正确认识不同区域能量和水分循环特征是研究局地地气相互作用及准确预测区域天气,气候变化的关键.为了研究属于干旱/半干旱气候的青藏高原(TP)和湿润/半湿润气候的长江流域(YRR)之间地表能量和水分交换的异同,本文对比分析了两个区域8...正确认识不同区域能量和水分循环特征是研究局地地气相互作用及准确预测区域天气,气候变化的关键.为了研究属于干旱/半干旱气候的青藏高原(TP)和湿润/半湿润气候的长江流域(YRR)之间地表能量和水分交换的异同,本文对比分析了两个区域8个不同地表类型(包括高山荒漠,高山草地,(平原)城市和(平原)草地等)观测站点的地表辐射和能量通量数据.结果显示:(1)TP由于高原大气层稀薄且空气洁净,年平均入射短波辐射为251.3W m^(-2),是YRR的1.7倍.加之高原地表反照率高导致反射辐射(59.6 W m^(-2))是YRR的2.87倍.入射及出射的长波辐射为231.5和338.0 W m^(-2),分别为YRR的0.64和0.83.而两个区域的净辐射差异不大;(2)草地站更多的潜热释放使得地表总加热效率高于城市和高山荒漠,TP和YRR的草地站的年平均潜热分别为35.0和38.8 W m^(-2),而植被稀疏且土壤干燥的高山荒漠地区感热最大,年平均感热为42.1 W m^(-2);其次是城市下垫面,其年平均感热为37.7 W m^(-2).研究结果揭示了不同气候背景下典型下垫面地气相互作用特征,为地气相互作用过程深入分析奠定了基础.展开更多
We investigate the energy exchange between (3+1)D colliding spatiotemporal solitons (STSs) in dispersive media with cubic-quintic (CQ) nonlinearity by numerical simulations. Energy exchange between two (3+1)...We investigate the energy exchange between (3+1)D colliding spatiotemporal solitons (STSs) in dispersive media with cubic-quintic (CQ) nonlinearity by numerical simulations. Energy exchange between two (3+1)D head on colliding STSs caused by their phase difference is observed, just as occurring in other optical media. Moreover, energy exchange between two head-on colliding STSs with different speeds is firstly shown in the CQ and saturable media. This phenomenon, we believe, may arouse some interest in the future studies of soliton collision in optical media.展开更多
Meeting the climate change mitigation targets will require a substantial shift from fossil to clean fuels in the heating sector.Heat pumps with deep borehole exchangers are a promising solution to reduce emissions.Her...Meeting the climate change mitigation targets will require a substantial shift from fossil to clean fuels in the heating sector.Heat pumps with deep borehole exchangers are a promising solution to reduce emissions.Here the thermal behavior of deep borehole exchangers(DBHEs)ranging from 1 to 2 km was analyzed for various heat flow profiles.A strong correlation between thermal energy extraction and power output from DBHEs was found,also influenced by the heating profile employed.Longer operating time over the year typically resulted in higher energy production,while shorter one yielded higher average thermal power output,highlighting the importance of the choice of heating strategy and system design for optimal performance of DBHEs.Short breaks in operation for regenerating the borehole,for example,with waste heat,proved to be favorable for the performance yielding an overall heat output close to the same as with continuous extraction of heat.The results demonstrate the usefulness of deep boreholes for dense urban areas with less available space.As the heat production from a single DBHE in Finnish conditions ranges from half up to even a few GWh a year,the technology is best suitable for larger heat loads.展开更多
1.Challenges circular methane energy systems In recent decades,methane-based energy systems have rapidly gained traction across the globe because of the increasing availability of low-cost methane production capacity....1.Challenges circular methane energy systems In recent decades,methane-based energy systems have rapidly gained traction across the globe because of the increasing availability of low-cost methane production capacity.However,fossil methane production and combustion lead to large greenhouse gas emissions,contributing to climate change[1].展开更多
Based on a single ion model, Hamiltonian of the simplest form about magnetocrystalline anisotropy for Tb3+ ion was solved by using the numerical method. The relation between the stabilization energy, crystal field coe...Based on a single ion model, Hamiltonian of the simplest form about magnetocrystalline anisotropy for Tb3+ ion was solved by using the numerical method. The relation between the stabilization energy, crystal field coefficient B20 and the magnetic exchange interaction was studied as temperature approaches to 0 K. The results show that the stabilization energy contributed by Tb3+ is linear with crystal field coefficient B20 approximately, but it is insensitive to the change of magnetic exchange interaction for the strong magnetic substances such as TbCo5, Tb2Co17 and Tb2Fe14B compounds.展开更多
The energy pile is a kind of building energy-saving technology using shallow geothermal energy,and its heat exchange performance is an important factor affecting its development.In this study,heat exchange tests were ...The energy pile is a kind of building energy-saving technology using shallow geothermal energy,and its heat exchange performance is an important factor affecting its development.In this study,heat exchange tests were carried out on three full-size cast-in place energy piles,and the influence of various factors on the heat exchange amount and the heat exchange rate was analyzed.The following conclusions are drawn:(1)the heat exchange rate of the cast-in place energy pile is greatly affected by the inlet water temperature;(2)increasing the pile length can increase the heat exchange amount,but has little effect on improving the heat exchange rate;(3)the increase in the heat exchange amount by heat exchange pipes in series is not significant,and therefore the parallel-type heat exchange pipes should be considered in practical engineering;(4)the appropriate circulating water flow velocity gives the best heat exchange efficiency.展开更多
