In this study, extractability of 13 organochlorine pesticides aged in six different soil types, was investigated. Acceptable recoveries were achieved for most of the analytes spiked into five of the soil types. No app...In this study, extractability of 13 organochlorine pesticides aged in six different soil types, was investigated. Acceptable recoveries were achieved for most of the analytes spiked into five of the soil types. No apparent correlation was perceptible between the soil characteristics and extractability of the aged analytes, signifying exhaustiveness of the extraction. However, recovery was considerably minimized (<75%) in the clay ensuring the hypothesis of study stating “extraction efficiency might be matrix dependent”. Therefore, the study demonstrates importance of optimizing extraction conditions even for those believed to be less prone to matrix effect, due to distinct properties of analyte-matrix interactions.展开更多
基金financial support provided by the Swedish International Development Agencythe Department for Research Co-operation(SIDA/SAREC)and the International Science Program(ISP).
文摘In this study, extractability of 13 organochlorine pesticides aged in six different soil types, was investigated. Acceptable recoveries were achieved for most of the analytes spiked into five of the soil types. No apparent correlation was perceptible between the soil characteristics and extractability of the aged analytes, signifying exhaustiveness of the extraction. However, recovery was considerably minimized (<75%) in the clay ensuring the hypothesis of study stating “extraction efficiency might be matrix dependent”. Therefore, the study demonstrates importance of optimizing extraction conditions even for those believed to be less prone to matrix effect, due to distinct properties of analyte-matrix interactions.
