Rare earth element(REE) is widely used in various fields of geology.Study of the existing forms of REE in geological objects is a necessity for us to solve geological problems related with REE.This paper tried to make...Rare earth element(REE) is widely used in various fields of geology.Study of the existing forms of REE in geological objects is a necessity for us to solve geological problems related with REE.This paper tried to make it clear the existing forms of REE in gold-bearing pyrite in Jinshan gold deposit by stepwise dissolution test with ICP-MS analysis.Results showed that content of REE in fluid-inclusions of gold-bearing pyrite was very low,which only took about 0.07%–0.70% of the ΣREE,and that of pyrite phase ...展开更多
Trace elements in cassiterite, including Ta, W, Fe, Mn, Ti, Zr, V, Sc, Si, kl, In, Ga, Ge, Be,Bi, Ag, Sb, As, Cu, Pb, Zn, Co and REE, have been studied by many workers (Shan Zhenhua etal., 1988; Huang Zhou Tianren et ...Trace elements in cassiterite, including Ta, W, Fe, Mn, Ti, Zr, V, Sc, Si, kl, In, Ga, Ge, Be,Bi, Ag, Sb, As, Cu, Pb, Zn, Co and REE, have been studied by many workers (Shan Zhenhua etal., 1988; Huang Zhou Tianren et al., 1987; Wu Qingsheng et al., l988; Hu Zening, 1988, Li Zhong-qing 1988 MingZhi et al.,1988; Wang Lihua et al., 1988, Liu Kanghuai, 1990). Up to now, however,most of the previous studiesareconcerned with tracoelement variations in cassiterites of diffirent occur-rences and colors from diffirent types of ore deposits, Data concerning the modes of occurrence of’ these trace elements are rare, except for the contention that Nb-Ta, F.2+-M.-F.3+ and W-F.3+ maysubstitute isomorphously for Sn as pointed out by Zhou Tianren et al. (1987) and Moller et al.(1988). In this paper we are concerned with the compositionaI characterishcs as well as the modes ofoccurrence of trace elements in cassiterites from quartz veins and greisens in the Dupangling tin field,Guangxi, based on mu1tivariate statistical analys es.Tin mineralization in the Dupang1ing area is found associated with the medium-to fine-grainedprotolithionite-albite granite and its outer contacts. Cassiterite occurs, with wolframite, both inquartz veins in the contact and in greisens within the granite.’ ) Spatially, greisens become dominantover quartz veins in going from the contact to the interior of the granite and with increasing depth.The greisens are of various shapes. The vein-shaPed and the sheet-shaped greisens at the top of thegranite are rich in quartz and the chambered greisens always constitute rich ores and contain abun-dant topaz or mica. Genetically, Sn, W ndneralizations associated with the protolithionite-albite gran-ite are considered to have been formed from fluid melt derived from the ore-forming magma re-sponsible for the展开更多
Dispersed elements do not always occur as associated elements in the ore deposits of other elements. Instead, they can constitute independent ore deposits. The focus of this paper is placed on the mechanism of super-e...Dispersed elements do not always occur as associated elements in the ore deposits of other elements. Instead, they can constitute independent ore deposits. The focus of this paper is placed on the mechanism of super-enrichment of the four dispersed elements Tl, Ge, Se, and Te under favorable geological conditions, where their enrichment coefficients are so high that their abundances can reach n×10+3-n×10+4, sometimes even up to n×10+6 times (e.g. Te) those of the crust. As a result, they can form their independent ore deposits. Studies have shown that such independent ore deposits are mostly distributed in the southwestern part of China, most of which belong to low-temperature ore deposits, ranging in age from Yanshanian to Himalayan (Cretaceous to Cenozoic), with a significant time gap with the host strata. Moreover, this paper also deals with the existing forms (as independent minerals, occurring isomorphously and being adsorbed) of the dispersed elements in those independent ore deposits. The discovery of independent ore deposits of dispersed elements is a great breakthrough in the study of dispersed element metallogenesis.展开更多
A detailed study on a small scale of the effect of phosphatization on the chemistry of marine cobalt-rich ferromanganese crusts supplies useful information for the evaluation and comprehensive utilization of crust min...A detailed study on a small scale of the effect of phosphatization on the chemistry of marine cobalt-rich ferromanganese crusts supplies useful information for the evaluation and comprehensive utilization of crust mineral resources. Sub-samples from top to bottom of a 10-cm thick sample from the NW Pacific Magellan seamount were taken at 5 mm intervals. The concentration profiles of ore-forming and rare earth elements show that obvious differences exist between young unphosphatized crusts and old phosphatized crusts. In the old crusts Fe, Mn, Si, Al, Zn, Mg, Co, Ni and Cu elements are depleted and Ca, P, Sr, Ba and Pb elements are enriched. The order of depletion is Co > Ni > Mg > Al > Mn > Si> Cu > Zn > Fe, while the order of enrichment is P > Ca > Ba > Pb > Sr. The phosphate mineral controls the concentration variation of the ore-forming elements in crusts and causes loss of the main ore-forming elements such as Co and Ni. The phosphatization also affects the abundance of REEs in the crusts. REEs are more abundant and the content of Ce in old crusts is higher than that in young crusts, however, the pattern of REEs and their fractionation characteristics in new and old crusts are not fundamentally changed. A Y-positive anomaly in old crusts has no relationship to the phosphatization.展开更多
基金supported by the National Natural Science Foundation of China (40373025)
文摘Rare earth element(REE) is widely used in various fields of geology.Study of the existing forms of REE in geological objects is a necessity for us to solve geological problems related with REE.This paper tried to make it clear the existing forms of REE in gold-bearing pyrite in Jinshan gold deposit by stepwise dissolution test with ICP-MS analysis.Results showed that content of REE in fluid-inclusions of gold-bearing pyrite was very low,which only took about 0.07%–0.70% of the ΣREE,and that of pyrite phase ...
