Phase Transition and Negative Thermal Expansion Property of ZrMnMo_3O_(12)

A novel material of ZrMnMo3012 with negative thermal expansion is presented. The phase transition temperature and coemcient of thermal expansion （CTE） are investigated by temperature-dependent x-ray diffraction and Raman spectra. It is shown that ZrMnMo3012 adopts monoclinic structure with space group P21/a （No. 14） from 298 to 358K and transforms to orthorhombic with space group Pnma （No. 62） above 363K. The linear CTE obtained from the results of XRD refinement is -2.80 × 10-6 K-1 from 363 to 873 K. The CTE of the bulk cylinder ceramic measured by a thermal dilatometer is -4.7× 10-6 K-1 from 373 to 773K approximatively.

Mechanical and Thermal Expansion Properties of SiCp/ZAlSi9Mg Composites Produced by Centrifugal Casting

Centrifugal casting was applied to produce cylindrical castings using SiCp/Al composite slurry,which contained 20%SiC particles.The castings comprised a particle free zone and a particle rich zone.The amount of SiC particles had a dramatic transformation from the particle rich zone to the particle free zone,and the maximum content of SiC particles in the particle rich zone reached up to 40 vol%.The ultimate tensile strength（UTS） of the as-cast SiCp / Al composites in the particle rich zone was 143 MPa,and the fracture was caused by the desorption of SiC particles from matrix alloy.The coefficient of thermal expansion（CTE） of the SiC_p / Al composites in the range of 20 and 100 ℃ was determined as 16.67×10^（-6） s^（-1）,and the experimental CTE was lower than the predicted data based on the Kerner＇s model.The results show that the decrease in CTE in the case of the composites at high temperature stage can be attributed to the solute concentration of Si in Al and the plastic deformation of the matrix alloy in the composites with void architecture.

Chemical, mechanical, and thermal expansion properties of a carbon nanotube-reinforced aluminum nanocomposite

In the present study,the chemical and mechanical properties and the thermal expansion of a carbon nanotube（CNT）-based crystalline nano-aluminum（nano Al） composite were reported.The properties of nanocomposites were tailored by incorporating CNTs into the nano Al matrix using a physical mixing method.The elastic moduli and the coefficient of thermal expansion（CTE） of the nanocomposites were also estimated to understand the effects of CNT reinforcement in the Al matrix.Microstructural characterization of the nanocomposite reveals that the CNTs are dispersed and embedded in the Al matrix.The experimental results indicate that the incorporation of CNTs into the nano Al matrix results in the increase in hardness and elastic modulus along with a concomitant decrease in the coefficient of thermal expansion The hardness and elastic modulus of the nanocomposite increase by 21%and 20%,respectively,upon CNT addition.The CTE of CNT/A1 nanocomposite decreases to 70%compared with that of nano Al.

Chemical expansion of solid oxide fuel cell materials: A brief overview

The importance of oxygen non-stoichiometry induced expansion, known as chemical expansion, for the mechanical properties of solid oxide fuel cells （SOFCs） is discussed. The methods used to measure chemical expansion and the defects responsible for its existence are introduced. Recent work demonstrating the origin of chemical expansion in fluorite structured oxides for SOFCs is presented. Models used to predict stress induced by chemical expansion in SOFCs, highlighting the necessity of considering electro-chemo-mechanical coupling relationships, are discussed.

Mechanical, electrical, and thermal expansion properties of carbon nanotube-based silver and silver–palladium alloy composites

The mechanical, electrical, and thermal expansion properties of carbon nanotube（CNT）-based silver and silver–palladium（10：1, w/w） alloy nanocomposites are reported. To tailor the properties of silver, CNTs were incorporated into a silver matrix by a modified molecular level-mixing process. CNTs interact weakly with silver because of their non-reactive nature and lack of mutual solubility. Therefore, palladium was utilized as an alloying element to improve interfacial adhesion. Comparative microstructural characterizations and property evaluations of the nanocomposites were performed. The structural characterizations revealed that decorated type-CNTs were dispersed, embedded, and anchored into the silver matrix. The experimental results indicated that the modification of the silver and silver–palladium nanocomposite with CNT resulted in increases in the hardness and Young＇s modulus along with concomitant decreases in the electrical conductivity and the coefficient of thermal expansion（CTE）. The hardness and Young＇s modulus of the nanocomposites were increased by 30%？40% whereas the CTE was decreased to 50%-60% of the CTE of silver. The significantly improved CTE and the mechanical properties of the CNT-reinforced silver and silver–palladium nanocomposites are correlated with the intriguing properties of CNTs and with good interfacial adhesion between the CNTs and silver as a result of the fabrication process and the contact action of palladium as an alloying element.

Thermal Expansion and Mechanical Properties of Middle Reinforcement Content SiCp/Al Composites Fabricated by PM Technology

Middle reinforcement content SiCp/Al composites（Vp=30%, 35% and 40%） for precision optical systems applications were fabricated by powder metallurgy technology. The composites were free of porosity and SiC particles distributed uniformly in the composites. The mean linear coefficients of thermal expansion（20-100 ℃） of SiCp/Al composites ranged from 11.6×10-6 to 13.3×10-6 K-1 and decreased with an increase in volume fraction of SiC content. The experimental coeffi cients of thermal expansion agreed well with predicted values based on Kerner＇s model. The Brinell hardness increased from 116 to 147, and the modulus increased from 99 to 112 GPa for the corresponding composites. The tensile strengths were higher than 320 MPa, but no signifi cant increasing trend between tensile strength and SiC content was observed.

The preparation and performance analysis of zirconium-modified aluminum phosphate-based high-temperature(RT-1500℃)resistant adhesive for joining alumina in extreme environment

High-temperature-resistant adhesives are critical materials in the aerospace field.The zirconium-modified aluminum phosphate-based adhesives developed in this work had the advantage of adjustable thermal expansibility,achieving a high matching of coefficient of thermal expansion(CTE)with alumina.The introduction of zirconium can significantly improve the thermal stability of the adhesive matrix,and the Zr/Al ratio substantially affects the various reaction processes inside the adhesive,especially the types of zirconium-containing compounds.Most of the zirconium-containing compounds in the A7Z3 adhesive were ZrO_(2) only when the mass ratio of zirconium hydroxide to aluminum hydroxide was 3:7,which was the key reason why it had the highest CTE.The room-temperature bonding strength of A7Z3 after heat treatment at 1500℃reached 67.2 MPa.After pretreatment at 1500℃,the high-temperature bonding strength of A7Z3 was greater than 50 MPa in the range of(room temperature)RT-1000℃.After 40 thermal cycles between RT and 1500℃,the bonding strength still reached 10 MPa.Physical bonding occurred at temperatures below 1000℃,while chemical bonding dominated above 1000℃based on the generation of Al5BO9 and mullite at the interfaces.