We present a simple and reliable method,based on the over-barrier model and Lindhard’s formula,to calculate the energy loss,charge transfer,and normalized intensity of highly charged ions penetrating through 2D ultra...We present a simple and reliable method,based on the over-barrier model and Lindhard’s formula,to calculate the energy loss,charge transfer,and normalized intensity of highly charged ions penetrating through 2D ultrathin materials,including graphene and carbon nanomembranes.According to our results,the interaction between the ions and the 2D material can be simplified as an equivalent two-body collision,and we find that full consideration of the charge exchange effect is key to understanding the mechanism of ion energy deposition in an ultrathin target.Not only can this semiclassical model be used to evaluate the ion irradiation effect to a very good level of accuracy,but it also provides important guidance for tailoring the properties of 2D materials using ion beams.展开更多
Calculation of total energies of the electronic ground states of atoms forms the basis for the frozen-core pseudopotentials used in atomistic calculations of much larger scale. Reference values for these energies prov...Calculation of total energies of the electronic ground states of atoms forms the basis for the frozen-core pseudopotentials used in atomistic calculations of much larger scale. Reference values for these energies provide a benchmark for the validation of new software to calculate such potentials. In addition, basic atomic-scale electronic properties such as the (first) ionization energy provide a simple check on the approximation used in the calculation method. We present a comparison of the total energies and ionization energies of atoms Z = 1 - 92 calculated in density functional theory with several levels of exchange-correlation functional and the Hartree-Fock method, comparing ionization energies to experiment. We also investigate the role of relativistic treatment on these energies.展开更多
There are several ways to increase the efficiency of energy consumption and to decrease energy consumption. In this paper. the application of pinch technology in analysis of the heat exchangers network (HEN) in orde...There are several ways to increase the efficiency of energy consumption and to decrease energy consumption. In this paper. the application of pinch technology in analysis of the heat exchangers network (HEN) in order to reduce the energy consumption in a thermal system is studied. Therefore, in this grass root design, the optimum value of △Tmin, is obtained about 10℃and area efficiency (a) is 0.95. The author also depicted the grid diagram and driving force plot for additional analysis. In order to increase the amount of energy saving, heat transfer from above to below the pinch point in the diagnosis stage is verified for all options including re-sequencing, re-piping, add heat exchanger and splitting of the flows. Results show that this network has a low potential of retrofit to decrease the energy consumption, which pinch principles are planned to optimize energy consumption of the unit. Regarding the results of pinch analysis, it is suggested that in order to reduce the energy consumption, no alternative changes in the heat exchangers network of the unit is required. The acquired results show that the constancy of network is completely confirmed by the high area efficiency infirmity of the heat exchanger to pass the pinch point and from of deriving force plot.展开更多
In this work it is shown that the kinetic energy and the exchange-correlation energy are mutual dependent on each other.This aspect is first derived in an orbital-free context.It is shown that the total Fermi potentia...In this work it is shown that the kinetic energy and the exchange-correlation energy are mutual dependent on each other.This aspect is first derived in an orbital-free context.It is shown that the total Fermi potential depends on the density only,the individual parts,the Pauli kinetic energy and the exchange-correlation energy,however,are orbital dependent and as such mutually influence each other.The numerical investigation is performed for the orbital-based non-interacting Kohn-Sham system in order to avoid additional effects due to further approximations of the kinetic energy.The numerical influence of the exchange-correlation functional on the non-interacting kinetic energy is shown to be of the orderof a few Hartrees.For chemical purposes,however,the energetic performance as a function of the nuclear coordinates is much more important than total energies.Therefore,the effect on the bond dissociation curve was studied exemplarily for the carbon monoxide.The data reveals that,the mutual influence between the exchange-correlation functional and the kinetic energy has a significant influence on bond dissociation energies and bond distances.Therefore,the effect of the exchange-correlation treatment must be considered in the design of orbital-free density functional approximations for the kinetic energy.展开更多
The Loess Plateau, located in northern China, has a significant impact on the climate and ecosystem evolvement over the East Asian continent. In this paper, the preliminary autumn daily characteristics of land surface...The Loess Plateau, located in northern China, has a significant impact on the climate and ecosystem evolvement over the East Asian continent. In this paper, the preliminary autumn daily characteristics of land surface energy and water exchange over the Chinese Loess Plateau mesa region are evaluated by using data collected during the Loess Plateau land-atmosphere interaction pilot experiment (LOPEX04), which was conducted from 25 August to 12 September 2004 near Pingliang city, Gansu Province of China. The experiment was carried out in a region with a typical landscape of the Chinese Loess Plateau, known as "loess mesa". The experiment's field land utilizations were cornfield and fallow farmland, with the fallow field later used for rotating winter wheat. The autumn daily characteristics of heat and water exchange evidently differed between the mesa cornfield and fallow, and the imbalance term of the surface energy was large. This is discussed in terms of sampling errors in the flux observations-footprint; energy storage terms of soil and vegetation layers; contribution from air advections; and low and high frequency loss of turbulent fluxes and instruments bias. Comparison of energy components between the mesa cornfield and the lowland cornfield did not reveal any obvious difference. Inadequacies of the field observation equipment and experimental design emerged during the study, and some new research topics have emerged from this pilot experiment for future investigation.展开更多
