Facile identification of fluorosurfactant category in aqueous film-forming foam concentrates via optimized^(19)F NMR

Aqueous film-forming foams(AFFFs)are the primary source of toxic perfluoroalkyl and polyfluoroalkyl substances(PFAS)in wastewater.Thus,it is urgent to develop a facile and fast method for identifying fluorosurfactants in commercially available AFFFs.In this work,fluorine nuclear magnetic resonance(^(19)F NMR)spectroscopy was optimized to measure AFFFs directly with the extra addition of 5%D_(2)O as the locking reagent,and high-quality spectra could be acquired within 4 min(0.1%fluorosurfactant content).Recovery experiments demonstrated that the use of different AFFFs had no marked influence on the quantitative analysis of fluorosurfactants.Such method works with low-field NMR spectroscopy(1.4 T)as well.Two-dimensional(2D)^(19)F COSY NMR was used to make signal assignments for different fluorosurfactant derivatives.The optimized ^(19)F NMR could quantify the commercially available fluorosurfactants in different AFFFs,identify them being in either the perfluorooctane sulfonate(PFOS)or fluorotelomer sulfonic acid(FTS)categories,and distinguish the head-group of PFOS and FTS derivatives,which exhibits great potentials in the developments of relevant commercial detections.

Accountable capability improvement based on interpretable capability evaluation using belief rule base

A new approach is proposed in this study for accountable capability improvement based on interpretable capability evaluation using the belief rule base(BRB).Firstly,a capability evaluation model is constructed and optimized.Then,the key sub-capabilities are identified by quantitatively calculating the contributions made by each sub-capability to the overall capability.Finally,the overall capability is improved by optimizing the identified key sub-capabilities.The theoretical contributions of the proposed approach are as follows.(i)An interpretable capability evaluation model is constructed by employing BRB which can provide complete access to decision-makers.(ii)Key sub-capabilities are identified according to the quantitative contribution analysis results.(iii)Accountable capability improvement is carried out by only optimizing the identified key sub-capabilities.Case study results show that“Surveillance”,“Positioning”,and“Identification”are identified as key sub-capabilities with a summed contribution of 75.55%in an analytical and deducible fashion based on the interpretable capability evaluation model.As a result,the overall capability is improved by optimizing only the identified key sub-capabilities.The overall capability can be greatly improved from 59.20%to 81.80%with a minimum cost of 397.Furthermore,this paper also investigates how optimizing the BRB with more collected data would affect the evaluation results:only optimizing“Surveillance”and“Positioning”can also improve the overall capability to 81.34%with a cost of 370,which thus validates the efficiency of the proposed approach.

Optical trapping capability of tornado circular Pearcey beams

We systemically investigate optical trapping capability of a kind of tornado waves on Rayleigh particles.Such tornado waves are named as tornado circular Pearcey beams(TCPBs)and produced by combining two circular Pearcey beams with different radii.Our theoretical exploration delves into various aspects,including the propagation dynamics,energy flux,orbital angular momentum,trapping force,and torque characteristics of TCPBs.The results reveal that the orbital angular momentum,trapping force,and torque of these beams can be finely tuned through the judicious manipulation of their topological charges(l_(1)and l_(2)).Notably,we observe a precise control mechanism wherein the force diminishes with|l_(1)+l_(2)|and|l_(1)-l_(2)|,while the torque exhibits enhancement by decreasing solely with|l_(1)+l_(2)|or increasing with|l_(1)-l_(2)|.These results not only provide quantitative insights into the optical trapping performance of TCPBs but also serve as a valuable reference for the ongoing development of innovative photonic tools.

From Knowledge Transfer to Capability Development:The Future of PBL+CBL Teaching Method in Operating Room Nursing Education

Concomitant with the advancement of contemporary medical technology,the significance of perioperative nursing has been increasingly accentuated,necessitating elevated standards for the pedagogy of perioperative nursing.Presently,the PBL(problem-based learning)pedagogical approach,when integrated with CBL(case-based learning),has garnered considerable interest.An extensive literature review has been conducted to analyze the application of the PBL-CBL fusion in the education of perioperative nursing.Findings indicate that this integrative teaching methodology not only enhances students’theoretical knowledge,practical competencies,and collaborative skills but also contributes to the elevation of teaching quality.In conclusion,the PBL-CBL teaching approach holds immense potential for broader application in perioperative nursing education.Nevertheless,it is imperative to continually refine this combined pedagogical strategy to further enhance the caliber of perioperative nursing instruction and to cultivate a greater number of exceptional nursing professionals in the operating room setting.

