Geological reservoir and resource potential(10^(13)m^(3))of gas hydrates in the South China Sea

A detailed understanding of the distribution and potential of natural gas hydrate(NGHs)resources is crucial to fostering the industrialization of those resources in the South China Sea,where NGHs are abundant.In this study,this study analyzed the applicability of resource evaluation methods,including the volumetric,genesis,and analogy methods,and estimated NGHs resource potential in the South China Sea by using scientific resource evaluation methods based on the factors controlling the geological accumulation and the reservoir characteristics of NGHs.Furthermore,this study compared the evaluation results of NGHs resource evaluations in representative worldwise sea areas via rational analysis.The results of this study are as follows:(1)The gas hydrate accumulation in the South China Sea is characterized by multiple sources of gas supply,multi-channel migration,and extensive accumulation,which are significantly different from those of oil and gas and other unconventional resources.(2)The evaluation of gas hydrate resources in the South China Sea is a highly targeted,stratified,and multidisciplinary evaluation of geological resources under the framework of a multi-type gas hydrate resource evaluation system and focuses on the comprehensive utilization of multi-source heterogeneous data.(3)Global NGHs resources is n×10^(15)m^(3),while the NGHs resources in the South China Sea are estimated to be 10^(13)m^(3),which is comparable to the abundance of typical marine NGHs deposits in other parts of the world.In the South China Sea,the NGHs resources have a broad prospect and provide a substantial resource base for production tests and industrialization of NGHs.

Tectonic-thermal history and hydrocarbon potential of the Pearl River Mouth Basin,northern South China Sea:Insights from borehole apatite fission-track thermochronology

The Pearl River Mouth Basin(PRMB)is one of the most petroliferous basins on the northern margin of the South China Sea.Knowledge of the thermal history of the PRMB is significant for understanding its tectonic evolution and for unraveling its poorly studied source-rock maturation history.Our investigations in this study are based on apatite fission-track(AFT)thermochronology analysis of 12 cutting samples from 4 boreholes.Both AFT ages and length data suggested that the PRMB has experienced quite complicated thermal evolution.Thermal history modeling results unraveled four successive events of heating separated by three stages of cooling since the early Middle Eocene.The cooling events occurred approximately in the Late Eocene,early Oligocene,and the Late Miocene,possibly attributed to the Zhuqiong II Event,Nanhai Event,and Dongsha Event,respectively.The erosion amount during the first cooling stage is roughly estimated to be about 455-712 m,with an erosion rate of 0.08-0.12 mm/a.The second erosion-driven cooling is stronger than the first one,with an erosion amount of about 747-814 m and an erosion rate between about 0.13-0.21 mm/a.The erosion amount calculated related to the third cooling event varies from 800 m to 3419 m,which is speculative due to the possible influence of the magmatic activity.

Geology and hydrocarbon accumulations in the deepwater of the northwestern South China Sea——with focus on natural gas

The deepwater of the northwestern South China Sea is located in the central to southern parts of the Qiongdongnan Basin （QDN Basin）, which is a key site for hydrocarbon exploration in recent years. In this study, the authors did a comprehensive analysis of gravity-magnetic data, extensive 3D seismic survey, cores and cuttings, paleontology and geochemical indexes, proposed the mechanism of natural gas origin, identified different oil and gas systems, and established the model of hydrocarbon accumulations in the deep-water region. Our basin tectonic simulation indicates that the evolution of QDN Basin was controlled by multiple-phased tectonic movements, such as Indochina-Eurasian Plate collision, Tibetan Uplift, Red River faulting and the expansion of the South China Sea which is characterized by Paleogene rifting, Neogene depression, and Eocene intensive faulting and lacustrine deposits. The drilling results show that this region is dominated by marine- terrestrial transitional and neritic-bathyal facies from the early Oligocene. The Yacheng Formation of the early Oligocene is rich in organic matter and a main gas-source rock. According to the geological-geochemical data from the latest drilling wells, Lingshui, Baodao, Changchang Sags have good hydrocarbon-generating potentials, where two plays from the Paleogene and Neogene reservoirs were developed. Those reservoirs occur in central canyon structural-lithologic trap zone, Changchang marginal trap zone and southern fault terrace of Baodao Sag. Among them, the central canyon trap zone has a great potential for exploration because the various reservoir- forming elements are well developed, i.e., good coal-measure source rocks, sufficient reservoirs from the Neogene turbidity sandstone and submarine fan, faults connecting source rock and reservoirs, effective vertical migration, late stage aggregation and favorable structural-lithological composite trapping. These study results provide an important scientific basis for hydrocarbon exploration in this region, evidenced by the recent discovery of the significant commercial LS-A gas field in the central canyon of the Lingshui Sag.

