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Study of the spatial growth of stimulated Brillouin scattering in a gas-filled hohlraum via detecting the driven ion acoustic wave
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作者 Chaoxin Chen Tao Gong +12 位作者 Zhichao Li Liang Hao Yonggang Liu Xiangming Liu Hang Zhao Yaoyuan Liu Kaiqiang Pan Qi Li Sanwei Li Zhijun Li Sai Jin Feng Wang Dong Yang 《Matter and Radiation at Extremes》 SCIE EI CSCD 2024年第2期36-49,共14页
In an experiment performed on the Shenguang-III prototype laser facility, collective Thomson scattering (TS) is used to study the spatialgrowth of stimulated Brillouin scattering (SBS) in a gas-filled hohlraum by dete... In an experiment performed on the Shenguang-III prototype laser facility, collective Thomson scattering (TS) is used to study the spatialgrowth of stimulated Brillouin scattering (SBS) in a gas-filled hohlraum by detecting the SBS-driven ion acoustic wave. High-quality timeresolved SBS and TS spectra are obtained simultaneously in the experiment, and these are analyzed by a steady-state code based on theray-tracing model. The analysis indicates that ion–ion collisions may play an important role in suppressing SBS growth in the Au plasma;as aresult, the SBS excited in the filled gas region is dominant. In the early phase of the laser pulse, SBS originates primarily from the high-densityplasma at the edges of the interaction beam channel, which is piled up by the heating of the interaction beam. Throughout the duration of thelaser pulse, the presence of the TS probe beam might mitigate SBS by perturbing the density distribution around the region overlapping withthe interaction beam. 展开更多
关键词 SCATTERING filled BRILLOUIN
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Synthetic polymers:A review of applications in drilling fluids
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作者 Shadfar Davoodi Mohammed Al-Shargabi +2 位作者 David A.Wood Valeriy S.Rukavishnikov Konstantin M.Minaev 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期475-518,共44页
With the growth of deep drilling and the complexity of the well profile,the requirements for a more complete and efficient exploitation of productive formations increase,which increases the risk of various complicatio... With the growth of deep drilling and the complexity of the well profile,the requirements for a more complete and efficient exploitation of productive formations increase,which increases the risk of various complications.Currently,reagents based on modified natural polymers(which are naturally occurring compounds)and synthetic polymers(SPs)which are polymeric compounds created industrially,are widely used to prevent emerging complications in the drilling process.However,compared to modified natural polymers,SPs form a family of high-molecular-weight compounds that are fully synthesized by undergoing chemical polymerization reactions.SPs provide substantial flexibility in their design.Moreover,their size and chemical composition can be adjusted to provide properties for nearly all the functional objectives of drilling fluids.They can be classified based on chemical ingredients,type of reaction,and their responses to heating.However,some of SPs,due to their structural characteristics,have a high cost,a poor temperature and salt resistance in drilling fluids,and degradation begins when the temperature reaches 130℃.These drawbacks prevent SP use in some medium and deep wells.Thus,this review addresses the historical development,the characteristics,manufacturing methods,classification,and the applications of SPs in drilling fluids.The contributions of SPs as additives to drilling fluids to enhance rheology,filtrate generation,carrying of cuttings,fluid lubricity,and clay/shale stability are explained in detail.The mechanisms,impacts,and advances achieved when SPs are added to drilling fluids are also described.The typical challenges encountered by SPs when deployed in drilling fluids and their advantages and drawbacks are also discussed.Economic issues also impact the applications of SPs in drilling fluids.Consequently,the cost of the most relevant SPs,and the monomers used in their synthesis,are assessed.Environmental impacts of SPs when deployed in drilling fluids,and their manufacturing processes are identified,together with advances in SP-treatment methods aimed at reducing those impacts.Recommendations for required future research addressing SP property and performance gaps are provided. 展开更多
关键词 Synthetic versus natural polymers Nanopolymers Drilling fluid additives LUBRICITY Clay swelling Hole cleaning