Model Estimation of Volatilization of Ammonia Appliedwith Surface Film-Forming Material

Greenhouse experiments were conducted to determine the ammonia volatilization loss with or withoutapplication of surface film-forming material (SFFM). Ammonia volatilization loss was estimated by the modeldeveloped by Jayaweera and Mikkelsen. The results showed that the model could estimate and predict wellammonia volatilization loss also in case of SFFM addition. There was an emended factor B introduced tothe model calculation when SFPM was used. Simulated calculation showed that the effect of factor B onNHa loss was obvious. The value of B was governed by SFFM and the environmental conditions. Sensitivityanalysis suggested that pH was the main factor coatrolling NH3 volatilization loss from the floodwater.

A Simulation Study on Effect of Surface Film-Forming Material on Water Evaporation

A greenhouse experiment was conducted to investigate the effect of surface film-forming material (SFFM), a mixture of 16-18-octadecanols by emulsification, on water evaporation. Air-dried soil with distilled water was incubated firstly for 7 days to reestablish soil biological activity and then for another 7 days after treated with SFFM at rates of 0, 1, 2, 4, 6 and 8 g m-2, respectively. Everyday during the 7-day incubation after addition of SFFM, water losses due to evaporation were ~measured by an electronic balance. The rate of water evaporation with the addition of SFFM was reduced significantly compared with the control treatment and the effectiveness of SFFM on water evaporation reduced with time. According to the equation expressions of the effect of SFFM on water evaporation, the half-life of electiveness of SFFM on water evaporation was introduced and calculated to analyze quantitative relationship between the effectiveness of SFFM on water evaporation and the addition rate of SFFM. The calculated half-life increased with the addition rate of SFFM and the confidence of the calculated values of the half-life was high, suggesting that the half-life of effectiveness of SFFM on water evaporation could be described quantitatively and may be helpful for ameliorating application method of SFFM and screening surface-film forming materials in order to improve nitrogen fertilizer use efficiency in flooded rice fields.

Rheological property of low-damage,ideal packing,film-forming amphoteric/sulfonation polymer drilling fluids

Low-permeability dense reservoirs,including micro-fractured reservoirs,are commonly characterized by high content of clay substances,high original water saturation,high sensitivity to invasive fluids,high capillary pressure,complicated structure and anisotropic,high flow-resistance and micro pore throats etc,.Generally they also have lots of natural micro fractures,probably leading to stress sensibility.Main damaging factors in such reservoirs are water-sensibility and water-blocking caused by invasive fluids during drilling and production operations.Once damaged,formation permeability can rarely recovered.Numerous studies have shown that damaging extent of water-blocking ranges from 70% to 90%.Main damaging mechanisms and influencing factors of water-blocking were systematically analyzed.Also some feasible precaution or treating approaches of water-blocking were put forward.In a laboratory setting,a new multi-functional drilling fluid composed mainly of amphion polymer,sulfonation polymer,high effectively preventive water-blocking surfactants,ideal packing temporary bridging agents(TBA) and film-forming agents,etc.,were developed.New low-damage drilling fluids has many advantages,such as good rheological properties,excellent effectiveness of water-blocking prevention,good temporary plugging effect,low filtration and ultra-low permeability(API filtration≤5 mL,HTHP filtration≤10 mL,mud cake frictional coefficient≤0.14,permeability recovery>81%),can efficiently prevent or minimize damage,preserve natural formation and enhance comprehensive development-investment effect in TUHA Jurassic dense sandstone reservoir formation with low-permeability,the only one developing integrated condense gas field.Some references can be provided to similar reservoir formations.

