The ceramic composite separators coated with silica or alumina particles have been used in power batteries due to their better electrolyte wettability and better thermal stability compared with bare polymer separators...The ceramic composite separators coated with silica or alumina particles have been used in power batteries due to their better electrolyte wettability and better thermal stability compared with bare polymer separators.However,these oxide ceramics are Liþion insulators,which increase internal resistance and hinder the improvement of rate capability of batteries.Herein,we report a strategy to further improving the performance of lithium-ion batteries(LIBs)by using fast ionic conductor ceramic composite separator as an alternative to traditional ceramic coated separators.Lithium lanthanum titanate(LLTO),a fast ionic conductor with excellent room temperature bulk conductivity,are coated on the common polyethylene(PE)separators.Our results demonstrate that such a novel LLTO-coated separator possess excellent electrolyte wettability and thermal stability;and the assembled NCM523/graphite lithium-ion pouch cells with LLTO-coated separator show better rate capability and cyclic performance with 88.7%capacity retention after 1000 cycles at room temperature compared with the pouch cells with Al2O_(3)-coated separators.The fast ionic conductor ceramic composite separators will be a potential competitor to the next-generation novel separators for high-performance Li-ion power batteries.展开更多
The cubic and/or tetragonal ZrO<sub>2</sub> solid solution polycrystalline ceramics obtained byaddition of appropriate amounts of oxides asCaO, Y<sub>2</sub>O<sub>3</sub>, MgO or ra...The cubic and/or tetragonal ZrO<sub>2</sub> solid solution polycrystalline ceramics obtained byaddition of appropriate amounts of oxides asCaO, Y<sub>2</sub>O<sub>3</sub>, MgO or rare earth oxides to zirconiahas ioinc conductivity and is used as fast ionicconductor for new ceramic fuel cells and sensors.For MgO-stabilized zirconia the MgO content展开更多
文摘The ceramic composite separators coated with silica or alumina particles have been used in power batteries due to their better electrolyte wettability and better thermal stability compared with bare polymer separators.However,these oxide ceramics are Liþion insulators,which increase internal resistance and hinder the improvement of rate capability of batteries.Herein,we report a strategy to further improving the performance of lithium-ion batteries(LIBs)by using fast ionic conductor ceramic composite separator as an alternative to traditional ceramic coated separators.Lithium lanthanum titanate(LLTO),a fast ionic conductor with excellent room temperature bulk conductivity,are coated on the common polyethylene(PE)separators.Our results demonstrate that such a novel LLTO-coated separator possess excellent electrolyte wettability and thermal stability;and the assembled NCM523/graphite lithium-ion pouch cells with LLTO-coated separator show better rate capability and cyclic performance with 88.7%capacity retention after 1000 cycles at room temperature compared with the pouch cells with Al2O_(3)-coated separators.The fast ionic conductor ceramic composite separators will be a potential competitor to the next-generation novel separators for high-performance Li-ion power batteries.
基金Project supported by Tianjin Higher Education Bureau and National Laboratory of Laser Technology.
文摘The cubic and/or tetragonal ZrO<sub>2</sub> solid solution polycrystalline ceramics obtained byaddition of appropriate amounts of oxides asCaO, Y<sub>2</sub>O<sub>3</sub>, MgO or rare earth oxides to zirconiahas ioinc conductivity and is used as fast ionicconductor for new ceramic fuel cells and sensors.For MgO-stabilized zirconia the MgO content