Petroleum Geology in Deepwater Settings in a Passive Continental Margin of a Marginal Sea:A Case Study from the South China Sea

Deepwater oil and gas exploration has become a global hotspot in recent years and the study of the deep waters of marginal seas is an important frontier research area.The South China Sea(SCS)is a typical marginal sea that includes Paleo SCS and New SCS tectonic cycles.The latter includes continental marginal rifting,intercontinental oceanic expansion and oceanic shrinking,which controlled the evolution of basins,and the generation,migration and accumulation of hydrocarbons in the deepwater basins on the continental margin of the northern SCS.In the Paleogene,the basins rifted along the margin of the continent and were filled mainly with sediments in marine-continental transitional environments.In the Neogene–Quaternary,due to thermal subsidence,neritic-abyssal facies sediments from the passive continental margin of the SCS mainly filled the basins.The source rocks include mainly Oligocene coal-bearing deltaic and marine mudstones,which were heated by multiple events with high geothermal temperature and terrestrial heat flow,resulting in the generation of gas and oil.The faults,diapirs and sandstones controlled the migration of hydrocarbons that accumulated principally in a large canyon channel,a continental deepwater fan,and a shelf-margin delta.

Sediment Compaction and Pore Pressure Prediction in Deepwater Basin of the South China Sea: Estimation from ODP and IODP Drilling Well Data

Overpressure in deepwater basins not only causes serious soft sediment deformation, but also significantly affects the safety of drilling operations. Therefore, prediction of overpressure in sediments has become an important task in deepwater oil exploration and development. In this study, we analyze the drilling data from ODP Leg 184 Sites 1144, 1146, and 1148, and IODP Leg 349 Sites U1431, U1432, U1433, and U1435 to study the sediment compaction and controls in the northern South China Sea. Sedimentation rate, sediment content, distribution area, and buried depth are the factors that influence sediment compaction in the deepwater basin of the South China Sea. Among these factors, the sediment content is the most important. The fitted normal compacted coefficients and mudline porosity for an interval of 50 m shows disciplinary variation versus depth. The pore pressure predicted from different fitted results shows varying overpressure situations. The normal compaction trend from Site 1144 reflects the porosity variation trend in stable deposition basins in the northern South China Sea. The predicted pore pressure shows overpressure at Site 1144, which is attributed to compaction disequilibrium. Nevertheless, the mixed lithology column may influence the predicted overpressure at Site 1148, which is responsible for the confusing result. Above all, we find that sediment compaction should serve as a proxy for pore pressure in the deepwater basin of the South China Sea.

Geochemical characteristics of Oligocene-Miocene sediments from the deepwater area of the northern South China Sea and their provenance implications

Geochemical and detrital zircon U-Pb dating data for drilled sediments from the Baiyun deepwater area of the northern South China Sea demonstrate a change of sedimentary sources from the Oligocene to the Miocene.Zircon ages of the pre-rift Eocene sequences are dominated by Yanshanian ages with various peak values（110–115 Ma for U1435 and L21; 150 Ma for H1）, indicating local sediment supply from the pre-existing Mesozoic magmatic belt. For the Oligocene sediments in the northern part of the basin, the rare earth elements show different distribution characteristics, indicating sediment supply from the paleo-Zhujiang River（Pearl River）, as also confirmed by the multimodal zircon age spectra of the Lower Oligocene strata in Well X28. By contrast, a positive Eu anomaly characterizes sediments from the western and southern parts of the basin, indicating potential provenances from intermediate to basic volcanic rock materials. The Baiyun Movement at the end of the Oligocene contributed to a large-scale subsidence in the deepwater area and also a northward retreat of continental shelf break, leading to deepening depositional environment in the basin. As a result, all the detrital zircon ages of the Upper Oligocene strata from Wells X28, L13, and L21 share a similar distribution, implying the possible control of a common source like the Zhujiang River. During the Miocene, whereas sediments in the northern area were mainly sourced from the Zhujiang River Delta, and those in the southern deepwater area continued to be affected by basic volcanic activities, the Dongsha Uplift could have contributed as the main source to the eastern area.