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High-performance and robust high-temperature polymer electrolyte membranes with moderate microphase separation by implementation of terphenyl-based polymers
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作者 Jinyuan Li Congrong Yang +3 位作者 Haojiang Lin Jicai Huang Suli Wang Gongquan Sun 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期572-578,共7页
Acid loss and plasticization of phosphoric acid(PA)-doped high-temperature polymer electrolyte membranes(HT-PEMs)are critical limitations to their practical application in fuel cells.To overcome these barriers,poly(te... Acid loss and plasticization of phosphoric acid(PA)-doped high-temperature polymer electrolyte membranes(HT-PEMs)are critical limitations to their practical application in fuel cells.To overcome these barriers,poly(terphenyl piperidinium)s constructed from the m-and p-isomers of terphenyl were synthesized to regulate the microstructure of the membrane.Highly rigid p-terphenyl units prompt the formation of moderate PA aggregates,where the ion-pair interaction between piperidinium and biphosphate is reinforced,leading to a reduction in the plasticizing effect.As a result,there are trade-offs between the proton conductivity,mechanical strength,and PA retention of the membranes with varied m/p-isomer ratios.The designed PA-doped PTP-20m membrane exhibits superior ionic conductivity,good mechanical strength,and excellent PA retention over a wide range of temperature(80–160°C)as well as satisfactory resistance to harsh accelerated aging tests.As a result,the membrane presents a desirable combination of performance(1.462 W cm^(-2) under the H_(2)/O_(2)condition,which is 1.5 times higher than that of PBI-based membrane)and durability(300 h at 160°C and 0.2 A cm^(-2))in the fuel cell.The results of this study provide new insights that will guide molecular design from the perspective of microstructure to improve the performance and robustness of HT-PEMs. 展开更多
关键词 Fuel cell High-temperature polymer electrolyte membranes Microphase separation Poly(terphenyl piperidinium)s Phosphoric acid
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Ignition processes and characteristics of charring conductive polymers with a cavity geometry in precombustion chamber for applications in micro/nano satellite hybrid rocket motors
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作者 Zhiyuan Zhang Hanyu Deng +2 位作者 Wenhe Liao Bin Yu Zai Yu 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第2期55-66,共12页
The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of... The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of micro/nano satellite.However,charring polymers alone need a relatively high input voltage to achieve pyrolysis and ignition,which increases the burden and cost of the power system of micro/nano satellite in practical application.Adding conductive substance into charring polymers can effectively decrease the conducting voltage which can realize low voltage and low power consumption repeated ignition of arc ignition system.In this paper,a charring conductive polymer ignition grain with a cavity geometry in precombustion chamber,which is composed of PLA and multiwall carbon nanotubes(MWCNT)was proposed.The detailed ignition processes were analyzed and two different ignition mechanisms in the cavity of charring conductive polymers were revealed.The ignition characteristics of charring conductive polymers were also investigated at different input voltages,ignition grain structures,ignition locations and injection schemes in a visual ignition combustor.The results demonstrated that the ignition delay and external energy required for ignition were inversely correlated with the voltages applied to ignition grain.Moreover,the incremental depth of cavity shortened the ignition delay and external energy required for ignition while accelerated the propagation of flame.As the depth of cavity increased from 2 to 6 mm(at 50 V),the time of flame propagating out of ignition grain changed from 235.6 to 108 ms,and values of mean ignition delay time and mean external energy required for ignition decreased from 462.8 to 320 ms and 16.2 to 10.75 J,respectively.The rear side of the cavity was the ideal ignition position which had a shorter ignition delay and a faster flame propagation speed in comparison to other ignition positions.Compared to direct injection scheme,swirling injection provided a more favorable flow field environment in the cavity,which was beneficial to ignition and initial flame propagation,but the ignition position needed to be away from the outlet of swirling injector.At last,the repeated ignition characteristic of charring conductive polymers was also investigated.The ignition delay time and external energy required for ignition decreased with repeated ignition times but the variation was decreasing gradually. 展开更多
