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A Comparative Overview of Indirect Field Oriented Control (IFOC) and Deadbeat-Direct Torque and Flux Control (DB-DTFC) for AC Motor Drives 被引量:2
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作者 Yukai Wang Yuying Shi +1 位作者 Yang Xu Robert D.Lorenz 《Chinese Journal of Electrical Engineering》 2015年第1期9-20,共12页
Indirect field oriented control(IFOC)has become a widely adopted solution for AC motor drives.Standard IFOC controls torque and rotor flux linkage via q-and d-axis current.Alternatively,deadbeat-direct torque and flux... Indirect field oriented control(IFOC)has become a widely adopted solution for AC motor drives.Standard IFOC controls torque and rotor flux linkage via q-and d-axis current.Alternatively,deadbeat-direct torque and flux control(DB-DTFC)has emerged as a promising motor control strategy for the future,which manipulates Volt-sec.vector directly.Air-gap torque and stator flux linkage are decoupled and independently controlled over each switching period.Stator flux linkage is used as a separated degree-of-freedom to manipulate losses dynamically without compromising torque dynamics and torque ripple.In voltage-limited operations,direct selection of Volt-sec.allows DB-DTFC to fully utilize the dc bus voltage and produce fast torque.A single control law is used over a wide speed range.This paper aims to provide a comparative overview of the two motor controls regarding their sensitivity to parameters,current-and voltage-limited operation,loss manipulation,and torque ripple during signal injection.Based on the comparison,the ultimate objective is to demonstrate the opportunities and remaining challenges in DB-DTFC. 展开更多
关键词 Deadbeat-direct torque and flux control field oriented control parameter sensitivity voltage-limited operation loss manipulation torque ripple
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Fingerprint singular points extraction based on orientation tensor field and Laurent series 被引量:3
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作者 刘琴 彭可 +4 位作者 刘巍 谢琴 李仲阳 兰浩 金耀 《Journal of Central South University》 SCIE EI CAS 2014年第5期1927-1934,共8页
Singular point(SP)extraction is a key component in automatic fingerprint identification system(AFIS).A new method was proposed for fingerprint singular points extraction,based on orientation tensor field and Laurent s... Singular point(SP)extraction is a key component in automatic fingerprint identification system(AFIS).A new method was proposed for fingerprint singular points extraction,based on orientation tensor field and Laurent series.First,fingerprint orientation flow field was obtained,using the gradient of fingerprint image.With these gradients,fingerprint orientation tensor field was calculated.Then,candidate SPs were detected by the cross-correlation energy in multi-scale Gaussian space.The energy was calculated between fingerprint orientation tensor field and Laurent polynomial model.As a global descriptor,the Laurent polynomial coefficients were allowed for rotational invariance.Furthermore,a support vector machine(SVM)classifier was trained to remove spurious SPs,using cross-correlation coefficient as a feature vector.Finally,experiments were performed on Singular Point Detection Competition 2010(SPD2010)database.Compared to the winner algorithm of SPD2010 which has best accuracy of 31.90%,the accuracy of proposed algorithm is 45.34%.The results show that the proposed method outperforms the state-of-the-art detection algorithms by large margin,and the detection is invariant to rotational transformations. 展开更多
关键词 fingerprint extraction singular point fingerprint orientation tensor field Laurent series rotational invariance supportvector machine (SVM)
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Fingerprint Matching Based on Local Relative Orientation Field 被引量:1
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作者 ZHUEn YINJian-ping ZHANGGuo-min 《Wuhan University Journal of Natural Sciences》 EI CAS 2004年第4期435-438,共4页
A fingerprint matching method based on local relative orientation field is proposed. It extracts local relative orientation field around each minutia for minutiae matching. Local orientation features are also used to ... A fingerprint matching method based on local relative orientation field is proposed. It extracts local relative orientation field around each minutia for minutiae matching. Local orientation features are also used to sorting minutiae in order to speed up searching a minutia when pairing minutiae. The experimental result reveals that this method achieves improved recognition accuracy. Key words fingerprint matching - ridge-based minutiae matching - local relative orientation field - sorting minutiae CLC number TP 391 Foundation item: Supported by the National Natural Science Foundation of China (60373023)Biography: ZHU En (1976-), male, Ph. D candidate, research direction: pattern recognition, image processing and information security. 展开更多
关键词 fingerprint matching ridge-based minutiae matching local relative orientation field sorting minutiae
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DEPENDENCE OF MAGNETISM OF Nd-Fe-B SINTERMAGNETS ON ORIENTATION MAGNETIC FIELD
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作者 GAO Ruwei, XIAO MingshanShandong University, Jinan, ChinaZHOU Shouzeng, LIFubiao, ZHANG LidongNational Laboratory, University of Science and Technology Beijing, China Manuscript received 11 April, 1994 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1994年第2期100-102,共3页