文摘Trace elements in cassiterite, including Ta, W, Fe, Mn, Ti, Zr, V, Sc, Si, kl, In, Ga, Ge, Be,Bi, Ag, Sb, As, Cu, Pb, Zn, Co and REE, have been studied by many workers (Shan Zhenhua etal., 1988; Huang Zhou Tianren et al., 1987; Wu Qingsheng et al., l988; Hu Zening, 1988, Li Zhong-qing 1988 MingZhi et al.,1988; Wang Lihua et al., 1988, Liu Kanghuai, 1990). Up to now, however,most of the previous studiesareconcerned with tracoelement variations in cassiterites of diffirent occur-rences and colors from diffirent types of ore deposits, Data concerning the modes of occurrence of’ these trace elements are rare, except for the contention that Nb-Ta, F.2+-M.-F.3+ and W-F.3+ maysubstitute isomorphously for Sn as pointed out by Zhou Tianren et al. (1987) and Moller et al.(1988). In this paper we are concerned with the compositionaI characterishcs as well as the modes ofoccurrence of trace elements in cassiterites from quartz veins and greisens in the Dupangling tin field,Guangxi, based on mu1tivariate statistical analys es.Tin mineralization in the Dupang1ing area is found associated with the medium-to fine-grainedprotolithionite-albite granite and its outer contacts. Cassiterite occurs, with wolframite, both inquartz veins in the contact and in greisens within the granite.’ ) Spatially, greisens become dominantover quartz veins in going from the contact to the interior of the granite and with increasing depth.The greisens are of various shapes. The vein-shaPed and the sheet-shaped greisens at the top of thegranite are rich in quartz and the chambered greisens always constitute rich ores and contain abun-dant topaz or mica. Genetically, Sn, W ndneralizations associated with the protolithionite-albite gran-ite are considered to have been formed from fluid melt derived from the ore-forming magma re-sponsible for the
文摘Dispersed elements do not always occur as associated elements in the ore deposits of other elements. Instead, they can constitute independent ore deposits. The focus of this paper is placed on the mechanism of super-enrichment of the four dispersed elements Tl, Ge, Se, and Te under favorable geological conditions, where their enrichment coefficients are so high that their abundances can reach n×10+3-n×10+4, sometimes even up to n×10+6 times (e.g. Te) those of the crust. As a result, they can form their independent ore deposits. Studies have shown that such independent ore deposits are mostly distributed in the southwestern part of China, most of which belong to low-temperature ore deposits, ranging in age from Yanshanian to Himalayan (Cretaceous to Cenozoic), with a significant time gap with the host strata. Moreover, this paper also deals with the existing forms (as independent minerals, occurring isomorphously and being adsorbed) of the dispersed elements in those independent ore deposits. The discovery of independent ore deposits of dispersed elements is a great breakthrough in the study of dispersed element metallogenesis.
基金supported by grant DY95-08-05 from the China Ocean Mineral Resources R&D Associationthe National Natural Science Foundation of China(Grant 40373002).
文摘A detailed study on a small scale of the effect of phosphatization on the chemistry of marine cobalt-rich ferromanganese crusts supplies useful information for the evaluation and comprehensive utilization of crust mineral resources. Sub-samples from top to bottom of a 10-cm thick sample from the NW Pacific Magellan seamount were taken at 5 mm intervals. The concentration profiles of ore-forming and rare earth elements show that obvious differences exist between young unphosphatized crusts and old phosphatized crusts. In the old crusts Fe, Mn, Si, Al, Zn, Mg, Co, Ni and Cu elements are depleted and Ca, P, Sr, Ba and Pb elements are enriched. The order of depletion is Co > Ni > Mg > Al > Mn > Si> Cu > Zn > Fe, while the order of enrichment is P > Ca > Ba > Pb > Sr. The phosphate mineral controls the concentration variation of the ore-forming elements in crusts and causes loss of the main ore-forming elements such as Co and Ni. The phosphatization also affects the abundance of REEs in the crusts. REEs are more abundant and the content of Ce in old crusts is higher than that in young crusts, however, the pattern of REEs and their fractionation characteristics in new and old crusts are not fundamentally changed. A Y-positive anomaly in old crusts has no relationship to the phosphatization.
