Characterization of carbon fibers recovered through mechanochemical-enhanced recycling of waste carbon fiber reinforced plastics

In this study,we present the characterization of the carbon fibers recovered from the mechanochemical-enhanced recycling of carbon fiber reinforced fibers.The objectives of the study were to investigate the effect of our modified recycling method on the interfacial properties of recovered fibers.The reinforced plastics were recycled;the recycling efficiency was determined and the recovered fibers were sized using 1 wt%and 3 wt%concentration of(3-aminopropyl)triethoxysilane.We characterized the morphologies utilizing the electron spectroscopy for chemical analysis(ESCA),atomic force microscopy(AFM),FTIR-attenuated total reflection(ATR)spectroscopy and scanning electron microscopy(SEM).Although the surface of the fibers had no cracks,there was evidence of contaminations which affected the interfacial properties and the quality of the fibers.Results showed that the trends in the recovered and virgin fibers were similar with an increase in sizing concentration.The results highlighted the perspectives of increasing the quality of recovered fibers after the recycling process.

Development and Properties of Glass Fiber Reinforced Plastics Geogrid

Glass fiber reinforced plastics geogrid has a wide application in the field of soil reinforcement because of its high strength, good toughness, and resistance to environmental stress, creep resistance and strong stability. In order to get high-powered glass fiber reinforced plastics geogrid and its mechanical characteristics, the properties and physical mechanical index of geogrid have been got through the study of its raw material, production process and important quality index. The analysis and study have been made to the geogrid＇s mechanical properties with loading speed, three-axial compression, temperature tensile test and FLAC3D numerical simulation, thus obtain the mechanical parameters of its displacement time curve, breaking strength and elongation at break. Some conclusions can be drawn as follows： （a） Using glass fiber materials, knurling and coated projection process, the f^acture strength and corrosion resistance of geogrid are greatly improved and the interlocking bite capability of soil is enhanced. （b） The fracture strength of geogrid is related to temperature and loading rate. When the surrounding rock pressure is fixed, the strength and anti-deformation ability of reinforced soil are significantly enhanced with increasing reinforced layers. （c） The pullout test shows the positive correlation between geogrid displacement and action time. （d） As a new reinforced material, the glass fiber reinforced plastics geogrid is not mature enough in theoretical research and practical experience, so it has become an urgent problem both in theoretical study and practical innovation.

Square concrete columns strengthened with carbon fiber reinforced plastics sheets at low temperatures

Twenty-one square concrete columns were constructed and tested. The testing results indicate that bonded carbon fiber reinforced plastics(CFRP) sheets can be used to increase the strength and improve the serviceability of damaged concrete columns at low temperatures. The failure of the specimens,in most cases,takes place within the middle half of the columns. And the failure of strengthened columns is sudden and explosive. The CFRP sheets increase both the axial load capacity and the ultimate concrete compressive strain of the columns. The ultimate loads of strengthened columns at-10,0 and 10 ℃ increase averagely by 9.09%,6.63% and 17.83%,respectively,as compared with those of the control specimens. The axial compressive strength of strengthened columns is related to the curing temperatures. The improvement of axial compressive strength decreases with reducing temperature,and when the temperature drops to a certain value,the improvement increases with falling temperature.

Behaviour of Multiscale Progressive Damage for Different Matrix Glass Fiber Reinforced Plastics Bars

The damage formation and evolution of glass fiber reinforced plastics( GFRP) bar on mechanical properties were mainly evaluated by theoretical analysis and numerical calculations which lack of test basis of damage process. The two different matrices of unsaturated polyester and vinylester GFRP bars were selected to carry out a series of macro-mesoscopic physical and mechanical tests to analyze the tensile progressive damage process on a multiscale. The formation of apparent crack,the bonding of internal components as well as the strain change were all reflected damage evolution of GFRP bar,and a certain correlation existed between them. Wherein the matrix has an obvious impact on the damage of bar,the component stress transfer effect of vinylester bar is better than unsaturated polyester from crack propagation observation and scanning electron microscopy( SEM). The cyclic loading tests quantitatively reflect the difference of damage accumulation between different matrix bars,and the failure load of bars decreases nearly 10%.