The effect of the orientation magnetic field on the permanent magnetism of Nd-Fe-B sintermagnets is investigated. The results show that the variation law of magnetism with orientation field obviously changes at the cr... The effect of the orientation magnetic field on the permanent magnetism of Nd-Fe-B sintermagnets is investigated. The results show that the variation law of magnetism with orientation field obviously changes at the critical orientation field and the intensity of the orientation field should he determined by the dimension ratio of the magnet for effectively utilizing its magnetic energy product. 展开更多
关键词 orientation magnetic field REMANENCE COERCIVITY maximum magnetic energy product
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Driving and Braking Control of PM Synchronous Motor Based on Low-resolution Hall Sensor for Battery Electric Vehicle 被引量:14
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作者 GU Jing OUYANG Minggao +3 位作者 LI Jianqiu LU Dongbin FANG Chuan MA Yan 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2013年第1期1-10,共10页
Resolvers are normally employed for rotor positioning in motors for electric vehicles, but resolvers are expensive and vulnerable to vibrations. Hall sensors have the advantages of low cost and high reliability, but t... Resolvers are normally employed for rotor positioning in motors for electric vehicles, but resolvers are expensive and vulnerable to vibrations. Hall sensors have the advantages of low cost and high reliability, but the positioning accuracy is low. Motors with Hall sensors are typically controlled by six-step commutation algorithm, which brings high torque ripple. This paper studies the high-performance driving and braking control of the in-wheel permanent magnetic synchronous motor (PMSM) based on low-resolution Hall sensors. Field oriented control (FOC) based on Hall-effect sensors is developed to reduce the torque ripple. The positioning accuracy of the Hall sensors is improved by interpolation between two consecutive Hall signals using the estimated motor speed. The position error from the misalignment of the Hall sensors is compensated by the precise calibration of Hall transition timing. The braking control algorithms based on six-step commutation and FOC are studied. Two variants of the six-step commutation braking control, namely, half-bridge commutation and full-bridge commutation, are discussed and compared, which shows that the full-bridge commutation could better explore the potential of the back electro-motive forces (EMF), thus can deliver higher efficiency and smaller current ripple. The FOC braking is analyzed with the phasor diagrams. At a given motor speed, the motor turns from the regenerative braking mode into the plug braking mode if the braking torque exceeds a certain limit, which is proportional to the motor speed. Tests in the dynamometer show that a smooth control could be realized by FOC driving control and the highest efficiency and the smallest current ripple could be achieved by FOC braking control, compared to six-step commutation braking control. Therefore, FOC braking is selected as the braking control algorithm for electric vehicles. The proposed research ensures a good motor control performance while maintaining low cost and high reliability. 展开更多
关键词 battery electric vehicle field oriented control low-resolution Hall sensor regenerative braking plug braking six-step commutation braking
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Genetic algorithm tuned PI controller on PMSM simplified vector control 被引量:11
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作者 WIBOWO Wahyu Kunto JEONG Seok-kwon 《Journal of Central South University》 SCIE EI CAS 2013年第11期3042-3048,共7页
A simple control structure in servo system is occasionally needed for simple industrial application which precise and high control performance is not exessively important so that the cost production can be reduced eff... A simple control structure in servo system is occasionally needed for simple industrial application which precise and high control performance is not exessively important so that the cost production can be reduced efficiently. Simplified vector control, which has simple control structure, is utilized as the permanent magnet synchronous motor control algorithm and genetic algorithm is used to tune three PI controllers used in simplified vector control. The control performance is obtained from simulation and investigated to verify the feasibility of the algorithm to be applied in the real application. Simulation results show that the speed and torque responses of the system in both continuous time and discrete time can achieve good performances. Furthermore, simplified vector control combined with genetic algorithm has a similar perfofmance with conventional field oriented control algorithm and possible to be realized into the real simple application in the future. 展开更多
关键词 simplified vector control conventional field oriented control permanent magnet synchronous motor genetic algorithm PI controller
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PSO Based Controlled Six-phase Grid Connected Induction Generator for Wind Energy Generation 被引量:7
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作者 Arif Iqbal Girish Kumar Singh 《CES Transactions on Electrical Machines and Systems》 CSCD 2021年第1期41-49,共9页
This paper deals a detailed performance investigation of asymmetrical six-phase grid connected induction generator(GCIG)in two proposed configurations in variable speed operation.During the system development,regulati... This paper deals a detailed performance investigation of asymmetrical six-phase grid connected induction generator(GCIG)in two proposed configurations in variable speed operation.During the system development,regulation of DC-link voltage has been proposed using particle swarm optimization(PSO)based PI controller,ensuring the power flow to utility grid through back to back converters.The closed loop operation of asymmetrical six-phase GCIG using indirect field oriented control in different configurations has been carried out in Matlab/Simulink environment.Analytical results have been verified using real time test results on virtual platform of Typhoon HIL supported with some experimental validation. 展开更多
