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Stress test and analysis based on SMS fiber structure with high sensitivity
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作者 张美芹 王冠军 +1 位作者 安永泉 王志斌 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2016年第3期297-301,共5页
Single mode-multimode-single mode (SMS) sensor is widely used for parameters measurement, such as bending, dis-placement, temperature, strain, refractive index, etc. Generally, SMS sensor has advantages of simpl... Single mode-multimode-single mode (SMS) sensor is widely used for parameters measurement, such as bending, dis-placement, temperature, strain, refractive index, etc. Generally, SMS sensor has advantages of simple structure, low cost and easy layout, therefore it has become a research hotspot in recent years. In this paper, the multimode fiber with large core is used for manufacturing SMS structure with high sensitivity. Firstly, the multimode fiber with core/cladding diameters of 105/ 125 jitm has access to the system by means of single mode optical fiber. Secondly, SMS device structure is manufactured by welding the eccentric shaft of multimode optical fiber. Afterwards, mode interference effect and spectral response characteristics of the structure of single mode-multimode-single mode optical fiber are analyzed theoretically. Finally, with the help of a wide spectrum light source and a spectrum analyzer, the transmission spectra characteristics of SMS optical fiber with strain is tested. By observing the curve that the wave changes with stress, the sensitivity is calculated and it is consistent with theoretical value . 展开更多
关键词 SMS optical fiber structure optical spectrum analyzer (OSA) amplified spontaneous emission stress test
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Dual-channel fiber-optic surface plasmon resonance sensor with cascaded coaxial dual-waveguide D-type structure and microsphere structure 被引量:1
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作者 李玲玲 魏勇 +4 位作者 刘春兰 任卓 周爱 刘志海 张羽 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第2期201-208,共8页
To address the restriction of fiber-optic surface plasmon resonance(SPR) sensors in the field of multi-sample detection, a novel dual-channel fiber-optic SPR sensor based on the cascade of coaxial dual-waveguide D-typ... To address the restriction of fiber-optic surface plasmon resonance(SPR) sensors in the field of multi-sample detection, a novel dual-channel fiber-optic SPR sensor based on the cascade of coaxial dual-waveguide D-type structure and microsphere structure is proposed in this paper. The fiber sidepolishing technique converts the coaxial dual-waveguide fiber into a D-type one, and the evanescent wave in the ring core leaks, generating a D-type sensing region;the fiber optic fused ball push technology converts the coaxial dual waveguides into microspheres, and the stimulated cladding mode evanescent wave leaks, producing the microsphere sensing region. By injecting light into the coaxial dual-waveguide middle core alone, the sensor can realize single-stage sensing in the microsphere sensing area;it can also realize dual-channel sensing in the D-type sensing area and microsphere sensing area by injecting light into the ring core. The refractive index measurement ranges for the two channels are 1.333–1.365 and 1.375–1.405, respectively, with detection sensitivities of 981.56 nm/RIU and 4138 nm/RIU. The sensor combines wavelength division multiplexing and space division multiplexing technologies, presenting a novel research concept for multi-channel fiber SPR sensors. 展开更多
关键词 coaxial dual-waveguide optical fiber D structure optical fiber microsphere structure dual-channel fiber-optic surface plasmon resonance(SPR)sensor
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All-Fiber Liquid-Level Sensor Based on In-Line MSM Fiber Structure 被引量:1
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作者 Tingting Sun Zigeng Liu +3 位作者 Yun Liu Yang Zhang Zhenguo Jing Wei Peng 《Photonic Sensors》 SCIE EI CSCD 2021年第3期291-297,共7页
We propose and demonstrate an all-fiber liquid-level sensor using an in-line multimode-single-mode-multimode (MSM) fiber structure. A piece of single-mode fiber (SMF) is spliced to two sections of equivalent multimode... We propose and demonstrate an all-fiber liquid-level sensor using an in-line multimode-single-mode-multimode (MSM) fiber structure. A piece of single-mode fiber (SMF) is spliced to two sections of equivalent multimode fiber (MMF) which are used as both mode splitter and mode coupler. The cladding mode will be excited when the light propagates from MMF to SMF, and then it will be combined with fundamental mode to form a Mach-Zehnder interferometer (MZI) when the light propagates from SMF to the other MMF. The liquid level is detected by the selected resonant dips shift of the transmission spectrum. A sensing sensitivity of 264.6 pm/mm is achieved for the proposed sensor with an SMF length of 26mm. Due to its compact structure, easy fabrication, and high sensitivity, the proposed liquid-level sensor is attractive for practical applications in a variety of fields, such as marine detection and chemical processing. 展开更多