Modeling underwater transport of oil spilled from deepwater area in the South China Sea

Based on a Lagrangian integral technique and Lagrangian particle-tracking technique,a numerical model was developed to simulate the underwater transport of oil from a deepwater spill. This model comprises two submodels: a plume dynamics model and an advection-diffusion model. The former is used to simulate the stages dominated by the initial jet momentum and plume buoyancy of the spilled oil,while the latter is used to simulate the stage dominated by the ambient current and turbulence. The model validity was verified through comparisons of the model predictions with experimental data from several laboratory flume experiments and a field experiment. To demonstrate the capability of the model further,it was applied to the simulation of a hypothetical oil spill occurring at the seabed of a deepwater oil/gas field in the South China Sea. The results of the simulation would be useful for contingency planning with regard to the emergency response to an underwater oil spill.

Geophysical Signature of the Shallow Water Flow in the Deepwater Basin of the Northern South China Sea

Shallow water flow(SWF), a disastrous geohazard in the continental margin, has threatened deepwater drilling operations. Under overpressure conditions, continual flow delivering unconsolidated sands upward in the shallow layer below the seafloor may cause large and long-lasting uncontrolled flows; these flows may lead to control problems and cause well damage and foundation failure. Eruptions from over-pressured sands may result in seafloor craters, mounds, and cracks. Detailed studies of 2D/3D seismic data from a slope basin of the South China Sea(SCS) indicated the potential presence of SWF. It is commonly characterized by lower elastic impedance, a higher Vp/Vs ratio, and a higher Poisson's ratio than that for the surrounding sediments. Analysis of geological data indicated the SWF zone originated from a deepwater channel system with gas bearing over-pressured fluid flow and a high sedimentation rate. We proposed a fluid flow model for SWF that clearly identifies its stress and pressure changes. The rupture of previous SWF zones caused the fluid flow that occurred in the Baiyun Sag of the northern SCS.

Mass transport deposits and processes in the north slope of the Xisha Trough,northern South China Sea

Triple mass-transport deposits （MTDs） with areas of 625, 494 and 902 km^2, respectively, have been identified on the north slope of the Xisha Trough, northern South China Sea margin. Based on high-resolution seismic reflection data and multi-beam bathymetric data, the Quaternary MTDs are characterized by typical geometric shapes and internal structures. Results of slope analysis showed that they are developed in a steep slope ranging from 5° to 35°. The head wall scarps of the MTDs arrived to 50 km in length （from headwall to termination）. Their inner structures include well developed basal shear surface, growth faults, stepping lateral scarps, erosion grooves, and frontal thrust deformation. From seismic images, the central deepwater channel system of the Xisha Trough has been filled by interbedded channel-levee deposits and thick MTDs. Therefore, we inferred that the MTDs in the deepwater channel system could be dominated by far-travelled slope failure deposits even though there are local collapses of the trough walls. And then, we drew the two-dimensional process model and three- dimensional structure model diagram af the MTDs. Combined with the regional geological setting and previous studies, we discussed the trigger mechanisms of the triple MTDs.