关键词 Six-phase induction generator particle swarm optimization(PSO) indirect field oriented control
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Torque-based Optimal Acceleration Control for Electric Vehicle 被引量:1
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作者 LU Dongbin OUYANG Minggao 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2014年第2期319-330,共12页
The existing research of the acceleration control mainly focuses on an optimization of the velocity trajectory with respect to a criterion formulation that weights acceleration time and fuel consumption. The minimum-f... The existing research of the acceleration control mainly focuses on an optimization of the velocity trajectory with respect to a criterion formulation that weights acceleration time and fuel consumption. The minimum-fuel acceleration problem in conventional vehicle has been solved by Pontryagin's maximum principle and dynamic programming algorithm, respectively. The acceleration control with minimum energy consumption for battery electric vehicle(EV) has not been reported. In this paper, the permanent magnet synchronous motor(PMSM) is controlled by the field oriented control(FOC) method and the electric drive system for the EV(including the PMSM, the inverter and the battery) is modeled to favor over a detailed consumption map. The analytical algorithm is proposed to analyze the optimal acceleration control and the optimal torque versus speed curve in the acceleration process is obtained. Considering the acceleration time, a penalty function is introduced to realize a fast vehicle speed tracking. The optimal acceleration control is also addressed with dynamic programming(DP). This method can solve the optimal acceleration problem with precise time constraint, but it consumes a large amount of computation time. The EV used in simulation and experiment is a four-wheel hub motor drive electric vehicle. The simulation and experimental results show that the required battery energy has little difference between the acceleration control solved by analytical algorithm and that solved by DP, and is greatly reduced comparing with the constant pedal opening acceleration. The proposed analytical and DP algorithms can minimize the energy consumption in EV's acceleration process and the analytical algorithm is easy to be implemented in real-time control. 展开更多
关键词 permanent magnet synchronous motor(PMSM) field oriented control(FOC) efficiency model electric vehicle energy optimal acceleration
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Continuous on-line adaptation of the rotor time constant in FOC induction machine system
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作者 齐昕 Ma Xianghua +1 位作者 Wang Changsong Xi Anmin 《High Technology Letters》 EI CAS 2013年第3期254-260,共7页
Rotor time constant is an important parameter for the indirect lleld oraentateO control of mauc- tion motor. Incorrect rotor tittle constant value will cause the flux observer generating a wrong angu- lar orientation ... Rotor time constant is an important parameter for the indirect lleld oraentateO control of mauc- tion motor. Incorrect rotor tittle constant value will cause the flux observer generating a wrong angu- lar orientation of the rotor field. A new approach serves for rotor time constant on-line adaptation by setting the stator current to be zero for a short period. A smooth eorrector is designed to prevent ab- normal detection result from making adaptation. Impact of zero current duration on detection error and rotor speed is analyzed by experiments. 展开更多
关键词 rotor time constant field oriented control (FOC) on-line adaptation inductionmotor
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Enhancement of ion transport in porous media by the use of a continuously reoriented electric field
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作者 Juan ALMEIRA Chang-sheng PENG Ahmed ABOU-SHADY 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2012年第7期546-558,共13页
Electromigration in porous media is enhanced by a new type of electrokinetic processing. Compared with a single -oriented electric field, a continuously reoriented electric field was proven to sharply enhance mass tra... Electromigration in porous media is enhanced by a new type of electrokinetic processing. Compared with a single -oriented electric field, a continuously reoriented electric field was proven to sharply enhance mass transport of several heavy metals in kaolin. The initial concentration of the metals was: Cd: 250 mg/kg; Cu: 250 mg/kg; Ni: 250 mg/kg; Zn: 900 mg/kg. Electric field reorientation was obtained by the use of a fixed anode and a cathode that rotated at different frequencies (0, 0.25, 1.00, 1.25, 2.00, 5.00 and 10.00 r/m). Mass transport evidently increased from 0 r/m to 1.25 r/m, and then decreased as the rotation speed reached 10 r/m. From 0 r/m to 1.25 r/m, mass transport increased 2.87 times for Cd, 3.17 times for Cu, 2.11 times for Ni, and 4.13 times for Zn. We suggest that continuous reorientation of the electric field facilitates the advance of ions through kaolin pores, minimizing the retardation effect caused by media tortuosity. 展开更多
关键词 ELECTROMIGRATION Heavy metals KAOLIN Electric field orientation TORTUOSITY Rotating electrodes
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Compensation of Dead-Time Effect of Speed Sensorless Vector Control System