Effects of fiber orientation on tool wear evolution and wear mechanism when cutting carbon fiber reinforced plastics

The aim of the present paper is to reveal the influence of different fiber orientations on the tool wear evolution and wear mechanism. Side-milling experiments with large-diameter milling tools are conducted. A finite element(FE) cutting model of carbon fiber reinforced plastics(CFRP)is established to get insight into the cutting stress status at different wear stages. The results show that different fiber orientations bring about distinct differences in the extent, profile and mechanism of tool wear. Severer wear occurs when cutting 45° and 90° plies, followed by 0°, correspondingly,the least wear is obtained when θ = 135°(θ represents the orientation of fibers). Moreover, the worn profiles of cutting tools when θ = 0° and 45° are waterfall edge, while round edge occurs whenθ = 135° and a combined shape of waterfall and round edge is obtained when θ = 90°. The wear mechanisms under different fiber orientations are strongly dependent on the cutting stress distributions. The evolution of tool wear profile is basically consistent with the stress distribution on the tool surface at different wear stages, and the extent of tool wear is determined by the magnitude of stress on the tool surface. Besides, the worn edges produce an actual negative clearance angle,which decreases the actual cutting thickness and leads to compressing and bending failure of fibers beneath the cutting region as well as low surface qualities.

Fabrication and Drilling Tests of Chemical Vapor Deposition Diamond Coated Drills in Machining Carbon Fiber Reinforced Plastics

Chemical vapor deposition (CVD) diamond coated drills are fabricated by depositing diamond films on Co-cemented tungsten carbide (WC-Co) drills. The characteristics of as-deposited diamond coatings are investigated by scanning electron microscope (SEM) and Raman spectra. To evaluate the cutting performance of diamond coated drills, comparative drilling tests are conducted using diamond coated and uncoated WC-Co drills, with carbon fiber reinforced plastics (CFRPs) as the workpiece on a high-speed computer numerical control (CNC) machine. Thrust force and tool wear are measured during the drilling process. The results show that diamond coated drill exhibits better cutting performance, compared with the uncoated drill. The value of flank wear is about 70 μm after machining 90 holes, about a half of that of the WC-Co drill with 145 μm after drilling only 30 holes. The wear rate of WC-Co drill is higher than that of diamond coated drill before diamond films peeling off. The diamond coated drill achieves more predictable hole quality. The improved cutting performance of the diamond coated drill is due to the high hardness, wear resistance and low coefficient of friction.

Impact Responses of the Carbon Fiber Fabric Reinforced Composites

To study the response characteristics of the carbon fiber fabric reinforced composites under impact loading, one dimensional strain impact test, multi gauge technique and Lagrange analysis method are used. The decaying rule of the stress σ , strain ε , strain rate ε · and density ρ with time and space is obtained. By the theory of dynamics, the impact response characteristics of the material is analyzed and discussed.

Entrance and Exit Defects During Coarse Pitch Orbital Drilling of Carbon Fiber Reinforced Plastic Plates

Formation of entrance and exit defects in coarse pitch orbital drilling(CPOD)of carbon fiber reinforced plastic(CFRP)plates was investigated.Deep observation on entrance and exit morphology shows tear and burr are typical defects.Meanwhile,tear is more obvious than burr,and more entrance tears emerge than exit tears.As one of the major causes of entrance and exit defects in CPOD,cutting forces were substaintially studied by contrast experiments.Then,the effect of cutting parameters on entrance and exit tear was qualitatively analyzed through a single factor test.Experiment results indicate that the variation of rotation speed has little influence on entrance and exit tear.Increasing tangential feed per tooth can enlarge entrance tear,but bring little effect on exit tear.By increasing axial feed pitch,the hole entrance and exit show severe tear.When revolution radius grows bigger and bigger,entrance and exit tear firstly decreases,and then increases.Finally,the models of tear and delamination during CPOD of CFRP were established,the formation mechanisms of entrance and exit defects were revealed,and the control strategies were accordingly put forward.

Quasi-plane-hypothesis of strain coordination for RC beams seismically strengthened with externally-bonded or near-surface mounted fiber reinforced plastic

The application of fiber reinforced plastic（FRP）,including carbon FRP and glass FRP,for structural repair and strengthening has grown due to their numerous advantages over conventional materials such as externally bonded reinforcement（EBR） and near-surface mounted（NSM） strengthening techniques.This paper summarizes the results from 21 reinforced concrete beams strengthened with different methods,including externally-bonded and near-surface mounted FRP,to study the strain coordination of the FRP and steel rebar of the RC beam.Since there is relative slipping between the RC beam and the FRP,the strain of the FRP and steel rebar of the RC beam satisfy the quasi-plane-hypothesis;that is,the strain of the longitudinal fiber that parallels the neutral axis of the plated beam within the scope of the effective height（h 0） of the cross section is in direct proportion to the distance from the fiber to the neutral axis.The strain of the FRP and steel rebar satisfies the equation：ε FRP =βε steel,and the value of β is equal to 1.1-1.3 according to the test results.