关键词 Liquid-level sensor MSM fiber structure MZI optical fiber sensor
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SMS Fiber Structure for Temperature Measurement Using an OTDR 被引量:1
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作者 A. M. HATTA K. INDRIAWATI +2 位作者 T. BESTARIYAN T. HUMADA SEKARTEDJO 《Photonic Sensors》 SCIE EI CAS 2013年第3期262-266,共5页
A singlemode-multimode-singlemode (SMS) fiber structure for temperature measurement using an optical time domain reflectometer (OTDR)-based interrogation system is proposed. A temperature measurement range of 40 ... A singlemode-multimode-singlemode (SMS) fiber structure for temperature measurement using an optical time domain reflectometer (OTDR)-based interrogation system is proposed. A temperature measurement range of 40 ℃-195 ℃ with a resolution of 0.12 ℃ and a linearity of 0.992 could be achieved for the multimode fiber (MMF) graded index with a length of 60mm. It was also demonstrated that two-point temperature measurement with two SMS fiber structures as temperature sensors could be made. The proposed temperature measurement system offered a high resolution and also benefited from a simple configuration with a capability of multi-point temperature measurement. 展开更多
关键词 Temperature sensor SMS fiber structure OTDR
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Modal interferometer based on tapering single-mode-multimode-single-mode fiber structure by hydrogen flame 被引量:1
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作者 张英 邹卫文 +3 位作者 李新碗 毛经纬 姜文宁 陈建平 《Chinese Optics Letters》 SCIE EI CAS CSCD 2012年第7期34-36,共3页
A modal interferometer is experimentally demonstrated based on tapering a single-mode-multimode-single- mode (SMS) fiber structure heated by hydrogen flame. The interference fringe begins to form when tapering lengt... A modal interferometer is experimentally demonstrated based on tapering a single-mode-multimode-single- mode (SMS) fiber structure heated by hydrogen flame. The interference fringe begins to form when tapering length is 19.8 mm, and becomes regular and clear when the tapering length is longer and the tapered waist diameter is smaller. Annealing process is undertaken to achieve a high extension ratio of approximately 17 dB with free spectral range of 1.5 nm when the tapering length is 33 mm and the tapered waist diameter is approximately 5 μm. The temperature and axial strain dependences of the tapered SMS structure are characterized, and the measured temperature and strain coefficients are +7 pm/℃ and -9.536 pm/με, respectively. 展开更多
关键词 mode Modal interferometer based on tapering single-mode-multimode-single-mode fiber structure by hydrogen flame SMS
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Fabrication and Electromechanical Characteristics of 2×2 Torsion-Mirror Optical Switch Arrays with Monolithically Integrated Fiber Self-Holding Structures
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作者 吴文刚 郝一龙 +2 位作者 栗大超 张培玉 武国英 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2002年第10期1024-1030,共7页
Novel 2×2 torsion-mirror optical switch arrays are fabricated by using the mixed micromachining based on the surface and bulk silicon microelectronics,then are investigated electromechanically in applied direct a... Novel 2×2 torsion-mirror optical switch arrays are fabricated by using the mixed micromachining based on the surface and bulk silicon microelectronics,then are investigated electromechanically in applied direct and alternating electric fields.When the thickness of the elastic torsion beams suspending the aluminum coated polysilicon micro-mirrors of the switches in the arrays is about 1μm,the electrostatic yielding voltages for driving the mirrors to achieve their ON-state are in the range of 270~290V,and the minimum holding voltages for mirrors ON-state are found as 55V or so.Theoretical analysis manifests that the yielding voltage is more sensitive to beam thickness than other design parameters do about the torsion-mirror switch structures.The lifetime can reach 10 8 times.The estimated shortest switching time of the switches at least lasts for less than 2ms.The force analysis on the two kinds of new fiber self-holding structures integrated monolithically in the chip of the optical switch arrays indicates that the structures can feature self-fixing and self-aligning of optical fibers. 展开更多