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作者 夏超英 张靖 《Transactions of Tianjin University》 EI CAS 2011年第5期351-355,共5页
The key of speed sensorless vector control system lies in the accurate orientation of magnetic field. In some field-oriented algorithms, the integrator of observers and the dead-time effect bring in system errors duri... The key of speed sensorless vector control system lies in the accurate orientation of magnetic field. In some field-oriented algorithms, the integrator of observers and the dead-time effect bring in system errors during the estimation of field position. In this paper, a saturated feedback integrator is used, and the dead-time effect is compen- sated by current positive feedback. Experiments were carried out on the hardware platform of MCK2407, with chip TMS320LF2407 from TI Company. The results show that the prooosed method is simole and effective, and the accuracy of field position is improved. 展开更多
关键词 induction motor speed sensorless vector control DSP COMPENSATION DEAD-TIME field orientation
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Relation of the Coercivity with the Grain Alignment Degree in Nd-Fe-B Sintermagnets
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作者 高汝伟 章亚明 +4 位作者 李华 姜寿亭 周寿增 李佛标 张黎东 《Journal of Rare Earths》 SCIE EI CAS CSCD 1994年第4期264-267,共4页
The experimental results show that the coercivity of Nd-Fe-B sintermagnet decreases with increasing of the grain alignment degree of the magnets (i.e. decreasing of the orientation distribution coefficient σ).The coe... The experimental results show that the coercivity of Nd-Fe-B sintermagnet decreases with increasing of the grain alignment degree of the magnets (i.e. decreasing of the orientation distribution coefficient σ).The coercivities of the magnets with different orientation degree are calculated based on the pinning,nucleation and starting field theory,respectively.The comparison of the calculated values with the experimental results shows that the theoretical results are deviating from the experiments seriously for both pinning mechanism and nucleation mechanism. In contrast with that,the calculated values based on the starting field theory are in good agreement with the experimental results. 展开更多
关键词 Orientation magnetic field Grain alignment degree Normalized coercivity Starting field Expanding field
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Starting Control of Free Piston Stirling Linear Generator System Based on FOC
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作者 Qiaoling Yang Kechun Zhang +2 位作者 Shenghui Guo Boliang Song Xiaoyu Zhang 《CES Transactions on Electrical Machines and Systems》 CSCD 2022年第2期195-200,共6页
Aiming at the problem of poor system dynamic performance caused by low parameter matching in the coordinated control of Stirling engine and linear generator in the starting stage control of free piston Stirling linear... Aiming at the problem of poor system dynamic performance caused by low parameter matching in the coordinated control of Stirling engine and linear generator in the starting stage control of free piston Stirling linear generator system,a joint control method of free piston Stirling permanent magnet synchronous linear generator system based on field orientation control is proposed,based on the theoretical derivation of the mathematical model of the system and the principle of controller parameters setting,the simulation experiments of the system starting stage under several Stirling engine working conditions are carried out under simulation.The experimental results show that the stability and rapidity of the system are improved,and the dynamic response speed of generator parameters under different working conditions is accelerated,what fully verifies the correctness and effectiveness of the method.It provides an effective way to improve the control performance of the system and stabilize the power generation operation. 展开更多
关键词 Parameter setting field orientation control Double closed loop Permanent magnet synchronous linear generator
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Orientation Field Guided Texture Synthesis 被引量:2
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作者 刘蓓蓓 翁彦琳 +1 位作者 王建南 童一颖 《Journal of Computer Science & Technology》 SCIE EI CSCD 2013年第5期827-835,共9页
We present a framework for example-based texture synthesis with feature directions aligned to vector fields with 2-way rotational symmetry, also known as orientation fields. Through a simple variational formulation, t... We present a framework for example-based texture synthesis with feature directions aligned to vector fields with 2-way rotational symmetry, also known as orientation fields. Through a simple variational formulation, the framework allows the user to design the orientation field with intuitive controls, by interactively manipulating singularities and field directions. The resulting field is then used to guide a parallel synthesis. Our contribution is twofold: a design tool for orientation fields with a natural boundary condition, and a parallel texture synthesis adapted specifically for using such fields in feature alignment. We demonstrate the advantages of the procedure through examples on planar and curved patches with trivial topology. 展开更多
关键词 orientation field natural boundary condition texture synthesis
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Investigating Magnetic Field Orientation as an Operational Parameter in Thermoelectric MHD Solidification
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作者 A.Kao K.Pericleous 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2012年第S1期260-264,共5页
