Application and Practice of Knowledge Graph in Experimental Teaching in Colleges and Universities

With the reform of experimental teaching in colleges and universities,the teaching mode of"experimental students as the main body,experimental teachers as the guide"needs to constantly explore new experimental teaching methods.In this paper,knowledge graph is integrated into the experiment of mechanical principle to guide undergraduates to use knowledge graph to analyze and summarize independently in experimental teaching activities,aiming at cultivating undergraduates interest in learning and innovative thinking,so as to improve the quality of experimental teaching.This study has a certain reference significance for experimental teaching in colleges and universities.

锆基MOF光催化制过氧化氢的综合化学实验设计

为了加强科研成果向实验教学转化和培养学生科研创新能力,设计基于金属有机框架(MOF)材料的光催化制过氧化氢(H_(2)O_(2))综合化学实验。以双氨基功能化联苯二甲酸为配体,四氯化锆为金属盐,苯甲酸为调节剂,通过溶剂热法合成锆基MOF催化剂UiO-67-(NH_(2))_(2)。利用PXRD和UV-DRS对样品结构和可见光吸收性能进行表征。以蓝光LED为光源,探究光源功率、催化剂浓度和反应时间对光催化制H_(2)O_(2)效率的影响。采用罗丹明B为模拟污染物,验证所制H_(2)O_(2)溶液的降解污染物性能。该综合实验涉及MOF合成及表征、仪器测试、数据分析等多个环节,不仅加深学生对化学、材料和环境等多学科基础知识的综合理解,还能激发学生的学习积极性和培养学生的创新能力。

气态碘在COF-103上吸附的理论研究

采用第一性原理和巨正则蒙特卡罗方法,模拟研究了气态碘分子(I2)在共价有机框架材料(COF-103)中的吸附行为,并讨论了气态氧化物、氯化物和挥发性有机化合物(VOCs)等杂质气体的竞争吸附影响.结果表明,I2偏向以垂直方式吸附于COF-103苯环的碳原子位,其中,长程色散相互作用具有重要的贡献,色散能在吸附能中的占比最多可达46%.I2与COF-103之间存在少量电荷转移,且可能形成具有弱共价相互作用的次级键.杂质气体中苯分子(C6H6)的吸附能和等量吸附热最大,与COF-103的亲和性最强,并且可以占据I2的吸附位点,从而引起I2吸附量的显著降低.

Changes of Organic Matter, N, P and K Content of Soils in Red Soil Areas Under Long-Term Experiment

The content of organic matter （OM）, nitrogen （N）, phosphorus （P）, and potassium （K） in the three selected soils, including Calcaric Purpli-Orthic Primosols （purple sand-shale parent material）, Dystric Turbi-Anthric Primosols （quaternary red clay parent material） and Typic Udi-Sandic Primosols （granite parent material） were studied under a long-term experiment by using crop straw and inorganic fertilizers at the Hunan Red Soil Experiment Station of Chinese Academy of Agricultural Sciences. The results showed that the contents of OM, N, P and K in the three selected soils increased after 23 years application of crop straw and inorganic fertilizers, but the contents increased much less when crop straw or inorganic fertilizers was applied alone. The nutrient contents in the three soils developed from granite changed more remarkably than those in the soil derived from quaternary red clay and purple sand-shale. It was also found that the contents of OM, N, and P increased slightly in the treatments without applying fertilizers or returning the crop straw to the root bed. Combined application of inorganic fertilizers and crop straw could remarkably increase the contents of OM, alkalihydrolyzable N and available K, the positive correlation between application of organic fertilizers and increase of OM in soil did not always happened, it provided evidence for the relation between appropriate C/N ratio and accumulation of OM in soil. The increase of nutrient content was influenced by the soil properties. By comparing the contents of nutrient in 0-20 cm depth in the three different soils, it was concluded that the most increases of OM, alkali-hydrolyzable N, and available P were observed in Typic Udi-Sandic Primosols with the average increase by 3.03, 27.38, and 21.73 mg kg^-1, respectively. The available K increased in Dystric Turbi-Anthric Primosols with the average increase by 25.82 mg kg^-1, while it decreased in Calcaric Purpli-Orthic Primosols and Typic Udi-Sandic Primosols. It was concluded that the application of inorganic fertilizer and crop straw was important to improve the soil fertility for all of three selected soils. The straw return to the field had played a significant role for enhancement of the soil quality in the study areas. The application of inorganic fertilizer combined with the straw return to the fields could remarkably improve the soil fertility.