关键词 Micro/nano satellite hybrid propulsion Arc ignition Charring conductive polymer Ignition mechanism Ignition characteristic Repeated ignition
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The Conversion of Non-Dispersed Polymers into Low-Potassium Anti-Collapse Drilling Fluids
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作者 Hao Hu Jian Guan +2 位作者 Shanfa Tang Jialuo Rong Yuanpeng Cheng 《Fluid Dynamics & Materials Processing》 EI 2024年第2期325-335,共11页
Different drillingfluid systems are designed according to mineral composition,lithology and wellbore stability of different strata.In the present study,the conversion of a non-dispersed polymer drillingfluid into a low ... Different drillingfluid systems are designed according to mineral composition,lithology and wellbore stability of different strata.In the present study,the conversion of a non-dispersed polymer drillingfluid into a low potas-sium anti-collapsing drillingfluid is investigated.Since the two drillingfluids belong to completely different types,the key to this conversion is represented by new inhibitors,dispersants and water-loss agents by which a non-dispersed drillingfluid can be turned into a dispersed drillingfluid while ensuring wellbore stability and reason-able rheology(carrying sand—inhibiting cuttings dispersion).In particular,the(QYZ-1)inhibitors and(FSJSS-2)dispersants are used.The former can inhibit the hydration expansion capacity of clay,reduce the dynamic shear force and weaken the viscosity;the latter can improve the sealing effect and reduce thefiltrate loss.The results have shown that after adding a reasonable proportion of these substances(QYZ-1:FSJSS-2)to the non-dispersed polymer drillingfluid,while the apparent viscosity,plastic viscosity,structural viscosity andfluidity index under-went almost negligible changes,the dynamic plastic ratio increased,and thefiltration loss decreased significantly,thereby indicating good compatibility.According to the tests(conducted in the Leijia area),the density was 1.293 g/cm3,and after standing for 24 h,the SF(static settlement factor)was 0.51.Moreover,thefiltration loss was reduced to 4.0 mL,the rolling recovery rate reached 96.92%,with excellent plugging and anti-collapse performances. 展开更多
关键词 Non-dispersed polymer drilling fluid low potassium anti-collapsing drilling fluid drilling fluid conversion drilling fluid reuse filter vector
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Metal organic polymers with dual catalytic sites for oxygen reduction and oxygen evolution reactions 被引量:1
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作者 Sijia Liu Minghao Liu +4 位作者 Xuewen Li Shuai Yang Qiyang Miao Qing Xu Gaofeng Zeng 《Carbon Energy》 SCIE CSCD 2023年第5期127-137,共11页
Metal-organic frameworks and covalent organic frameworks have been widely employed in electrochemical catalysis owing to their designable skeletons,controllable porosities,and well-defined catalytic centers.However,th... Metal-organic frameworks and covalent organic frameworks have been widely employed in electrochemical catalysis owing to their designable skeletons,controllable porosities,and well-defined catalytic centers.However,the poor chemical stability and low electron conductivity limited their activity,and single-functional sites in these frameworks hindered them to show multifunctional roles in catalytic systems.Herein,we have constructed novel metal organic polymers(Co-HAT-CN and Ni-HAT-CN)with dual catalytic centers(metal-N_(4) and metal-N_(2))to catalyze oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).By using different metal centers,the catalytic activity and selectivity were well-tuned.Among them,Co-HAT-CN catalyzed the ORR in a 4e^(-)pathway,with a half-wave potential of 0.8 V versus RHE,while the Ni-HAT-CN catalyze ORR in a 2e^(-)pathway with H_(2)O_(2) selectivity over 90%.Moreover,the Co-HAT-CN delivered an overpotential of 350 mV at 10 mA cm^(-2) with a corresponding Tafel slope of 24 mV dec^(-1) for OER in a 1.0 M KOH aqueous solution.The experimental results revealed that the activities toward ORR were due to the M-N_(4) sites in the frameworks,and both M-N_(4) and M-N_(2) sites contributed to the OER.This work gives us a new platform to construct bifunctional catalysts. 展开更多