A fully coupled 3-dimensional numerical model is used to analyse the effect of magnetic field orientation on dendritic growth.For materials that exhibit a significant thermoelectric power,the results show significant ... A fully coupled 3-dimensional numerical model is used to analyse the effect of magnetic field orientation on dendritic growth.For materials that exhibit a significant thermoelectric power,the results show significant differences in the dendritic morphology for different orientations of the field.These variations can be attributed to fluid flow generated through Thermoelectric Magnetohydrodynamics.A simplified,steady-state,low-field solution during the early stages of growth is used to describe how the fluid flow alters with the orientation of the field and how these flow features can lead to the final morphologies for well developed dendrites. 展开更多
关键词 thermoelectric MHD magnetic field orientation dendritic growth
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Robust Sliding Mode Control Using Adaptive Switching Gain for Induction Motors 被引量:5
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作者 K. Jamoussi L. Chrifi-Alaoui +2 位作者 H. Benderradji A. El Hajjaji M. Ouali 《International Journal of Automation and computing》 EI CSCD 2013年第4期303-311,共9页
A robust sliding mode approach combined with a field oriented control (FOC) for induction motor (IM) speed control is presented. The proposed sliding mode control (SMC) design uses an adaptive switching gain and... A robust sliding mode approach combined with a field oriented control (FOC) for induction motor (IM) speed control is presented. The proposed sliding mode control (SMC) design uses an adaptive switching gain and an integrator. This approach guarantees the same robustness and dynamic performance of traditional SMC algorithms. And at the same time, it attenuates the chattering phenomenon, which is the main drawback in actual implementation of this technique. This approach is insensitive to uncertainties and permits to decrease the requirement for the bound of these uncertainties. The stability and robustness of the closed- loop system are proven analytically using the Lyapunov synthesis approach. The proposed method attenuates the effect of both uncertainties and external disturbances. Experimental results are presented to validate the effectiveness and the good performance of the developed method. 展开更多
关键词 Sliding mode control field oriented control (FOC) practical validation switching gain induction motor.
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Overview of Advanced Control Strategies for Electric Machines 被引量:6
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作者 Chunhua Liu Yixiao Luo 《Chinese Journal of Electrical Engineering》 CSCD 2017年第2期53-61,共9页
Control strategies play a key role for operation of electric machines,which would directly affect the whole system performance.In fact,different control strategies have been executed and explored for electric machines... Control strategies play a key role for operation of electric machines,which would directly affect the whole system performance.In fact,different control strategies have been executed and explored for electric machines,which bring great impacts to industrial development and human society.This paper investigates and discusses the advantages control strategies for electric machines,including the field oriented control(FOC),direct torque control(DTC),finite control set model predictive control(FCS-MPC),sensorless control,and fault tolerant control(FTC).The corresponding control principles,control targets,fundamental approaches,advanced approaches,methodologies,merits and shortcomings are revealed and analyzed in detail. 展开更多
关键词 Electric machine permanent-magnet(PM)machine AC machine control strategy advanced control field oriented control(FOC) direct torque control(DTC) finite control set model predictive control(FCS-MPC) sensorless control and fault tolerant control(FTC)
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Overview of Model Predictive Control for Induction Motor Drives 被引量:7
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作者 Yongchang Zhang Bo Xia +1 位作者 Haitao Yang Jose Rodriguez 《Chinese Journal of Electrical Engineering》 2016年第1期62-76,共15页
Model predictive control(MPC)has attracted widespread attention in both academic and industry communities due to its merits of intuitive concept,quick dynamic response,multi-variable control,ability to handle various ... Model predictive control(MPC)has attracted widespread attention in both academic and industry communities due to its merits of intuitive concept,quick dynamic response,multi-variable control,ability to handle various nonlinear constraints,and so on.It is considered a powerful alternative to field oriented control(FOC)and direct torque control(DTC)in high performance AC motor drives.Compared to FOC,MPC eliminates the use of internal current control loops and modulation block,hence featuring very quick dynamic response.Compared to DTC,MPC uses a cost function rather than a heuristic switching table to select the best voltage vector,producing better steady state performance.In spite of the merits above,MPC also presents some drawbacks such as high computational burden,nontrivial weighting factor tuning,high sampling frequency,variable switching frequency,model/parameter dependence and relatively high steady ripples in torque and stator flux.This paper presents the state of the art of MPC in high performance induction motor(IM)drives,and in particular the progress on solving the drawbacks of conventional MPC.Finally,one of the improved MPC is compared to FOC to validate its superiority.It is shown that the improved MPC has great potential in the future high performance AC motor drives. 展开更多
关键词 Model predictive control(MPC) field oriented control(FOC) direct torque control(DTC) induction motor(IM).