Effects of Organic Enrichment on Sandy Beach Meiofauna:A Laboratory Microcosm Experiment

Meiofauna samples from intertidal sediments of Qingdao No.2 Bathing Beach, China, were collected for field study, and subjected to organic enrichment in a laboratory microcosm experiment for 21 d. There were three different treatments including non-organic addition as the control, low-organic enrichment (2 g DW green algae per 150 mL) and high-organic enrichment (10 g DW green algae per 150 mL). After 21 d, the meiofauna richness decreased in both organic enrichment treatments. Among the three treatments, total meiofauna abundance was significantly different, and the control groups had higher abundance than the other two treatment groups. However, the responses of the meiofauna abundance in the two organic enrichment treatments were non-significantly different. The relationship of meiofaunal abundance and nematode/copepod ratios to organic matter and oxygen level in the microcosm experiments were discussed.

Remarks on interpretations of the Eotvos experiment and misinterpretation of E=mc^2

The Eotvos experiment on the verification of equivalence between inertial mass and gravitational mass of a body is famous for its accuracy. A question is, however, can these experimental results be applied to the case of a physical space in general relativity, where the space coordinates could be arbitrary？ It is pointed out that it can be validly applied because it has been proven that Einstein＇s equivalence principle for a physical space must have a frame of reference with the Euclidean-like structure. Will claimed further that such an overall accuracy can be translated into an accuracy of the equivalence between inertial mass and each type of energy. It is shown that, according to general relativity, such a claim is incorrect. The root of this problem is due to an inadequate understanding of special relativity that produced the famous equation E=mc^2, which must be understood in terms of energy conservation. Concurrently, it is pointed out that this error is a problem in Will＇s book, ‘Theory and Experiment in Gravitational Physics＇.

Crop yields and soil organic carbon dynamics in a long-term fertilization experiment in an extremely arid region of northern Xinjiang, China

A long-term fertilization experiment was set up in northern Xinjiang, China to evaluate the dynamics of crop production and soil organic carbon （SOC） from 1990 to 2012 with seven fertilization treatments. The seven treatments included an unfertilized control （CK） and six different combinations of phosphorus （P）, potassium （K）, nitrogen （N）, straw （S） and animal manure （M）. The balanced fertilization treatments had significantly （P〈0.05） higher average yields than the unbalanced ones. The treatment with 2/3 N from potassium sulfate （NPK） and 1/3 N from farmyard manure （NPKM） had a higher average yield than the other treatments. The average yields （over the 23 years） in the treatments of NPK, and urea, calcium superphosphate （NP） did not differ significantly （P〉0.05） but were higher than that in the treatment with urea and potassium sulfate （NK; P〈0.05）. The results also show that the highest increases in SOC （P〈0.05） occurred in NPKM with a potential increase of 1.2 t C/（hm2.a）. The increase in SOC was only 0.31, 0.30 and 0.12 t C/（hm2.a） for NPKS （9/10 N from NPK and 1/10 N from straw）, NPK and NP, respectively; and the SOC in the NP, NK and CK treatments were approaching equilibrium and so did not rise or fall significantly over the 23-year experiment. A complete NPK plus manure fertilization program is recommended for this extremely arid region to maximize both yields and carbon sequestration.

基于“芳酸结构形貌调控的Zn-MOFs制备表征”构建无机化学综合实验

金属有机框架化合物(MOFs)是有机配体与金属离子或金属簇通过配位键组装而成的具有分子内孔隙结构的有机-无机杂化材料,具有比表面积大、孔隙率高、孔径可调、稳定性好等特征,在催化、能源、药物输送及传感等领域广泛应用。MOFs的物性特征与其形貌及组成密切相关,故形貌调控至关重要。本文以对苯二甲酸、均苯三甲酸、2,6-萘二羧酸为有机配体,以锌离子为金属中心,采用室温沉淀法制备Zn-MOFs纳米材料体系,基于有机配体调控Zn-MOFs形貌。采用扫描电子显微镜表征其形貌,X-射线衍射光谱表征其晶体结构,红外光谱表征化学组成,紫外可见吸收光谱表征其光谱特性,并修饰至玻碳电极表面,构建光电化学界面,考察三种Zn-MOFs纳米材料的光电转换性能。通过该综合实验,有助于延伸无机化学金属配合物之理论基础,拓展光电化学及化学修饰电极知识领域,有利于强化科研创新意识、提升材料制备及表征相关实验技能、建立数据处理与结果分析的思维模式,有助于培养学生立志创新、勇于探索之精神。

