Electron transfer through the self-assembled monolayers (SAMs) on gold nanopar-ticles is investigated by using the monolayer protected gold nanoclusters (MPCs) as elec-tron-transfer mediators. 3-Mercaptopropionic acid...Electron transfer through the self-assembled monolayers (SAMs) on gold nanopar-ticles is investigated by using the monolayer protected gold nanoclusters (MPCs) as elec-tron-transfer mediators. 3-Mercaptopropionic acid (MPA) and 11-meraptoundecanoic acid (MUA) MPCs were employed to catalyze the redox reaction between potassium ferricyanide and sodium thiosulfate. The catalytic mechanism was proposed that the MPCs act as diffusing elec-tron-mediators and electron transfers to and from the MPCs surface. Therefore the electron transfer rate through the capping layers would be proportional to the MPCs catalyzed reaction rate, which was monitored by the UV absorbance of ferricyanide. The calculated apparent rate constant was orders of magnitude smaller than that of the maximum of tunneling current, which was attributed to the splited energy level of the nanoscale particles.展开更多
Mesh stiffness is one of important base parameters of face gear dynamic studies.However,a calculation solution of mesh stiffness of face gear drives is not to be constructed due to complex geometric flakes of face gea...Mesh stiffness is one of important base parameters of face gear dynamic studies.However,a calculation solution of mesh stiffness of face gear drives is not to be constructed due to complex geometric flakes of face gear teeth.Thus,a calculation solution of mesh stiffness of face gear drives with a spur gear,which is based on the proposed equivalent face gear teeth and Ishikawa model,is constructed,and the influence of contact effects on mesh stiffness of face gear drives is investigated.The results indicate the mesh stiffness of face gear drives is sensitive to contact effects under heavy loaded operating conditions,specially.These contributions will benefit to improve dynamic studies of face gear drives.展开更多
Based on mathematical foresight and beyond the mainstream inertial thinking pattern, the author believes that if neutrinos were really tachyons, the mystery of neutrinos might be solved. Fortunately, the space-like th...Based on mathematical foresight and beyond the mainstream inertial thinking pattern, the author believes that if neutrinos were really tachyons, the mystery of neutrinos might be solved. Fortunately, the space-like theory of special relativity reveals that there would exist an observable effect i.e. a “face-changing effect”, not oscillation, which was just related to the superluminal motion. As long as the motion velocity of an electron anti-neutrino was greater than c2/v, where v was the instantaneous thermal motion velocity of its mother neutron at the time of β-decay, a corresponding electron neutrino formed from the face-changing would be observed on the journey. Therefore, a special and easy way to judge the physical nature of neutrinos may be suggested the reactor neutrino experimental groups all over the world, in addition to the current studies involving the disappearance mode of , to add a new experimental search after ve in the current, to see whether a few ve neutrinos would exceed the background counting. “Yes” result would reveal the neutrinos being tachyons, and “no” would be not.展开更多
Interface imperfection can significantly affect the mechanical properties and failure mechanisms as well as the strength and toughness of nanocomposites. The elastic behavior of a screw dislocation in nanoscale coatin...Interface imperfection can significantly affect the mechanical properties and failure mechanisms as well as the strength and toughness of nanocomposites. The elastic behavior of a screw dislocation in nanoscale coating with imperfect interface is studied in the three-phase composite cylinder model. The interface between inner nanoin- homogeneity and intermediate coating is assumed as perfectly bonded. The bonding between intermediate coating and outer matrix is considered to be imperfect with the assumption that interface imperfection is uniform, and a linear spring model is adopted to describe the weakness of imperfect interface. The explicit expression for image force acting on dislocation is obtained by means of a complex variable method. The analytic results indicate that inner interface effect and outer interface imperfection, simultaneously taken into account, would influence greatly image force, equilibrium position and stability of dislocation, and various critical parameters that would change dislocation stability. The weaker interface is a very strong trap for glide dislocation and, thus, a more effective barrier for slip transmission.展开更多
基金financially supported by the National Natural Science Foundation of China(Outstanding Youth Fund Grant No.20125513)a research fellowship from the K.C.Wong Educational Foundation.
文摘Electron transfer through the self-assembled monolayers (SAMs) on gold nanopar-ticles is investigated by using the monolayer protected gold nanoclusters (MPCs) as elec-tron-transfer mediators. 3-Mercaptopropionic acid (MPA) and 11-meraptoundecanoic acid (MUA) MPCs were employed to catalyze the redox reaction between potassium ferricyanide and sodium thiosulfate. The catalytic mechanism was proposed that the MPCs act as diffusing elec-tron-mediators and electron transfers to and from the MPCs surface. Therefore the electron transfer rate through the capping layers would be proportional to the MPCs catalyzed reaction rate, which was monitored by the UV absorbance of ferricyanide. The calculated apparent rate constant was orders of magnitude smaller than that of the maximum of tunneling current, which was attributed to the splited energy level of the nanoscale particles.
基金supported by the National Natural Science Foundations of China(Nos.51105194,51375226)the Fundamental Research Funds for the Central Universities(No.NS2015049)
文摘Mesh stiffness is one of important base parameters of face gear dynamic studies.However,a calculation solution of mesh stiffness of face gear drives is not to be constructed due to complex geometric flakes of face gear teeth.Thus,a calculation solution of mesh stiffness of face gear drives with a spur gear,which is based on the proposed equivalent face gear teeth and Ishikawa model,is constructed,and the influence of contact effects on mesh stiffness of face gear drives is investigated.The results indicate the mesh stiffness of face gear drives is sensitive to contact effects under heavy loaded operating conditions,specially.These contributions will benefit to improve dynamic studies of face gear drives.
文摘Based on mathematical foresight and beyond the mainstream inertial thinking pattern, the author believes that if neutrinos were really tachyons, the mystery of neutrinos might be solved. Fortunately, the space-like theory of special relativity reveals that there would exist an observable effect i.e. a “face-changing effect”, not oscillation, which was just related to the superluminal motion. As long as the motion velocity of an electron anti-neutrino was greater than c2/v, where v was the instantaneous thermal motion velocity of its mother neutron at the time of β-decay, a corresponding electron neutrino formed from the face-changing would be observed on the journey. Therefore, a special and easy way to judge the physical nature of neutrinos may be suggested the reactor neutrino experimental groups all over the world, in addition to the current studies involving the disappearance mode of , to add a new experimental search after ve in the current, to see whether a few ve neutrinos would exceed the background counting. “Yes” result would reveal the neutrinos being tachyons, and “no” would be not.
基金supported by the National Natural Science Foundation of China(11172094 and 11172095)the NCET-11-0122 and Hunan Provincial Natural Science Foundation for Creative Research Groups of China(12JJ7001)
文摘Interface imperfection can significantly affect the mechanical properties and failure mechanisms as well as the strength and toughness of nanocomposites. The elastic behavior of a screw dislocation in nanoscale coating with imperfect interface is studied in the three-phase composite cylinder model. The interface between inner nanoin- homogeneity and intermediate coating is assumed as perfectly bonded. The bonding between intermediate coating and outer matrix is considered to be imperfect with the assumption that interface imperfection is uniform, and a linear spring model is adopted to describe the weakness of imperfect interface. The explicit expression for image force acting on dislocation is obtained by means of a complex variable method. The analytic results indicate that inner interface effect and outer interface imperfection, simultaneously taken into account, would influence greatly image force, equilibrium position and stability of dislocation, and various critical parameters that would change dislocation stability. The weaker interface is a very strong trap for glide dislocation and, thus, a more effective barrier for slip transmission.
