Sustainable and untethered soft robots created using printable and recyclable ferromagnetic fibers

Integrated printing of magnetic soft robots with complex structures using recyclable materials to achieve sustainability of the soft robots remains a persistent challenge.Here,we propose a kind of ferromagnetic fibers that can be used to print soft robots with complex structures.These ferromagnetic fibers are recyclable and can make soft robots sustainable.The ferromagnetic fibers based on thermoplastic polyurethane(TPU)/NdFeB hybrid particles are extruded by an extruder.We use a desktop three-dimensional(3D)printer to demonstrate the feasibility of printing two-dimensional(2D)and complex 3D soft robots.These printed soft robots can be recycled and reprinted into new robots once their tasks are completed.Moreover,these robots show almost no difference in actuation capability compared to prior versions and have new functions.Successful applications include lifting,grasping,and moving objects,and these functions can be operated untethered wirelessly.In addition,the locomotion of the magnetic soft robot in a human stomach model shows the prospect of medical applications.Overall,these fully recyclable ferromagnetic fibers pave the way for printing and reprinting sustainable soft robots while also effectively reducing e-waste and robotics waste materials,which is important for resource conservation and environmental protection.

Influence of exchange bias on spin torque ferromagnetic resonance for quantification of spin–orbit torque efficiency

Antiferromagnet(AFM)/ferromagnet(FM)heterostructure is a popular system for studying the spin–orbit torque(SOT)of AFMs.However,the interfacial exchange bias field induces that the magnetization in FM layer is noncollinear to the external magnetic field,namely the magnetic moment drag effect,which further influences the characteristic of SOT efficiency.In this work,we study the SOT efficiencies of IrMn/NiFe bilayers with strong interfacial exchange bias by using spin-torque ferromagnetic resonance(ST-FMR)method.A full analysis on the AFM/FM systems with exchange bias is performed,and the angular dependence of magnetization on external magnetic field is determined through the minimum rule of free energy.The ST-FMR results can be well fitted by this model.We obtained the relative accurate SOT efficiencyξ_(DL)=0.058 for the IrMn film.This work provides a useful method to analyze the angular dependence of ST-FMR results and facilitates the accurate measurement of SOT efficiency for the AFM/FM heterostructures with strong exchange bias.

Ab initio nonadiabatic molecular dynamics study on spin–orbit coupling induced spin dynamics in ferromagnetic metals

Understanding the photoexcitation induced spin dynamics in ferromagnetic metals is important for the design of photo-controlled ultrafast spintronic device.In this work,by the ab initio nonadiabatic molecular dynamics simulation,we have studied the spin dynamics induced by spin–orbit coupling(SOC)in Co and Fe using both spin-diabatic and spin-adiabatic representations.In Co system,it is found that the Fermi surface(E_(F))is predominantly contributed by the spin-minority states.The SOC induced spin flip will occur for the photo-excited spin-majority electrons as they relax to the E_(F),and the spin-minority electrons tend to relax to the EFwith the same spin through the electron–phonon coupling(EPC).The reduction of spin-majority electrons and the increase of spin-minority electrons lead to demagnetization of Co within100 fs.By contrast,in Fe system,the E_(F) is dominated by the spin-majority states.In this case,the SOC induced spin flip occurs for the photo-excited spin-minority electrons,which leads to a magnetization enhancement.If we move the E_(F) of Fe to higher energy by 0.6eV,the E_(F) will be contributed by the spin-minority states and the demagnetization will be observed again.This work provides a new perspective for understanding the SOC induced spin dynamics mechanism in magnetic metal systems.

C-Type Antiferromagnetic Structure of Topological Semimetal CaMnSb_(2)

Determination of the magnetic structure and confirmation of the presence or absence of inversion(P)and time reversal(Τ)symmetry is imperative for correctly understanding the topological magnetic materials.Here highquality single crystals of the layered manganese pnictide CaMnSb_(2)are synthesized using the self-flux method.