The heat exchanger network(HEN) synthesis problem based on entransy theory is analyzed. According to the characteristics of entransy representation of thermal potential energy, the entransy dissipation represents the ...The heat exchanger network(HEN) synthesis problem based on entransy theory is analyzed. According to the characteristics of entransy representation of thermal potential energy, the entransy dissipation represents the irreversibility of the heat transfer process, the temperature difference determines the entransy dissipation, and four HEN design steps based on entransy theory are put forward. The present study shows how it is possible to set energy targets based on entransy and achieve them with a network of heat exchangers by an example of heat exchanger network design for four streams. In order to verify the correctness of the heat exchanger networks design method based on entransy theory, the synthesis of the HEN for the diesel hydrogenation unit is studied. Using the heat exchange networks design method based on entransy theory, the HEN obtained is consistent with energy targets. The entransy transfer efficiency of HEN based on entransy theory is 92.29%, higher than the entransy transfer efficiency of the maximum heat recovery network based on pinch technology.展开更多
To investigate the reaction between CO2-CO and wustite using the isotope exchange method at 1073, 1173, 1273, and 1373 K, the experiment apparatus was designed to simulate the fluidized bed. The chemical rate constant...To investigate the reaction between CO2-CO and wustite using the isotope exchange method at 1073, 1173, 1273, and 1373 K, the experiment apparatus was designed to simulate the fluidized bed. The chemical rate constant was estimated by considering the effect of gas phase mass transfer on the reaction. It is found that the chemical rate constant is inversely decreased with the increase in the ratio of CO2/CO by volume. The activation energy of reaction is in a linear relationship with the ratio of COs/CO by volume, and the average activation energy is 155.37 kJ/mol.展开更多
An environmental force termed KELEA (kinetic energy limiting electrostatic attraction) is postulated to reduce the strength of intermolecular (hydrogen) bonding of water molecules, resulting in increased kinetic activ...An environmental force termed KELEA (kinetic energy limiting electrostatic attraction) is postulated to reduce the strength of intermolecular (hydrogen) bonding of water molecules, resulting in increased kinetic activity of the water. While regular water does not directly absorb KELEA from the environment, various dipolar compounds with separated electrical charges can seemingly act as a primary antenna for KELEA, with secondary transfer of energy into nearby water. Moreover, once sufficiently activated, the separated electrical charges in activated water can apparently function as a receiver for KELEA, leading to further activation of the water and also to the activation of added water. Prior publications have addressed the agricultural and potential clinical benefits of using KELEA activated water. This article is intended as the first in a series of papers describing useful industrial applications of KELEA activated water. The focus of the present paper is on the improved efficiency of industrial water heating and cooling systems by using KELEA activated water provided by pelleted, ground and heated volcanic rock as supplied by Kiko Technology.展开更多
Due to its large heat transfer area and stable thermal performance,the middledeep coaxial borehole heat exchanger(CBHE)has become one of the emerging technologies to extract geothermal energy.In this paper,a numerical...Due to its large heat transfer area and stable thermal performance,the middledeep coaxial borehole heat exchanger(CBHE)has become one of the emerging technologies to extract geothermal energy.In this paper,a numerical modeling on a three-dimensional unsteady heat transfer model of a CBHE was conducted by using software FEFLOW,in which the model simulation was compared with the other studies and was validated with experimental data.On this basis,a further simulation was done in respect of assessing the influencing factors of thermal extraction performance and thermal influence radius of the CBHE.The results show that the outlet temperature of the heat exchanger decreases rapidly at the initial stage,and then tended to be stable;and the thermal influence radius increases with the increase of borehole depth.The heat extraction rate of the borehole increases linearly with the geothermal gradient.Rock heat capacity has limited impact on the heat extraction rate,but has a great influence on the thermal influence radius of the CBHE.When there is groundwater flow in the reservoir,the increase of groundwater velocity will result in the rise of both outlet temperature and heat extraction rate.The heat affected zone extends along with the groundwater flow direction;and its influence radius is increasing along with flow velocity.In addition,the material of the inner pipe has a significant effect on the heat loss in the pipe,so it is recommended that the material with low thermal conductivity should be used if possible.展开更多