Banana-shaped electron acceptors with an electron-rich core fragment and 3D packing capability

The emergence of Y6-type nonfullerene acceptors has greatly enhanced the power conversion efficiency(PCE)of organic solar cells(OSCs).However,which structural feature is responsible for the excellent photovoltaic performance is still under debate.In this study,two Y6-like acceptors BDOTP-1 and BDOTP-2 were designed.Different from previous Y6-type acceptors featuring an A–D–Aʹ–D–A structure,BDOTP-1,and BDOTP-2 have no electron-deficient Aʹfragment in the core unit.Instead,there is an electron-rich dibenzodioxine fragment in the core.Although this modification leads to a marked change in the molecular dipole moment,electrostatic potential,frontier orbitals,and energy levels,BDOTP acceptors retain similar three-dimensional packing capability as Y6-type acceptors due to the similar banana-shaped molecular configuration.BDOTP acceptors show good performance in OSCs.High PCEs of up to 18.51%(certified 17.9%)are achieved.This study suggests that the banana-shaped configuration instead of the A–D–Aʹ–D–A structure is likely to be the determining factor in realizing high photovoltaic performance.

Investigating the effect of cosolvents on P3HT/O-IDTBR film-forming kinetics and film morphology

The morphology of active layer in bulk heterojunction(BHJ) organic solar cells is decisive to the device performance. Previous works have shown that the solvent engineering is an effective method to optimize the morphology of active layer. However, screening the proper solvent is a tedious task, and we know very little about how to select a proper solvent for a particular system, especially for polymer/nonfullerene blend systems. Here, we combined the spectroscopic analysis in various solvent mixtures during film-forming process to reveal the relationship among the cosolvent characteristics, film-forming kinetics and film morphology. In this article, P3 HT/O-IDTBR blend was selected as model system due to being facile synthesized under a large-scale. Chlorobenzene(CB) was selected as main solvent, and the cosolvents were grouped into three categories according to its boiling point(bp) compared to CB.The cosolvents with lower bp, like chloroform(CF), can facilitate a faster film-forming process, reducing the domain size but sacrificing the crystallinity of both components. For the cosolvents with higher bp,like o-dichlorobenzene(DCB) and 1,2,4-trichlorobenzene(TCB), the self-organization process of P3 HT and O-IDTBR is separated and its duration was extended, constructing highly crystalline nanointerpenetrating network. However, the cosolvents with very high bp, such as chlornaphthalene(CN),would residue in film and keep P3 HT and O-IDTBR self-organizing for longer time, leading to larger phase separation. This work systematically investigated the effect of cosolvent on the film-forming kinetics, and proposed a guideline of how to select a proper cosolvent according to the crystallinity and domain size of active layer.

The Use of an Innovative Film-Forming Wound Dressing in the Treatment of Radiation Dermatitis during Concomitant Chemotherapy

There is currently no consensus regarding the management of acute cutaneous reactions emerging from a concurrent treatment of radio-and chemotherapy, the goal of this case study series is to provide scientific evidence based on clinical practice regarding the efficacy of a film-forming wound dressing for patients receiving combined cancer therapy, in particular examples where the reactions are expected to be intense. In all the described cases, management of acute skin reactions allowed the cancer therapy to be finalized, instead of being interrupted due to an increase in the severity of the reactions. It has been shown in the current literature that the lack of compliance with treatment plans correlates with poorer clinical outcome. Evidence from the cases presented suggest that the studied dressing is safe and efficacious in the treatment and the prevention of acute cutaneous reactions arising from combined cancer therapy.

Challenges in the Development of Film-Forming Additives for Lithium Ion Battery: A Review

Electrolytes additives are ubiquitous and indispensable in all electrochemical devices. In this sense, the principle and the classification of film-forming additives for lithium ion secondary batteries are described. The film formation mechanism and research progress of the pyrazole derivatives, organic halogenide, esters and derivatives, boron compounds and inorganic compounds are introduced. Emphasis is focused on the principles and film-forming mechanisms of each additive. The development of film-forming additives is forecasted and prospected.