Double linear strain distribution assumption of RC beam strengthened with external-bonded or near-surface mounted fiber reinforced plastic

Rehabilitation of existing structures with fiber reinforced plastic(FRP)has been growing in popularity because they offer superior performance in terms of resistance to corrosion and high specific stiffness.The strain coordination results of 34 reinforced concrete beams(four groups)strengthened with different methods were presented including external-bonded or near-surface mounted glass or carbon FRP or helical rib bar in order to study the strain coordination of the strengthening materials and steel rebar of RC beam.Because there is relative slipping between concrete and strengthening materials(SM),the strain of SM and steel rebar of RC beam satisfies the double linear strain distribution assumption,that is,the strain of longitudinal fiber parallel to the neutral axis of plated beam within the scope of effective height(h0)of the cross section is in direct proportion to the distance from the fiber to the neutral axis.The strain of SM and steel rebar satisfies the equation εGCH=βεsteel,where the value of β is equal to 1.1-1.3 according to the test results.

Strain coordination of quasi-plane-hypothesis for reinforced concrete beam strengthened by epoxy-bonded glass fiber reinforced plastic plate

The testing of thirteen reinforeed concrete （RC） beams strengthened by epoxy-bonded glass fiber reinforced plastic plate （GFRP） shows that the RC beam and the GFRP plate with epoxy bonding on it can work fairly well in coordination to eaeh other. But there is relative slipping between RC beam and GFRP plate. And the strain of GFRP and steel rebar of RC beam satisfies the quasi-plane-hypothesis, that is, the strain of longitudinal fiher that parallels to the neutral axis of plated beam within the scope of effective height （ h0 ） of the cross section is in direct proportion to the distance from the fiber to the neutral axis. The strain of GFRP and steel rebar satisfies the equation： εGFRP=Kεsteel.

Feasibility study of wave-motion milling of carbon fiber reinforced plastic holes

Carbon fiber reinforced plastic(CFRP)has been applied in aeronautics,aerospace,automotive and medical industries due to its superior mechanical properties.However,due to its difficult-to-cut characteristic,various damages in twist drilling and chip removal clog in core drilling could happen,inevitably reducing hole quality and hole-manufacturing efficiency.This paper proposes the wave-motion milling(WMM)method for CFRP hole-manufacturing to improve hole quality.This paper presents a motion path model based on the kinematics of the WMM method.The wave-motion cutting mode in WMM was analyzed first.Then,comparison experiments on WMM and conventional helical milling(CHM)of CFRP were carried out under dry conditions.The results showed that the hole surface quality of the CFRP significantly improved with a decrease of 18.1%–36%of Ra value in WMM compared to CHM.WMM exerted a significantly weaker thrust force than that of CHM with a reduction of 12.0%–24.9%and 3%–7.7%for different axial feed per tooth and tangential feed per tooth,respectively.Meanwhile,the hole exit damages significantly decreased in WMM.The average tear length at the hole exit in WMM was reduced by 3.5%–29.5%and 35.5%–44.7%at different axial feed per tooth and tangential feed per tooth,respectively.Moreover,WMM significantly alleviated tool wear.The experimental results suggest that WMM is an effective and promising strategy for CFRP hole-manufacturing.

Dynamic Characteristics Analysis of Multilayer Fiber Reinforced Plastic Shaft

In order to study the dynamic characteristics of multilayer fiber reinforced plastic(MFRP)shaft,the coupling model of three-dimensional equivalent bending stiffness theory and transfer matrix method is established,and the influence of thickness-radius ratio,length-radius ratio,layer angles,layer proportion,and stacked approaches on MFRP shaft dynamic characteristics is investigated.The result shows that the proposed coupling model has high accuracy in MFRP shaft dynamic performance prediction.The proportion of small-angle layers is the decisive factor of MFRP shaft natural frequency.With the increase of thickness-radius ratio and length-radius ratio,the natural frequency of MFRP shaft decreases.The natural frequency of MFRP shaft with the angle layers combination of±45°and±90°is smaller compared with the metal shaft no matter in simple/free boundary condition or simple/simple supported boundary condition.

STUDY ON THE CONDUCTING FIBER REINFORCED PLASTIC

The conductive fiber reinforced plastic was prepared by dispersing electrical conducting filler particles such as aluminum powder, graphite and carbon black to glass fiber reinforced resin. The effects that each or double kinds of fillers, also the conductive fiber cloth had done on the electrical and mechanical properties of plastic composites were studied. This paper also provided discussion on the conductive mechanism of fiber reinforced plastic. (Author abstract) 8 Refs.

Thermal Structure of Glass Fiber Reinforce Plastic Support Structure

The assembled form of thick-wall glass fiber reinforced plastics (GFRP) tube and 0Cr18Ni9 austenitic stainless steel pipes was designed as the radius thermal-insulating and load-supporting structure in cryogenic vessels. In order to study the thermal leakage and gap changes on the support structure, as well as radius temperature and stress distribution on GFRP tube, an experimental investigation has been taken. The results indicate that the support structure is proved to fit well as thermal-insulating and load-supporting part in cryo-genic vessels, furthermore has high security during cryogenic applications.