Coexistence of natural gas hydrate,free gas and water in the gas hydrate system in the Shenhu Area,South China Sea

Shenhu Area is located in the Baiyun Sag of Pearl River Mouth Basin,which is on the northern continental slope of the South China Sea.Gas hydrates in this area have been intensively investigated,achieving a wide coverage of the three-dimensional seismic survey,a large number of boreholes,and detailed data of the seismic survey,logging,and core analysis.In the beginning of 2020,China has successfully conducted the second offshore production test of gas hydrates in this area.In this paper,studies were made on the structure of the hydrate system for the production test,based on detailed logging data and core analysis of this area.As to the results of nuclear magnetic resonance(NMR)logging and sonic logging of Well GMGS6-SH02 drilled during the GMGS6 Expedition,the hydrate system on which the production well located can be divided into three layers:(1)207.8–253.4 mbsf,45.6 m thick,gas hydrate layer,with gas hydrate saturation of 0–54.5%(31%av.);(2)253.4–278 mbsf,24.6 m thick,mixing layer consisting of gas hydrates,free gas,and water,with gas hydrate saturation of 0–22%(10%av.)and free gas saturation of 0–32%(13%av.);(3)278–297 mbsf,19 m thick,with free gas saturation of less than 7%.Moreover,the pore water freshening identified in the sediment cores,taken from the depth below the theoretically calculated base of methane hydrate stability zone,indicates the occurrence of gas hydrate.All these data reveal that gas hydrates,free gas,and water coexist in the mixing layer from different aspects.

Stability analysis of submarine slopes in the area of the test production of gas hydrate in the South China Sea

In this paper, the mechanical properties of gas hydrate-bearing sediments (GHBS) were summarized and the instability mechanism of submarine hydrate-bearing slope (SHBS) was analyzed under the background of the test production of gas hydrate in the northern part of the South China Sea. The strength reduction finite element method (SRFEM) was introduced to the stability analysis of submarine slopes for the safety of the test production. Two schemes were designed to determine the physical and mechanical parameters of four target wells. Through the division of the hydrate dissociation region and the design of four working conditions, the range and degree of hydrate dissociation at different stages during the test production were simulated. Based on the software ABAQUS, 37 FEM models of SHBS were set up to analyze and assess the stability of the submarine slopes in the area of the test production. Necessary information such as safety factors, deformation, and displacement were obtained at different stages and under different working conditions. According to the calculation results, the submarine slope area is stable before the test production, and the safety factors almost remains the same during and after the test production. All these indicate that the test production has no obvious influence on the area of the test production and the submarine slopes in the area are stable during and after the test production.

Research progress and challenges of natural gas hydrate resource evaluation in the South China Sea

As an efficient clean energy,natural gas hydrate(NGH)has become a hot topic in recent researches.Since1990 s,China has made great achievements and progress in NGH exploration in the South China Sea(SCS),including determination of the favorable distribution areas and favorable strata thickness,identification of the dual source for accumulation,evaluation of the prospective gas contents,verification of the widespread existence,and confirmation of the technical recoverability of NGH resources.However,there are three major challenges in the NGH studies.First,all the 24 national key and major projects in the SCS focused on trial production engineering and geological engineering in the past 20 years,while 8 of the 10 international NGH research projects focused on resource potential.Second,resource evaluation methods are outdated and some parameter selection are subjective.Third,the existing resource evaluation results are low-level with a great uncertainty,and cannot be used to guide NGH exploration and production or strategic research.To improve the evaluation of NGH resources in the SCS,future researches should focus on four aspects:(1)improve the research on the criterion of the objective existence of NGH and the method of prediction and evaluation;(2)apply new theories and methods from the global NGH research;(3)boost the research on the difference and correlation of the conditions of hydrocarbon migration and accumulation in different basins;(4)innovate the theory and method of NGH resource potential evaluation.

Evaluation of clayed silt properties on the behavior of hydrate production in South China Sea

Gas hydrate is one kind of potential energy resources that is buried under deep seafloor or frozen areas.The first trial offshore production from the silty reservoir was conducted in the South China Sea by the China Geological Survey(CGS).During this test,there were many unique characteristics different from the sand reservoir,which was believed to be related to the clayed silt physical properties.In this paper,simulation experiments,facilities analysis,and theoretical calculation were used to confirm the hydrate structure,reservoir thermo-physical property,and bond water movement rule.And the behavior of how they affected production efficiency was analyzed.The results showed that:It was reasonable to use the structure I rather than structure II methane hydrate phase equilibrium data to make the production plan;the dissociation heat absorbed by hydrate was large enough to cause hydrate self-protection or reformation depend on the reservoir thermal transfer and gas supply;clayed silt got better thermal conductivity compared to coarse grain,but poor thermal convection especially with hydrate;clayed silt sediment was easy to bond water,but the irreducible water can be exchanged to free water under high production pressure,and the most obvious pressure range of water increment was 1.9–4.9 MPa.