Crude distillation unit(CDU)is regarded as the main energy consumer in the entire refinery process.In this paper,the process simulation software and the energy management software are used to simulate the flowsheet an...Crude distillation unit(CDU)is regarded as the main energy consumer in the entire refinery process.In this paper,the process simulation software and the energy management software are used to simulate the flowsheet and analyze the energy consumption,respectively.Stream data obtained from an existing CDU are applicable in the pinch analysis.To reduce the amount of cross-pinch heat transfer,three approaches of resequencing,repiping,and adding heat exchangers are adopted.Compared with the existing CDU,the results demonstrate that the inlet temperature of the furnace can be increased by 25.4℃,the amount of hot and cold utilities can be reduced by 15.1%and 19.6%,respectively.The economic evaluation indicates that the operating cost is saved by 8×106$/a,and the payback period is about 9 months.展开更多
Diesel hydrotreating unit(DHT)is an integral part of the refinery,and its energy-saving optimization is of great significance to the enterprise.In this paper,process simulation software and energy management software ...Diesel hydrotreating unit(DHT)is an integral part of the refinery,and its energy-saving optimization is of great significance to the enterprise.In this paper,process simulation software and energy management software are used to simulate the flowsheet and analyze the energy consumption,respectively.Stream data obtained from an existing DHT are applied in the pinch analysis for retrofitting the heat exchanger network(HEN)to achieve maximum energy utilization by using pinch analysis.Since DHT is constrained by pressure,the pressure factor is considered in the process of retrofitting.The results show that the amount of cross-pinch heat transfer is reduced,the inlet temperature of the furnace is increased by 55℃,and the amount of hot and cold utilities can be reduced by 70.25%and 50.16%,respectively.The economic evaluation indicates that the operating cost is saved by 4.39×10^(6)$/a,and the payback period is about 2 months.展开更多
Based on the phase change material (PCM) thermal characteristic,some testing methods such as differential scanning calorimeter (DSC) etc were used to select the low melting mixture of capric and lauric acid as PCM of ...Based on the phase change material (PCM) thermal characteristic,some testing methods such as differential scanning calorimeter (DSC) etc were used to select the low melting mixture of capric and lauric acid as PCM of phase change wallboard (PCW). The PCW room was established,and some contrast analysis of the storage and exchange thermal characteristic of PCW room and ordinary wall room were made under different conditions. The results show that the fluctuation of indoor air temperature in PCW room is smaller than that in ordinary room obviously. The exchange energy of PCM room with outdoor is less than that of ordinary wall room. In the winter condition,PCW room utilizes valley period electricity to storage energy in the night,while releases at peak period electricity in daytime,which can divert 40% of peak load. In the summer condition,PCW room can reduce the peak cooling load by 25% compared with ordinary wall room.展开更多
Based on the characteristics of heat transfer for corrugated pipe,a method of calculating and design on the submersible corrugated pipe sewage heat exchanger was put forward theoretically and experimentally.The actual...Based on the characteristics of heat transfer for corrugated pipe,a method of calculating and design on the submersible corrugated pipe sewage heat exchanger was put forward theoretically and experimentally.The actual movement parameters of air-conditioning system used in this heat exchanger were measured.The experimental result shows that the quantity of heat transfer of the corrugated pipe sewage heat exchanger can satisfy the building's load with the average coefficient of performance 4.55.At the same time,the quantity of heat transfer of the corrugated pipe sewage heat exchanger was compared with that of the other nonmetallic sewage heat exchangers(i.e.,the plastic-Al pipe sewage heat exchanger and PP-R pipe sewage heat exchanger)experimentally.It is found out that the effect of heat transfer for submersible corrugated pipe sewage heat exchanger is superior to those of the plastic-Al pipe and the PP-R pipe.The quantity of heat transfer per mile of corrugated pipe sewage heat exchanger is 5.2 times as much as that of the plastic-Al pipe,and it is 8.1 times as much as that of PP-R pipe.展开更多
This paper reports that the CoFe/IrMn bilayers are deposited by magnetron sputtering on the surfaces of thermallyoxidized Si substrates. It investigates the thermal relaxations of both non-irradiated and Ca^+ ion irr...This paper reports that the CoFe/IrMn bilayers are deposited by magnetron sputtering on the surfaces of thermallyoxidized Si substrates. It investigates the thermal relaxations of both non-irradiated and Ca^+ ion irradiated CoFe/IrMn bilayers by means of holding the bilayers in a negative saturation field. The results show that exchange bias field decreases with the increase of holding time period for both non-irradiated and Ca^+ ion irradiated CoFe/IrMn bilayers. Exchange bias field is also found to be smaller upon irradiation at higher ion dose. This reduction of exchange bias field is attributed to the change of energy barrier induced by ion-radiation.展开更多
基金supported by the National Natural Science Foundation of China,under the project entitled“The study of land-atmosphere water and heat flux interaction over the complex terrain of the north and south slopes of the Qomolangma region"[grant number 42230610]a Ministry of Science and Technology of China project called“Landatmosphere interaction and its climate effect of the Second Tibetan Plateau Scientific Expedition and Research Program"[grant number 2019QzKK0103]the Youth Innovation Promotion Association of the Chinese Academy of Sciences[2022069].