Film-Forming Systems in Topically Administered Pharmaceutical Formulations

The skin is the most extensive and outermost organ in the body and can be greatly exploited both from the point of view of alternative routes of systemic drug delivery and treatment of dermatological diseases. Because of its main function as a barrier against harmful external agents, it also becomes a barrier to drug administration, but there are strategies to reduce this limitation of this promising route of administration. The development of polymer-based film-forming formulations is extensively studied for this purpose, since the formation of a film on the skin increases the contact time of the drug, for this being characterized as a controlled release reservoir system. There are a multitude of possible polymers to compose these formulations and their choice must be made according to the purpose of each application. This work, therefore, aims to study the state of the art of film forming systems for topical application of pharmaceutical formulations.

The Research of Polymer Film-Forming Plugging Agent for Drilling Fluid

In order to improve the plugging and anti-collapse performance of water-based drilling fluid,a polymer film-forming plugging agent LWFD is synthesized by emulsion polymerization.The effect of the agent on rheology,API filtration loss,lubricity and film plugging of polymer drilling fluid and cationic drilling fluid is evaluated in laboratory.The experimental results show that the agent has little effect on the rheology and filtration loss of polymer drilling fluid and cationic drilling fluid,and can improve the lubricity of drilling fluid.The synthesized polymer film-forming plugging agent LWFD has good plugging properties for sand discs with different permeabilities,and the agent can effectively improve the film-forming plugging and temperature resistance of drilling fluid when combined with the inorganic nano-plugging agent NMFD.The high performance polymer drilling fluid formed by introducing polymer film-forming plugging agent LWFD and inorganic nano-plugging agent NMFD into polymer drilling fluid has comparable performance as Halliburton’s SHALEDRIL high performance drilling fluid,which can meet the requirements of on-site drilling and has application value.

Experimental study of the temporary plugging capability of diverters to block hydraulic fractures in high-temperature geothermal reservoirs

The effective plugging of artificial fractures is key to the success of temporary plugging and diverting fracturing technology,which is one of the most promising ways to improve the heat recovery efficiency of hot dry rock.At present,how temporary plugging agents plug artificial fractures under high temperature remains unclear.In this paper,by establishing an improved experimental system for the evaluation of temporary plugging performance at high temperature,we clarified the effects of high temperature,injection rate,and fracture width on the pressure response and plugging efficiency of the fracture.The results revealed that the temporary plugging process of artificial fractures in hot dry rock can be divided into four main stages:the initial stage of temporary plugging,the bridging stage of the particles,the plugging formation stage,and the high-pressure dense plugging stage.As the temperature increases,the distribution distance of the temporary plugging agent,the number of pressure fluctuations,and the time required for crack plugging increases.Particularly,when the temperature increases by 100℃,the complete plugging time increases by 90.7%.

Sb-Cu alloy cathode with a novel lithiation mechanism of ternary intermetallic formation: Enabling high energy density and superior rate capability of liquid metal battery

Antimony(Sb) is an attractive cathode for liquid metal batteries(LMBs) because of its high theoretical voltage and low cost.The main obstacles associated with the Sb-based cathodes are unsatisfactory energy density and poor rate-capability.Herein,we propose a novel Sb_(64)Cu_(36)cathode that effectively tackles these issues.The Sb_(64)Cu_(36)(melting point:525℃) cathode presents a novel lithiation mechanism involving sequentially the generation of Li_(2)CuSb,the formation of Li_(3)Sb,and the conversion reaction of Li_(2)CuSb to Li_(3)Sb and Cu.The generated intermetallic compounds show a unique microstructure of the upper floated Li_(2)CuSb layer and the below cross-linked structure with interpenetrated Li_(2)CuSb and Li_(3)Sb phases.Compared with Li_(3)Sb,the lower Li migration energy barrier(0.188 eV) of Li_(2)CuSb significantly facilitates the lithium diffusion across the intermediate compounds and accelerates the reaction kinetics.Consequently,the Li‖Sb_(64)Cu_(36)cell delivers a more excellent electrochemical performance(energy density:353 W h kg^(-1)at 0.4 A cm^(-2);rate capability:0.59 V at 2.0 A cm^(-2)),and a much lower energy storage cost of only 38.45 $ kW h^(-1)than other previously reported Sb-based LMBs.This work provides a novel cathode design concept for the development of high-performance LMBs in applications for large-scale energy storage.