关键词 covalent organic frameworks metal organic polymers oxygen evolution reaction oxygen reduction reaction single atom catalysts
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Assembly of N-and P-functionalized carbon nanostructures derived from precursor-defined ternary copolymers for high-capacity lithiumion batteries
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作者 Luyao Guo Mengru Wang +6 位作者 Ronghe Lin Jiaxin Ma Shuanghao Zheng Xiaoling Mou Jun Zhang Zhong-Shuai Wu Yunjie Ding 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第1期280-288,共9页
Synthesis of new carbon nanostructures with tunable properties is vital for precisely regulating electrochemical performance in the wide applications.Herein,we report a novel approach for the oxidative polymerization ... Synthesis of new carbon nanostructures with tunable properties is vital for precisely regulating electrochemical performance in the wide applications.Herein,we report a novel approach for the oxidative polymerization of N-and P-bearing copolymers from the self-assembly of three different monomers(aniline,pyrrole,and phytic acid),and further prepare the respective carbon nanostructures with relatively consistent N dopant(6.2%–8.0%,atom)and varying P concentrations(0.4%–2.8%,atom)via controllable pyrolysis.The impacts of phytic acid addition on the compositional,structural,and morphological evolution of the copolymers and the resulting nanocarbons are well studied through a spectrum of characterizations including N2 sorption,Fourier transform infrared spectroscopy,gel permeation chromatograph,scanning/transmission electron microscopy,and X-ray photoelectron spectroscopy.Gradual fragmentation of the nanosphere structures is evidenced with increasing addition of phytic acid,leading to different nanostructures from hollow nanospheres to 3D aggregates.Nanocarbons decorated with N and P dopants from pyrolysis are further utilized as anode materials in lithium-ion batteries,demonstrating enhanced electrochemical performance,i.e.,a reversible capacity of 380 mAhg^(-1)at 2 Ag^(-1)for NPC-0.5 during 200 cycles.The superior performance originates from the balanced porosity,and appropriate concentrations of P and pyrrolic N,thus pointing the direction for designing high-performance anode materials. 展开更多
关键词 Carbon nanospheres Doping Lithium-ion batteries polymers Porosity
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Synthesis of Sustainable Sulfur-Rich Copolymers as Mercury Sorbents at 130℃ Using Tung Oil as an Activator
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作者 Lyu Ya Zhang Sai 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2023年第3期60-70,共11页
Sulfur-rich copolymers made through inverse vulcanization exhibit a wide range of potentially valuable applications, for example as adsorbents to capture mercury pollution. Among the diverse second monomers of the cop... Sulfur-rich copolymers made through inverse vulcanization exhibit a wide range of potentially valuable applications, for example as adsorbents to capture mercury pollution. Among the diverse second monomers of the copolymers, vegetable oil is a renewable resource, and recycled cooking oils have an important role in saving natural products. However, they need relatively high temperatures(160–180 ℃) to react with sulfur. To develop a low-temperature(130 ℃) reaction process for non-conjugated vegetable oil, we incorporate a small amount of tung oil, which contains conjugated trienes that can produce highly active free radicals during reactions. A variety of analytical techniques(proton nuclear magnetic resonance and Fourier-transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis, X-ray diffraction, and dynamic mechanical analysis) are used to characterize the chemical structures and physical properties of the copolymers. The addition of tung oil is found to significantly improve the thermal stability and mechanical properties of the copolymers. We also investigate the effect of different ratios of raw materials on the gel time, free sulfur content, glass transition temperature T_(g), and degradation temperature of the copolymers. We find that increasing the amount of tung oil in the raw material mixture decreases the gel time and free sulfur content, but increases T_(g) and the degradation temperature. The copolymers exhibit a high adsorption capacity for mercury ions up to 33 mg Hg^(2+) per gram of adsorbent. These results demonstrate the feasibility of using sulfur-rich copolymers as effective mercury removal adsorbents, with the potential for further improvement by foaming the copolymers into porous materials. 展开更多
