 from Chlamydomonas reinhardtii were determined by picosecond titanium sapphire second harmonic laser pulse energy transmission measurement TE through RetA as a function of laser input peak energy density w0P. The complete absorption cross-section spectrum展开更多
基金supported by the Guangdong Provincial Science&Technology Project(No.2023A0505050084)the National Natural Science Foundation of China(No.22361132525)+1 种基金the Fundamental Research Funds for the Central Universities(No.2023ZYGXZR002)the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(No.2017BT01X137).
文摘Mn^(2+)doping has been adopted as an efficient approach to regulating the luminescence properties of halide perovskite nano-crystals(NCs).However,it is still difficult to understand the interplay of Mn^(2+)luminescence and the matrix self-trapped exciton(STE)emission therein.In this study,Mn^(2+)-doped CsCdCl_(3) NCs are prepared by hot injection,in which CsCdCl_(3) is selected because of its unique crystal structure suitable for STE emission.The blue emission at 441 nm of undoped CsCdCl_(3) NCs originates from the defect states in the NCs.Mn^(2+)doping promotes lattice distortion of CsCdCl_(3) and generates bright orange-red light emission at 656 nm.The en-ergy transfer from the STEs of CsCdCl_(3) to the excited levels of the Mn^(2+)ion is confirmed to be a significant factor in achieving efficient luminescence in CsCdCl_(3):Mn^(2+)NCs.This work highlights the crucial role of energy transfer from STEs to Mn^(2+)dopants in Mn^(2+)-doped halide NCs and lays the groundwork for modifying the luminescence of other metal halide perovskite NCs.
基金Project supported by the National Natural Science Foundation of China(Grant No.11647071)the Natural Science Foundation of Jiangsu Province,China(Grant No.BK20160435)
文摘We present a perturbation study of the ground-state energy of the beryllium atom by incorporating double parameters in the atom's Hamiltonian. The eigenvalue of the Hamiltonian is then solved with a double-fold perturbation scheme,where the spin-spin interaction of electrons from different shells of the atom is also considered. Calculations show that the obtained ground-state energy is in satisfactory agreement with experiment. It is found that the Coulomb repulsion of the inner-shell electrons enhances the effective nuclear charge seen by the outer-shell electrons, and the shielding effect of the outer-shell electrons to the nucleus is also notable compared with that of the inner-shell electrons.
文摘The new method proposed recently by Friedberg,Lee and Zhao is applied to the derivation of the atomic ground-state energy with the inclusion of the screening effect.The present results are compared with those obtained in the pure Coulomb potential and by the variational approach.The overall good results are obtained with this new method.
文摘We study the ground-state information of one-dimensional Heisenberg chain with alternating D-term. Given the ground-state phase diagram, the ground-state energy and the entanglement entropy are obtained by tensor-net work algorithm. The phase transition points are shown in the entanglement entropy figure. The results are agreed with the phase diagram.
基金Project supported by the National Natural Science Foundations of China (Grant Nos O69C041001 and 2007CB924904)
文摘This paper studies the size dependence of biexciton binding energy in single quantum dots (QDs) by using atomic force microscopy and micro-photoluminescence measurements. It finds that the biexciton binding energies in the QDs show "binding" and "antibinding" properties which correspond to the large and small sizes of QDs, respectively. The experimental results can be well interpreted by the biexciton potential curve, calculated from the exciton molecular model and the Heitler London method.
文摘We consider a hybrid heterostructure containing an inorganic quantum well in close proximity with organic material as overlayer. The resonant optical pumping of Frenkel exciton can lead to an efficient indirect pumping of Wannier excitons. As organic material in such a hybrid structure, we consider crystalline tetracene. In tetracene, the singlet exciton energy is close to twice the one of triplet exciton state and singlet exciton fission into two triplets can be efficient. This process in tetracene is thermally activated and we investigate here how the temperature-dependent exciton energy transfer affects the functional properties of hybrid organic-inorganic nanostructures. We have obtained the exact analytical solution of diffusion equation for organics at different temperatures defining different diffusion lengths of excitons. The effectiveness of energy transfer in hybrid with tetracene was calculated by definite method for two selected temperatures that open possibility to operate in full region of temperatures. Temperature dependence of energy transfer opens a new possibility to turn on and off the indirect pumping due to energy transfer from the organic subsystem to the inorganic subsystem.
文摘This paper shows that the experimental results of quantum well energy transitions can be found numerically. The cases of several ZnO-ZnMgO wells are considered and their excitonic transition energies were calculated using the finite difference method. In that way, the one-dimensional Schrödinger equation has been solved by using the BLAS and LAPACK libraries. The numerical results are in good agreement with the experimental ones.
