The transformation behavior and microstructure development in the heat affected zone(HAZ)of 800MPa grade ultra fine structured steel was investigated.It was found that the HAZ has intermediate temperature transformati...The transformation behavior and microstructure development in the heat affected zone(HAZ)of 800MPa grade ultra fine structured steel was investigated.It was found that the HAZ has intermediate temperature transformation characteristics in a wide range of cooling rates,with the bainite sheaves consisting of bainite ferrite plates without carbide precipitation and retained austenite in the fast cooling regime.At relatively high cooling rates,which corresponded to low heat inputs,the hardness of the simulated HAZ was above that of the base metal.When the cooling rate was below 9C/s,the welding HAZ would have an obvious softening.The analysis of transformation rates in continuous cooling processes was completed by numerical differential method.The result indicated that the microstructure transformation rate of the HAZ in 800MPa grade ultra fine structured steel changed sharply to slow speeds when the cooling time t8/5 is longer than 7s.展开更多
The transmission electron microscopy has been used to investigate the fine structure variation of 18R martensite under deformation in a polycrvstalline CuZnAl shape memory alloys.It has been found that the strain is g...The transmission electron microscopy has been used to investigate the fine structure variation of 18R martensite under deformation in a polycrvstalline CuZnAl shape memory alloys.It has been found that the strain is gabined by the reorientation of martensite variants in the ini- tial deformation stage.In addition to the result of optical microscopy studies,however,the reorientation is often incomplete and the interfaces among the prior variants still remain.A lot of twins will appear in martensite under enormous deformation,and the twin plane is(001) phane of martensite lattice.The dislocations has also been observed in some regions.In this case,the martensite will lose its thermoelasticitv and the shape memory effect will be damaged.展开更多
Under normal forging and annealing conditions, there are different ultra fine carbides (M3C, M23C6, M7Cj, M6C and MC) in high carbon alloy steels when alloy composition design is carried out properly. On the basis of ...Under normal forging and annealing conditions, there are different ultra fine carbides (M3C, M23C6, M7Cj, M6C and MC) in high carbon alloy steels when alloy composition design is carried out properly. On the basis of carbides transformation orderliness, the alloy composition design of the high carbon alloy steels is conducted by phase-equilibrium thermodynamic calculation for Fe-Cr-W-Mo-V-C system. The nucleation and growth of new carbides, dissolution of previous partial carbides in these steels during annealing process, all these lead to ultra-fine distribution of carbides. Due to different crystal structures of carbides and different thermodynamics as well dynamics parameters of the carbides dissolution and precipitation, the range of quenching temperature of these steels is widened, and the good temper-resistance is obtained. The characteristics of heat treatment process and microstructure variance, and the carbides transformation for different temperature are explained by the phase-equilibrium component satisfactorily. Their bend and yield strength, flexibility and toughness all are advanced markedly comparing with that of kindred steels. Results of the applications have proved that the microstructure of ultra-fine carbides in these steels played importance roles in the enhancement of edginess and fatigue crack resistance of the die and knives.展开更多
In biological systems, conformational transformations of nucleic acids play critical roles in genetic regulation. However, it remains a tricky task to design and optimize specific labeling strategies to track these ch...In biological systems, conformational transformations of nucleic acids play critical roles in genetic regulation. However, it remains a tricky task to design and optimize specific labeling strategies to track these changes.In this study, we exploited an intercalating fluorescent dye,GelRed, to characterize different DNA structures. We studied the correlation between fluorescence intensity and DNA structural properties. We showed that single-stranded DNAs with predicted self-folded secondary structures show much stronger fluorescence than those without such structures. For double-stranded DNAs, we observed that fluorescence intensity is positively correlated to their GCcontent. We also demonstrated that GelRed can be used to monitor DNA conformational changes upon temperature variations in real time. Based on these findings, we concluded that the fluorescence intensity of a GelRed-stained DNA structure has a good correlation with its thermostability in the form of a change in Gibbs free energy.展开更多
A CR-structure on a 2n +1-manifold gives a conformal class of Lorentz metrics on the Fefferman S1-bundle. This analogy is carried out to the quarternionic conformal 3-CR structure (a generalization of quaternionic CR-...A CR-structure on a 2n +1-manifold gives a conformal class of Lorentz metrics on the Fefferman S1-bundle. This analogy is carried out to the quarternionic conformal 3-CR structure (a generalization of quaternionic CR- structure) on a 4n + 3 -manifold M. This structure produces a conformal class [g] of a pseudo-Riemannian metric g of type (4n + 3,3) on M × S3. Let (PSp(n +1,1), S4n+3) be the geometric model obtained from the projective boundary of the complete simply connected quaternionic hyperbolic manifold. We shall prove that M is locally modeled on (PSp(n +1,1), S4n+3) if and only if (M × S3 ,[g]) is conformally flat (i.e. the Weyl conformal curvature tensor vanishes).展开更多
Effect of multiple direct and reverse martensitic transformations on fragmentation of austenitic grains in Fe-Ni alloys have been studied by X-ray diffraction and scanning electron microscopy. An ultra-fine structure ...Effect of multiple direct and reverse martensitic transformations on fragmentation of austenitic grains in Fe-Ni alloys have been studied by X-ray diffraction and scanning electron microscopy. An ultra-fine structure was formed by fragmentation inside austenitic grains due to progressing misorientation of austenitic sub-grains during multiple γ-α-γ-martensitic phase transitions. An increase in the number of γ-α-γ-transformations increases misorientation angle between austenitic sub-grains and leads to transformation of an austenitic single crystal into a textured polycrystal. It has been shown that multiple γ-α-γ-martensitic phase transitions change the mechanism of internal stress relaxation from dislocation-based to deformation twinning.展开更多
文摘The transformation behavior and microstructure development in the heat affected zone(HAZ)of 800MPa grade ultra fine structured steel was investigated.It was found that the HAZ has intermediate temperature transformation characteristics in a wide range of cooling rates,with the bainite sheaves consisting of bainite ferrite plates without carbide precipitation and retained austenite in the fast cooling regime.At relatively high cooling rates,which corresponded to low heat inputs,the hardness of the simulated HAZ was above that of the base metal.When the cooling rate was below 9C/s,the welding HAZ would have an obvious softening.The analysis of transformation rates in continuous cooling processes was completed by numerical differential method.The result indicated that the microstructure transformation rate of the HAZ in 800MPa grade ultra fine structured steel changed sharply to slow speeds when the cooling time t8/5 is longer than 7s.