关键词 SULFUR vegetable oil polymer MERCURY reaction mechanism
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Experimental and Numerical Analysis of Oil-Water Flow with Drag Reducing Polymers in Horizontal Pipes
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作者 Amer A.Abdulrahman Bashar J.Kadhim +6 位作者 Zainab Y.Shnain Hassan Sh.Majidi Asawer A.Alwaiti Farooq Al-Sheikh Adnan A.AbdulRazak Mohammed Shorbaz Mazin J.Shibeeb 《Fluid Dynamics & Materials Processing》 EI 2023年第10期2579-2595,共17页
The well-known frictional effect related to liquid-liquid two-phaseflow in pipelines can be reduced using drag-reducing additives.In this study,such an effect has been investigated experimentally using a mixture of oil... The well-known frictional effect related to liquid-liquid two-phaseflow in pipelines can be reduced using drag-reducing additives.In this study,such an effect has been investigated experimentally using a mixture of oil and water.Moreover,numerical simulations have been carried out using the COMSOL simulation software.The mea-surements were taken in a horizontal pipe with the length and diameter equal to 3 and 0.125 m,respectively.Moreover,Polyethylene oxide with 150 ppm was exploited to reduce the drag effect while considering different water-to-oil fractions(0.3,0.4,0.5,and 0.7)and a constant totalflow velocity of 2.3 m/s.As made evident by the results,a significant reduction can be obtained in terms of pressure drop,which becomes even more significant as the water to oil fraction is increased.The maximum achieved drag reduction is 70%with a water fraction of 0.7.The results also show that the addition of polymer additives can also have an impact on theflow pattern.Com-parison of experimental and numerically determined pressure drop indicates that the error is smaller than 7%. 展开更多
关键词 Two-phase flow drag reduction POLYMER COMSOL
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Encapsulation of lipases on coordination polymers and their catalytic performance in glycerolysis and esterification
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作者 Can Zeng Nanjing Zhong 《Grain & Oil Science and Technology》 CAS 2023年第3期113-119,共7页
In this study,lipases of CALB(Candida antarctica lipase B),TLL(Thermomyces lanuginosa lipase),RML(Rhizomucor miehei lipase),CALA(Candida antarctica lipase A)and LU(Lecitase?Ultra)were encapsulated into the nucleotideh... In this study,lipases of CALB(Candida antarctica lipase B),TLL(Thermomyces lanuginosa lipase),RML(Rhizomucor miehei lipase),CALA(Candida antarctica lipase A)and LU(Lecitase?Ultra)were encapsulated into the nucleotidehybrid metal coordination polymers(CPs)for diacylglyerols(DAG)preparation.Guanosine 5'-monophosphate(GMP)and adenosine 5'-monophosphate(AMP)were used as coordinating molecules,and metal ions of Fe^(3+),Ba^(2+),Mn^(2+),Ni^(2+)and Cr^(3+)were applied to prepare matrix.Results indicated that,besides Ba^(2+)with AMP,all other metal ions can coordinate with AMP and GMP to generate CPs.In addition,the AMP/Ni was amorphous when standing temperature was 4℃,while it was crystalline when standing temperature was from 30 to 180℃.DAG content from 47.55%to 64.99%was obtained from glycerolysis by CALB@GMP/Ba,RML@GMP/Ba,TLL@GMP/Ba,RML@GMP/Mn and TLL@GMP/Mn.Additionally,CALB@GMP/Fe showed selectivity towards DAG formation in the esterification and DAG content up to 61.88%was obtained. 展开更多
关键词 LIPASE Coordination polymers ENCAPSULATION GLYCEROLYSIS ESTERIFICATION
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Hydrophobic Small-Molecule Polymers as High-Temperature-Resistant Inhibitors in Water-Based Drilling Fluids
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作者 Xuyang Yao Kecheng Liu +5 位作者 Zenan Zhou Jun Zhou Xianbin Huang Tiemei Lu Yongsheng Yu He Li 《Fluid Dynamics & Materials Processing》 EI 2023年第7期1775-1787,共13页
Water-based drilling fluids can cause hydration of the wellbore rocks,thereby leading to instability.This study aimed to synthesize a hydrophobic small-molecule polymer(HLMP)as an inhibitor to suppress mud shale hydra... Water-based drilling fluids can cause hydration of the wellbore rocks,thereby leading to instability.This study aimed to synthesize a hydrophobic small-molecule polymer(HLMP)as an inhibitor to suppress mud shale hydration.An infrared spectral method and a thermogravimetric technique were used to characterize the chemical composition of the HLMP and evaluate its heat stability.Experiments were conducted to measure the linear swelling,rolling recovery rate,and bentonite inhibition rate and evaluate accordingly the