基金Project supported by the National Natural Science Foundation of China (Grant No. 16Z103060007) (PA)。
文摘We investigate the transfer of phosphorescent energy between co-assembled metallophosphors in crystalline nanostructures [Angew. Chem. Int. Ed. 57 7820(2018) and J. Am. Chem. Soc. 140 4269(2018)]. Neither Dexter's nor Forster's mechanism of resonance energy transfer(RET) could account fully for the observed rates, which exceed 85% with significant temperature dependence. But there exists an alternative pathway on RET mediated by intermediate states of resonantly confined exciton–polaritons. Such a mechanism was used to analyze artificial photosynthesis in organic fluorescents [Phys.Rev. Lett. 122 257402(2019)]. For metallophosphors, the confined modes act as extended states lying between the molecular S_(1) and T_(1) states, offering a bridge for the long-lived T_(1) excitons to migrate from donors to acceptors. Population dynamics with parameters taken entirely based on experiments fits the observed lifetimes of phosphorescence across a broad range of doping and temperature.
基金financially supported by the National Natural Science Foundation of China(No.22171136)the Natural Science Foundation of Jiangsu Province(Nos.BK20220928,BK20220079)+4 种基金the Fundamental Research Funds for the Central Universities(Nos.30921011102,30922010902)the Medical Innovation and Development Project of Lanzhou University(No.lzuyxcx-2022-156)CAMS Innovation Fund for Medical Sciences(CIFMS,Nos.2019-I2M-5-074,2021-I2M-1-026,2021-I2M-3-001)the Startup Funding from Nanjing University of Science and Technology(Nos.AE89990,AE89991/376)G.Zhang acknowledges the support of the Thousand Young Talent Plan.
文摘Owing to the large exciton binding energy(>100 meV)of most organic materials,the process of exciton dissociation into free electrons and holes is seriously hindered,which plays a key role in the photocatalytic system.In this study,a series of chalcogen(S,Se)-substituted mesoporous covalent organic frameworks(COFs)have been synthesized for enhanced photocatalytic organic transformations.Photoelectrochemical measurements indicate that the introduction of semi-metallic Se atom and the enlargement of conjugation degree can not only reduce the exciton binding energy accelerating the charge separation,but also reduce the band gap of COFs.As a result,the COF-NUST-36 with the lowest exciton binding energy(39.5 meV)shows the highest photocatalytic performance for selective oxidation of amines(up to 98%Conv.and 97.5%Sel.).This work provides a feasible method for designing COFs with high photocatalytic activity by adjusting exciton binding energy.
文摘Exciton energies as a function of radii of quantum dots in the range of 5-35 A are calculated based on effective mass approximation model with the B-spline technique and compared with experimental and other theoretical data for the CdS dots. This method leads to accurate and fast convergent exciton energy, which are in good agreement with experimental data in the whole confinement regime. The effect of penetration of wave function from the inside to the outside of the dots and the effect of dielectric constants are taken into account. The magnitudes of dynamical parameters are discussed. It is found that the different materials surrounding the CdS quantum dot affect not only the potential energy and Coulomb interaction energy of the system, but also the effective masses. The comparison shows that the effective mass approximation model can describe very well the quantum size effects observed experimentally on the exciton ground state energy.
文摘The effects of exciton-optical phonon interaction on the binding energy and the total and reduced effective masses of an exciton in a cylindrical quantum wire have been investigated. We adopt a perturbative-PLL [T.D. Lee,F. Low, and D. Pines, Phys. Rev. B90 (1953) 297] technique to construct an effective Hamiltonian and then use a variational solution to deal with the exciton-phonon system. The interactions of exciton with the longitudinal-optical phonon and the surface-optical phonon have been taken into consideration. The numerical calculations for GaAs show that the influences of phonon modes on the exciton in a quasi-one-dimensional quantum wire are considerable and should not be neglected. Moreover the numerical results for heavy- and light-hole exciton are obtained, which show that the polaronic effects on two types of excitons are very different but both depend heavily on the sizes of the wire.
基金Project supported by the National Natural Science Foundation of China(Grant No.11304011)the Fundamental Research Funds for the Central Universitie China
文摘Binding energies of excitons in GaAs films on AlxGal-xAs substrates are studied theoretically with the fractional- dimensional approach. In this approach, the real anisotropic "exciton + film" semiconductor system is mapped into an effective fractional-dimensional isotropic space. For different aluminum concentrations and substrate thicknesses, the exci- ton binding energies are obtained as a function of the film thickness. The numerical results show that, for different aluminum concentrations and substrate thicknesses, the exciton binding energies in GaAs films on AlxGal_xAs substrates all exhibit their maxima with increasing film thickness. It is also shown that the binding energies of heavy-hole and light-hole excitons both have their maxima with increasing film thickness.