文摘正确认识不同区域能量和水分循环特征是研究局地地气相互作用及准确预测区域天气,气候变化的关键.为了研究属于干旱/半干旱气候的青藏高原(TP)和湿润/半湿润气候的长江流域(YRR)之间地表能量和水分交换的异同,本文对比分析了两个区域8个不同地表类型(包括高山荒漠,高山草地,(平原)城市和(平原)草地等)观测站点的地表辐射和能量通量数据.结果显示:(1)TP由于高原大气层稀薄且空气洁净,年平均入射短波辐射为251.3W m^(-2),是YRR的1.7倍.加之高原地表反照率高导致反射辐射(59.6 W m^(-2))是YRR的2.87倍.入射及出射的长波辐射为231.5和338.0 W m^(-2),分别为YRR的0.64和0.83.而两个区域的净辐射差异不大;(2)草地站更多的潜热释放使得地表总加热效率高于城市和高山荒漠,TP和YRR的草地站的年平均潜热分别为35.0和38.8 W m^(-2),而植被稀疏且土壤干燥的高山荒漠地区感热最大,年平均感热为42.1 W m^(-2);其次是城市下垫面,其年平均感热为37.7 W m^(-2).研究结果揭示了不同气候背景下典型下垫面地气相互作用特征,为地气相互作用过程深入分析奠定了基础.
基金Project supported by the Key Project of Hunan Provincial Educational Department of China(Grant No04A058)
文摘We investigate the energy exchange between (3+1)D colliding spatiotemporal solitons (STSs) in dispersive media with cubic-quintic (CQ) nonlinearity by numerical simulations. Energy exchange between two (3+1)D head on colliding STSs caused by their phase difference is observed, just as occurring in other optical media. Moreover, energy exchange between two head-on colliding STSs with different speeds is firstly shown in the CQ and saturable media. This phenomenon, we believe, may arouse some interest in the future studies of soliton collision in optical media.
文摘Meeting the climate change mitigation targets will require a substantial shift from fossil to clean fuels in the heating sector.Heat pumps with deep borehole exchangers are a promising solution to reduce emissions.Here the thermal behavior of deep borehole exchangers(DBHEs)ranging from 1 to 2 km was analyzed for various heat flow profiles.A strong correlation between thermal energy extraction and power output from DBHEs was found,also influenced by the heating profile employed.Longer operating time over the year typically resulted in higher energy production,while shorter one yielded higher average thermal power output,highlighting the importance of the choice of heating strategy and system design for optimal performance of DBHEs.Short breaks in operation for regenerating the borehole,for example,with waste heat,proved to be favorable for the performance yielding an overall heat output close to the same as with continuous extraction of heat.The results demonstrate the usefulness of deep boreholes for dense urban areas with less available space.As the heat production from a single DBHE in Finnish conditions ranges from half up to even a few GWh a year,the technology is best suitable for larger heat loads.
基金funding from the European Research Council (ERC)under grant agreement no.834134 (WATUSO)VLAIO for Moonshot funding (ARCLATH,No.HBC.2019.0110 and ARCLATH2,No.HBC.2021.0254)+3 种基金supported by the Flemish Government as an international research infrastructure (I001321N)infrastructure support by Department EWI via the Hermes Fund (AH.2016.134)the Hercules Foundation (AKUL/13/21)FWO Vlaanderen for an FWO-SB fellowship。
文摘1.Challenges circular methane energy systems In recent decades,methane-based energy systems have rapidly gained traction across the globe because of the increasing availability of low-cost methane production capacity.However,fossil methane production and combustion lead to large greenhouse gas emissions,contributing to climate change[1].