关键词 MEMS optical switch torsion-mirror fiber self-holding structures mixed micromachining
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Simultaneous measurement of axial strain and temperature based on twisted fiber structure
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作者 Xinyue Jiang Ping Lu +4 位作者 Yuan Sun Hao Liao Deming Liu Ziangshan Zhang Hui Liao 《Chinese Optics Letters》 SCIE EI CAS CSCD 2018年第4期20-24,共5页
In this Letter, an alternative solution is proposed and demonstrated for simultaneous measurement of axial strain and temperature. This sensor consists of two twisted points on a commercial single mode fiber introduce... In this Letter, an alternative solution is proposed and demonstrated for simultaneous measurement of axial strain and temperature. This sensor consists of two twisted points on a commercial single mode fiber introduced by flame-heated and rotation treatment. The fabrication process modifies the geometrical configuration and refractive index of the fiber. Different cladding modes are excited at the first twisted point, and part of them are coupled back to the fiber core at the second twisted point. Experimental results show distinct sensitivities of 34.9 pm/με with 49.23 pm/℃ and -36.19 pm/με with 62.99 pm/℃ for the two selected destructive interference wavelengths. 展开更多
关键词 length Simultaneous measurement of axial strain and temperature based on twisted fiber structure
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Radio Fiber Fine Structure During the Solar Flare on July 14, 2000
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作者 钟晓春 王蜀娟 《Journal of Southwest Jiaotong University(English Edition)》 2004年第1期42-45,共4页
On July 14, 2000, a type IV solar radio burst was observed at 10:43-11:00 UT with the 1-2 GHz digital spectrometer of National Astronomical Observatories of China (NAOC). Many fiber fine structures superposed on the t... On July 14, 2000, a type IV solar radio burst was observed at 10:43-11:00 UT with the 1-2 GHz digital spectrometer of National Astronomical Observatories of China (NAOC). Many fiber fine structures superposed on the type IV burst were detected in the same interval. A theoretical interpretation for the fibers is performed based upon a model of magnetic-mirror loop configuration in the solar corona. In this model, the source of the fiber emission is considered as the ducting of whistler solitons within the magnetic-mirror loop. A quantitative estimation using the observed data indicats that the magnetic field strength of the radio source is about 1.451×10 -2≤B 0≤2.734×10 -2 T, and that a fiber is composed of 4×10 15 solitons occupying a volume of about 1.2×108 km3. For the duct through which the whistler solitons passed within the magnetic-mirror loop, its diameter and the length are worked out, namely, d≈120 km and Δr≈104 km, respectively. 展开更多
关键词 Solar flare Radio burst fiber structures
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Study on the Structure and Properties of Polynosic Fiber Treated by Alkali
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作者 魏孟媛 薛文良 程隆棣 《Journal of Donghua University(English Edition)》 EI CAS 2007年第3期419-423,共5页
The regenerated cellulose fibers, made from wood pulp, have excellent physical properties like cotton fiber. Especially polynosic fibers can be mercerized by alkali, but conventional Viscose fiber can not be treated o... The regenerated cellulose fibers, made from wood pulp, have excellent physical properties like cotton fiber. Especially polynosic fibers can be mercerized by alkali, but conventional Viscose fiber can not be treated or mercerized by alkali. The paper studies on behavior of polynosic fibers treated by alkali, including physical properties, such as weight loss, tensile strength and elongation, and fiber structures properties. In this paper, on the basis of study on polynosic fibers treated by alkali, the conclusions were drawn as following. Firstly, polynosic fiber is good at alkali resistance. Secondly, the changes of fiber structure and physical properties begin declining at 5 wt% NaOH concentration and reverse changes take place at 10 wt%. 展开更多
关键词 regenerated cellulose fiber ~ Alkali treatmentphysical properties fiber structure
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Concurrent multi-scale design optimization of composite frame structures using the Heaviside penalization of discrete material model 被引量:6