Application of wellhead suction anchor technology in the second production test of natural gas hydrates in the South China Sea

Traditional suction anchor technology is mainly used in the fields of subsea structure bearing foundations,single-point mooring systems and offshore wind power.It is characterized by providing sufficient lateral and vertical bearing capacities and lateral bending moment.The anchor structure of a traditional suction anchor structure is improved with wellhead suction anchor technology,where a central pipe is added as a channel for drilling and completion operations.To solve the technical problems of a low wellhead bearing capacity,shallow built-up depth,and limited application of conductor jetting in the second production test of natural gas hydrates(NGHs)in the South China Sea(SCS),the China Geological Survey(CGS)took the lead in independently designing and manufacturing a wellhead suction anchor,which fulfilled the requirements of the production test.This novel anchor was successfully implemented in the second production test for the first time,providing a stable wellhead foundation for the success of the second production test of NGHs in the SCS.

Seismic fine imaging and its significance for natural gas hydrate exploration in the Shenhu Test Area, South China Sea

Shenhu area in South China Sea includes extensive collapse and diapir structures,forming high-angle faults and vertical fracture system,which functions as a fluid migration channel for gas hydrate formation.In order to improve the imaging precision of natural gas hydrate in this area,especially for fault and fracture structures,the present work propose a velocity stitching technique that accelerates effectively the convergence of the shallow seafloor,indicating seafloor horizon interpretation and the initial interval velocity for model building.In the depth domain,pre-stack depth migration and residual curvature are built into the model based on high-precision grid-tomography velocity inversion,after several rounds of tomographic iterations,as the residual velocity field converges gradually.Test results of the Shenhu area show that the imaging precision of the fault zone is obviously improved,the fracture structures appear more clearly,the wave group characteristics significantly change for the better and the signal-to-noise ratio and resolution are improved.These improvements provide the necessary basis for the new reservoir model and field drilling risk tips,help optimize the favorable drilling target,and are crucial for the natural gas resource potential evaluation.

Deep structural research of the South China Sea: Progresses and directions

The South China Sea(SCS)is the hotspot of geological scientific research and nature resource exploration and development due to the potential for enormous hydrocarbon resource development and a complex formation and evolution process.The SCS has experienced complex geological processes including continental lithospheric breakup,seafloor spreading and oceanic crust subduction,which leads debates for decades.However,there are still no clear answers regarding to the following aspects:the crustal and Moho structure,the structure of the continent-ocean transition zone,the formation and evolution process and geodynamic mechanism,and deep processes and their coupling relationships with the petroliferous basins in the SCS.Under the guidance of the“Deep-Earth”science and technology innovation strategy of the Ministry of Natural Resources,deep structural and comprehensive geological research are carried out in the SCS.Geophysical investigations such as long array-large volume deep reflection seismic,gravity,magnetism and ocean bottom seismometer are carried out.The authors proposed that joint gravitymagnetic-seismic inversion should be used to obtain deep crustal information in the SCS and construct high resolution deep structural sections in different regions of the SCS.This paper systematically interpreted the formation and evolution of the SCS and explored the coupling relationship between deep structure and evolution of Mesozoic-Cenozoic basins in the SCS.It is of great significance for promoting the geosystem scientific research and resource exploration of the SCS.