Stacking-dependent exchange bias in two-dimensional ferromagnetic/antiferromagnetic bilayers

A clear microscopic understanding of exchange bias is crucial for its application in magnetic recording, and further progress in this area is desired. Based on the results of our first-principles calculations and Monte Carlo simulations,we present a theoretical proposal for a stacking-dependent exchange bias in two-dimensional compensated van der Waals ferromagnetic/antiferromagnetic bilayer heterostructures. The exchange bias effect emerges in stacking registries that accommodate inhomogeneous interlayer magnetic interactions between the ferromagnetic layer and different spin sublattices of the antiferromagnetic layer. Moreover, the on/off switching and polarity reversal of the exchange bias can be achieved by interlayer sliding, and the strength can be modulated using an external electric field. Our findings push the limits of exchange bias systems to extreme bilayer thickness in two-dimensional van der Waals heterostructures, potentially stimulating new experimental investigations and applications.

Semiclassical approach to spin dynamics of a ferromagnetic S = 1 chain

Motivated by recent experimental progress on the quasi-one-dimensional quantum magnet Ni Nb2O6, we study the spin dynamics of an S = 1 ferromagnetic Heisenberg chain with single-ion anisotropy by using a semiclassical molecular dynamics approach. This system undergoes a quantum phase transition from a ferromagnetic to a paramagnetic state under a transverse magnetic field, and the magnetic response reflecting this transition is well described by our semiclassical method.We show that at low temperature the transverse component of the dynamical structure factor depicts clearly the magnon dispersion, and the longitudinal component exhibits two continua associated with single-and two-magnon excitations,respectively. These spin excitation spectra show interesting temperature dependence as effects of magnon interactions. Our findings shed light on the experimental detection of spin excitations in a large class of quasi-one-dimensional magnets.

Evolution of anomalous Hall effect in ferromagnetic Weyl semimetal Nb_(x)Zr_(1-x)Co_(2)Sn

Magnetic topological semimetal can host various topological non-trivial states leading to exotic novel transport properties.Here we report the systematic magneto-transport studies on the Heusler alloy Nb_(x)Zr_(1-x)Co_(2)Sn considered as a ferromagnetic(FM)Weyl semimetal.The cusp anomaly of temperature-dependent resistivity and large isotropic negative magneto-resistivity(MR)emerge around the FM transition consistent with the theoretical half-metallic predictions.The prominent anomalous Hall effect(AHE)has the same behavior with the applied field along various crystal directions.The Nb doping introduces more disorder resulting in the enhancement of the upturn for the temperature-dependent resistivity in low temperatures.With Nb doping,the AHE exhibits systemic evolution with the Fermi level lifted.At the doping level of x=0.25,the AHE mainly originates from the intrinsic contribution related to non-trivial topological Weyl states.

Half-metallic ferromagneticWeyl fermions related to dynamic correlations in the zinc-blende compound VAs

The realization of 100%polarized topologicalWeyl fermions in half-metallic ferromagnets is of particular importance for fundamental research and spintronic applications.Here,we theoretically investigate the electronic and topological properties of the zinc-blende compound VAs,which was deemed as a half-metallic ferromagnet related to dynamic correlations.Based on the combination of density functional theory and dynamical mean field theory,we uncover that the half-metallic ferromagnet VAs exhibits attractive Weyl semimetallic behaviors which are very close to the Fermi level in the DFT+U regime with effect U values ranging from 1.5 eV to 2.5 eV.Meanwhile,we also investigate the magnetization-dependent topological properties;the results show that the change of magnetization directions only slightly affects the positions of Weyl points,which is attributed to the weak spin–orbital coupling effects.The topological surface states of VAs projected on semi-infinite(001)and(111)surfaces are investigated.The Fermi arcs of all Weyl points are clearly visible on the projected Fermi surfaces.Our findings suggest that VAs is a fully spin-polarized Weyl semimetal with many-body correlated effects in the effective U values range from 1.5 eV to 2.5 eV.