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Classical state feedback controller for nonlinear systems using mean value theorem: closed Ioop-FOC of PMSM motor application
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作者 Abrar ALLAG Abdelhamid BENAKCHA +2 位作者 Meriem ALLAG Ismail ZEIN Mohamed Yacine AYAD 《Frontiers in Energy》 SCIE CSCD 2015年第4期413-425,共13页
The problem of state feedback controllers for a class of Takagi-Sugeno (T-S) Lipschitz nonlinear systems is investigated. A simple systematic and useful synthesis method is proposed based on the use of the different... The problem of state feedback controllers for a class of Takagi-Sugeno (T-S) Lipschitz nonlinear systems is investigated. A simple systematic and useful synthesis method is proposed based on the use of the differential mean value theorem (DMVT) and convex theory. The proposed design approach is based on the mean value theorem (MVT) to express the nonlinear error dynamics as a convex combination of known matrices with time varying coefficients as linear parameter varying (LPV) systems. Using the Lyapunov theory, stability conditions are obtained and expressed in terms of linear matrix inequalities (LMIs). The controller gains are then obtained by solving linear matrix inequalities. The effectiveness of the proposed approach for closed loop-field oriented control (CL-FOC) of permanent magnet synchronous machine (PMSM) drives is demonstrated through an illustrative simulation for the proof of these approaches. Furthermore, an extension for controller design with parameter uncertainties and perturbation performance is discussed. 展开更多
关键词 Takagi-Sugeno (T-S) fuzzy systems sectornonlinearity nonlinear controller linear matrix inequality(LMI) approach differential mean value theorem (DMVT) field oriented control (FOC) linear parameter varying(LPV)
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Organic ligand mediated evolution from superalkalis to superatomic molecules and nanowires 被引量:1
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作者 Jun Li Haicai Huang +2 位作者 Jing Chen Yuxiang Bu Shibo Cheng 《Nano Research》 SCIE EI CSCD 2022年第2期1162-1170,共9页
Superatoms are considered as promising building blocks for customizing superatomic molecules and cluster-assembly nanomaterials due to their tunable electronic structures and functionalities.Electron counting rules,wh... Superatoms are considered as promising building blocks for customizing superatomic molecules and cluster-assembly nanomaterials due to their tunable electronic structures and functionalities.Electron counting rules,which mainly adjust the shell-filling of clusters,are classical strategies in designing superatoms.Here,by employing the density functional theory(DFT)calculations,we proved that the 1,4-phenylene diisocyanide(CNC_(6)H_(4)NC)ligand could dramatically reduce the adiabatic ionization potentials(AlPs)of the aluminum-based clusters,which have 39,40,and 41 valence electrons,respectively,to give rise to superalkali species without changing their shell-filling.Moreover,the rigid structure of the ligand can be used as a bridge firmly linking the same or different aluminum-based clusters to form superatomic molecules and nanowires.In particular,the bridging process was observed to enhance their nonlinear optical(NLO)responses,which can be further promoted by the oriented external electric field(OEEF).Also,the stable cluster-assembly XAl_(12)(CNC_(6)H_(4)NC)(X=Al,C,and P)nanowires were constructed,which exhibit strong absorption in the visible light region.These findings not only suggest an effective ligand-field strategy in superatom design but also unveil the geometrical and electronic evolution from the CNC_(6)H_(4)NC-based superatoms to superatomic molecules and nanomaterials. 展开更多
关键词 superatom-assembly nanomaterial density functional theory(DFT)calculation superatom networks superatomic molecule ligand-field strategy oriented external electric field
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