inhibition performance of the HLMP.Moreover,the HLMP was characterized through measurements of the zeta potential,particle size distribution,contact angles,and interlayer space testing.As confirmed by the results,the HLMP could successfully be synthesized with a favorable heat stability.Furthermore,favorable results were found for the inhibitory processes of the HLMP on swelling and dispersed hydration during mud shale hydration.The positively charged HLMP could be electrically neutralized with clay particles,thereby inhibiting diffusion in the double electron clay layers.The hydrophobic group in the HLMP molecular structure resulted in the formation of a hydrophobic membrane on the rock surface,enhancing the hydrophobicity of the rock.In addition,the small molecules of the HLMP could plug the spaces between the layers of bentonite crystals,thereby reducing the entry of water molecules and inhibiting shale hydration. 展开更多
关键词 Water-based drilling fluids hydrophobic polymers shale inhibitor temperature resistance
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A Comparative Investigation of the Biodegradation Behaviour of Linseed Oil-Based Cross-Linked Composites Filled with Industrial Waste Materials in Two Different Soils
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作者 Eglė Malachovskienė Danguolė Bridžiuvienė +2 位作者 Jolita Ostrauskaitė Justina Vaičekauskaitė Gailė Žalūdienė 《Journal of Renewable Materials》 SCIE EI 2023年第3期1254-1268,共15页
The biodegradation of polymeric biocomposites formed from epoxidized linseed oil and various types of fillers(pine needles,pine bark,grain mill waste,rapeseed cake)and a control sample without filler was studied durin... The biodegradation of polymeric biocomposites formed from epoxidized linseed oil and various types of fillers(pine needles,pine bark,grain mill waste,rapeseed cake)and a control sample without filler was studied during 180 days of exposure to two types of forest soil:deciduous and coniferous.The weight loss,morphological,and structural changes of polymer composites were noticed after 180 days of the soil burial test.The greatest weight loss of all tested samples was observed in coniferous forest soil(41.8%–63.2%),while in deciduous forest soil,it ranged between 37.7%and 42.3%.The most significant changes in the intensities of the signals evaluated by attenuated total reflectance infrared spectroscopy,as well as morphological changes determined by scanning electron microscopy,were assessed for polymer composite with rapeseed cake and specimen without filler in coniferous forest soil and are in a good agreement with weight loss results.Whereas significantly lower changes in weight loss,morphology,and structure of polymeric film with pine bark were noticed in both soils.It was suggested that fungi of Trichoderma,Penicillium,Talaromyces and Clonostachys genera are the possible soil microorganisms that degrade linseed oil-based cross-linked polymer composites.Moreover,the novel polymer composites have the potential to be an environmentally friendly alternative to petroleum-based mulching films. 展开更多
关键词 Polymer composites linseed oil industrial waste materials BIODEGRADATION soil burial
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Synthesis of energetic coordination polymers based on 4-nitropyrazole by solid-melt crystallization in non-ionization condition
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作者 Ting-wei Wang Shu Bu +4 位作者 Kun Wang Lu Zhang Zhen-xin Yi Shun-guan Zhu Jian-guo Zhang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2023年第10期13-22,共10页
Based on the theory of crystallization,a solvent-free solid-liquid phase crystallization method called solid-melt crystallization was designed to prepare energetic coordination polymers.Two target compounds[Cu(NPyz)_(... Based on the theory of crystallization,a solvent-free solid-liquid phase crystallization method called solid-melt crystallization was designed to prepare energetic coordination polymers.Two target compounds[Cu(NPyz)_(4)NO_(3)]·NO_(3)(ECPs-1)and Cu(NPyz)_(4)(ClO_(4))_(2)(ECCs-2)were prepared through programmed heating and cooling by using 4-nitropyrazole(NPyz),(Cu(NO_(3))_(2)·5H_(2)O and Cu(ClO_(4))_(2)·5H_(2)O) as raw materials.In addition,crystallization pre-experiments and annealing experiments also verified the feasibility of the method.Their structures were confirmed by IR,elemental analysis,single-crystal X-ray diffraction and powder X-ray diffraction.The physicochemical properties and sensitivity test results showed that ECCs-2 has better thermal stability(T_(d)=221℃),while ECPs-1 is less sensitive to mechanical stimuli(IS=12 J,FS=240 N).Calculations based on EXPLO5 and the Kamlet-Jacobs equation showed that ECCs-2 has more considerable detonation performance(P=25.2 GPa,D=7.5 km/s).In comparison,the more intuitive results from the HN test,flame test,thermal resistance test and lead plate explosion test revealed that ECCs-2 has an“acceptable”detonation performance.The laser detonation test also showed that ECCs-2 is a promising excellent laser detonation material(E=408 mJ,P=24 W,τ=17 ms). 展开更多
