A kind of novel compound containing S and Mo elements was synthesized. Its chemical structure was characterized by elemental analysis, IR and 3MR. hs anti-wear property and the load-carrying capacity, as an extreme pr...A kind of novel compound containing S and Mo elements was synthesized. Its chemical structure was characterized by elemental analysis, IR and 3MR. hs anti-wear property and the load-carrying capacity, as an extreme pressure （EP） additive of lubricating oil, were investigated using a four-bull tester. The experimentul results show that the additive exhibits a superior anti-wear property and a high load-carrying capacity . The presence of other additives does not interfere with the anti-wear prnperty of the extreme pressure additive. The influences of load and temperature on the propert） of the additive were examined. The possible mechanism uas investigated by means of sufface analysis of the tested steel ball specimen , using XPS. The lubricatian films formed on the rubbing surface are mainly composed of MoS2, MoO3 and MoO2.展开更多
To enhance the lubricating and extreme pressure(EP) performance of base oils, two types of oil-soluble ionic liquids(ILs) with similar anion albeit dissimilar cations were synthesized. The physical properties of the p...To enhance the lubricating and extreme pressure(EP) performance of base oils, two types of oil-soluble ionic liquids(ILs) with similar anion albeit dissimilar cations were synthesized. The physical properties of the prepared ILs were measured. The anticorrosion properties of ILs were assessed by conducting corrosion tests on steel discs and copper strips, which revealed the remarkable anticorrosion properties of the ILs in comparison with those of the commercial additive zinc dialkyldithiophosphate(ZDDP). The tribological properties of the two ILs as additives for poly-α-olefin-10(PAO10) with various mass concentrations were investigated. The tribological test results indicate that these ILs as additives are capable of reducing friction and wear of sliding contacts remarkably as well as enhance the EP performance of blank PAO10. Under similar test conditions, these IL additives exhibit higher lubricating and anti-wear(AW) performances than those of ZDDP based additive package in PAO10. Subsequently, X-ray photoelectron spectroscopy(XPS) and energy dispersive spectrometer(EDS) were conducted to study the lubricating mechanism of the two ILs. The results indicate that the formation of tribochemical film plays the most crucial role in enhancing the lubricating and AW behavior of the mixture lubricants.展开更多
以硫化物、磷化物、氮化物以及硼化物为原料合成了多功能润滑油添加剂———硼化硫代磷酸酯胺盐,对比考察了所合成的添加剂同几种常见商品添加剂的极压抗磨特性,探讨了在添加剂分子中引入B元素对其热氧化稳定性及腐蚀性能的影响,初步考...以硫化物、磷化物、氮化物以及硼化物为原料合成了多功能润滑油添加剂———硼化硫代磷酸酯胺盐,对比考察了所合成的添加剂同几种常见商品添加剂的极压抗磨特性,探讨了在添加剂分子中引入B元素对其热氧化稳定性及腐蚀性能的影响,初步考察了硼化硫代磷酸酯胺盐在无灰液压油和齿轮油中的应用性能.结果表明:引入B元素可以显著改善S P N类多功能润滑油添加剂的热氧化稳定性和腐蚀性能;含有S、P、N和B等多种活性元素的合成添加剂在无灰液压油及齿轮油中具有广阔应用前景.展开更多
文摘A kind of novel compound containing S and Mo elements was synthesized. Its chemical structure was characterized by elemental analysis, IR and 3MR. hs anti-wear property and the load-carrying capacity, as an extreme pressure （EP） additive of lubricating oil, were investigated using a four-bull tester. The experimentul results show that the additive exhibits a superior anti-wear property and a high load-carrying capacity . The presence of other additives does not interfere with the anti-wear prnperty of the extreme pressure additive. The influences of load and temperature on the propert） of the additive were examined. The possible mechanism uas investigated by means of sufface analysis of the tested steel ball specimen , using XPS. The lubricatian films formed on the rubbing surface are mainly composed of MoS2, MoO3 and MoO2.
基金the financial support from the National Natural Science Foundation of China (NSFC,Nos.51675512,51227804,and 51305428)Natural Science Foundation of Gansu Province (No.1606RJZA051)the National Key Basic Research and Development (973) Program of China (No.2013CB632301)
文摘To enhance the lubricating and extreme pressure(EP) performance of base oils, two types of oil-soluble ionic liquids(ILs) with similar anion albeit dissimilar cations were synthesized. The physical properties of the prepared ILs were measured. The anticorrosion properties of ILs were assessed by conducting corrosion tests on steel discs and copper strips, which revealed the remarkable anticorrosion properties of the ILs in comparison with those of the commercial additive zinc dialkyldithiophosphate(ZDDP). The tribological properties of the two ILs as additives for poly-α-olefin-10(PAO10) with various mass concentrations were investigated. The tribological test results indicate that these ILs as additives are capable of reducing friction and wear of sliding contacts remarkably as well as enhance the EP performance of blank PAO10. Under similar test conditions, these IL additives exhibit higher lubricating and anti-wear(AW) performances than those of ZDDP based additive package in PAO10. Subsequently, X-ray photoelectron spectroscopy(XPS) and energy dispersive spectrometer(EDS) were conducted to study the lubricating mechanism of the two ILs. The results indicate that the formation of tribochemical film plays the most crucial role in enhancing the lubricating and AW behavior of the mixture lubricants.
文摘以硫化物、磷化物、氮化物以及硼化物为原料合成了多功能润滑油添加剂———硼化硫代磷酸酯胺盐,对比考察了所合成的添加剂同几种常见商品添加剂的极压抗磨特性,探讨了在添加剂分子中引入B元素对其热氧化稳定性及腐蚀性能的影响,初步考察了硼化硫代磷酸酯胺盐在无灰液压油和齿轮油中的应用性能.结果表明:引入B元素可以显著改善S P N类多功能润滑油添加剂的热氧化稳定性和腐蚀性能;含有S、P、N和B等多种活性元素的合成添加剂在无灰液压油及齿轮油中具有广阔应用前景.