Kolmogorov’s Probability Spaces for “Entangled” Data-Subsets of EPRB Experiments: No Violation of Einstein’s Separation Principle

It is demonstrated that the use of Kolmogorov’s probability theory to describe results of quantum probability for EPRB (Einstein-Podolsky-Rosen-Bohm) experiments requires extreme care when different subsets of measurement outcomes are considered. J. S. Bell and his followers have committed critical inaccuracies related to spin-gauge and probability measures of such subsets, because they use exclusively a single probability space for all data sets and sub-sets of data. It is also shown that Bell and followers use far too stringent epistemological requirements for the consequences of space-like separation. Their requirements reach way beyond Einstein’s separation principle and cannot be met by the major existing physical theories including relativity and even classical mechanics. For example, the independent free will does not empower the experimenters to choose multiple independent spin-gauges in the two EPRB wings. It is demonstrated that the suggestion of instantaneous influences at a distance (supposedly “derived” from experiments with entangled quantum entities) is a consequence of said inaccuracies and takes back rank as soon as the Kolmogorov probability measures are related to a consistent global spin-gauge and permitted to be different for different data subsets: Using statistical interpretations and different probability spaces for certain subsets of outcomes instead of probability amplitudes related to single quantum entities, permits physical explanations without a violation of Einstein’s separation principle.

The Application of Visual Organization Principle in the Detection of Sleep Spindles

In order to detect the sleep spindles simply and efficiently, a novel time-domain approach to detect sleep spindles based on the principles of visual organization is proposed. The code idea of the visual organization is to organize the primary visual elements according to some rules of organization, and to form a more meaningful object of visual processing, as the input of next process. After the collected EEG is processed with the merging algorithm based on the principle of visual organization, it can extract the time-domain feature frequency and duration time better. Use these features with a simple algorithm to detect spindles achieving sensitivity of 92.5% and specificity of 98.1%, which verifies the validity of this method to detect the sleep spindles.

Simulation Experiments and Kinetics for the Formation of Organic Sulfide in Marine Carbonate Reservoirs

Thermal simulation experiments on the system of gasoline and magnesium sulfate were carried out using an autoclave operating at high temperature and high pressure in the presence of water. Properties of the gas-oil-solid 3-phase products were analyzed by some advanced analytical methods including gas chromatography, microcoulometry, capillary gas chromatography in combination with a pulsed flame photometric detector, FT-IR and X-ray diffraction. The results showed that the reaction could proceed at 450℃ - 550℃ to produce MgO, S, C, H2S, CO2 and a series of organic sulfides such as mercaptans, sulfoethers and thiophenes as the main products. According to the reaction kinetics, the calculated activation energy of the reaction is 68.9 kJ·mol-1.

International Experience of Farmers Specialized Cooperative Economic Organizations in Marketing of Agricultural Products

In the world,development modes of farmers specialized cooperative economic organizations mainly includes two types:( i) specialized agricultural cooperatives with the United States of America as representative,and( ii) comprehensive agricultural cooperatives with Japan and South Korea as representative. In comparison,China mainly develops farmers specialized cooperatives which are agricultural production with family as unit and small in land and management scale like agricultural production in Japan. Therefore,in marketing of agricultural products,cooperatives in the United States of America and Japan have successful experience. China may learn such experience in the development of farmers specialized cooperatives.