关键词 4-Amino-1 2 5-oxadiazole-3-carbohydrazide Crystallization Coordination polymers Laser Primary explosives
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助力汽车座舱消音降噪,ELIX Polymers推出特殊牌号ABS及PC/ABS
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《塑料工业》 CAS CSCD 北大核心 2023年第7期137-137,共1页
ELIX Polymers公司近期开发了一系列特殊等级的ABS和PC/ABS,以减少汽车座舱内不同塑料零件以及塑料零件与皮革、PVC箔或其他产品接触时产生的杂音。在汽车座舱内部,这些噪音会对驾驶的舒适性以及驾驶员对汽车质量的感知产生负面影响。
关键词 PC/ABS 塑料零件 polymers PVC 消音降噪 座舱
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An investigation on multilayer shape memory polymers under finite bending through nonlinear thermo-visco-hyperelasticity
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作者 A.BAKHTIYARI M.BAGHANI S.SOHRABPOUR 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第1期73-88,共16页
This study presents a semi-analytical solution to describe the behavior of shape memory polymers(SMPs) based on the nonlinear thermo-visco-hyperelasticity which originates from the concepts of internal state variables... This study presents a semi-analytical solution to describe the behavior of shape memory polymers(SMPs) based on the nonlinear thermo-visco-hyperelasticity which originates from the concepts of internal state variables and rational thermodynamics.This method is developed for the finite bending of multilayers in a dual-shape memory effect(SME) cycle.The layer number and layering order are investigated for two different SMPs and a hyperelastic material.In addition to the semi-analytical solution,the finite element simulation is performed to verify the predicted results,where the outcomes demonstrate the excellent accuracy of the proposed solution for predicting the behavior of the multilayer SMPs.Since this method has a much lower computational cost than the finite element method(FEM),it can be used as an effective tool to analyze the SMP behavior under different conditions,including different materials,different geometries,different layer numbers,and different layer arrangements. 展开更多
关键词 smart material shape memory polymer(SMP) semi-analytical solution thermo-visco-hyperelasticity finite strain bending
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High-sensitivity phase imaging eddy current magneto-optical system for carbon fiber reinforced polymers detection
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作者 Jiang-Shan Ai Quan Zhou +5 位作者 Yi-Ping Liang Chun-Rui Feng Bing Long Li-Bing Bai Yong-Gang Wang Chao Ren 《Journal of Electronic Science and Technology》 EI CSCD 2023年第4期48-59,共12页
This paper proposed a high-sensitivity phase imaging eddy current magneto-optical (PI-ECMO) system for carbon fiber reinforced polymer (CFRP) defect detection. In contrast to other eddy current-based detection systems... This paper proposed a high-sensitivity phase imaging eddy current magneto-optical (PI-ECMO) system for carbon fiber reinforced polymer (CFRP) defect detection. In contrast to other eddy current-based detection systems, the proposed system employs a fixed position excitation coil while enabling the detection point to move within the detection region. This configuration effectively mitigates the interference caused by the lift-off effect, which is commonly observed in systems with moving excitation coils. Correspondingly, the relationship between the defect characteristics (orientation and position) and the surface vertical magnetic field distribution (amplitude and phase) is studied in detail by theoretical analysis and numerical simulations. Experiments conducted on woven CFRP plates demonstrate that the designed PI-ECMO system is capable of effectively detecting both surface and internal cracks, as well as impact defects. The excitation current is significantly reduced compared with traditional eddy current magneto-optical (ECMO) systems. 展开更多
关键词 Carbon fiber reinforced polymers Defect detection Eddy current magneto-optical Nondestructive testing Phase imaging
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Experimental and Numerical Studies on Sea Sand Concrete Filled Stainless Steel Tube with Inner FRP Tube Subjected to Axial Compression