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作者 Jun Yan Zunyi Duan +1 位作者 Erik Lund Guozhong Zhao 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2016年第3期430-441,共12页
This paper deals with the concurrent multi-scale optimization design of frame structure composed of glass or carbon fiber reinforced polymer laminates. In the composite frame structure, the fiber winding angle at the ... This paper deals with the concurrent multi-scale optimization design of frame structure composed of glass or carbon fiber reinforced polymer laminates. In the composite frame structure, the fiber winding angle at the micro-material scale and the geometrical parameter of components of the frame in the macro-structural scale are introduced as the independent variables on the two geometrical scales. Considering manufacturing requirements, discrete fiber winding angles are specified for the micro design variable. The improved Heaviside penalization discrete material optimization interpolation scheme has been applied to achieve the discrete optimization design of the fiber winding angle. An optimization model based on the minimum structural compliance and the specified fiber material volume constraint has been established. The sensitivity information about the two geometrical scales design variables are also deduced considering the characteristics of discrete fiber winding angles. The optimization results of the fiber winding angle or the macro structural topology on the two single geometrical scales, together with the concurrent two-scale optimization, is separately studied and compared in the paper. Numerical examples in the paper show that the concurrent multi-scale optimization can further explore the coupling effect between the macro-structure and micro-material of the composite to achieve an ultralight design of the composite frame structure. The novel two geometrical scales optimization model provides a new opportunity for the design of composite structure in aerospace and other industries. 展开更多
关键词 Composite frame structure Multi-scale optimization Topology optimization fiber winding angle Structural compliance
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Progressive collapse resisting capacity of reinforced concrete load bearing wall structures 被引量:1
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作者 Alireza Rahai Alireza Shahin Farzad Hatami 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第7期2730-2738,共9页
Reinforced concrete(RC) load bearing wall is widely used in high-rise and mid-rise buildings. Due to the number of walls in plan and reduction in lateral force portion, this system is not only stronger against earthqu... Reinforced concrete(RC) load bearing wall is widely used in high-rise and mid-rise buildings. Due to the number of walls in plan and reduction in lateral force portion, this system is not only stronger against earthquakes, but also more economical. The effect of progressive collapse caused by removal of load bearing elements, in various positions in plan and stories of the RC load bearing wall system was evaluated by nonlinear dynamic and static analyses. For this purpose, three-dimensional model of 10-story structure was selected. The analysis results indicated stability, strength and stiffness of the RC load-bearing wall system against progressive collapse. It was observed that the most critical condition for removal of load bearing walls was the instantaneous removal of the surrounding walls located at the corners of the building where the sections of the load bearing elements were changed. In this case, the maximum vertical displacement was limited to 6.3 mm and the structure failed after applying the load of 10 times the axial load bored by removed elements. Comparison between the results of the nonlinear dynamic and static analyses demonstrated that the "load factor" parameter was a reasonable criterion to evaluate the progressive collapse potential of the structure. 展开更多
关键词 reinforced concrete(RC) load bearing wall structure progressive collapse fiber sections nonlinear analysis load factor method
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Pullout of the Cylindrical Helicoidal Fiber 被引量:1
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作者 Chenhan Hu Weihao Tao +2 位作者 Hongjun Yu Qinghua Qin Jianshan Wang 《Acta Mechanica Solida Sinica》 SCIE EI CSCD 2024年第3期444-456,共13页