Experimental Simulation Study of the Dominant Enrichment Area of Terrestrial Organic Matter in the Shallow-Delta Sedimentary System of the Yacheng Formation in the Qiongdongnan Basin

Shallow-delta sedimentary systems receive both terrestrial and marine organic matter. As oil and gas exploration activities determine that the source rocks of the deep-water area of the Qiongdongnan Basin, northern South China Sea, are generally rich in and even dominated by terrestrial organic matter, this has led many researchers to examine the rules governing terrestrial organic matter enrichment in shallow-delta sea sedimentary systems. However, the deep burial of source rocks in deep-water areas and the relatively small amount of drilling undertaken have greatly restricted the study of these rules. In this study, the ‘forward modeling' research method was used to observe and analyze the deposition and preservation of terrestrial organic matter through flume experiments, where the depositional results were carefully depicted and sampled. The total organic carbon content of selected samples was measured and when combined with qualitative observations and quantitative comparison results, the dominant enrichment areas of terrestrial organic matter were identified. The experimental results show that the overbank parts of the delta front, the dune countercurrent surface, the low-lying parts, the delta front slope area and the shallow-prodelta sea area are where terrestrial organic matter is predominantly enriched. This provides an important basis and guidance for the prediction of the development areas of marine source rocks with terrestrial input in the deep-water areas of the Qiongdongnan Basin.

Developing Integrated Collective Bargaining System in a Bi National Organization:The Case of the Tanzania Zambia Railway Authority(TAZARA)

The Tanzania Zambia Railway stretches 1,860 kilometers from the East African Indian Ocean port of Dar es Salaam in Tanzania to New Kapiri-Mposhi in land locked Zambia.It is defined as a bi-national organization as opposed to either transnational or multinational because it is jointly owned and managed by the Governments of Tanzania and Zambia.Its construction was made possible by Chinese interest-free loan to the two Governments.Few development projects in Africa have been charged with as much political and ideological dynamite as Tanzania Zambia Railway.To the Western powers,angry that the Chinese had entered territory which they considered their own preserve,it was a Red Railway intended to thrust communism into the very heart of Africa.For the white regimes in Southern Africa,grimly attempting to hold back demands for majority rule,it was seen as Africa’s Ho Chi Minh Trail,carrying guerrilla further,armed with Chinese thoughts and weapons to the banks of the Zambezi River.The Chinese regarded the project as a Friendship Route to strengthen the new African states against the forces of imperialism and for Tanzania and Zambia it was a Freedom Railway,which should prove an instrument in increasing their independence.These reactions underpin not only the complexity of the establishment and management of a bi-national organization but also present challenges to the two national trade unions on how best they can represent their members.Industrial relations literature has cited differences in countries’historical,social,political,economic,and ideological background as the main obstacles in the development of collective bargaining machinery in transnational or multinational organizations.A study in Tanzania Zambia Railway Authority has attempted to develop an integrated bi-national collective bargaining machinery whose collective agreements are likely to be legally enforceable in their respective countries.This paper explores the development of trade unions in both Tanzania and Zambia which can be divided in three phases:first,the construction phase;second,the consolidation phase;and the third and final phase,trade union liberalization and political pluralism which covers the development of a bi national collective bargaining model with its Joint Industrial Council structure and negotiation procedures.The paper compares and contrasts trade union development in the two contracting states and critically examines how each phase has influenced trade union development.It provides a brief historical outline of collective bargaining process and spells out advantages and limitations of bi-national collective bargaining machinery.The paper concludes by observing that one of the main objectives of regional groupings is economic integration and suggests that integrated collective bargaining machinery be adopted as an ideal industrial relations model for regional groupings such as the African Union(AU),Southern African Development Community(SADC),Common Market for Eastern and Southern Africa(COMESA),Economic Community for West African States(ECOWAS),Eastern African Community,and other regional groupings around the world since it localizes industrial relations function in general and collective bargaining in particular.

Generativity of Self-Organizing Processes and Their Correlative Description in Terms of a Formal Language of Meta-Ordinal Generative Nature, in the Light of the Maximum Ordinality Principle and the Explicit Solution to the “Three-Body Problem”

The main objective of this paper is to demonstrate that the internal processes of Self-Organizing Systems represent a unique and singular process, characterized by their specific generativity. This process can be modeled using the Maximum Ordinality Principle and its associated formal language, known as the “Incipient” Differential Calculus (IDC).