Mechanism study on electromagnetic acoustic transducer for ultrasonic generation in ferromagnetic material

Based on the proper assumptions and approximations, the coupling mechanism of the electromagnetic acoustic transducer (EMAT) for ultrasonic generation within ferromagnetic material was studied by analyzing the eddy current distribution, Lorentz force, magnetostriction force and magnetization force. Some useful numerical calculations are presented to explain the EMAT behavior with general geometric arrangements. It is indicated that for the ferromagnetic material the magnetostriction effect dominates the EMAT phenomenon for ultrasonic wave generation in low magnetic field intensity, while the material does not reach its magnetizing saturation. But, with the increase of the bias magnetic field and saturation, the magnetostrictive terms will make no contributions to the ultrasonic generation and the Lorentz force becomes the only exciting mechanism. It is important to determine both the Lorentz and magnetostriction forces and select the appropriate working manner for achieving an optimized design.

Ferroic domain characterization of Ni_(55)Mn_(20.6)Ga_(24.4) ferromagnetic shape memory alloy

The microstructure and coupling between structural and magnetic domains of ferromagnetic shape memory alloy Ni55Mn20.6Ga24.4 were investigated by scanning electron acoustic microscopy （SEAM）. Stripe ferroelastic domains （martensite variants） exist in every grain, and exhibit the configurations of the typical self-accommodation arrangement. Magnetic domain structure of Ni55Mn20.6Ga24.4 was observed by the Bitter method and magnetic force microscopy （MFM）. Due to the unique subsurface imaging capability of SEAM, combined with the Bitter method, the ferroelastic domain structure can be compared with in situ ferromagnetic domain structure. It is found that the martensitic variant boundaries coincide well with the ferromagnetic domain walls, which is beneficial for the understanding of the correlation between two kinds of ferroic domains.

Microwave ferromagnetic properties of as-deposited Co_2FeSi Heusler alloy films prepared by oblique sputtering

The Co2FeSi films are deposited on Si （100） substrates by an oblique sputtering method at ambient temperature. It is revealed that the microwave ferromagnetic properties of Co2FeSi films are sensitive to sample position and sputtering power. It is exciting that the as-deposited films without any magnetic annealing exhibit high in-plane uniaxial anisotropy fields in a range of 200 Oe-330 Oe （1 Oe = 79.5775 A.m ^-1）, and low coercivities in a range of 5 Oe-28 Oe. As a result, high self-biased ferromagnetic resonance frequency up to 4.75 GHz is achieved in as-deposited oblique sputtered films. These results indicate that Co2FeSi Heusler alloy films are promising in practical applications of RF/microwave devices.

Current spin polarization and spin injection efficiency in ZnO-based ferromagnetic semiconductor junctions

[FeNi（3 nm）/Zn1-xCoxO（3 nm）]2/ZnO（d nm）/[Zn1-xCoxO（3 nm）/Co（3 nm）]2 （d=3 and 10） semiconductor junctions were prepared by magnetron sputtering system and photolithography. The spin valve effect was observed in these junctions because the utility of the ferromagnetic composite layers acted as soft and hard magnetic layers. The electrical detection was performed by measuring the magnetoresistance of these junctions to investigate the current spin polarization asc in the ZnO layer and the spin injection efficiency η of spin-polarized electrons. asc was reduced from 11.7% （and 10.5%） at 90 K to 7.31% （and 5.93%） at room temperature for d=3 （and d=10）. And η was reduced from 39.5% （and 35.5%） at 90 K to 24.7% （and 20.0%） at room temperature for d=3 （and d=10）.

Li_(2)NiSe_(2):A new-type intrinsic two-dimensional ferromagnetic semiconductor above 200 K

By using first-principles electronic structure calculations,we propose a two-dimensional ferromagnetic semiconductor Li_(2)NiSe_(2)with a Curie temperature above 200 K.The structure of monolayer Li_(2)NiSe_(2)is dynamically stable,which is derived from the synthesized prototype compound Li_(2)Ni O_(2)and can be denoted as Li-decorated 1T-type NiSe_(2).The Ni–Se–Ni ferromagnetic superexchange dominates the magnetic couplings between the Ni atoms,which can be understood in the frame of the Goodenough–Kanamori–Anderson(GKA)rules.Our systematic study of monolayer Li_(2)NiSe_(2)enables its promising applications in spintronics and suggests a new choice to design two-dimensional ferromagnetic semiconductors.