文摘Based on a single ion model, Hamiltonian of the simplest form about magnetocrystalline anisotropy for Tb3+ ion was solved by using the numerical method. The relation between the stabilization energy, crystal field coefficient B20 and the magnetic exchange interaction was studied as temperature approaches to 0 K. The results show that the stabilization energy contributed by Tb3+ is linear with crystal field coefficient B20 approximately, but it is insensitive to the change of magnetic exchange interaction for the strong magnetic substances such as TbCo5, Tb2Co17 and Tb2Fe14B compounds.
基金National Natural Science Foundation of China(No.51808203)Major Technological Innovation Projects of Hubei Province,China(No.2017AAA128)Youth Science and Technology Research Program of Hubei Education Department,China(No.Q20181405)。
文摘The energy pile is a kind of building energy-saving technology using shallow geothermal energy,and its heat exchange performance is an important factor affecting its development.In this study,heat exchange tests were carried out on three full-size cast-in place energy piles,and the influence of various factors on the heat exchange amount and the heat exchange rate was analyzed.The following conclusions are drawn:(1)the heat exchange rate of the cast-in place energy pile is greatly affected by the inlet water temperature;(2)increasing the pile length can increase the heat exchange amount,but has little effect on improving the heat exchange rate;(3)the increase in the heat exchange amount by heat exchange pipes in series is not significant,and therefore the parallel-type heat exchange pipes should be considered in practical engineering;(4)the appropriate circulating water flow velocity gives the best heat exchange efficiency.
基金supported by the NSFC(Grant No.11705010)the NSAF(Grant No.U1230111),the IAEA(CRP No.F11020 and Contract No.21063)the China Postdoctoral Science Foundation(Grant No.2019M650351)。
文摘We present a simple and reliable method,based on the over-barrier model and Lindhard’s formula,to calculate the energy loss,charge transfer,and normalized intensity of highly charged ions penetrating through 2D ultrathin materials,including graphene and carbon nanomembranes.According to our results,the interaction between the ions and the 2D material can be simplified as an equivalent two-body collision,and we find that full consideration of the charge exchange effect is key to understanding the mechanism of ion energy deposition in an ultrathin target.Not only can this semiclassical model be used to evaluate the ion irradiation effect to a very good level of accuracy,but it also provides important guidance for tailoring the properties of 2D materials using ion beams.
文摘Calculation of total energies of the electronic ground states of atoms forms the basis for the frozen-core pseudopotentials used in atomistic calculations of much larger scale. Reference values for these energies provide a benchmark for the validation of new software to calculate such potentials. In addition, basic atomic-scale electronic properties such as the (first) ionization energy provide a simple check on the approximation used in the calculation method. We present a comparison of the total energies and ionization energies of atoms Z = 1 - 92 calculated in density functional theory with several levels of exchange-correlation functional and the Hartree-Fock method, comparing ionization energies to experiment. We also investigate the role of relativistic treatment on these energies.
文摘There are several ways to increase the efficiency of energy consumption and to decrease energy consumption. In this paper. the application of pinch technology in analysis of the heat exchangers network (HEN) in order to reduce the energy consumption in a thermal system is studied. Therefore, in this grass root design, the optimum value of △Tmin, is obtained about 10℃and area efficiency (a) is 0.95. The author also depicted the grid diagram and driving force plot for additional analysis. In order to increase the amount of energy saving, heat transfer from above to below the pinch point in the diagnosis stage is verified for all options including re-sequencing, re-piping, add heat exchanger and splitting of the flows. Results show that this network has a low potential of retrofit to decrease the energy consumption, which pinch principles are planned to optimize energy consumption of the unit. Regarding the results of pinch analysis, it is suggested that in order to reduce the energy consumption, no alternative changes in the heat exchangers network of the unit is required. The acquired results show that the constancy of network is completely confirmed by the high area efficiency infirmity of the heat exchanger to pass the pinch point and from of deriving force plot.
基金The project was supported by the Fund for Scientific Research in Flanders (FWO-Vlaanderen) for Research Grant G021115N.
文摘In this work it is shown that the kinetic energy and the exchange-correlation energy are mutual dependent on each other.This aspect is first derived in an orbital-free context.It is shown that the total Fermi potential depends on the density only,the individual parts,the Pauli kinetic energy and the exchange-correlation energy,however,are orbital dependent and as such mutually influence each other.The numerical investigation is performed for the orbital-based non-interacting Kohn-Sham system in order to avoid additional effects due to further approximations of the kinetic energy.The numerical influence of the exchange-correlation functional on the non-interacting kinetic energy is shown to be of the orderof a few Hartrees.For chemical purposes,however,the energetic performance as a function of the nuclear coordinates is much more important than total energies.Therefore,the effect on the bond dissociation curve was studied exemplarily for the carbon monoxide.The data reveals that,the mutual influence between the exchange-correlation functional and the kinetic energy has a significant influence on bond dissociation energies and bond distances.Therefore,the effect of the exchange-correlation treatment must be considered in the design of orbital-free density functional approximations for the kinetic energy.