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作者 ZENG Lan YU Wen-lan +2 位作者 MO Zi-yong HUANG Shi-qing YUAN Hong 《China Ocean Engineering》 SCIE EI CSCD 2023年第2期272-287,共16页
Since fibre-reinforced polymer(FRP) and stainless steel(SS) offer advantages of corrosion resistance and hybrid confinement, this study proposed a new type of composite column: sea sand concrete(SSC)-filled SS tubular... Since fibre-reinforced polymer(FRP) and stainless steel(SS) offer advantages of corrosion resistance and hybrid confinement, this study proposed a new type of composite column: sea sand concrete(SSC)-filled SS tubular columns with an inner FRP tube(CFSTFs) to help exploit abundant ocean resources in marine engineering. To study compressive behaviours of these novel members, eight CFSTFs and two SSC-filled SS tubular columns(CFSTs)were tested under axial compression. Their axial load-displacement curves, axial load-strain curves in SS or FRP tubes were obtained, and influences of key test parameters(the existence of glass FRP(GFRP) tubes, steel tube shapes, and GFRP tube thicknesses and diameters) were discussed. Further, specimen failure mechanism was analyzed employing the finite element method using ABAQUS software. Test results confirmed the excellent ductility and load-bearing capacity of CFSTFs. The existence of GFRP tubes inside can postpone SS tube buckling, and the content of inner FRP tubes, particularly increasing diameters, was found to improve compressive behaviours. GFRP contents helped develop the second elastic-plastic stage of the load-displacement curves. Furthermore, the bearing capacity of CFSTFs with a circular cross-section was approximately 26% higher than that with a square cross-section, and this difference narrowed with the increase in GFRP ratios. 展开更多
关键词 sea-sand concrete(SSC) confined concrete column fibre-reinforced polymer(FRP)tube stainless steel tube axial compression
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2023年积石山Ms6.2级地震同震地质灾害初步分析 被引量:3
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作者 李为乐 许强 +6 位作者 李雨森 单云锋 韦春豪 巨袁臻 郁文龙 王运生 卢佳燕 《成都理工大学学报(自然科学版)》 CAS CSCD 北大核心 2024年第1期33-45,90,共14页
2023年12月18日,甘肃省临夏回族自治州积石山县发生Ms6.2级地震,触发了大量同震地质灾害,亟需查明同震地质灾害的基本特征、发育分布规律和成因机制,为震后恢复重建与地质灾害防治提供支撑。本文基于多源高分辨率遥感解译和已有研究成... 2023年12月18日,甘肃省临夏回族自治州积石山县发生Ms6.2级地震,触发了大量同震地质灾害,亟需查明同震地质灾害的基本特征、发育分布规律和成因机制,为震后恢复重建与地质灾害防治提供支撑。本文基于多源高分辨率遥感解译和已有研究成果对比分析,初步揭示了此次地震地质灾害的基本特征和发育分布规律,并探讨了草滩村液化滑坡—泥流的成因机制。结果表明:此次地震Ⅶ度及以上烈度区内共发育1 535处同震地质灾害,主要为中小规模黄土滑坡和浅表层岩质崩塌,集中分布于黄土梁和黄土塬内冲沟两侧、单薄黄土梁两侧以及大型历史滑坡后壁等局部地形较陡峭的部位。地震因素控制了同震地质灾害的区域分布规律,而地形因素控制了同震地质灾害的局部分布规律。同震地质灾害在0.1~0.3 g震峰值加速度区域、发震断层下盘区域、南东坡向、30~60 m坡高范围、斜坡中部以上20~40 m范围分布数量最多。受广泛关注的草滩村“砂涌”灾害本质是饱水黄土在地震作用下发生的液化滑坡。2016年完成的填沟造地工程改变了滑源区地表和地下水流通条件,地下水通道被堵塞,导致地下水位抬升和下部土体饱和可能是该处发生液化滑坡的重要原因。 展开更多
关键词 积石山地震 同震地质灾害 分布规律 黄土滑坡 液化滑坡—泥流 填沟造地工程
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煤矿负碳高效充填开采理论与技术构想 被引量:1
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作者 谢和平 张吉雄 +4 位作者 高峰 李百宜 李存宝 谢亚辰 周楠 《煤炭学报》 EI CAS CSCD 北大核心 2024年第1期36-46,共11页
矿山安全高效绿色低碳开采是永恒的主题,近零冲击地压、近零生态损害以及低碳、零碳、负碳的绿色开采将成为保障我国能源安全供应与绿色低碳发展的新要求。充填开采是实现这一要求的必然途径。然而,现有充填开采原理与技术装备体系难以... 矿山安全高效绿色低碳开采是永恒的主题,近零冲击地压、近零生态损害以及低碳、零碳、负碳的绿色开采将成为保障我国能源安全供应与绿色低碳发展的新要求。充填开采是实现这一要求的必然途径。然而,现有充填开采原理与技术装备体系难以突破高产高效、低碳开采的技术瓶颈,对充填材料及充填模式进行变革已势在必行。针对“千米深井资源开发和千万吨产能矿井充填(两个一千)”与“近零生态损害和近零冲击地压(两个近零)”的煤炭绿色低碳开采战略目标,提出了负碳高效充填开采技术全新构想,系统阐述了负碳高效充填开采的定义与科学内涵,提出和建立了由CO_(2)、矸石与快速胶结物混合而成的负碳高孔隙充填材料结构CGIF(CO_(2)Gangue Inorganic Framework)拓扑构型与强度理论以及CGIF混合物充填体固碳理论、快速黏凝胶结材料反应动力学理论、矿区充填开采防治冲击地压等负碳高效充填理论构想;提出了矸石快速高效胶结高孔隙充填材料制备技术、快速黏凝胶结材料绿色高效制备技术、CGIF充填体负碳高效充填开采技术、多面并采高效充填开采技术与工艺、全周期立体高效充填开采防冲技术等关键技术体系。在此基础上,明确了煤矿负碳高效充填开采“基础研究—技术攻关—工程示范”的“三阶段”发展规划,构建了煤矿负碳高效充填开采理论与技术体系构想;评估了煤矿负碳高效充填CO_(2)封存能力,可望实现煤炭负碳开采、低碳利用的煤炭开发利用全过程自身实现碳中和的新格局。 展开更多
关键词 负碳充填 高孔隙材料 CGIF充填体 固碳理论 防冲技术
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瓮马铁路乌江特大桥设计关键技术研究 被引量:1
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作者 王小飞 张杰 +2 位作者 王新国 周继 罗春林 《铁道标准设计》 北大核心 2024年第3期91-98,共8页
新建瓮马铁路乌江特大桥跨越两山之间深谷,地形复杂、设计难度大。为研究该桥梁方案,首先阐述了主桥的方案构思和结构设计,然后通过空间有限元软件对本桥进行静、动力仿真分析,总结了大跨铁路劲性骨架混凝土拱桥构造和受力特性。结果表... 新建瓮马铁路乌江特大桥跨越两山之间深谷,地形复杂、设计难度大。为研究该桥梁方案,首先阐述了主桥的方案构思和结构设计,然后通过空间有限元软件对本桥进行静、动力仿真分析,总结了大跨铁路劲性骨架混凝土拱桥构造和受力特性。结果表明:主跨337 m上承式劲性骨架混凝土拱桥具有刚度大、徐变小、后期养护维修工作量小等优点,主拱圈采用小矢跨比设计,兼顾安全、经济、环保和美观,能够满足铁路桥梁跨越山区“V”形峡谷的要求;主拱圈由劲性钢管混凝土骨架外包C55无收缩混凝土构成,通过分层分段浇筑方案改善拱圈各构件的内力;拱上结合梁采用两片工字形钢与混凝土桥面板相结合的形式,钢梁栓焊结合,便于制造、运输和施工;拱座采用梯形断面扩大基础,基础开挖永临结合,有效降低施工风险;数值分析表明该桥结构的刚度、强度、稳定性均能满足规范要求,能够满足客货共线铁路的安全性和乘坐舒适性要求。可为其他山区铁路桥梁桥式研究提供参考。 展开更多
关键词 山区铁路 铁路桥 钢管混凝土劲性骨架拱桥 数值计算 设计
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