文摘DFT and TD-DFT calculations of HOMO and LUMO energies and photovoltaic properties are carried out on four selected pentathiophene donor and one IDIC-4F acceptor molecules using B3LYP and PBE0 functionals for the ground state energy calculations and CAM-B3LYP functional for the excited state calculations.The discrepancy between the calculated and experimental energies is reduced by correlating them with a linear fit.The fitted energies of HOMO and LUMO are used to calculate the Voc of an OSC based on these donors and acceptor blend and compared with experimental values.Using the Scharber model the calculated PCE of the donor-acceptor molecules agree with the experiment.It has been found that fluorine substitution can be used to improve charge transport by reducing the electron and hole reorganization energies of the molecules.It is also found that the introduction of fluorine onto the donor pentathiophene unit of the donor molecule results in a change of polarity of the distributed charges in the molecule due to the high electronegativity of the fluorine atom.The quantum chemical potential(μ),chemical hardness(η)and electronegativity(χ),and electrostatic potential maps(EPMs)are also calculated to identify different charge distribution regions in all five molecules.
文摘This paper investigates the effects of quantum well size changes on center frequency and slow down factor of an slow light device. In this way, we consider the quantum well size alteration effects on oscillator strength and binding energy of exciton. First, we investigate the variations in oscillator strength of exciton due to different quantum well size. Second, exciton binding energy level shift due to size of quantum well is investigated. According to this analysis, we have developed a new method for tuning slow light device bandwidth center frequency and slow down factor. Analysis and simulation of a basic GaAs/AlGaAs quantum wells optical slow light device based on excitonic population oscillation shows that size of quantum wells could tune both of the frequency properties and slow down factor of an optical slow light device. In our simulation with 34 quantum wells each with the width of 60?, we have received the slow down factor of more than 60,000. These achievements are useful in optical nonlinearity enhancements, all-optical signal processing applications and optical communications.
文摘The outstanding difference between high temperature superconductors and low temperature superconductors is the sign of the Hall coefficient, properly understood. Since the Lorentz force acts on particles, not voids nor immobile ions, we propose that the experimental positive coefficient is due to dispersion dynamics in valence bands, i.e. on electrons with positive charge/mass ratio, but with negative charge and negative effective mass. In HiT ccompounds, anionic and cationic doping creates holes that substitute for the lattice distortions that bind Cooper pairs in metallic superconductors such as Nb. In both types of superconductor, the conventional notion of antiparallel spins S = 0, with paired wave vectors k and -k, is maintained;but in the ceramics “holes” h, produced by chemical doping and measured in the normal state, are available to bond super-conducting Boson pairs via h−or h02?excitons.
基金Supported by Technology Projects of the Education Bureau of Fujian Province umder Grant No. JK2009038
文摘Based on the framework of the effective-mass approximation,the ionized acceptor bound exciton(A-,X) binding energy and the emission wavelength are investigated for a cylindrical wurtzite(WZ) GaN/Al x Ga1-x N quantum dot(QD) with finite potential barriers by means of a variational method.Numerical results show that the binding energy and the emission wavelength highly depend on the QD size,the position of the ionized acceptor and the Al composition x of the barrier material Al x Ga1-x N.The binding energy and the emission wavelength are larger when the acceptor is located in the vicinity of the left interface of the QD.In particular,the binding energy of(A-,X) complex is insensitive to the dot height when the acceptor is located at the left boundary of the QD.The ionized acceptor bound exciton binding energy and the emission wavelength are both increased if Al composition x is increased.
基金The project supported by National Natural Science Foundation of China under Grant No. 10574036, and the Natural Science Foundation of Hebei Province of China under Grant No. A2004000140
文摘在领带中有效团的近似,用简单二参数的波浪功能并且一一个维(1D ) 相等的潜在的模型,我们计算激子的有约束力的精力绑了在一个中立施主的变化联盟者(D~0, X ) 在有限 GaAs-Al_xGa_(1-x ) 作为量井电线(QWW ) 。在 25 A 的电线宽度,有约束力的精力有山峰值,它也在激子绑定精力,和 center-of-mass 的山峰的位置激子活动范围的波浪函数最集中的分发。另外,一般水准的变化趋势内部电线宽度对有约束力的精力的反向的粒子距离。
文摘Laser pulse nonlinear transmission measurements through saturable absorbers of known absorption parameters allow the measurement of their energy density. On the other hand, nonlinear transmission measurements of laser pulses of known energy density through absorbing media allow their absorption parameter determination. The peak energy density w0P of second harmonic pulses of a mode-locked titanium sapphire laser at wavelength λP = 400 nm is determined by nonlinear energy transmission measurement TE through the dye ADS084BE (1,4-bis(9-ethyl-3-car-bazovinylene)-2-methoxy-5-(2’-ethyl-hexyloxy)-benzene) in tetrahydrofuran. TE(w0P) calibration curves are calculated for laser pulse peak energy density reading w0P from measured pulse energy transmissions TE. The ground-state absorption cross-section σP and the excited-state absorption cross-section σex at λP, and the number density N0 of the retinal Schiff base isoform RetA in pH 7.4 buffer of the blue-light adapted recombinant rhodopsin fragment of the histidine kinase rhodopsin HKR1 from Chlamydomonas reinhardtii were determined by picosecond titanium sapphire second harmonic laser pulse energy transmission measurement TE through RetA as a function of laser input peak energy density w0P. The complete absorption cross-section spectrum