文摘The Loess Plateau, located in northern China, has a significant impact on the climate and ecosystem evolvement over the East Asian continent. In this paper, the preliminary autumn daily characteristics of land surface energy and water exchange over the Chinese Loess Plateau mesa region are evaluated by using data collected during the Loess Plateau land-atmosphere interaction pilot experiment (LOPEX04), which was conducted from 25 August to 12 September 2004 near Pingliang city, Gansu Province of China. The experiment was carried out in a region with a typical landscape of the Chinese Loess Plateau, known as "loess mesa". The experiment's field land utilizations were cornfield and fallow farmland, with the fallow field later used for rotating winter wheat. The autumn daily characteristics of heat and water exchange evidently differed between the mesa cornfield and fallow, and the imbalance term of the surface energy was large. This is discussed in terms of sampling errors in the flux observations-footprint; energy storage terms of soil and vegetation layers; contribution from air advections; and low and high frequency loss of turbulent fluxes and instruments bias. Comparison of energy components between the mesa cornfield and the lowland cornfield did not reveal any obvious difference. Inadequacies of the field observation equipment and experimental design emerged during the study, and some new research topics have emerged from this pilot experiment for future investigation.
基金Supported the National Natural Science Foundation of China(21406124)
文摘The heat exchanger network(HEN) synthesis problem based on entransy theory is analyzed. According to the characteristics of entransy representation of thermal potential energy, the entransy dissipation represents the irreversibility of the heat transfer process, the temperature difference determines the entransy dissipation, and four HEN design steps based on entransy theory are put forward. The present study shows how it is possible to set energy targets based on entransy and achieve them with a network of heat exchangers by an example of heat exchanger network design for four streams. In order to verify the correctness of the heat exchanger networks design method based on entransy theory, the synthesis of the HEN for the diesel hydrogenation unit is studied. Using the heat exchange networks design method based on entransy theory, the HEN obtained is consistent with energy targets. The entransy transfer efficiency of HEN based on entransy theory is 92.29%, higher than the entransy transfer efficiency of the maximum heat recovery network based on pinch technology.
基金supported by the National Natural Science Foundation of China (Nos. 50874128 and 50834007)
文摘To investigate the reaction between CO2-CO and wustite using the isotope exchange method at 1073, 1173, 1273, and 1373 K, the experiment apparatus was designed to simulate the fluidized bed. The chemical rate constant was estimated by considering the effect of gas phase mass transfer on the reaction. It is found that the chemical rate constant is inversely decreased with the increase in the ratio of CO2/CO by volume. The activation energy of reaction is in a linear relationship with the ratio of COs/CO by volume, and the average activation energy is 155.37 kJ/mol.
文摘An environmental force termed KELEA (kinetic energy limiting electrostatic attraction) is postulated to reduce the strength of intermolecular (hydrogen) bonding of water molecules, resulting in increased kinetic activity of the water. While regular water does not directly absorb KELEA from the environment, various dipolar compounds with separated electrical charges can seemingly act as a primary antenna for KELEA, with secondary transfer of energy into nearby water. Moreover, once sufficiently activated, the separated electrical charges in activated water can apparently function as a receiver for KELEA, leading to further activation of the water and also to the activation of added water. Prior publications have addressed the agricultural and potential clinical benefits of using KELEA activated water. This article is intended as the first in a series of papers describing useful industrial applications of KELEA activated water. The focus of the present paper is on the improved efficiency of industrial water heating and cooling systems by using KELEA activated water provided by pelleted, ground and heated volcanic rock as supplied by Kiko Technology.
基金This study was supported by China Geological Survey Program(No.DD20160190 and DD20190128)Natural Science Foundation of Hebei Province(No.E2020202065).
文摘Due to its large heat transfer area and stable thermal performance,the middledeep coaxial borehole heat exchanger(CBHE)has become one of the emerging technologies to extract geothermal energy.In this paper,a numerical modeling on a three-dimensional unsteady heat transfer model of a CBHE was conducted by using software FEFLOW,in which the model simulation was compared with the other studies and was validated with experimental data.On this basis,a further simulation was done in respect of assessing the influencing factors of thermal extraction performance and thermal influence radius of the CBHE.The results show that the outlet temperature of the heat exchanger decreases rapidly at the initial stage,and then tended to be stable;and the thermal influence radius increases with the increase of borehole depth.The heat extraction rate of the borehole increases linearly with the geothermal gradient.Rock heat capacity has limited impact on the heat extraction rate,but has a great influence on the thermal influence radius of the CBHE.When there is groundwater flow in the reservoir,the increase of groundwater velocity will result in the rise of both outlet temperature and heat extraction rate.The heat affected zone extends along with the groundwater flow direction;and its influence radius is increasing along with flow velocity.In addition,the material of the inner pipe has a significant effect on the heat loss in the pipe,so it is recommended that the material with low thermal conductivity should be used if possible.