基于离子液体MOF复合材料的碘吸附性能在化学实验教学中的设计与探索

针对当下本科化学实验课教学存在的问题进行教学改革的探索,将科学研究的模式和本科化学实验教学相结合,设计了“基于离子液体MOF复合材料的碘吸附性能”实验,不仅可以巩固学生在本科化学实验中学习的实验操作内容,而且又将MOF材料、吸附分离等前沿热点内容融入其中,可提高化工专业本科生的理论水平、实验能力和创新能力。本实验覆盖了化工、材料和环境等多个领域的学科内容,具有显著的多学科交叉特性。

综合创新实验:功能化COFs在锂硫电池中的应用

将碳纳米管作为载体,通过1,3,5-均苯三甲醛与3,8-二氨基-6-苯基菲啶在乙酸存在下的可逆席夫碱反应,合成了一种碳纳米管支撑的共价有机骨架复合材料(COF@CNT)。并用1,3-丙磺酸内酯将其功能化,进一步得到两性离子功能化的共价有机骨架复合材料(ZW-COF@CNT)。将该复合材料作为正极的硫宿主材料组装到锂硫电池中,研究其对电化学性能的影响。本实验涉及抽滤、真空干燥、纽扣电池组装等操作过程,也包括材料表征、电池性能测试等分析过程。

Effects of Long-Term Organic Amendments on Soil Organic Carbon in a Paddy Field: A Case Study on Red Soil

Soil organic carbon （SOC） is one of the main carbon reservoirs in the terrestrial ecosystem. It is important to study SOC dynamics and effects of organic carbon amendments in paddy fields because of their vest expansion in south China. A study was carried out to evaluate the relationship between the SOC content and organic carbon input under various organic amendments at a long-term fertilization experiment that was established on a red soil under a double rice cropping system in 1981. The treatments included non-fertilization （CK）, nitrogen-phosphorus-potassium fertilization in early rice only （NPK）, green manure （Astragalus sinicus L.） in early rice only （OM1）, high rate of green manure in early rice only （OM2）, combined green manure in early rice and farmyard manure in late rice （OM3）, combined green manure in early rice, farmyard manure in late rice and rice straw mulching in winter （OM4）, combined green manure in early rice and rice straw mulching in winter （OMS）. Our data showed that the SOC content was the highest under OM3 and OM4, followed by OM1, OM2 and OM5, then NPK fertilization, and the lowest under non-fertilization. However, our analyses in SOC stock indicated a significant difference between OM3 （33.9 t ha^-1） and OM4 （31.8 t ha^-1）, but no difference between NPK fertilization （27 t ha^-1） and nonfertilization （28.1 t ha^-1）. There was a significant linear increase in SOC over time for all treatments, and the slop of linear equation was greater in organic manure treatments （0.276-0.344 g kg-1 yr^-1） than in chemical fertilizer （0.216 g kg^-1 yr^-1） and no fertilizer （0.127 g kg^-1 yr^-1）.

Hydrocarbon Generation Kinetic Characteristics from Different Types of Organic Matter

In order to contrast the hydrocarbon generation kinetic characteristics from different types of organic matter（OM）,18 samples from different basins were pyrolyzed using Rock-Eval-Ⅱapparatus under the open system.From the experimental results,the curve of hydrocarbon generation rate vs.temperature can be easily obtained,which usually can be used to optimize kinetic parameters （A,E,F）of the hydrocarbon generation model.In this paper,the parallel first-order reaction with a single frequency factor model is selected to describe the hydrocarbon generation kinetic characteristics. The hydrocarbon generation kinetic parameters reveal that the types of compound structures and chemical bonds of the lacustrine fades typeⅠOM are relatively homogeneous,with one dominating activation energy.The types of chemical bonds of the lacustrine facies typeⅡ2 OM and the terrestrial facies typeⅢOM are relative complex,with a broad activation energy distribution,and the reaction fraction of the preponderant activation energy drops with the decrease of hydrogen index.The impact of the activation energy distribution spaces on the geological extrapolation of kinetic parameters is also investigated.The results show that it has little effect on the hydrocarbon transformation ratio（TR）and therefore,the parallel first-order reaction model with proper number of activation energies can be better used to describe the hydrocarbon generation process.The geological extrapolation results of 18 samples of kinetic parameters show that the distribution range of the hydrocarbon generation rate of the typeⅠOM is relatively narrow and the hydrocarbon generation curve is smooth.In comparison,the distribution range of the hydrocarbon generation for typeⅢand typeⅡ2-ⅢOM are quite wide,and the hydrocarbon generation curves have fluctuation phenomena.The distribution range of the hydrocarbon generation rate and the fluctuation phenomena are related to the kinetic parameters of OM;the narrower the activation energy distribution,the narrower the hydrocarbon generation rate distribution,and the smoother the hydrocarbon generation curve,and vice versa.