Chemical components, main mineral content and mineral composition of rare earth ore in Yunnan Province was measurated by the analysis of the spectrum and the chemical components. The study shows that main metals miner...Chemical components, main mineral content and mineral composition of rare earth ore in Yunnan Province was measurated by the analysis of the spectrum and the chemical components. The study shows that main metals mineral in the rare earth ore are magnetite, tatanomagnetite, limonite; less metals mineral are ilmenite, hematite; some minim minerals were iron pyrites, zircon, scheelite, and so on. Main nonmetals mineral are quartz, feldspar(plagioclase, K-feldspar); less nonmetals mineral are hopfnerite, biotite, titanite; some minim minerals are kaolinite and dolomite. Ilmenite has the highest content of Sc as 175 g·t -1, next is titanite as 81.2 g·t -1. Based on this result, A new method of extracting Sc is put forward. The technological flowsheet of separating Sc of low-intensity magnetic separation,tabing, gravity concentrate, high-gradient magnetic separation, and electrostatic separation was prepared. Amplified experiment obtained Sc concentrate with Sc content of 148.54 g·t -1, the yield of 7.92%,recovery of 69.20%, at the same time, a Fe concentrate with the grade of 63.88% and the yield of 5.91% is obtained.展开更多
Objective: To investigate the effect of temperature and pressure on supercritical CO_2 extraction of Triognella foenum graecum Linn seeds, to determine the optimal condition which leads to highest percentage of the ac...Objective: To investigate the effect of temperature and pressure on supercritical CO_2 extraction of Triognella foenum graecum Linn seeds, to determine the optimal condition which leads to highest percentage of the accumulative yield and revealing the chemical composition of supercritical CO_2 extract.Methods: Temperatures in the range of 40–60C and pressures in the range of 10–25 MPa were used. FTIR and GC–MS analysis were used to detect the bioactive compounds present in the extract. The broth dilution method and slope method were used to evaluate the anti-microbial and anti-tuberculosis activities and the in vitro anti-malarial assay was carried out according to the micro assay protocol of Rieckmann and his coworkers.Results: The temperature was more affected than the pressure on the extraction performance and the highest yield of the extract(3.111%) was attained at 60C and 10 MPa.FTIR and GC–MS showed that the chemical composition of the extract included conjugated linoleic acid methyl ester as the major active principle(with concentration of72.28%), followed by saturated fatty acid methyl esters(16.03%), steroids(8.09%) and organic siloxane compound(3.61%). The extract showed moderate anti-bacterial activity with MIC values 100, 250, 125 mg/m L towards Escherichia coli, Staphylococcus aureus and Streptococcus pyogenus respectively. It exhibited high inhibition effect towards the fungi Candida albican with MFC value(250 mg/m L). The extract had low antituberculosis activity with MIC value(100 mg/m L) and comparable MIC value(0.29 mg/m L) towards Plasmodium flaciparum.Conclusions: Supercritical CO_2 extraction as alternate and green technology is performed successfully to extract the bioactive compounds from the seeds of T. foenum graecum Linn and it is concluded that this extract can be used as an alternate source of synthetic anti-biotic drugs.展开更多
文摘Chemical components, main mineral content and mineral composition of rare earth ore in Yunnan Province was measurated by the analysis of the spectrum and the chemical components. The study shows that main metals mineral in the rare earth ore are magnetite, tatanomagnetite, limonite; less metals mineral are ilmenite, hematite; some minim minerals were iron pyrites, zircon, scheelite, and so on. Main nonmetals mineral are quartz, feldspar(plagioclase, K-feldspar); less nonmetals mineral are hopfnerite, biotite, titanite; some minim minerals are kaolinite and dolomite. Ilmenite has the highest content of Sc as 175 g·t -1, next is titanite as 81.2 g·t -1. Based on this result, A new method of extracting Sc is put forward. The technological flowsheet of separating Sc of low-intensity magnetic separation,tabing, gravity concentrate, high-gradient magnetic separation, and electrostatic separation was prepared. Amplified experiment obtained Sc concentrate with Sc content of 148.54 g·t -1, the yield of 7.92%,recovery of 69.20%, at the same time, a Fe concentrate with the grade of 63.88% and the yield of 5.91% is obtained.
基金acknowledge to Hodeidah University, Yemen for supporting this work
文摘Objective: To investigate the effect of temperature and pressure on supercritical CO_2 extraction of Triognella foenum graecum Linn seeds, to determine the optimal condition which leads to highest percentage of the accumulative yield and revealing the chemical composition of supercritical CO_2 extract.Methods: Temperatures in the range of 40–60C and pressures in the range of 10–25 MPa were used. FTIR and GC–MS analysis were used to detect the bioactive compounds present in the extract. The broth dilution method and slope method were used to evaluate the anti-microbial and anti-tuberculosis activities and the in vitro anti-malarial assay was carried out according to the micro assay protocol of Rieckmann and his coworkers.Results: The temperature was more affected than the pressure on the extraction performance and the highest yield of the extract(3.111%) was attained at 60C and 10 MPa.FTIR and GC–MS showed that the chemical composition of the extract included conjugated linoleic acid methyl ester as the major active principle(with concentration of72.28%), followed by saturated fatty acid methyl esters(16.03%), steroids(8.09%) and organic siloxane compound(3.61%). The extract showed moderate anti-bacterial activity with MIC values 100, 250, 125 mg/m L towards Escherichia coli, Staphylococcus aureus and Streptococcus pyogenus respectively. It exhibited high inhibition effect towards the fungi Candida albican with MFC value(250 mg/m L). The extract had low antituberculosis activity with MIC value(100 mg/m L) and comparable MIC value(0.29 mg/m L) towards Plasmodium flaciparum.Conclusions: Supercritical CO_2 extraction as alternate and green technology is performed successfully to extract the bioactive compounds from the seeds of T. foenum graecum Linn and it is concluded that this extract can be used as an alternate source of synthetic anti-biotic drugs.