文摘The transmission electron microscopy has been used to investigate the fine structure variation of 18R martensite under deformation in a polycrvstalline CuZnAl shape memory alloys.It has been found that the strain is gabined by the reorientation of martensite variants in the ini- tial deformation stage.In addition to the result of optical microscopy studies,however,the reorientation is often incomplete and the interfaces among the prior variants still remain.A lot of twins will appear in martensite under enormous deformation,and the twin plane is(001) phane of martensite lattice.The dislocations has also been observed in some regions.In this case,the martensite will lose its thermoelasticitv and the shape memory effect will be damaged.
文摘Under normal forging and annealing conditions, there are different ultra fine carbides (M3C, M23C6, M7Cj, M6C and MC) in high carbon alloy steels when alloy composition design is carried out properly. On the basis of carbides transformation orderliness, the alloy composition design of the high carbon alloy steels is conducted by phase-equilibrium thermodynamic calculation for Fe-Cr-W-Mo-V-C system. The nucleation and growth of new carbides, dissolution of previous partial carbides in these steels during annealing process, all these lead to ultra-fine distribution of carbides. Due to different crystal structures of carbides and different thermodynamics as well dynamics parameters of the carbides dissolution and precipitation, the range of quenching temperature of these steels is widened, and the good temper-resistance is obtained. The characteristics of heat treatment process and microstructure variance, and the carbides transformation for different temperature are explained by the phase-equilibrium component satisfactorily. Their bend and yield strength, flexibility and toughness all are advanced markedly comparing with that of kindred steels. Results of the applications have proved that the microstructure of ultra-fine carbides in these steels played importance roles in the enhancement of edginess and fatigue crack resistance of the die and knives.
基金supported by the National Natural Science Foundation of China(Nos.U1532119,21775157,21675167,and 31571014)the Instrument Developing Project of the Chinese Academy of Sciences(Develop the Microsystems for Single Particle Tracking)
文摘In biological systems, conformational transformations of nucleic acids play critical roles in genetic regulation. However, it remains a tricky task to design and optimize specific labeling strategies to track these changes.In this study, we exploited an intercalating fluorescent dye,GelRed, to characterize different DNA structures. We studied the correlation between fluorescence intensity and DNA structural properties. We showed that single-stranded DNAs with predicted self-folded secondary structures show much stronger fluorescence than those without such structures. For double-stranded DNAs, we observed that fluorescence intensity is positively correlated to their GCcontent. We also demonstrated that GelRed can be used to monitor DNA conformational changes upon temperature variations in real time. Based on these findings, we concluded that the fluorescence intensity of a GelRed-stained DNA structure has a good correlation with its thermostability in the form of a change in Gibbs free energy.
文摘A CR-structure on a 2n +1-manifold gives a conformal class of Lorentz metrics on the Fefferman S1-bundle. This analogy is carried out to the quarternionic conformal 3-CR structure (a generalization of quaternionic CR- structure) on a 4n + 3 -manifold M. This structure produces a conformal class [g] of a pseudo-Riemannian metric g of type (4n + 3,3) on M × S3. Let (PSp(n +1,1), S4n+3) be the geometric model obtained from the projective boundary of the complete simply connected quaternionic hyperbolic manifold. We shall prove that M is locally modeled on (PSp(n +1,1), S4n+3) if and only if (M × S3 ,[g]) is conformally flat (i.e. the Weyl conformal curvature tensor vanishes).
文摘Effect of multiple direct and reverse martensitic transformations on fragmentation of austenitic grains in Fe-Ni alloys have been studied by X-ray diffraction and scanning electron microscopy. An ultra-fine structure was formed by fragmentation inside austenitic grains due to progressing misorientation of austenitic sub-grains during multiple γ-α-γ-martensitic phase transitions. An increase in the number of γ-α-γ-transformations increases misorientation angle between austenitic sub-grains and leads to transformation of an austenitic single crystal into a textured polycrystal. It has been shown that multiple γ-α-γ-martensitic phase transitions change the mechanism of internal stress relaxation from dislocation-based to deformation twinning.