The multi-layer cylindrical helicoidal fiber structure(MCHFS)exists widely in biological materials such as bone and wood at the microscale.MCHFSs typically function as reinforcing elements to enhance the toughness of ... The multi-layer cylindrical helicoidal fiber structure(MCHFS)exists widely in biological materials such as bone and wood at the microscale.MCHFSs typically function as reinforcing elements to enhance the toughness of materials.In this study,we establish a shear lag-based pullout model of the cylindrical helicoidal fiber(CHF)for investigating interlayer stress transfer and debonding behaviors,with implications regarding the underlying toughening mechanism of MCHFS.Based on the shear lag assumptions,analytical solutions for the stress and displacement fields of the MCHFS during the pullout are derived by considering the CHF as a cylindrically monoclinic material and verified through the 3D finite element simulation.It is found that the helical winding of CHF results in both axial and hoop interlayer shear stresses.Both the helical winding angle and the elastic moduli of the fiber and matrix have significant influences on interlayer stress transfer.This work reveals a new interlayer stress transfer mechanism in the MCHFS existing widely in biological materials. 展开更多
关键词 Cylindrical helicoidal fiber structure Cylindrically monoclinic material Helical winding of fiber PULLOUT Interlayer stress transfer
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Heterogeneous fiberous structured Mg-Zn-Zr alloy with superior strength-ductility synergy 被引量:4
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作者 Wei Fu Pengfei Dang +4 位作者 Shengwu Guo Zijun Ren Daqing Fang Xiangdong Ding Jun Sun 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2023年第3期67-80,共14页
Here we reported a heterogeneous fiberous structured Mg-5.6Zn-0.6Zr(wt%)alloy obtained by conventional extrusion method,which exhibited high yield strength of∼345 MPa,ultimate tensile strength of∼370 MPa,and high te... Here we reported a heterogeneous fiberous structured Mg-5.6Zn-0.6Zr(wt%)alloy obtained by conventional extrusion method,which exhibited high yield strength of∼345 MPa,ultimate tensile strength of∼370 MPa,and high tensile strain of∼20.5%,superior to most of the Mg-Zn based alloys reported so far.The extraordinarily high mechanical properties were mainly attributed to the heterogeneous fiberous structure consisting of alternating coarse-and fine-grain layers.Grains in the different layers grew into the neighboring layers,ensuring a good layer bonding.A high Schmid factor and geometric compatibility factor for pyramidal slip led to full slip transfer between the neighboring coarse grains and fine grains,which could help to release the stress concentration and avoid early fracture.The profuse acti-vated<c+a>glide dislocations could render the unprecedented high tensile strain.The constraint by the hard fine-grain domains made the soft coarse-grain domains strong like the hard fine-grain domains,as well as the nanoscale precipitates pinning dislocations,contributed to the high strength.The hetero-geneous microstructure design was shown to have synergistic improvement in strength-ductility balance,which could be an inspiring strategy to improve mechanical properties of hexagonal close-packed(hcp)metals. 展开更多
关键词 ZK60 Mg alloy Heterogeneous fiberous structure High strength-ductility synergy Pyramidal dislocations Bimodal grain sizes
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Long-Range Displacement Sensor Based on SMS Fiber Structure and OTDR 被引量:5
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作者 A. ARIFIN A. M. HATTA +2 位作者 SEKARTEDJO M. S. MUNTINI A. RUBIYANTO 《Photonic Sensors》 SCIE EI CAS CSCD 2015年第2期166-171,共6页
This paper presents a long-range displacement measurement method by using a single- multi-single mode (SMS) fiber structure, attached to a flexible plate between two permanent poles and the optical time domain refle... This paper presents a long-range displacement measurement method by using a single- multi-single mode (SMS) fiber structure, attached to a flexible plate between two permanent poles and the optical time domain reflectometer (OTDR)-based interrogator. The SMS fiber structure sensors are prepared with two different configurations, i.e. straight and sinusoidal configurations. It is demonstrated that the displacement sensor can perform a displacement measurement with a range from 0 mm to 150 mm with a resolution of 0.159 mm. The sinusoidal configuration provides a better sensitivity than the straight configuration. The proposed sensor offers a low cost, and it can be implemented for quasi-distributed displacement measurement which is suitable for civil structure monitoring. 展开更多
关键词 Displacement sensor SMS fiber structure OTDR
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Density Functional Based Tight Binding (DFTB) Study on the Thermal Evolution of Amorphous Carbon