基于情感和认知协同的道德判断方法

随着大语言模型的迅速发展,大语言模型的安全性逐渐引起了研究者和公众的密切关注.为了防止大语言模型在与人类协作中对人类产生伤害,如何确保大语言模型在日常场景中的判断能与人类道德观念相符成为了一个重要问题.其中一个关键的挑战是,如何确保大语言模型在道德判断方面,能够像人类那样,针对不同的情境,灵活地调整或重新考虑预定的规则,从而使其判断与人类的道德观念保持一致.受心理学和认知科学中关于人类道德判断的情感和认知影响因素研究的启发,结合大语言模型在认知推理和情感分析能力上的优势,设计了一种模仿人类道德判断过程中情感判断和认知判断能力交互的方法,从而提升了大语言模型的道德判断表现.实验结果证明了所提方法在该任务上的有效性.总的来说,不仅为大语言模型的道德判断提供了一种创新的方法,也强调了心理学与认知科学理论在此领域的重要性,为未来的进一步研究奠定基础.

考虑碳流约束的电力系统能碳安全域模型与计算方法

针对当前电力系统碳减排任务与安全稳定运行需求,研究电力系统低碳安全运行技术。现有的能量流安全域模型使电力系统安全监视与控制更加科学有效,但忽略了系统运行过程中可能存在的“高碳”风险。文中提出了一种考虑碳流约束的电力系统能碳耦合安全域(简称能碳安全域)模型与计算方法,旨在保证系统安全性的同时减排提效。为完整刻画电力系统的低碳运行能力极限,分别从负荷端和源端角度提出了考虑碳流约束的系统最大供电能力曲线及最大消纳能力曲线模型。基于系统最大供电能力工作点,提出了能碳安全边界仿真拟合计算方法,实现了能碳安全域的降维观测。最后,结合算例验证了所提模型的有效性。

企业数字化能力影响因素分析——以广东省制造业为例

制造业是我国国民经济的重要组成部分,随着新一代信息技术和数字技术的迅猛发展,民众日益增长的智能化需求和数字化市场趋势推动着企业不断探索和构建自身的数字化能力来实现数字化转型,进而获取持续的竞争优势。本文基于动态能力理论和TOE分析框架,以广东省制造业为例,设计了企业数字化能力的研究模型,并提出假设,在对模型和假设的不同影响路径进行实证检验和修正后,分析了组织结构、高层管理者和数字技术能力对广东省制造企业数字化能力构建的作用机理。

数字化转型与企业国际化绩效研究——基于供应链能力的中介作用

本文借助Python爬虫技术刻画上市公司数字化转型强度,利用2012—2021年A股上市公司和国泰安数据库相关匹配数据,从理论和实证两个方面探讨数字化转型对企业国际化绩效的影响及其作用机理。研究结果表明,数字化转型对企业国际化绩效具有显著的促进作用且通过一系列内生性和稳健性检验,供应链能力在其中发挥了中介效应。进一步分析发现,数字化转型对企业国际化绩效的提升效果在非国有企业、技术和资本密集型行业、发达国家或地区更明显。这一结论对促进企业实现数字化转型、提升国际化绩效、增强国际竞争力具有重要的现实意义。

计及灾后恢复全过程储能应急响应能力的配电网韧性规划

储能因响应快、灵活性高的特点,已成为可再生能源发展必不可少的支撑技术,不仅具有削峰填谷、改善电能质量的作用,在灾后恢复过程中的应急响应能力同样不可忽视。提出了一种计及灾后恢复全过程储能应急响应能力的配电网韧性规划方法,构建了同时考虑网架增强和储能配置策略的配电网韧性增强双层规划模型,系统地刻画了极端灾害发生后配电网网架重构、设备抢修及复电等灾后恢复全过程的源-网-荷-储互动模式场景。最后,通过IEEE33节点系统的算例分析表明,所提方法能更充分地挖掘储能的应急响应潜力,有效提高增强性规划决策的精准度,获得更佳的投资回报。