基金This work was supported by the National Natural Science Foundation of China(Grant:21878333).
文摘Crude distillation unit(CDU)is regarded as the main energy consumer in the entire refinery process.In this paper,the process simulation software and the energy management software are used to simulate the flowsheet and analyze the energy consumption,respectively.Stream data obtained from an existing CDU are applicable in the pinch analysis.To reduce the amount of cross-pinch heat transfer,three approaches of resequencing,repiping,and adding heat exchangers are adopted.Compared with the existing CDU,the results demonstrate that the inlet temperature of the furnace can be increased by 25.4℃,the amount of hot and cold utilities can be reduced by 15.1%and 19.6%,respectively.The economic evaluation indicates that the operating cost is saved by 8×106$/a,and the payback period is about 9 months.
基金This work was supported by the National Natural Science Foundation of China(Grant:21878333).
文摘Diesel hydrotreating unit(DHT)is an integral part of the refinery,and its energy-saving optimization is of great significance to the enterprise.In this paper,process simulation software and energy management software are used to simulate the flowsheet and analyze the energy consumption,respectively.Stream data obtained from an existing DHT are applied in the pinch analysis for retrofitting the heat exchanger network(HEN)to achieve maximum energy utilization by using pinch analysis.Since DHT is constrained by pressure,the pressure factor is considered in the process of retrofitting.The results show that the amount of cross-pinch heat transfer is reduced,the inlet temperature of the furnace is increased by 55℃,and the amount of hot and cold utilities can be reduced by 70.25%and 50.16%,respectively.The economic evaluation indicates that the operating cost is saved by 4.39×10^(6)$/a,and the payback period is about 2 months.
基金Project(50878133) supported by the National Natural Science Foundation of ChinaProject (2007R37) supported by Excellent Talents in Liaoning Province+1 种基金Project (2008S193) supported by the Key Laboratory Fund of Education Department in Liaoning ProvinceProject(1071211-1-00) supported by the Scientific and Technical Fund Project Subsidy of Shenyang Province
文摘Based on the phase change material (PCM) thermal characteristic,some testing methods such as differential scanning calorimeter (DSC) etc were used to select the low melting mixture of capric and lauric acid as PCM of phase change wallboard (PCW). The PCW room was established,and some contrast analysis of the storage and exchange thermal characteristic of PCW room and ordinary wall room were made under different conditions. The results show that the fluctuation of indoor air temperature in PCW room is smaller than that in ordinary room obviously. The exchange energy of PCM room with outdoor is less than that of ordinary wall room. In the winter condition,PCW room utilizes valley period electricity to storage energy in the night,while releases at peak period electricity in daytime,which can divert 40% of peak load. In the summer condition,PCW room can reduce the peak cooling load by 25% compared with ordinary wall room.
基金Supported by Jilin Significant Tranformation Project of Science and Techrological Achievements[(2009)17]
文摘Based on the characteristics of heat transfer for corrugated pipe,a method of calculating and design on the submersible corrugated pipe sewage heat exchanger was put forward theoretically and experimentally.The actual movement parameters of air-conditioning system used in this heat exchanger were measured.The experimental result shows that the quantity of heat transfer of the corrugated pipe sewage heat exchanger can satisfy the building's load with the average coefficient of performance 4.55.At the same time,the quantity of heat transfer of the corrugated pipe sewage heat exchanger was compared with that of the other nonmetallic sewage heat exchangers(i.e.,the plastic-Al pipe sewage heat exchanger and PP-R pipe sewage heat exchanger)experimentally.It is found out that the effect of heat transfer for submersible corrugated pipe sewage heat exchanger is superior to those of the plastic-Al pipe and the PP-R pipe.The quantity of heat transfer per mile of corrugated pipe sewage heat exchanger is 5.2 times as much as that of the plastic-Al pipe,and it is 8.1 times as much as that of PP-R pipe.
基金Project supported by the National Natural Science Foundation of China (Grant No. 50671048)
文摘This paper reports that the CoFe/IrMn bilayers are deposited by magnetron sputtering on the surfaces of thermallyoxidized Si substrates. It investigates the thermal relaxations of both non-irradiated and Ca^+ ion irradiated CoFe/IrMn bilayers by means of holding the bilayers in a negative saturation field. The results show that exchange bias field decreases with the increase of holding time period for both non-irradiated and Ca^+ ion irradiated CoFe/IrMn bilayers. Exchange bias field is also found to be smaller upon irradiation at higher ion dose. This reduction of exchange bias field is attributed to the change of energy barrier induced by ion-radiation.