Assessment of natural gas hydrate reservoirs at Site GMGS3-W19 in the Shenhu area,South China Sea based on various well logs

To obtain the characteristics of the gas hydrate reservoirs at GMGS3-W19,extensive geophysical logging data and cores were analyzed to assess the reservoir properties.Sediment porosities were estimated from density,neutron,and nuclear magnetic resonance(NMR)logs.Both the resistivity and NMR logs were used to calculate gas hydrate saturations,the Simandoux model was employed to eliminate the effects of high clay content determined based on the ECS and core data.The density porosity was closely in agreement with the core-derived porosity,and the neutron porosity was higher while the NMR porosity was lower than the density porosity of sediments without hydrates.The resistivity log has higher vertical resolution than the NMR log and thus is more favorable for assessing gas hydrate saturation with strong heterogeneity.For the gas hydrate reservoirs at GMGS3-W19,the porosity,gas hydrate saturation and free gas saturation was 52.7%,42.7%and 10%,on average,respectively.The various logs provide different methods for the comprehensive evaluation of hydrate reservoir,which supports the selection of candidate site for gas hydrate production testing.

A 3D basin modeling study of the factors controlling gas hydrate accumulation in the Shenhu Area of the South China Sea

Great advancement has been made on natural gas hydrates exploration and test production in the northern South China Sea.However,there remains a lot of key questions yet to be resolved,particularly about the mechanisms and the controls of gas hydrates enrichment.Numerical simulaution would play signficant role in addressing these questions.This study focused on the gas hydrate exploration in the Shenhu Area,Northern South China Sea.Based on the newly obtained borehole and multichannel reflection seismic data,the authors conducted an integrated 3D basin modeling study on gas hydrate.The results indicate that the Shenhu Area has favorable conditions for gas hydrate accumulation,such as temperature,pressure,hydrocarbon source,and tectonic setting.Gas hydrates are most concentrated in the Late Miocene strata,particularly in the structual highs between the Baiyun Sag and the Liwan Sag,and area to the south of it.It also proved the existence of overpressure in the main sag of source rocks,which was subject to compaction disequilibrium and hydrocarbon generation.It also shown that the regional fault activity is not conducive to gas hydrate accumulation due to excess gas seepage.The authors conjecture that fault activity may slightly weaken overpressure for the positive effect of hydrocarbon expulsion and areas lacking regional fault activity have better potential.

Stability analysis of seabed strata and casing structure during the natural gas hydrates exploitation by depressurization in horizontal wells in South China Sea

Natural gas hydrates(NGHs)are a new type of clean energy with great development potential.However,it is urgent to achieve safe and economical NGHs development and utilization.This study established a physical model of the study area using the FLAC^(3D) software based on the key parameters of the NGHs production test area in the South China Sea,including the depressurization method,and mechanical parameters of strata,NGHs occurrence characteristics,and the technological characteristics of horizontal wells.Moreover,this study explored the law of influences of the NGHs dissociation range on the stability of the overburden strata and the casing structure of a horizontal well.The results are as follows.With the dissociation of NGHs,the overburden strata of the NGHs dissociation zone subsided and formed funnelshaped zones and then gradually stabilized.However,the upper interface of the NGHs dissociation zone showed significant redistribution and discontinuity of stress.Specifically,distinct stress concentration and corresponding large deformation occurred in the build-up section of the horizontal well,which was thus prone to suffering shear failure.Moreover,apparent end effects occurred at the end of the horizontal well section and might cause the deformation and failure of the casing structure.Therefore,it is necessary to take measures in the build-up section and at the end of the horizontal section of the horizontal well to prevent damage and ensure the wellbore safety in the long-term NGHs exploitation.

Velocity model and time-depth conversion for the northwestern South China Sea deepwater areas

There are rich natural gas resources in the northwestern South China Sea deepwater areas, with poor degree of exploration. Because of the unique tectonic, sedimentary background of the region, velocity model building and time-depth conversion have been an important and difficult problem for a long time. Recent researches in this direction have revealed three major problems for deepwater areas, i.e., the way to determine error correction for drilling velocity, the optimization of velocity modeling, and the understanding and analysis of velocity variations in the slope areas. The present contribution proposes technical solutions to the problems：（1） velocity correction version can be established by analyzing the geology, reservoir, water depths and velocity spectrum characteristics;（2） a unified method can be adopted to analyze the velocity variation patterns in drilled pale structural positions;and （3） across-layer velocity is analyzed to establish the velocity model individually for each of the layers. Such a solution is applicable, as shown in an example from the northwestern South China Sea deepwater areas, in which an improved prediction precision is obtained.