The correlation between outdoor exposure and indoor accelerated corrosion test for high polymer materials was investigated according to the variation of the functional group of exposure models aged. Environment aging ...The correlation between outdoor exposure and indoor accelerated corrosion test for high polymer materials was investigated according to the variation of the functional group of exposure models aged. Environment aging intensities at different zones ( Wuhan and Lasa with the same latitude ) and the influences of indoor accelerating factors including water and ultraviolet on weathering performant.e of high polymer materials were also studied by comparing different indoor accelerated corrosion testing results. The experimental results show that : by testing variations of carbonyl exponent of polythene ( which represented the degradation behavior of high polymer materials due to ultraviolet oxidation of douIole bond) and ultraviolet absorbance of polycarbonate (which represented the degradation behavior of high polymer materials due to abevacuation of branched chain ), the degradation behavior of high polymer materials could be studied. Carbonyl exponent of polythene exposed in Wuhan and Lasa for 1 year was equal to that exposed in indoor cycle ultraviolet for 128 h anti 170 It, respectively, the ultraviolet absorbance of polycarbonate exposed in Wuhan for 1 year was equal to that exposed in indoor cycle ultraviolet for 240 h. The ratio of environment aging intensity of Lasa to Wuhan was around 1.2. With the prolongation of cycle accelerated ultraviolet exposure time, the variations of carbonyl exponent of polythene and the ultraviolet absorbance of polycarbonate were in the same shape of first order exponential decay curiae. Accompanied with ultraviolet, the effect of water condensated on the sample on weathering performance of polythene was more .significant than that of polycarbonate.展开更多
The assessment of potential health risks posed by formaldehyde in clothing to consumers is of increasing concern worldwide. Because of this, it is necessary to develop an exposure model that can realistically mimic cl...The assessment of potential health risks posed by formaldehyde in clothing to consumers is of increasing concern worldwide. Because of this, it is necessary to develop an exposure model that can realistically mimic clothes wearing conditions. This study aims to preliminarily develop a health risk assessment model for formaldehyde in clothing, and then to assess the potential health risk posed by formaldehyde in textiles to adults and infants in Vietnam using the model. Finally, this study aims to examine the plausibility of the adopted permissible values for formaldehyde in cloth- ing in Vietnam. In the model, two exposure factors for dermal exposure and overall exposure routes, i.e. sweat type and perspiration area, were considered. The margins of exposure (MOE) were calculated to estimate the health risks from worst case and average exposures. The assessment shows that acute exposure via inhalation can pose health risks to Vietnamese consumers in both cases. In regards to chronic exposure, dermal exposure is about four (for infants) and seven (for adults) times higher than exposure via inhalation, but no risks were found for average exposure. If a MOE of 100 is defined as ‘safe’ used, dermal and total chronic exposure to worst case cause potential risks, whereas no health risks were found for exposure to average case. With the model, the adopted Vietnamese permissible values for formaldehyde in clothing were assessed as not posing a health risk to Vietnamese consumers, hence they are accepted.展开更多
This paper investigates a simple step-stress accelerated lifetime test(SSALT)model for the inferential analysis of exponential competing risks data.A generalized type-I hybrid censoring scheme is employed to improve t...This paper investigates a simple step-stress accelerated lifetime test(SSALT)model for the inferential analysis of exponential competing risks data.A generalized type-I hybrid censoring scheme is employed to improve the efficiency and controllability of the test.Firstly,the MLEs for parameters are established based on the cumulative exposure model(CEM).Then the conditional moment generating function(MGF)for unknown parameters is set up using conditional expectation and multiple integral techniques.Thirdly,confidence intervals(CIs)are constructed by the exact MGF-based method,the approximate normality-based method,and the bias-corrected and accelerated(BCa)percentile bootstrap method.Finally,we present simulation studies and an illustrative example to compare the performances of different methods.展开更多
基金Funded by Ministry of Science and Technology of China (No.50499331)
文摘The correlation between outdoor exposure and indoor accelerated corrosion test for high polymer materials was investigated according to the variation of the functional group of exposure models aged. Environment aging intensities at different zones ( Wuhan and Lasa with the same latitude ) and the influences of indoor accelerating factors including water and ultraviolet on weathering performant.e of high polymer materials were also studied by comparing different indoor accelerated corrosion testing results. The experimental results show that : by testing variations of carbonyl exponent of polythene ( which represented the degradation behavior of high polymer materials due to ultraviolet oxidation of douIole bond) and ultraviolet absorbance of polycarbonate (which represented the degradation behavior of high polymer materials due to abevacuation of branched chain ), the degradation behavior of high polymer materials could be studied. Carbonyl exponent of polythene exposed in Wuhan and Lasa for 1 year was equal to that exposed in indoor cycle ultraviolet for 128 h anti 170 It, respectively, the ultraviolet absorbance of polycarbonate exposed in Wuhan for 1 year was equal to that exposed in indoor cycle ultraviolet for 240 h. The ratio of environment aging intensity of Lasa to Wuhan was around 1.2. With the prolongation of cycle accelerated ultraviolet exposure time, the variations of carbonyl exponent of polythene and the ultraviolet absorbance of polycarbonate were in the same shape of first order exponential decay curiae. Accompanied with ultraviolet, the effect of water condensated on the sample on weathering performance of polythene was more .significant than that of polycarbonate.
文摘The assessment of potential health risks posed by formaldehyde in clothing to consumers is of increasing concern worldwide. Because of this, it is necessary to develop an exposure model that can realistically mimic clothes wearing conditions. This study aims to preliminarily develop a health risk assessment model for formaldehyde in clothing, and then to assess the potential health risk posed by formaldehyde in textiles to adults and infants in Vietnam using the model. Finally, this study aims to examine the plausibility of the adopted permissible values for formaldehyde in cloth- ing in Vietnam. In the model, two exposure factors for dermal exposure and overall exposure routes, i.e. sweat type and perspiration area, were considered. The margins of exposure (MOE) were calculated to estimate the health risks from worst case and average exposures. The assessment shows that acute exposure via inhalation can pose health risks to Vietnamese consumers in both cases. In regards to chronic exposure, dermal exposure is about four (for infants) and seven (for adults) times higher than exposure via inhalation, but no risks were found for average exposure. If a MOE of 100 is defined as ‘safe’ used, dermal and total chronic exposure to worst case cause potential risks, whereas no health risks were found for exposure to average case. With the model, the adopted Vietnamese permissible values for formaldehyde in clothing were assessed as not posing a health risk to Vietnamese consumers, hence they are accepted.
基金Humanities and Social Sciences Fund in Ministry of Education in China(18YJC910009)the National Natural Science Foundation of China(12061091)Program for the Philosophy and Social Sciences Research of Higher Learning Institutions of Shanxi(201803050)。
文摘This paper investigates a simple step-stress accelerated lifetime test(SSALT)model for the inferential analysis of exponential competing risks data.A generalized type-I hybrid censoring scheme is employed to improve the efficiency and controllability of the test.Firstly,the MLEs for parameters are established based on the cumulative exposure model(CEM).Then the conditional moment generating function(MGF)for unknown parameters is set up using conditional expectation and multiple integral techniques.Thirdly,confidence intervals(CIs)are constructed by the exact MGF-based method,the approximate normality-based method,and the bias-corrected and accelerated(BCa)percentile bootstrap method.Finally,we present simulation studies and an illustrative example to compare the performances of different methods.