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作者 Chung-Kiak Poh Han-Ping D. Shieh 《Graphene》 2016年第2期51-54,共4页
Density functional based tight binding (DFTB) model is employed to study the sp3-to-sp2 transformation of diamond-like carbon at elevated temperatures. The understanding could lead to the direct-growth of graphene on ... Density functional based tight binding (DFTB) model is employed to study the sp3-to-sp2 transformation of diamond-like carbon at elevated temperatures. The understanding could lead to the direct-growth of graphene on a wide variety of substrates. 展开更多
关键词 Diamond-Like Carbon GRAPHENE DFTB fiber structure CLUSTER Molecular Dynamics
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A Numerical Study of Densification Behavior of Silicon Carbide Matrix Composites in Isothermal Chemical Vapor Infiltration 被引量:2
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作者 GUAN Kang WU Jianqing CHENG Laifei 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2018年第6期1365-1371,共7页
We studied the characteristics of two-scale pore structure of preform in the deposition process and the mass transfer of reactant gas in dual-scale pores, and observed the physiochemical phenomenon associated with the... We studied the characteristics of two-scale pore structure of preform in the deposition process and the mass transfer of reactant gas in dual-scale pores, and observed the physiochemical phenomenon associated with the reaction. Thereby, we established mathematical models on two scales, respectively, preform and reactor. These models were used for the numerical simulation of the process of ceramic matrix composites densified by isothermal chemical vapor infiltration(ICVI). The models were used to carry out a systematic study on the influence of process conditions and the preform structure on the densification behaviors. The most important findings of our study are that the processing time could be reduced by about 50% without compromising the quality of the material, if the processing temperature is 950-1 000 ℃ for the first 70 hours and then raised to 1 100 ℃. 展开更多
关键词 isothermal chemical vapor infiltration ceramic matrix composites process parameters fiber preform structure densification behavior
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Case studies of high-sensitivity monitoring of natural and engineered slopes 被引量:2
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作者 Werner Lienhart 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2015年第4期379-384,共6页
High-sensitivity monitoring solutions are crucial for early warning systems of earth structures. In this paper, we discuss the design and implementation of such systems for natural and engineered slopes using two case... High-sensitivity monitoring solutions are crucial for early warning systems of earth structures. In this paper, we discuss the design and implementation of such systems for natural and engineered slopes using two case studies. At the Gradenbach Observatory, one key element of the monitoring system is a large fiber optic strain rosette embedded in the slope. We demonstrate that the strain rosette can depict landslide deformations much earlier than geodetic sensors like GPS or total stations and is therefore well suitable for an early warning system. In a second application we report the construction of a reinforced earth structure using geogrids. A distributed fiber optic measurement system was installed to measure the current operating grade of the geogrids within the earth structure. About 2 km of Brillouin sensing cables were installed in the project area. It is demonstrated that the developed monitoring system is well suited for assessing the current state of health of reinforced earth structures. 展开更多
关键词 Structural health monitoring fiber optic sensors Brillouin optical frequency domain analyzer(BOFDA) SOFO sensors Reinforced eart
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Grating Writing in Structured Optical Fibers
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作者 John CANNING Nathaniel GROOTHOFF +4 位作者 Kevin COOK Michael STEVENSON John HOLDSWORTH Matthieu LANCRY Bertrand POUMELLEC 《Photonic Sensors》 SCIE EI CAS 2011年第3期199-203,共5页
Grating writing in structured optical fibers is reviewed. Various laser sources have been used including UV and near IR nanosecond and femtosecond lasers, each enabling different material processing regimes. The issue... Grating writing in structured optical fibers is reviewed. Various laser sources have been used including UV and near IR nanosecond and femtosecond lasers, each enabling different material processing regimes. The issue of scattering is modeled through simulation and compared with experiment. Good agreement has been established. 展开更多