Ferromagnetic MnSb Films Consisting of Nanorods and Nanoleaves

Ferromagnetic MnSb films were synthesized on Si wafers by physical vapor deposition. X-ray diffraction revealed that the films primarily consisted of MnSb alloy. Nanorods and nanoleaves were observed in the MnSb films by field-emission scanning electron microscopy. These nanorods had an average diameter of 20nm and a length of up to hundreds of nanometers. The nanoleaves had a width and thickness of about 100 and 20nm, respectively. Magnetic hysteresis loops were measured by an alternative gradient magnetometer, and the loops showed strong geometrical anisotropy.

Preparation and characterization of ferromagnetic fluids for hyperthermia of tumor

Aim To prepare and characterize ferromagnetic fluids for hyperthermia of tumor. Methods Ferromagnetic fluids （FFs） of magnetite （Fe3O4） was prepared in the presence of polyethylene glycol （PEG-6000） by chemical precipitation method. The iron content of the FFs was determined by spectrophotometric method using o-phenanthroline. The FFs/PEG-6000 was characterized by transmission electron microscopy （TEM）, X-ray diffraction （XRD）, infrared spectrometry （IR）, and vibrating sample magnetometer （VSM）. Heating effects of the FFs was measured in an alternating magnetic field in vitro. The hyperthermia of FFs in a rabbit was performed. Results The FFs/PEG-6000 was proved to be composed of Fe3O4 by XRD and IR. TEM showed that the ferromagnetic particles appeared to be almost spherical and dispersed well The average particle size was 13.3 ± 3.8 nm by XRD. The saturation magnetization and residual magnetization of the FFs were 23.39 A/m （1.556 emu/g） and 0.56 A/m （0.02604 emu/g）, respectively. The coercive force was 12 Oe. The specific absorption rate （SAR） of FFs was 69 ± 10W/g [Fe]. After direct injection of FFs to hepatic VX2 carcinoma of a rabbit, the temperature in the core of the tumor was between 41 - 46 ℃ in an alternating magnetic field. Conclusion FFs/PEG-6000 was expected to be useful in hyperthermia of tumor.

Ferromagnetic Resonance Study on the Permalloy Submicron Rectangular Arrays Prepared by Electron Beam Lithography

In this paper, we report a ferromagnetic resonance study on the permalloy film of submicron sized rectangular arrays prepared by electron beam lithography and the theoretical simulation to the non uniform demagnetizing effect and ferromagnetic resonance data. By theoretical simulation, the magnetization, gyromagnetic ratio and g value of the sample are determined. The theoretical curves of the dependence of the resonance field on the field orientation φ H fit well with the experimental data. When the steady magnetic field is applied near the film normal, a series of additional regular peaks (up to eight ) appeared in the FMR spectrum on the low field side of the main FMR peak. The resonance field of these side peaks decreases linearly with the peak number. The possible physical mechanism of these multiple peaks was discussed.

Magnetoelastic combined resonance and stability analysis of a ferromagnetic circular plate in alternating magnetic field

The nonlinear combined resonance problem of a ferromagnetic circular plate in a transverse alternating magnetic field is investigated. On the basis of the deformation potential energy, the strain potential energy, and the kinetic energy of the circular plate, the Hamilton principle is used to induce the magnetoelastic coupling transverse vibration dynamical equation of the ferromagnetic circular plate. Based on the basic electromagnetic theory, the expressions of the magnet force and the Lorenz force of the circular plate are presented. A displacement function satisfying clamped-edge combined with the Galerkin method is used to derive the Duffing vibration differential equation of the circular plate. The amplitude-frequency response equations of the system under various combined resonance forms are obtained by means of the multi-scale method, and the stability of the steady-state solutions is analyzed according to the Lyapunov theory. Through examples, the amplitude-frequency characteristic curves with different parameters, the amplitude of resonance varying with magnetic field intensity and excitation force, and the time-course response diagram, phase diagram, Poincar′e diagram of the system vibration are plotted, respectively. The effects of different parameters on the amplitude and stability of the system are discussed. The results show that the electromagnetic parameters have a significant effect on the multi-valued attribute and stability of the resonance solutions, and the system may exhibit complex nonlinear dynamical behavior including multi-period and quasi-periodic motion.