Multi-Scale Design and Optimization of Composite Material Structure for Heavy-Duty Truck Protection Device

In this paper,to present a lightweight-developed front underrun protection device(FUPD)for heavy-duty trucks,plain weave carbon fiber reinforced plastic(CFRP)is used instead of the original high-strength steel.First,the mechanical and structural properties of plain carbon fiber composite anti-collision beams are comparatively analyzed from a multi-scale perspective.For studying the design capability of carbon fiber composite materials,we investigate the effects of TC-33 carbon fiber diameter(D),fiber yarn width(W)and height(H),and fiber yarn density(N)on the front underrun protective beam of carbon fiber compositematerials.Based on the investigation,a material-structure matching strategy suitable for the front underrun protective beam of heavy-duty trucks is proposed.Next,the composite material structure is optimized by applying size optimization and stack sequence optimization methods to obtain the higher performance carbon fiber composite front underrun protection beam of commercial vehicles.The results show that the fiber yarn height(H)has the greatest influence on the protective beam,and theH1matching scheme for the front underrun protective beamwith a carbon fiber composite structure exhibits superior performance.The proposed method achieves a weight reduction of 55.21% while still meeting regulatory requirements,which demonstrates its remarkable weight reduction effect.

Experimental study on slender reinforced concrete columns wrapped with CFRP

By axial compression tests on 6 reinforced concrete slender columns wrapped with carbon fiber-reinforced plastic (CFRP),with slenderness ratio(SR) from 4.5 to 17.5,the results show that when SR increases the retrofitting effect declines. In the case of same SR,the stability coefficient (SC) for the reinforced concrete(RC) columns with CFRP is much less than that without CFRP. There is 20% increase of stable bearing capacity to the former as compared with the latter when the SR in less than 17.5. The study summarized the simplified formula for SC,which provides a reference for engineering designers.

Numerical Determination of Shear Strength of Steel Reinforced Concrete Column Strengthened by CFRP Sheets

The earthquake resistant property of reinforced concrete members depends on the interaction between reinforcing bars and surrounding concrete through bond to a large degree. In this paper a general system aimed at dealing with the failure analysis of reinforced concrete columns strengthened with carbon fiber reinforced plastic (CFRP) sheets including bond slip of the anchored reinforcing bars at the foot of the columns is presented. It is based on the yield design theory with a mixed modeling of the structure, according to which the concrete material is treated as a classical two dimensional continuum, whereas the longitudinal reinforcing bars are regarded as one dimensional rods including bond slip at the foot of the columns. In shear reinforced zones both the shear CFRP sheets and transverse reinforcing bars are incorporated in the analysis through a homogenization procedure and they are only in tension. The approach is then implemented numerically by means of the finite element formulation. The numerical procedure produces accurate estimates for the loading carrying capacity of the shear members taken as an illustrative application by correlation with the experimental results, so the proposed approach is valid.

Shear capacity of reinforced concrete columns strengthened with CFRP sheet

This paper discusses the results of tests on the shear capacity of reinforced concrete columns strengthened with carbon fiber reinforced plastic (CFRP) sheet. The shear transfer mechanism of the specimens reinforced with CFRP sheet was studied. The factors affecting the shear capacity of reinforced concrete columns strengthened with CFRP sheet were analyzed. Several sug-gestions such as the number of layers, width and tensile strength of the CFRP sheet are proposed for this new strengthening technique. Finally, a simple and practical design method is presented in the paper. The calculated results of the suggested method are shown to be in good agreement with the test results. The suggested design method can be used in evaluating the shear capacity of reinforced concrete columns strengthened with CFRP sheet.

Temperature field characteristics of CF/PEEK thermoplastic composites formed by automated fiber placement using hot gas torch with slit structure nozzle

In-situ consolidation forming of high-performance thermoplastic composites by Automated Fiber Placement(AFP)is of significant interest in aerospace.During the laying process,the heating temperature has a great influence on the quality of the formed components.A threedimensional heat transfer finite element model of Carbon Fiber(CF)/Polyether Ether Ketone(PEEK)heated by Slit Structure Nozzle Hot Gas Torch(SSNHGT)assisted AFP is proposed.The influence of gas flow rate,heat transfer distance,and laying speed on heating temperature is analysed.The results show that the overall temperature increases and then decreases as the gas flow rate increases.With the increase in heat transfer distance and laying speed,the overall temperature decreases.Meanwhile,the gas flow rate has the greatest influence on the temperature of CF/PEEK being heated,followed by the laying speed and finally the heat transfer distance.Furthermore,the model can also be extended to other fiber-reinforced polymer composites formed by hot gas torch assisted AFP,which can guide the optimization of process parameters for subsequent heating temperature control.