关键词 GRATINGS structured optical fibers Fresnel fibers photonic crystal fibers microstructured optical fibers sensors
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Self-supported copper-based gas diffusion electrodes improve the local CO_(2)concentration for efficient electrochemical CO_(2)reduction
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作者 Azeem Mustafa Bachirou Guene Lougou +6 位作者 Yong Shuai Zhijiang Wang Haseeb-ur-Rehman Samia Razzaq Wei Wang Ruming Pan Jiupeng Zhao 《Frontiers of Chemical Science and Engineering》 SCIE EI CSCD 2024年第3期51-62,共12页
Electrochemical CO_(2)reduction is a sustainable approach in green chemistry that enables the production of valuable chemicals and fuels while mitigating the environmental impact associated with CO_(2)emissions.Despit... Electrochemical CO_(2)reduction is a sustainable approach in green chemistry that enables the production of valuable chemicals and fuels while mitigating the environmental impact associated with CO_(2)emissions.Despite its several advantages,this technology suffers from an intrinsically low CO_(2)solubility in aqueous solutions,resulting in a lower local CO_(2)concentration near the electrode,which yields lower current densities and restricts product selectivity.Gas diffusion electrodes(GDEs),particularly those with tubular architectures,can solve these issues by increasing the local CO_(2)concentration and triple-phase interface,providing abundant electroactive sites to achieve superior reaction rates.In this study,robust and self-supported Cu flow-through gas diffusion electrodes(FTGDEs)were synthesized for efficient formate production via electrochemical CO_(2)reduction.They were further compared with traditional Cu electrodes,and it was found that higher local CO_(2)concentration due to improved mass transfer,the abundant surface area available for the generation of the triple-phase interface,and the porous structure of Cu FTGDEs enabled high formate Faradaic efficiency(76%)and current density(265 mA¸cm^(−2))at–0.9 V vs.reversible hydrogen electrode(RHE)in 0.5 mol·L^(−1)KHCO3.The combined phase inversion and calcination process of the Cu FTGDEs helped maintain a stable operation for several hours.The catalytic performance of the Cu FTGDEs was further investigated in a non-gas diffusion configuration to demonstrate the impact of local gas concentration on the activity and performance of electrochemical CO_(2)reduction.This study demonstrates the potential of flow-through gas-diffusion electrodes to enhance reaction kinetics for the highly efficient and selective reduction of CO_(2),offering promising applications in sustainable electrochemical processes. 展开更多
关键词 CO_(2)electroreduction flow-through delivery hollow fiber structure local concentration FORMATE
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Enhanced zinc storage performance of mixed valent manganese oxide for flexible coaxial fiber zinc-ion battery by limited reduction control 被引量:3
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作者 Xiaobei Zang Li Lingtong +4 位作者 Jiaxin Meng Lijia Liu Yuanyuan Pan Qingguo Shao Ning Cao 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2021年第15期52-59,共8页
While manganese-based cathodes have been intensively studied for zinc-ion batteries(ZIBs),the limited rate capability and cycle life have always been a difficult problem to be solved.Here,we report a mixed valent mang... While manganese-based cathodes have been intensively studied for zinc-ion batteries(ZIBs),the limited rate capability and cycle life have always been a difficult problem to be solved.Here,we report a mixed valent manganese oxide(MnOx)cathode with superior electrochemical performance,which exhibits a high specific capacity of 450 mA h/g at 0.2 C and a satisfactory specific capacity of 158.3 mA h/g at a high rate of 5 C.The mixed cathode system reduces the charge transfer resistance,and show good surface stability and adsorption properties,so it is beneficial for the storage of Zn^(2+).Meanwhile,coaxial fiber ZIBs(CFZIBs)with splendid flexibility are assembled utilizing the elaborately prepared cathode material.The CFZIBs achieve a reversible capacity of 255.8 m A h/g and the capacity retention rate is as high as 80%after 1000 bending deformations.This study provides new opportunities for designing ZIBs with high performance and high flexibility. 展开更多
关键词 Mixed valent manganese oxide Limited reduction Storage mechanism Flexible zinc-ion battery Coaxial fiber structure
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