Progress of novel diluted ferromagnetic semiconductors with decoupled spin and charge doping: Counterparts of Fe-based superconductors

Diluted ferromagnetic semiconductors（DMSs） that combine the properties of semiconductors with ferromagnetism have potential application in spin-sensitive electronic（spintronic） devices. The search for DMS materials exploded after the observation of ferromagnetic ordering in Ⅲ-Ⅴ（Ga,Mn）As films. Recently, a series of DMS compounds isostructural to iron-based superconductors have been reported. Among them, the highest Curie temperature TCo f 230 K has been achieved in（Ba,K）（Zn,Mn）2As2. However, most DMSs, including（Ga,Mn）As, are p-type, i.e., the carriers that mediate the ferromagnetism are holes. For practical applications, DMSs with n-type carriers are also advantageous. Very recently,a new DMS Ba（Zn,Co）2As2 with n-type carriers has been synthesized. Here we summarize the recent progress on this research stream. We will show that the homogeneous ferromagnetism in these bulk form DMSs has been confirmed by microscopic techniques, i.e., nuclear magnetic resonance（NMR） and muon spin rotation（μSR）.

PERTURBATION ANALYSIS FOR MAGNETO-PLASTIC INSTABILITY OF FERROMAGNETIC BEAM-PLATES WITH GEOMETRIC IMPERFECTION

The magneto-plastic instability of a ferromagnetic beam-type plate with simple supports and small initial imperfection is analytically investigated in this paper for that the plastic deformation of the plate with a linear-strain hardening relation is considered when the plate is located in a strong uniformly distributed magnetic ?eld. After the distribution of magnetic ?elds related to the de?ected con?guration of plate is imaginably divided into two parts, i.e., one is related to the ?at plate and the other dependent on the perturbation of magnetic ?elds for which the plate con?guration changes from the ?at into the deformed state, the perturbation technique is employed to analyze the distribution of the perturbation magnetic ?elds in and out-of the magnetic medium of the ferromagnetic structure in a transverse magnetic ?eld, which leads to some analytical formulae/solutions for the magnetic ?elds and the resulting magnetic force exerted on the plate. Based on them, the magneto-plastic buckling and snapping of the plate in a transverse magnetic ?eld is discussed, and the critical magnetic ?eld is analytically formulated in terms of the parameters of geometry and material of the plate employed by solving the governing equation of the magneto-plastic plate in the applied magnetic ?eld. Further, the sensitivity of the initial imperfection on the magneto-plastic instability, expressed by an ampli?cation function, is obtained by solving the dynamic equation of de?ection of the plate after the inertial force in the transverse direction is taken into account. The results obtained show that the critical magnetic ?eld is sensitive to the plastic characteristic, e.g., hardening coe?cient, and the instability mode and de?ection of the plate are dependent on the geometrical imperfection as well.

Metal magnetic memory testing for early damage assessment in ferromagnetic materials

In order to investigate the physical mechanism of metal magnetic memory testing, both the influences of earth magnetic field and applied stress on magnetic domain structure were discussed. Static tension and fatigue tests for low carbon steel plate specimens were carried out on hydraulic servo testing machine of MTS810 type and magnetic signals were measured during the processes by the type of EMS-2003 instrument. The results indicate that the initial magnetic signals of specimens are different before loading. The magnetic signals curves are transformed from initial random to regular pattern due to the effect of two types of loads. However, the shape and distribution of magnetic signal curves in the elastic region are different from that of plastic region in tension test. While in fatigue test those magnetic signals curves corresponding to different cycles are similar. The H_p(y) value of magnetic signals on the fracture zone increases dramatically at the breaking transient time and positive-negative magnetic poles occur on the two parts of fracture zone.